BR112018013476A2 - sistema catalisador isento de ftalato, e, processo para preparação de uma poliolefina - Google Patents
sistema catalisador isento de ftalato, e, processo para preparação de uma poliolefinaInfo
- Publication number
- BR112018013476A2 BR112018013476A2 BR112018013476-7A BR112018013476A BR112018013476A2 BR 112018013476 A2 BR112018013476 A2 BR 112018013476A2 BR 112018013476 A BR112018013476 A BR 112018013476A BR 112018013476 A2 BR112018013476 A2 BR 112018013476A2
- Authority
- BR
- Brazil
- Prior art keywords
- phthalate
- catalyst system
- free catalyst
- polyolefin
- preparing
- Prior art date
Links
Classifications
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F4/00—Polymerisation catalysts
- C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
- C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
- C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
- C08F4/62—Refractory metals or compounds thereof
- C08F4/64—Titanium, zirconium, hafnium or compounds thereof
- C08F4/647—Catalysts containing a specific non-metal or metal-free compound
- C08F4/649—Catalysts containing a specific non-metal or metal-free compound organic
- C08F4/6494—Catalysts containing a specific non-metal or metal-free compound organic containing oxygen
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
- B01J31/26—Catalysts comprising hydrides, coordination complexes or organic compounds containing in addition, inorganic metal compounds not provided for in groups B01J31/02 - B01J31/24
- B01J31/38—Catalysts comprising hydrides, coordination complexes or organic compounds containing in addition, inorganic metal compounds not provided for in groups B01J31/02 - B01J31/24 of titanium, zirconium or hafnium
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F10/00—Homopolymers and copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
- C08F10/04—Monomers containing three or four carbon atoms
- C08F10/06—Propene
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F110/00—Homopolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
- C08F110/04—Monomers containing three or four carbon atoms
- C08F110/06—Propene
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F210/00—Copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
- C08F210/04—Monomers containing three or four carbon atoms
- C08F210/06—Propene
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F4/00—Polymerisation catalysts
- C08F4/02—Carriers therefor
- C08F4/022—Magnesium halide as support anhydrous or hydrated or complexed by means of a Lewis base for Ziegler-type catalysts
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F4/00—Polymerisation catalysts
- C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
- C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
- C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
- C08F4/62—Refractory metals or compounds thereof
- C08F4/64—Titanium, zirconium, hafnium or compounds thereof
- C08F4/65—Pretreating the metal or compound covered by group C08F4/64 before the final contacting with the metal or compound covered by group C08F4/44
- C08F4/651—Pretreating with non-metals or metal-free compounds
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J2231/00—Catalytic reactions performed with catalysts classified in B01J31/00
- B01J2231/10—Polymerisation reactions involving at least dual use catalysts, e.g. for both oligomerisation and polymerisation
- B01J2231/12—Olefin polymerisation or copolymerisation
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J2523/00—Constitutive chemical elements of heterogeneous catalysts
- B01J2523/20—Constitutive chemical elements of heterogeneous catalysts of Group II (IIA or IIB) of the Periodic Table
- B01J2523/22—Magnesium
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J2523/00—Constitutive chemical elements of heterogeneous catalysts
- B01J2523/40—Constitutive chemical elements of heterogeneous catalysts of Group IV (IVA or IVB) of the Periodic Table
- B01J2523/47—Titanium
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F2500/00—Characteristics or properties of obtained polyolefins; Use thereof
- C08F2500/04—Broad molecular weight distribution, i.e. Mw/Mn > 6
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F2500/00—Characteristics or properties of obtained polyolefins; Use thereof
- C08F2500/12—Melt flow index or melt flow ratio
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F2500/00—Characteristics or properties of obtained polyolefins; Use thereof
- C08F2500/15—Isotactic
Landscapes
- Chemical & Material Sciences (AREA)
- Health & Medical Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Organic Chemistry (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
- Emergency Medicine (AREA)
- Inorganic Chemistry (AREA)
- Transition And Organic Metals Composition Catalysts For Addition Polymerization (AREA)
Abstract
esta invenção refere-se a um sistema catalisador isento de ftalato para polimerização de olefina. o sistema catalisador isento de ftalato compreende (a) uma composição de catalisador ziegler-natta sólido compreendendo um metal de transição, um metal de grupo 2 e um ou mais halogênios; e um ou mais compostos doadores internos de elétron; e (b) um ou mais compostos doadores internos de elétrons.
