BR8506004A - Processo para remover teores em cobalto de produto de uma reacao de hidroformilacao catalisado com cobalto,processo para formar uma mistura de produto e processo para produzir aldeidos superiores e alcoois superiores - Google Patents
Processo para remover teores em cobalto de produto de uma reacao de hidroformilacao catalisado com cobalto,processo para formar uma mistura de produto e processo para produzir aldeidos superiores e alcoois superioresInfo
- Publication number
- BR8506004A BR8506004A BR8506004A BR8506004A BR8506004A BR 8506004 A BR8506004 A BR 8506004A BR 8506004 A BR8506004 A BR 8506004A BR 8506004 A BR8506004 A BR 8506004A BR 8506004 A BR8506004 A BR 8506004A
- Authority
- BR
- Brazil
- Prior art keywords
- cobalt
- product
- hydroformillation
- reaction catalyst
- aldehyde
- Prior art date
Links
- 229910017052 cobalt Inorganic materials 0.000 title 2
- 239000010941 cobalt Substances 0.000 title 2
- GUTLYIVDDKVIGB-UHFFFAOYSA-N cobalt atom Chemical compound [Co] GUTLYIVDDKVIGB-UHFFFAOYSA-N 0.000 title 2
- 150000001298 alcohols Chemical class 0.000 title 1
- 150000001299 aldehydes Chemical class 0.000 title 1
- 239000007809 chemical reaction catalyst Substances 0.000 title 1
- 239000000203 mixture Substances 0.000 title 1
Classifications
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
- B01J31/16—Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes
- B01J31/20—Carbonyls
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
- B01J31/40—Regeneration or reactivation
- B01J31/4015—Regeneration or reactivation of catalysts containing metals
- B01J31/4023—Regeneration or reactivation of catalysts containing metals containing iron group metals, noble metals or copper
- B01J31/403—Regeneration or reactivation of catalysts containing metals containing iron group metals, noble metals or copper containing iron group metals or copper
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
- B01J31/40—Regeneration or reactivation
- B01J31/4015—Regeneration or reactivation of catalysts containing metals
- B01J31/4092—Regeneration or reactivation of catalysts containing metals involving a stripping step, with stripping gas or solvent
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C29/00—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring
- C07C29/16—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring by oxo-reaction combined with reduction
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C45/00—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds
- C07C45/49—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds by reaction with carbon monoxide
- C07C45/50—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds by reaction with carbon monoxide by oxo-reactions
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C45/00—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds
- C07C45/78—Separation; Purification; Stabilisation; Use of additives
- C07C45/783—Separation; Purification; Stabilisation; Use of additives by gas-liquid treatment, e.g. by gas-liquid absorption
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C45/00—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds
- C07C45/78—Separation; Purification; Stabilisation; Use of additives
- C07C45/80—Separation; Purification; Stabilisation; Use of additives by liquid-liquid treatment
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J2231/00—Catalytic reactions performed with catalysts classified in B01J31/00
- B01J2231/30—Addition reactions at carbon centres, i.e. to either C-C or C-X multiple bonds
- B01J2231/32—Addition reactions to C=C or C-C triple bonds
