BR112018013476B8 - Sistema catalisador isento de ftalato, e, processo para preparação de uma poliolefina - Google Patents

Sistema catalisador isento de ftalato, e, processo para preparação de uma poliolefina

Info

Publication number
BR112018013476B8
BR112018013476B8 BR112018013476A BR112018013476A BR112018013476B8 BR 112018013476 B8 BR112018013476 B8 BR 112018013476B8 BR 112018013476 A BR112018013476 A BR 112018013476A BR 112018013476 A BR112018013476 A BR 112018013476A BR 112018013476 B8 BR112018013476 B8 BR 112018013476B8
Authority
BR
Brazil
Prior art keywords
phthalate
catalyst system
free catalyst
polyolefin
preparing
Prior art date
Application number
BR112018013476A
Other languages
English (en)
Other versions
BR112018013476A2 (pt
BR112018013476B1 (pt
Inventor
Mitchell Brandi
Meverden Craig
Original Assignee
Braskem America Inc
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Braskem America Inc filed Critical Braskem America Inc
Publication of BR112018013476A2 publication Critical patent/BR112018013476A2/pt
Publication of BR112018013476B1 publication Critical patent/BR112018013476B1/pt
Publication of BR112018013476B8 publication Critical patent/BR112018013476B8/pt

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Classifications

    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F4/00—Polymerisation catalysts
    • C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
    • C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
    • C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
    • C08F4/62—Refractory metals or compounds thereof
    • C08F4/64—Titanium, zirconium, hafnium or compounds thereof
    • C08F4/647—Catalysts containing a specific non-metal or metal-free compound
    • C08F4/649—Catalysts containing a specific non-metal or metal-free compound organic
    • C08F4/6494—Catalysts containing a specific non-metal or metal-free compound organic containing oxygen
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
    • B01J31/26—Catalysts comprising hydrides, coordination complexes or organic compounds containing in addition, inorganic metal compounds not provided for in groups B01J31/02 - B01J31/24
    • B01J31/38—Catalysts comprising hydrides, coordination complexes or organic compounds containing in addition, inorganic metal compounds not provided for in groups B01J31/02 - B01J31/24 of titanium, zirconium or hafnium
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F10/00—Homopolymers and copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
    • C08F10/04—Monomers containing three or four carbon atoms
    • C08F10/06—Propene
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F110/00—Homopolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
    • C08F110/04—Monomers containing three or four carbon atoms
    • C08F110/06—Propene
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F210/00—Copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
    • C08F210/04—Monomers containing three or four carbon atoms
    • C08F210/06—Propene
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F4/00—Polymerisation catalysts
    • C08F4/02—Carriers therefor
    • C08F4/022—Magnesium halide as support anhydrous or hydrated or complexed by means of a Lewis base for Ziegler-type catalysts
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F4/00—Polymerisation catalysts
    • C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
    • C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
    • C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
    • C08F4/62—Refractory metals or compounds thereof
    • C08F4/64—Titanium, zirconium, hafnium or compounds thereof
    • C08F4/65—Pretreating the metal or compound covered by group C08F4/64 before the final contacting with the metal or compound covered by group C08F4/44
    • C08F4/651—Pretreating with non-metals or metal-free compounds
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2231/00—Catalytic reactions performed with catalysts classified in B01J31/00
    • B01J2231/10—Polymerisation reactions involving at least dual use catalysts, e.g. for both oligomerisation and polymerisation
    • B01J2231/12—Olefin polymerisation or copolymerisation
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2523/00—Constitutive chemical elements of heterogeneous catalysts
    • B01J2523/20—Constitutive chemical elements of heterogeneous catalysts of Group II (IIA or IIB) of the Periodic Table
    • B01J2523/22—Magnesium
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2523/00—Constitutive chemical elements of heterogeneous catalysts
    • B01J2523/40—Constitutive chemical elements of heterogeneous catalysts of Group IV (IVA or IVB) of the Periodic Table
    • B01J2523/47—Titanium
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F2500/00—Characteristics or properties of obtained polyolefins; Use thereof
    • C08F2500/04—Broad molecular weight distribution, i.e. Mw/Mn > 6
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F2500/00—Characteristics or properties of obtained polyolefins; Use thereof
    • C08F2500/12—Melt flow index or melt flow ratio
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F2500/00—Characteristics or properties of obtained polyolefins; Use thereof
    • C08F2500/15—Isotactic

Landscapes

  • Chemical & Material Sciences (AREA)
  • Health & Medical Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Organic Chemistry (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Emergency Medicine (AREA)
  • Inorganic Chemistry (AREA)
  • Transition And Organic Metals Composition Catalysts For Addition Polymerization (AREA)

Abstract

SISTEMA CATALISADOR ISENTO DE FTALATO, E, PROCESSO PARA PREPARAÇÃO DE UMA POLIOLEFINA. Esta invenção refere-se a um sistema catalisador isento de ftalato para polimerização de olefina. O sistema catalisador isento de ftalato compreende (a) uma composição de catalisador Ziegler-Natta sólido compreendendo um metal de transição, um metal de Grupo 2 e um ou mais halogênios; e um ou mais compostos doadores internos de elétron; e (b) um ou mais compostos doadores internos de elétrons.
BR112018013476A 2015-12-31 2016-12-29 Sistema catalisador isento de ftalato, e, processo para preparação de uma poliolefina BR112018013476B8 (pt)