Applications Claiming Priority (5)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
US201562273584P | 2015-12-31 | 2015-12-31 | |
US62/273584 | 2015-12-31 | ||
US201662278256P | 2016-01-13 | 2016-01-13 | |
US62/278256 | 2016-01-13 | ||
PCT/US2016/069295 WO2017117439A1 (en) | 2015-12-31 | 2016-12-29 | Non-phthalate catalyst system and its use in the polymerization of olefins |
Publications (3)
Publication Number | Publication Date |
---|---|
BR112018013476A2 true BR112018013476A2 (pt) | 2018-12-04 |
BR112018013476B1 BR112018013476B1 (pt) | 2022-10-11 |
BR112018013476B8 BR112018013476B8 (pt) | 2022-11-08 |
Family
ID=59225403
Family Applications (4)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
BR112018013506-2A BR112018013506B1 (pt) | 2015-12-31 | 2016-12-29 | Sistema catalisador isento de ftalato |
BR112018013487-2A BR112018013487B1 (pt) | 2015-12-31 | 2016-12-29 | Sistema catalisador isento de ftalato para polimerização de olefina, e, processo para preparação de uma poliolefina |
BR122022010417-7A BR122022010417B1 (pt) | 2015-12-31 | 2016-12-29 | Sistema catalisador isento de ftalato |
BR112018013476A BR112018013476B8 (pt) | 2015-12-31 | 2016-12-29 | Sistema catalisador isento de ftalato, e, processo para preparação de uma poliolefina |
Family Applications Before (3)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
BR112018013506-2A BR112018013506B1 (pt) | 2015-12-31 | 2016-12-29 | Sistema catalisador isento de ftalato |
BR112018013487-2A BR112018013487B1 (pt) | 2015-12-31 | 2016-12-29 | Sistema catalisador isento de ftalato para polimerização de olefina, e, processo para preparação de uma poliolefina |
BR122022010417-7A BR122022010417B1 (pt) | 2015-12-31 | 2016-12-29 | Sistema catalisador isento de ftalato |
Country Status (5)
Country | Link |
---|---|
US (4) | US10633463B2 (pt) |
EP (3) | EP3397657A4 (pt) |
BR (4) | BR112018013506B1 (pt) |
MX (3) | MX2018008209A (pt) |
WO (3) | WO2017117433A1 (pt) |
Families Citing this family (7)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN109678997B (zh) * | 2017-10-19 | 2021-11-19 | 中国石油化工股份有限公司 | 用于烯烃聚合的催化剂组分及催化剂和预聚合催化剂及烯烃聚合方法 |
CN109912735B (zh) * | 2017-12-12 | 2020-09-29 | 中国科学院化学研究所 | 烯烃聚合催化剂用外给电子体、催化剂体系以及聚烯烃的制备方法 |
CA3134613A1 (en) | 2019-04-02 | 2020-10-08 | Aligos Therapeutics, Inc. | Compounds targeting prmt5 |
WO2020242714A1 (en) | 2019-05-31 | 2020-12-03 | The Procter & Gamble Company | Method and apparatus for bonding elastic parts under tension to an advancing carrier |
CN110483666A (zh) * | 2019-07-02 | 2019-11-22 | 浙江石油化工有限公司 | 一种丙烯聚合催化剂 |
WO2021226034A1 (en) | 2020-05-05 | 2021-11-11 | The Procter & Gamble Company | Absorbent articles including improved elastic panels |
KR20240019289A (ko) * | 2021-06-10 | 2024-02-14 | 더블유.알. 그레이스 앤드 캄파니-콘. | 3차원 인쇄를 위한 폴리프로필렌 랜덤 공중합체 및 이로부터 제조된 필라멘트 |
Family Cites Families (28)
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IT1096661B (it) | 1978-06-13 | 1985-08-26 | Montedison Spa | Procedimento per la preparazione di prodotti in forma sferoidale solidi a temperatura ambiente |
