BR112018011032A2 - carregamento de um catalisador em uma coluna de bolhas para a síntese de fischer-tropsch - Google Patents

carregamento de um catalisador em uma coluna de bolhas para a síntese de fischer-tropsch

Info

Publication number
BR112018011032A2
BR112018011032A2 BR112018011032-9A BR112018011032A BR112018011032A2 BR 112018011032 A2 BR112018011032 A2 BR 112018011032A2 BR 112018011032 A BR112018011032 A BR 112018011032A BR 112018011032 A2 BR112018011032 A2 BR 112018011032A2
Authority
BR
Brazil
Prior art keywords
reactor
catalyst
solvent
loading
fischer
Prior art date
Application number
BR112018011032-9A
Other languages
English (en)
Inventor
Desgranges Régis
Heraud Jean-Philippe
Viguie Jean-Christophe
Boucher Sébastien
Della Torre Chiara
Mignone Elsa
Original Assignee
IFP Energies Nouvelles
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by IFP Energies Nouvelles filed Critical IFP Energies Nouvelles
Publication of BR112018011032A2 publication Critical patent/BR112018011032A2/pt

Links

Classifications

    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J8/00—Chemical or physical processes in general, conducted in the presence of fluids and solid particles; Apparatus for such processes
    • B01J8/18—Chemical or physical processes in general, conducted in the presence of fluids and solid particles; Apparatus for such processes with fluidised particles
    • B01J8/20—Chemical or physical processes in general, conducted in the presence of fluids and solid particles; Apparatus for such processes with fluidised particles with liquid as a fluidising medium
    • B01J8/22—Chemical or physical processes in general, conducted in the presence of fluids and solid particles; Apparatus for such processes with fluidised particles with liquid as a fluidising medium gas being introduced into the liquid
    • B01J8/224—Chemical or physical processes in general, conducted in the presence of fluids and solid particles; Apparatus for such processes with fluidised particles with liquid as a fluidising medium gas being introduced into the liquid the particles being subject to a circulatory movement
    • B01J8/228—Chemical or physical processes in general, conducted in the presence of fluids and solid particles; Apparatus for such processes with fluidised particles with liquid as a fluidising medium gas being introduced into the liquid the particles being subject to a circulatory movement externally, i.e. the particles leaving the vessel and subsequently re-entering it
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J8/00—Chemical or physical processes in general, conducted in the presence of fluids and solid particles; Apparatus for such processes
    • B01J8/0015—Feeding of the particles in the reactor; Evacuation of the particles out of the reactor
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J8/00—Chemical or physical processes in general, conducted in the presence of fluids and solid particles; Apparatus for such processes
    • B01J8/005—Separating solid material from the gas/liquid stream
    • B01J8/007—Separating solid material from the gas/liquid stream by sedimentation
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J8/00—Chemical or physical processes in general, conducted in the presence of fluids and solid particles; Apparatus for such processes
    • B01J8/18—Chemical or physical processes in general, conducted in the presence of fluids and solid particles; Apparatus for such processes with fluidised particles
    • B01J8/1836—Heating and cooling the reactor
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J8/00—Chemical or physical processes in general, conducted in the presence of fluids and solid particles; Apparatus for such processes
    • B01J8/18—Chemical or physical processes in general, conducted in the presence of fluids and solid particles; Apparatus for such processes with fluidised particles
    • B01J8/20—Chemical or physical processes in general, conducted in the presence of fluids and solid particles; Apparatus for such processes with fluidised particles with liquid as a fluidising medium
    • B01J8/22—Chemical or physical processes in general, conducted in the presence of fluids and solid particles; Apparatus for such processes with fluidised particles with liquid as a fluidising medium gas being introduced into the liquid
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
    • C10G2/00—Production of liquid hydrocarbon mixtures of undefined composition from oxides of carbon
    • C10G2/30—Production of liquid hydrocarbon mixtures of undefined composition from oxides of carbon from carbon monoxide with hydrogen
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
    • C10G2/00—Production of liquid hydrocarbon mixtures of undefined composition from oxides of carbon
    • C10G2/30—Production of liquid hydrocarbon mixtures of undefined composition from oxides of carbon from carbon monoxide with hydrogen
    • C10G2/32—Production of liquid hydrocarbon mixtures of undefined composition from oxides of carbon from carbon monoxide with hydrogen with the use of catalysts
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
    • C10G2/00—Production of liquid hydrocarbon mixtures of undefined composition from oxides of carbon
    • C10G2/30—Production of liquid hydrocarbon mixtures of undefined composition from oxides of carbon from carbon monoxide with hydrogen
    • C10G2/32—Production of liquid hydrocarbon mixtures of undefined composition from oxides of carbon from carbon monoxide with hydrogen with the use of catalysts
    • C10G2/34—Apparatus, reactors
    • C10G2/342—Apparatus, reactors with moving solid catalysts
    • C10G2/344—Apparatus, reactors with moving solid catalysts according to the "fluidised-bed" technique
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2208/00—Processes carried out in the presence of solid particles; Reactors therefor
    • B01J2208/00008—Controlling the process
    • B01J2208/00017—Controlling the temperature
    • B01J2208/00106—Controlling the temperature by indirect heat exchange
    • B01J2208/00115—Controlling the temperature by indirect heat exchange with heat exchange elements inside the bed of solid particles
    • B01J2208/00132—Tubes
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2208/00—Processes carried out in the presence of solid particles; Reactors therefor
    • B01J2208/00008—Controlling the process
    • B01J2208/00628—Controlling the composition of the reactive mixture
    • B01J2208/00646—Means for starting up the reaction
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2208/00—Processes carried out in the presence of solid particles; Reactors therefor
    • B01J2208/00008—Controlling the process
    • B01J2208/00654—Controlling the process by measures relating to the particulate material
    • B01J2208/0069—Attrition
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2208/00—Processes carried out in the presence of solid particles; Reactors therefor
    • B01J2208/00008—Controlling the process
    • B01J2208/00716—Means for reactor start-up
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2208/00—Processes carried out in the presence of solid particles; Reactors therefor
    • B01J2208/00743—Feeding or discharging of solids
    • B01J2208/00752—Feeding
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2208/00—Processes carried out in the presence of solid particles; Reactors therefor
    • B01J2208/00743—Feeding or discharging of solids
    • B01J2208/00769—Details of feeding or discharging
    • B01J2208/00787—Bringing the solid in the form of a slurry before feeding it to the reactor