- B01J2231/321—Hydroformylation, metalformylation, carbonylation or hydroaminomethylation
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J2531/00—Additional information regarding catalytic systems classified in B01J31/00
- B01J2531/02—Compositional aspects of complexes used, e.g. polynuclearity
- B01J2531/0202—Polynuclearity
- B01J2531/0205—Bi- or polynuclear complexes, i.e. comprising two or more metal coordination centres, without metal-metal bonds, e.g. Cp(Lx)Zr-imidazole-Zr(Lx)Cp
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J2531/00—Additional information regarding catalytic systems classified in B01J31/00
- B01J2531/80—Complexes comprising metals of Group VIII as the central metal
- B01J2531/84—Metals of the iron group
- B01J2531/845—Cobalt
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
- B01J31/02—Catalysts comprising hydrides, coordination complexes or organic compounds containing organic compounds or metal hydrides
- B01J31/04—Catalysts comprising hydrides, coordination complexes or organic compounds containing organic compounds or metal hydrides containing carboxylic acids or their salts
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02P—CLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
- Y02P20/00—Technologies relating to chemical industry
- Y02P20/50—Improvements relating to the production of bulk chemicals
- Y02P20/584—Recycling of catalysts
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
- Inorganic Chemistry (AREA)
- Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
Applications Claiming Priority (2)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| GB848430225A GB8430225D0 (en) | 1984-11-30 | 1984-11-30 | Hydroformylation catalyst removal |
| CN86103921A CN1006790B (zh) | 1984-11-30 | 1986-06-03 | 醛化反应催化剂的去除 |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| BR8506004A true BR8506004A (pt) | 1986-08-19 |
Family
ID=25742220
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| BR8506004A BR8506004A (pt) | 1984-11-30 | 1985-11-29 | Processo para remover teores em cobalto de produto de uma reacao de hidroformilacao catalisado com cobalto,processo para formar uma mistura de produto e processo para produzir aldeidos superiores e alcoois superiores |
Country Status (13)
| Country | Link |
|---|---|
| US (1) | US4625067A (pt) |
| EP (1) | EP0183546B1 (pt) |
| JP (1) | JPH0638921B2 (pt) |
| CN (1) | CN1006790B (pt) |
| AR (1) | AR241107A1 (pt) |
| AT (1) | ATE57908T1 (pt) |
| AU (1) | AU591491B2 (pt) |
| BR (1) | BR8506004A (pt) |
| CA (1) | CA1290350C (pt) |
| DE (1) | DE3580339D1 (pt) |
| GB (1) | GB8430225D0 (pt) |
| GR (1) | GR852831B (pt) |
| SG (1) | SG65292G (pt) |
Families Citing this family (28)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| GB8430226D0 (en) * | 1984-11-30 | 1985-01-09 | Exxon Research Engineering Co | Hydroformylation of olefins |
| GB8907577D0 (en) * | 1989-04-04 | 1989-05-17 | Exxon Chemical Patents Inc | Catalyst recovery in the production of alcohols |
| US4970472A (en) * | 1989-09-01 | 1990-11-13 | Delco Electronics Corporation | Compensated phase locked loop circuit |
| US5215667A (en) * | 1991-08-20 | 1993-06-01 | Exxon Chemical Patents Inc. | Method for separating water soluble noble metal catalyst from a noble metal catalyzed hydroformylation reaction |
| US5288818A (en) * | 1991-08-20 | 1994-02-22 | Exxon Chemical Patents Inc. | Method for separating a water soluble noble metal catalyst from a noble metal catalyzed hydroformylation reaction |
| US5235112A (en) * | 1992-05-29 | 1993-08-10 | Exxon Chemical Patents Inc. | Stripper-reactor for volatile cobalt recovery |
