BR6906260D0 - PROCESS TO PRODUCE HYDRODIMERS OF OLEFINIC COMPOUNDS - Google Patents

PROCESS TO PRODUCE HYDRODIMERS OF OLEFINIC COMPOUNDS

Info

Publication number
BR6906260D0
BR6906260D0 BR206260/69A BR20626069A BR6906260D0 BR 6906260 D0 BR6906260 D0 BR 6906260D0 BR 206260/69 A BR206260/69 A BR 206260/69A BR 20626069 A BR20626069 A BR 20626069A BR 6906260 D0 BR6906260 D0 BR 6906260D0
Authority
BR
Brazil
Prior art keywords
catholyte
copolymer
feb
hydrodimers
aromatic
Prior art date
Application number
BR206260/69A
Other languages
Portuguese (pt)
Inventor
R Johnson
R Jones
Original Assignee
Monsanto Co
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Monsanto Co filed Critical Monsanto Co
Publication of BR6906260D0 publication Critical patent/BR6906260D0/en

Links

Classifications

    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08JWORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
    • C08J5/00Manufacture of articles or shaped materials containing macromolecular substances
    • C08J5/20Manufacture of shaped structures of ion-exchange resins
    • C08J5/22Films, membranes or diaphragms
    • C08J5/2206Films, membranes or diaphragms based on organic and/or inorganic macromolecular compounds
    • C08J5/2275Heterogeneous membranes
    • CCHEMISTRY; METALLURGY
    • C25ELECTROLYTIC OR ELECTROPHORETIC PROCESSES; APPARATUS THEREFOR
    • C25BELECTROLYTIC OR ELECTROPHORETIC PROCESSES FOR THE PRODUCTION OF COMPOUNDS OR NON-METALS; APPARATUS THEREFOR
    • C25B3/00Electrolytic production of organic compounds
    • C25B3/20Processes
    • C25B3/29Coupling reactions
    • C25B3/295Coupling reactions hydrodimerisation
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08JWORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
    • C08J2309/00Characterised by the use of homopolymers or copolymers of conjugated diene hydrocarbons
    • C08J2309/02Copolymers with acrylonitrile
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08JWORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
    • C08J2325/00Characterised by the use of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by an aromatic carbocyclic ring; Derivatives of such polymers
    • C08J2325/02Homopolymers or copolymers of hydrocarbons
    • C08J2325/04Homopolymers or copolymers of styrene

Abstract

1,257,215. Electrohydrodimerization process. MONSANTO CO. 5 Feb., 1969 [9 Feb., 1968], No. 6223/69. Heading C2C. [Also in Division C7] Hydrodimers of olefinic compounds are produced by passing electric current through an aqueous olefinic nitrile-, ester- and/or carboxamide-containing catholyte separated from an aqueous acidic, e.g. H 2 SO 4 anolyte by a solid cation-permeable membrane of a conductive polymeric matrix reinforced by at least two parallel sheets of woven glass fabric embedded therein. Preferably, the matrix comprises a copolymer of a polyvinyl aromatic (e.g. divinyl benzene, naphthalene, diphenyl or alkyl-substituted derivative thereof) compound and a monovinyl aromatic (e.g. vinyl naphthalene or alkyl-substituted derivative thereof) compound having sulphonic groups bonded to the aromatic nuclei of the copolymer. The catholyte may contain a quaternary ammonium or amine alkylsulphate or sulphonate. The electrodes may be of Pb or alloy thereof. For example, acrylonitrile may be continuously hydrodimerized to adiponitrile in a series of cells using tetraethylammonium ethylsulphate as the electrolytic salt in the catholyte and sulphonated divinylbenzene-styrene copolymer as polymeric matrix for the cation-permeable membrane.
BR206260/69A 1968-02-09 1969-02-10 PROCESS TO PRODUCE HYDRODIMERS OF OLEFINIC COMPOUNDS BR6906260D0 (en)

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
US70427968A 1968-02-09 1968-02-09

Publications (1)

Publication Number Publication Date
BR6906260D0 true BR6906260D0 (en) 1973-01-09

Family

ID=24828816

Family Applications (1)

Application Number Title Priority Date Filing Date
BR206260/69A BR6906260D0 (en) 1968-02-09 1969-02-10 PROCESS TO PRODUCE HYDRODIMERS OF OLEFINIC COMPOUNDS

Country Status (13)