IT1098272B (it) | 1978-08-22 | 1985-09-07 | Montedison Spa | Componenti,di catalizzatori e catalizzatori per la polimerizzazione delle alfa-olefine |
IT1274253B (it) | 1995-02-21 | 1997-07-15 | Himont Inc | Processo per la preparazione di componenti catalitici solidi per la polimerizzazione di olefine |
AUPO591797A0 (en) | 1997-03-27 | 1997-04-24 | Commonwealth Scientific And Industrial Research Organisation | High avidity polyvalent and polyspecific reagents |
CN1169845C (zh) | 2002-02-07 | 2004-10-06 | 中国石油化工股份有限公司 | 用于烯烃聚合的固体催化剂组分和含该催化剂组分的催化剂及其应用 |
US7491670B2 (en) | 2003-09-23 | 2009-02-17 | Dow Global Technologies Inc. | Self limiting catalyst composition and propylene polymerization process |
BRPI0606453B1 (pt) | 2005-01-19 | 2016-11-29 | Mitsui Chemicals Inc | processo para a produção de um polímero de olefina |
US7888438B2 (en) | 2005-01-19 | 2011-02-15 | Mitsui Chemicals, Inc. | Catalyst for olefin polymerization and process for olefin polymerization |
US7388060B2 (en) | 2006-01-04 | 2008-06-17 | China Petroleum & Chemical Corporation | Catalyst component for olefin (co)polymerization, preparation thereof, a catalyst comprising the same and use thereof |
BRPI0819666B1 (pt) | 2007-11-27 | 2018-07-10 | Mitsui Chemicals, Inc. | Componente catalisador de titânio sólido, catalisador de polimerização de olefina e processo de polimerização de olefina |
US8003558B2 (en) | 2008-07-29 | 2011-08-23 | Basf Corporation | Internal donor for olefin polymerization catalysts |
BRPI0919007B1 (pt) | 2008-09-22 | 2019-04-24 | Mitsui Chemical, Inc. | Copolímero em bloco à base de propileno, composição quecontém o copolímero e produtos moldados obtidos a partirdeste |
JP5969210B2 (ja) | 2008-12-31 | 2016-08-17 | ダブリュー・アール・グレイス・アンド・カンパニー−コネチカット | 強化されたプロ触媒組成物及びプロセス |
KR101600365B1 (ko) | 2008-12-31 | 2016-03-07 | 더블유.알. 그레이스 앤드 캄파니-콘. | 치환된 1,2-페닐렌 방향족 디에스테르 내부 공여체를 갖는 전촉매 조성물 및 방법 |
US8211819B2 (en) | 2009-12-21 | 2012-07-03 | Basf Corporation | Internal and external donor compounds for olefin polymerization catalysts |
US8569195B2 (en) * | 2010-02-24 | 2013-10-29 | Basf Corporation | Internal and external donor compounds for olefin polymerization catalysts II |
BR112012033011B1 (pt) | 2010-06-24 | 2020-05-26 | Basell Poliolefine Italia S.R.L. | Sistema catalisador e processo para polimerizar olefinas utilizando tal sistema |
EP2415790B1 (en) | 2010-07-13 | 2014-09-24 | Borealis AG | Catalyst component |
BR112013008900A2 (pt) | 2010-10-19 | 2016-06-28 | Basell Poliolefine Srl | "sistema da catalisação para a polimerização de olefinas" |
US8227370B2 (en) | 2010-11-10 | 2012-07-24 | Basf Corporation | High activity catalyst component for olefin polymerization and method of using the same |
US10647790B2 (en) | 2011-06-30 | 2020-05-12 | W. R. Grace & Co.-Conn. | Process for gas-phase polymerization having high bed bulk density |
EP2610273B1 (en) | 2011-12-30 | 2018-02-07 | Borealis AG | Catalyst component |
US9481741B2 (en) | 2012-11-26 | 2016-11-01 | Lummus Novolen Technology Gmbh | High performance Ziegler-Natta catalyst systems, process for producing such supported catalysts and use thereof |