| US5237104A (en) * | 1992-05-29 | 1993-08-17 | Exxon Chemical Patents Inc. | Cobalt catalyst recovery using heavy olefin absorbent |
| CA2135885C (en) * | 1992-05-29 | 2002-10-08 | Jan M. De Rijke | Catalyst regeneration |
| US5237105A (en) * | 1992-05-29 | 1993-08-17 | Exxon Chemical Patents Inc. | Method for removing hydroformylation catalyst |
| GB9211880D0 (en) * | 1992-06-04 | 1992-07-15 | Exxon Chemical Patents Inc | Method and apparatus for the recovery of metal catalysts |
| US5300617A (en) * | 1993-01-21 | 1994-04-05 | Exxon Chemical Patents Inc. | Potassium para-diphenyl phosphino benzene sulfonate ligand |
| US5354908A (en) * | 1993-07-16 | 1994-10-11 | Exxon Chemical Patents Inc. | Method and system for cobalt absorption in a hydroformylation process |
| US5457240A (en) * | 1994-01-10 | 1995-10-10 | Exxon Chemical Patents, Inc. | Use of stripper reactor reflux as an initiator for preforming reaction of cobaltous salts to cobalt carbonyls |
| US5434318A (en) * | 1994-03-23 | 1995-07-18 | Exxon Chemical Patents Inc. | Reactivation or regeneration of cobalt preformer catalyst for oxo process |
| US5410090A (en) * | 1994-04-08 | 1995-04-25 | Exxon Chemical Patents Inc. | Airless cobalt demetalling in the cobalt flash combination catalyst cycle |
| US5406006A (en) * | 1994-05-24 | 1995-04-11 | Exxon Chemical Patents Inc | Method for preparing a preformer catalyst via in-situ activation |
| EP0927203B1 (de) * | 1996-09-20 | 2001-06-13 | Basf Aktiengesellschaft | Verfahren zur hydroformylierung |
| DE10045056A1 (de) * | 2000-09-12 | 2002-03-21 | Basf Ag | Verfahren zur kontinuierlichen Hydroformylierung von Polyalkenen mit 30 bis 700 Kohlenstoffatomen |
| WO2003082788A1 (en) * | 2002-03-29 | 2003-10-09 | Exxonmobil Chemical Patents Inc. | Improved cobalt flash process |
| US7081554B2 (en) * | 2002-03-29 | 2006-07-25 | Exxonmobil Chemical Patent Inc. | Oxo process |
| TW200642745A (en) * | 2005-02-03 | 2006-12-16 | Shell Int Research | Process for inhibiting deposition of solids from a gaseous stream |
| TW200630156A (en) * | 2005-02-03 | 2006-09-01 | Shell Int Research | Treatment of an aqueous mixture containing an alkylene oxide with an ion exchange resin |
| TW200732292A (en) * | 2006-02-01 | 2007-09-01 | Shell Int Research | A method of treating an aldehyde mixture, use of the treated aldehyde, and an alcohol |
| US8247618B2 (en) * | 2007-04-18 | 2012-08-21 | Exxonmobil Chemical Patents Inc. | Oxidative demetalling |
| DE102008007080A1 (de) | 2008-01-31 | 2009-08-06 | Evonik Oxeno Gmbh | Verfahren zur Herstellung von C9-Alkohol aus C8-Olefinen |
| CN102137834B (zh) * | 2008-08-29 | 2013-09-25 | 埃克森美孚化学专利公司 | 烯烃加氢甲酰化中的废气净化 |
| EP2321245B1 (en) * | 2008-08-29 | 2016-04-13 | ExxonMobil Chemical Patents Inc. | Hydroformylation process including catalyst recycle |
| US20230159424A1 (en) | 2020-04-01 | 2023-05-25 | Exxonmobil Chemical Patents Inc. | Hydroformylation Catalysts Comprising Fluorophosphine Ligands and Precursors Thereof |
Family Cites Families (18)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US2595096A (en) * | 1948-05-20 | 1952-04-29 | Standard Oil Dev Co | Synthesis of alcohol from olefins, carbon monoxide, and hydrogen |
| GB667824A (en) * | 1949-04-01 | 1952-03-05 | Bataafsche Petroleum | Decomposition of metal compounds dissolved in oxygencontaining organic products |
| US2779796A (en) * | 1950-11-02 | 1957-01-29 | Du Pont | Decobalting of oxo products with live steam |
| GB690977A (en) * | 1951-03-29 | 1953-04-29 | Standard Oil Dev Co | Improvements in or relating to oxo synthesis |
