BR112023022154A2 - Processo para a coprodução de alquil mercaptana e de dissulfeto de dialquila a partir de álcool - Google Patents
Processo para a coprodução de alquil mercaptana e de dissulfeto de dialquila a partir de álcoolInfo
- Publication number
- BR112023022154A2 BR112023022154A2 BR112023022154A BR112023022154A BR112023022154A2 BR 112023022154 A2 BR112023022154 A2 BR 112023022154A2 BR 112023022154 A BR112023022154 A BR 112023022154A BR 112023022154 A BR112023022154 A BR 112023022154A BR 112023022154 A2 BR112023022154 A2 BR 112023022154A2
- Authority
- BR
- Brazil
- Prior art keywords
- alkyl mercaptan
- stream
- hydrogen sulfide
- alcohol
- dialkyl disulfide
- Prior art date
Links
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 title abstract 3
- 238000000034 method Methods 0.000 title abstract 3
- 238000004519 manufacturing process Methods 0.000 title abstract 2
- LSDPWZHWYPCBBB-UHFFFAOYSA-N Methanethiol Chemical compound SC LSDPWZHWYPCBBB-UHFFFAOYSA-N 0.000 title 1
- -1 alkyl mercaptan Chemical compound 0.000 abstract 8
- BWGNESOTFCXPMA-UHFFFAOYSA-N Dihydrogen disulfide Chemical compound SS BWGNESOTFCXPMA-UHFFFAOYSA-N 0.000 abstract 5
- RWSOTUBLDIXVET-UHFFFAOYSA-N Dihydrogen sulfide Chemical compound S RWSOTUBLDIXVET-UHFFFAOYSA-N 0.000 abstract 5
- 229910000037 hydrogen sulfide Inorganic materials 0.000 abstract 4
- NINIDFKCEFEMDL-UHFFFAOYSA-N Sulfur Chemical compound [S] NINIDFKCEFEMDL-UHFFFAOYSA-N 0.000 abstract 1
- 238000006243 chemical reaction Methods 0.000 abstract 1
- 230000003647 oxidation Effects 0.000 abstract 1
- 238000007254 oxidation reaction Methods 0.000 abstract 1
- 238000000746 purification Methods 0.000 abstract 1
- 238000011084 recovery Methods 0.000 abstract 1
- 238000004064 recycling Methods 0.000 abstract 1
- 229910052717 sulfur Inorganic materials 0.000 abstract 1
- 239000011593 sulfur Substances 0.000 abstract 1
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 abstract 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C319/00—Preparation of thiols, sulfides, hydropolysulfides or polysulfides
- C07C319/22—Preparation of thiols, sulfides, hydropolysulfides or polysulfides of hydropolysulfides or polysulfides
- C07C319/24—Preparation of thiols, sulfides, hydropolysulfides or polysulfides of hydropolysulfides or polysulfides by reactions involving the formation of sulfur-to-sulfur bonds
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C321/00—Thiols, sulfides, hydropolysulfides or polysulfides
- C07C321/02—Thiols having mercapto groups bound to acyclic carbon atoms
- C07C321/04—Thiols having mercapto groups bound to acyclic carbon atoms of an acyclic saturated carbon skeleton
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C319/00—Preparation of thiols, sulfides, hydropolysulfides or polysulfides
- C07C319/02—Preparation of thiols, sulfides, hydropolysulfides or polysulfides of thiols
- C07C319/08—Preparation of thiols, sulfides, hydropolysulfides or polysulfides of thiols by replacement of hydroxy groups or etherified or esterified hydroxy groups
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C319/00—Preparation of thiols, sulfides, hydropolysulfides or polysulfides
- C07C319/26—Separation; Purification; Stabilisation; Use of additives
- C07C319/28—Separation; Purification
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C321/00—Thiols, sulfides, hydropolysulfides or polysulfides
- C07C321/12—Sulfides, hydropolysulfides, or polysulfides having thio groups bound to acyclic carbon atoms
- C07C321/14—Sulfides, hydropolysulfides, or polysulfides having thio groups bound to acyclic carbon atoms of an acyclic saturated carbon skeleton
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
- Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)
Abstract
processo para a coprodução de alquil mercaptana e de dissulfeto de dialquila a partir de álcool. a invenção refere-se a um processo para a coprodução de alquil mercaptana e de dissulfeto de dialquila, compreendendo as seguintes etapas sucessivas: a) reação de um álcool c1-c4 na presença de sulfeto de hidrogênio (h2s) para formar uma corrente (m) compreendendo uma alquil mercaptana, água e possivelmente sulfeto de hidrogênio não reagido, b) purificação da corrente (m) para se obter uma corrente (n) enriquecida em alquil mercaptana, c) recuperação de uma primeira porção da corrente (n) incluindo a alquil mercaptana purificada na etapa b), d) oxidação com enxofre da segunda porção da corrente (n) de alquil mercaptana, para formar uma corrente (o) compreendendo um dissulfeto de dialquila, sulfeto de hidrogênio e possivelmente alquil mercaptana não reagida, e) purificação da corrente (o) para separar, por um lado, o dissulfeto de dialquila enriquecido e, por outro lado, o sulfeto de hidrogênio e possivelmente a alquil mercaptana que não reagiu na etapa d), f) reciclagem do sulfeto de hidrogênio e possivelmente da alquil mercaptana isolada na etapa e) na corrente (m) obtida a partir da etapa a), g) recuperação do dissulfeto de dialquila isolado na etapa e).