US9790291B2 (en) | 2013-03-14 | 2017-10-17 | Formosa Plastics Corporation, Usa | Non-phthalate compounds as electron donors for polyolefin catalysts |
TWI639626B (zh) | 2013-09-30 | 2018-11-01 | 中國石油化工科技開發有限公司 | Catalyst composition for olefin polymerization and application thereof |
RU2731442C2 (ru) | 2013-11-21 | 2020-09-02 | У.Р. Грейс Энд Ко.-Конн | Получение полимеров на основе пропилена с высоким содержанием сомономера |
SG11201608923UA (en) * | 2014-04-24 | 2016-11-29 | China Petroleum & Chem Corp | Catalyst component for propylene polymerization, preparation method therefor and catalyst having same |
EP2960257B1 (en) | 2014-06-27 | 2022-09-28 | Borealis AG | Improved process for preparing a particulate olefin polymerisation catalyst component |
-
2016
- 2016-12-29 US US16/067,346 patent/US10633463B2/en active Active
- 2016-12-29 MX MX2018008209A patent/MX2018008209A/es unknown
- 2016-12-29 BR BR112018013506-2A patent/BR112018013506B1/pt active IP Right Grant
- 2016-12-29 MX MX2018008208A patent/MX2018008208A/es unknown
- 2016-12-29 US US16/067,348 patent/US10633464B2/en active Active
- 2016-12-29 BR BR112018013487-2A patent/BR112018013487B1/pt active IP Right Grant
- 2016-12-29 WO PCT/US2016/069287 patent/WO2017117433A1/en active Application Filing
- 2016-12-29 EP EP16882686.5A patent/EP3397657A4/en active Pending
- 2016-12-29 EP EP16882692.3A patent/EP3397659A4/en active Pending
- 2016-12-29 US US16/067,350 patent/US11117982B2/en active Active
- 2016-12-29 BR BR122022010417-7A patent/BR122022010417B1/pt active IP Right Grant
- 2016-12-29 WO PCT/US2016/069295 patent/WO2017117439A1/en active Application Filing
- 2016-12-29 MX MX2018008207A patent/MX2018008207A/es unknown
- 2016-12-29 BR BR112018013476A patent/BR112018013476B8/pt active IP Right Grant
- 2016-12-29 EP EP16882689.9A patent/EP3397658B1/en active Active
- 2016-12-29 WO PCT/US2016/069299 patent/WO2017117443A1/en active Application Filing
-
2020
- 2020-03-04 US US16/809,413 patent/US11041028B2/en active Active
Also Published As
Publication number | Publication date |
---|---|
BR112018013487B1 (pt) | 2022-08-30 |
EP3397659A1 (en) | 2018-11-07 |
US10633463B2 (en) | 2020-04-28 |
US20190016832A1 (en) | 2019-01-17 |
WO2017117433A1 (en) | 2017-07-06 |
BR112018013487A2 (pt) | 2018-12-04 |
EP3397659A4 (en) | 2019-09-04 |
EP3397658A1 (en) | 2018-11-07 |
MX2018008207A (es) | 2018-08-28 |
BR122022010417B1 (pt) | 2023-01-31 |
MX2018008208A (es) | 2018-08-28 |
EP3397658B1 (en) | 2022-07-27 |
BR112018013476B8 (pt) | 2022-11-08 |
BR112018013506A2 (pt) | 2018-12-11 |
US10633464B2 (en) | 2020-04-28 |
US20190010258A1 (en) | 2019-01-10 |
US20200199262A1 (en) | 2020-06-25 |
US11041028B2 (en) | 2021-06-22 |
EP3397657A4 (en) | 2019-09-11 |
EP3397657A1 (en) | 2018-11-07 |
BR112018013476B1 (pt) | 2022-10-11 |
WO2017117443A1 (en) | 2017-07-06 |
EP3397658A4 (en) | 2019-09-11 |
US11117982B2 (en) | 2021-09-14 |
MX2018008209A (es) | 2018-08-28 |
US20190010264A1 (en) | 2019-01-10 |
WO2017117439A1 (en) | 2017-07-06 |
BR112018013506B1 (pt) | 2022-10-11 |
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