Country Link
US (1) US3616319A (en)
JP (1) JPS541687B1 (en)
AT (1) AT287670B (en)
BE (1) BE728204A (en)
BR (1) BR6906260D0 (en)
CA (1) CA920532A (en)
CH (1) CH509985A (en)
DE (1) DE1906545A1 (en)
FR (1) FR2001648A1 (en)
GB (1) GB1257215A (en)
IL (1) IL31582A0 (en)
LU (1) LU57935A1 (en)
NL (1) NL6902080A (en)

Families Citing this family (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US3976549A (en) * 1973-02-26 1976-08-24 Hooker Chemicals & Plastics Corporation Electrolysis method
US4164463A (en) * 1975-05-20 1979-08-14 E. I. Du Pont De Nemours And Company Hydrophilic fluoropolymers
JPS5626554A (en) * 1979-08-10 1981-03-14 Asahi Chem Ind Co Ltd Improved cation exchange membrane
US4391663A (en) * 1980-12-05 1983-07-05 Hutter Iii Charles G Method of curing adhesive
US5523181A (en) * 1992-09-25 1996-06-04 Masahiro Watanabe Polymer solid-electrolyte composition and electrochemical cell using the composition
FI20095084A0 (en) * 2009-01-30 2009-01-30 Pekka Vallittu Composite and its use

Also Published As

Publication number Publication date
LU57935A1 (en) 1969-09-17
GB1257215A (en) 1971-12-15
FR2001648A1 (en) 1969-09-26
JPS541687B1 (en) 1979-01-27
AT287670B (en) 1971-02-10
IL31582A0 (en) 1969-04-30
DE1906545B2 (en) 1974-04-04
DE1906545A1 (en) 1969-08-28
US3616319A (en) 1971-10-26
BE728204A (en) 1969-08-11
NL6902080A (en) 1969-08-12
CA920532A (en) 1973-02-06
CH509985A (en) 1971-07-15
DE1906545C3 (en) 1974-10-31

Similar Documents

Publication Publication Date Title
BR7606050A (en) CATHOD, PROCESS FOR ITS PRODUCTION, AND CELL PERFORMANCE FOR HALO-ALKALI ELECTROLYSIS AND WATER ELECTROLYZER
JPS52145397A (en) Electrolysis
KR930016433A (en) Process for preparing α-glycosyl-L-ascorbic acid high content and separation system for the preparation thereof
UA26465C2 (en) ELECTROCHEMICAL DEVICE FOR ACCUMULATION AND ENERGY SUPPLY
DE59104734D1 (en) Process for the electrochemical splitting of alkali sulfates.
BR6906260D0 (en) PROCESS TO PRODUCE HYDRODIMERS OF OLEFINIC COMPOUNDS
US3402115A (en) Preparation of quaternary ammonium hydroxides by electrodialysis
DE2821982A1 (en) PARTITION WALL WITH A MEMBRANE FOR ELECTROLYSIS CELLS ARRANGED LIKE A FILTER PRESS
JPS527390A (en) High normality ion exchange materials and its manufacture
DE1468306B2 (en) Process for the production of adipic acid dinitrile by electrolytic hydrodimerizates of acrylonitrile
EP0339341A3 (en) Electrically conducting polyheteroaromatics, and process for their preparation
GB1547534A (en) Method of characteristic of cation-exchange membrane
JPS504352B1 (en)
IT1003398B (en) SODIUM-SULFUR ELEMENT HAVING ANODIC AND CATHODIC PARTITION SEPA RATI FROM A SOLID ELECTROLYTE WITH SODIUM ION DUCTOR
IE76465B1 (en) Method for separating organic substances
DE2621590C3 (en) Electrolysis and electrodialysis method for an aqueous solution of a base
DE967953C (en) Process for the discontinuous desalting of solutions in an electrodialysis cell with selective membranes
IT8821004A0 (en) ELECTRICALLY CONDUCTIVE WATER-IN-OIL MICROEMULSIONS BASED ON PERFLUORINATED COMPOUNDS USED AS CATHOLYTE IN ELECTROCHEMICAL PROCESSES.
DE1811114A1 (en) Desalination of seawater
GB1066377A (en) Electro-dialytic method for separating and enriching isotopes
DE1211597B (en) Process and device for the extraction of pure acids and bases from their salts by electrodialytic means
US3595769A (en) Prevention of calcium precipitation in the electrodialytic demineralization of whey
GB1150303A (en) A Process for Reducing Anode Corrosion in an Acrylonitrile Hydrodimerization Cell.
DE1941847A1 (en) Cation exchange diaphragm for electrolysis - cells
GB850958A (en) Improvements in purification of photographic emulsions