Applications Claiming Priority (2)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| FR2104977A FR3122876B1 (fr) | 2021-05-11 | 2021-05-11 | Procédé de co-production d’alkylmercaptan et de dialkyldisulfure à partir d’alcool |
| PCT/FR2022/050888 WO2022238650A1 (fr) | 2021-05-11 | 2022-05-10 | Procédé de co-production d'alkylmercaptan et de dialkyldisulfure à partir d'alcool |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| BR112023022154A2 true BR112023022154A2 (pt) | 2024-01-16 |
Family
ID=76920913
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| BR112023022154A BR112023022154A2 (pt) | 2021-05-11 | 2022-05-10 | Processo para a coprodução de alquil mercaptana e de dissulfeto de dialquila a partir de álcool |
Country Status (9)
| Country | Link |
|---|---|
| US (1) | US11897837B2 (pt) |
| EP (1) | EP4337637A1 (pt) |
| JP (1) | JP2024517482A (pt) |
| KR (1) | KR20240006067A (pt) |
| CN (1) | CN117295714A (pt) |
| BR (1) | BR112023022154A2 (pt) |
| CA (1) | CA3217844A1 (pt) |
| FR (1) | FR3122876B1 (pt) |
| WO (1) | WO2022238650A1 (pt) |
Family Cites Families (8)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| FR2567513B1 (fr) | 1984-07-10 | 1987-01-02 | Elf Aquitaine | Procede de fabrication de methylmercaptan a partir des oxydes de carbone |
| DE3572657D1 (en) * | 1985-04-26 | 1989-10-05 | Pennwalt Corp | Preparation of dialkyl disulfides |
| FR2781795B1 (fr) | 1998-07-31 | 2000-09-08 | Atochem Elf Sa | Compositions a base de dimethyldisulfure a odeur masquee |
| US6294699B1 (en) * | 1999-08-30 | 2001-09-25 | Richmond, Hitchcock, Fish & Dollar | Oxidation of mercaptans to organic disulfides |
| EP1982764A1 (en) | 2007-04-17 | 2008-10-22 | Evonik Degussa GmbH | Catalyst for the preparation of methyl mercaptan |
| FR2935142B1 (fr) * | 2008-08-20 | 2010-11-19 | Arkema France | Dimethyldisulfure issu au moins partiellement de matieres renouvellables |
| FR3023287B1 (fr) * | 2014-07-04 | 2016-07-22 | Arkema France | Procede de preparation de methylmercaptan |
| FR3023288B1 (fr) * | 2014-07-04 | 2016-07-15 | Arkema France | Procede de preparation de disulfure de dimethyle |
-
2021
- 2021-05-11 FR FR2104977A patent/FR3122876B1/fr active Active
-
2022
- 2022-05-10 BR BR112023022154A patent/BR112023022154A2/pt unknown
- 2022-05-10 JP JP2023570062A patent/JP2024517482A/ja active Pending
- 2022-05-10 EP EP22727376.0A patent/EP4337637A1/fr active Pending
- 2022-05-10 CA CA3217844A patent/CA3217844A1/fr active Pending
- 2022-05-10 CN CN202280034097.0A patent/CN117295714A/zh active Pending
- 2022-05-10 US US17/740,655 patent/US11897837B2/en active Active
- 2022-05-10 WO PCT/FR2022/050888 patent/WO2022238650A1/fr active Application Filing
- 2022-05-10 KR KR1020237042431A patent/KR20240006067A/ko unknown
Also Published As
| Publication number | Publication date |
|---|---|
| FR3122876A1 (fr) | 2022-11-18 |
| KR20240006067A (ko) | 2024-01-12 |
| FR3122876B1 (fr) | 2024-03-08 |
| JP2024517482A (ja) | 2024-04-22 |
| EP4337637A1 (fr) | 2024-03-20 |
| WO2022238650A1 (fr) | 2022-11-17 |
| CA3217844A1 (fr) | 2022-11-17 |
| US11897837B2 (en) | 2024-02-13 |
| US20220363631A1 (en) | 2022-11-17 |
| CN117295714A (zh) | 2023-12-26 |
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