| GB702950A (en) * | 1951-04-27 | 1954-01-27 | Standard Oil Dev Co | Improvements in or relating to oxo alcohol synthesis |
| US2757204A (en) * | 1951-04-27 | 1956-07-31 | Exxon Research Engineering Co | Acid decobalting of oxo products |
| GB742879A (en) * | 1952-04-20 | 1956-01-04 | Exxon Research Engineering Co | Improvements in or relating to the oxo synthesis process |
| US2779794A (en) * | 1952-07-31 | 1957-01-29 | Exxon Research Engineering Co | Carbonylation of olefins; water decobalting |
| US2757203A (en) * | 1955-04-15 | 1956-07-31 | Exxon Research Engineering Co | Synthesis of alcoiiol and aldehyde from olefins, carbon monoxide and hydrogen |
| US2905716A (en) * | 1956-07-17 | 1959-09-22 | Ruhrchemie Ag | Purification of oxo aldehydes |
| US3092670A (en) * | 1957-08-16 | 1963-06-04 | Gulf Research Development Co | Oxo process for the production of alcohols |
| GB893524A (en) * | 1958-08-22 | 1962-04-11 | Magyar Asvanyolaj Es Foeldgaz | Method of removing dissolved cobalt compounds from the products of cobalt-catalysed reactions |
| NL271606A (pt) * | 1960-11-21 | 1900-01-01 | ||
| US3868422A (en) * | 1971-12-23 | 1975-02-25 | Eastman Kodak Co | Multistage hydroformylation process |
| US4061687A (en) * | 1971-12-30 | 1977-12-06 | Chemische Werke Huls Aktiengesellschaft | Oxo process with recovery of cobalt hydrocarbonyl in solution for recycle |
| US4255279A (en) * | 1979-07-20 | 1981-03-10 | Exxon Research & Engineering Co. | Dual demetalling of oxo products with catalyst recycle |
| GB8430223D0 (en) * | 1984-11-30 | 1985-01-09 | Exxon Research Engineering Co | Hydroformylation of olefins |
| GB8430226D0 (en) * | 1984-11-30 | 1985-01-09 | Exxon Research Engineering Co | Hydroformylation of olefins |
-
1984
- 1984-11-30 GB GB848430225A patent/GB8430225D0/en active Pending
-
1985
- 1985-11-25 GR GR852831A patent/GR852831B/el unknown
- 1985-11-27 EP EP85308638A patent/EP0183546B1/en not_active Expired - Lifetime
- 1985-11-27 AT AT85308638T patent/ATE57908T1/de not_active IP Right Cessation
- 1985-11-27 US US06/803,087 patent/US4625067A/en not_active Expired - Lifetime
- 1985-11-27 DE DE8585308638T patent/DE3580339D1/de not_active Expired - Lifetime
- 1985-11-29 AR AR302442A patent/AR241107A1/es active
- 1985-11-29 BR BR8506004A patent/BR8506004A/pt not_active IP Right Cessation
- 1985-11-29 CA CA000496531A patent/CA1290350C/en not_active Expired - Lifetime
- 1985-11-29 JP JP60269242A patent/JPH0638921B2/ja not_active Expired - Lifetime
-
1986
- 1986-05-21 AU AU57635/86A patent/AU591491B2/en not_active Ceased
- 1986-06-03 CN CN86103921A patent/CN1006790B/zh not_active Expired
-
1992
- 1992-06-30 SG SG652/92A patent/SG65292G/en unknown
Also Published As
| Publication number | Publication date |
|---|---|
| EP0183546B1 (en) | 1990-10-31 |
| JPH0638921B2 (ja) | 1994-05-25 |
| EP0183546A1 (en) | 1986-06-04 |
| DE3580339D1 (de) | 1990-12-06 |
| JPS61192348A (ja) | 1986-08-26 |
| AR241107A1 (es) | 1991-11-15 |
| SG65292G (en) | 1992-12-04 |
| AU5763586A (en) | 1987-11-26 |
| GB8430225D0 (en) | 1985-01-09 |
| ATE57908T1 (de) | 1990-11-15 |
| AR241107A2 (es) | 1991-11-15 |
| CA1290350C (en) | 1991-10-08 |
| CN86103921A (zh) | 1987-12-16 |
| US4625067A (en) | 1986-11-25 |
| AU591491B2 (en) | 1989-12-07 |
| GR852831B (pt) | 1986-03-27 |
| CN1006790B (zh) | 1990-02-14 |
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Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| B21A | Patent or certificate of addition expired [chapter 21.1 patent gazette] |
Free format text: PATENTE EXTINTA EM 29/11/2000 |