Applications Claiming Priority (5)

Application Number Priority Date Filing Date Title
US201562273584P 2015-12-31 2015-12-31
US62/273584 2015-12-31
US201662278256P 2016-01-13 2016-01-13
US62/278256 2016-01-13
PCT/US2016/069295 WO2017117439A1 (en) 2015-12-31 2016-12-29 Non-phthalate catalyst system and its use in the polymerization of olefins

Publications (3)

Publication Number Publication Date
BR112018013476A2 BR112018013476A2 (pt) 2018-12-04
BR112018013476B1 BR112018013476B1 (pt) 2022-10-11
BR112018013476B8 true BR112018013476B8 (pt) 2022-11-08

Family

ID=59225403

Family Applications (4)

Application Number Title Priority Date Filing Date
BR112018013487-2A BR112018013487B1 (pt) 2015-12-31 2016-12-29 Sistema catalisador isento de ftalato para polimerização de olefina, e, processo para preparação de uma poliolefina
BR112018013506-2A BR112018013506B1 (pt) 2015-12-31 2016-12-29 Sistema catalisador isento de ftalato
BR122022010417-7A BR122022010417B1 (pt) 2015-12-31 2016-12-29 Sistema catalisador isento de ftalato
BR112018013476A BR112018013476B8 (pt) 2015-12-31 2016-12-29 Sistema catalisador isento de ftalato, e, processo para preparação de uma poliolefina

Family Applications Before (3)

Application Number Title Priority Date Filing Date
BR112018013487-2A BR112018013487B1 (pt) 2015-12-31 2016-12-29 Sistema catalisador isento de ftalato para polimerização de olefina, e, processo para preparação de uma poliolefina
BR112018013506-2A BR112018013506B1 (pt) 2015-12-31 2016-12-29 Sistema catalisador isento de ftalato
BR122022010417-7A BR122022010417B1 (pt) 2015-12-31 2016-12-29 Sistema catalisador isento de ftalato

Country Status (5)

Country Link
US (4) US11117982B2 (pt)
EP (3) EP3397659A4 (pt)
BR (4) BR112018013487B1 (pt)
MX (3) MX2018008208A (pt)
WO (3) WO2017117439A1 (pt)

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CN109678997B (zh) * 2017-10-19 2021-11-19 中国石油化工股份有限公司 用于烯烃聚合的催化剂组分及催化剂和预聚合催化剂及烯烃聚合方法
CN109912735B (zh) * 2017-12-12 2020-09-29 中国科学院化学研究所 烯烃聚合催化剂用外给电子体、催化剂体系以及聚烯烃的制备方法
MX2021011606A (es) 2019-04-02 2021-12-10 Aligos Therapeutics Inc Compuestos dirigidos a prmt5.
WO2020242715A1 (en) 2019-05-31 2020-12-03 The Procter & Gamble Company Absorbent article having a waist gasketing element
CN110483666A (zh) * 2019-07-02 2019-11-22 浙江石油化工有限公司 一种丙烯聚合催化剂
WO2021226034A1 (en) 2020-05-05 2021-11-11 The Procter & Gamble Company Absorbent articles including improved elastic panels
US20240287345A1 (en) * 2021-06-10 2024-08-29 W.R. Grace & Co.-Conn. Polypropylene random copolymer for three-dimensional printing and filament made therefrom

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Also Published As

Publication number Publication date
EP3397658B1 (en) 2022-07-27
WO2017117439A1 (en) 2017-07-06
BR112018013487B1 (pt) 2022-08-30
EP3397658A4 (en) 2019-09-11
MX2018008208A (es) 2018-08-28
US10633464B2 (en) 2020-04-28
EP3397658A1 (en) 2018-11-07
WO2017117433A1 (en) 2017-07-06
US11041028B2 (en) 2021-06-22
BR112018013476A2 (pt) 2018-12-04
US10633463B2 (en) 2020-04-28
BR122022010417B1 (pt) 2023-01-31
MX2018008209A (es) 2018-08-28
EP3397657B1 (en) 2024-06-12
WO2017117443A1 (en) 2017-07-06
US11117982B2 (en) 2021-09-14
US20190016832A1 (en) 2019-01-17
US20190010258A1 (en) 2019-01-10
MX2018008207A (es) 2018-08-28
BR112018013506A2 (pt) 2018-12-11
US20190010264A1 (en) 2019-01-10
BR112018013476B1 (pt) 2022-10-11
EP3397657A1 (en) 2018-11-07
US20200199262A1 (en) 2020-06-25
BR112018013487A2 (pt) 2018-12-04
EP3397659A4 (en) 2019-09-04
EP3397659A1 (en) 2018-11-07
EP3397657A4 (en) 2019-09-11
BR112018013506B1 (pt) 2022-10-11

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