Landscapes

  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Engineering & Computer Science (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • Combustion & Propulsion (AREA)
  • General Chemical & Material Sciences (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
  • Production Of Liquid Hydrocarbon Mixture For Refining Petroleum (AREA)
  • Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)
  • Catalysts (AREA)
  • Devices And Processes Conducted In The Presence Of Fluids And Solid Particles (AREA)

Abstract

a presente invenção refere-se um método para carregar um catalisador em um reator (40) compreendendo um circuito de separação (21), compreendendo as etapas a seguir: a) encher o reator (40) com um solvente s1; b) encher o circuito de separação (21) com dito solvente s1; c) fazer com que dito solvente s1 mova no reator de síntese (40) e no circuito de separação (21); d) aquecer o reator (40) a uma temperatura de 100°c ou menos; e) injetar um gás inerte na base do reator (40); f) misturar o dito catalisador com um solvente s2 em um recipiente (30) a fim de obter uma mistura líquido/sólido; g) aumentar a pressão no recipiente (30) então enviar a mistura líquido/sólido ao reator (40); h) remover o dito solvente s1 e/ou s2.
BR112018011032-9A 2015-12-08 2016-11-08 carregamento de um catalisador em uma coluna de bolhas para a síntese de fischer-tropsch BR112018011032A2 (pt)

Applications Claiming Priority (3)

Application Number Priority Date Filing Date Title
FR1562031 2015-12-08
FR1562031A FR3044565B1 (fr) 2015-12-08 2015-12-08 Chargement d'un catalyseur dans une colonne a bulles pour la synthese fischer-tropsch
PCT/EP2016/076938 WO2017097525A1 (fr) 2015-12-08 2016-11-08 Chargement d'un catalyseur dans une colonne a bulles pour la synthese fischer-tropsch

Publications (1)

Publication Number Publication Date
BR112018011032A2 true BR112018011032A2 (pt) 2018-11-21

Family

ID=55752403

Family Applications (1)

Application Number Title Priority Date Filing Date
BR112018011032-9A BR112018011032A2 (pt) 2015-12-08 2016-11-08 carregamento de um catalisador em uma coluna de bolhas para a síntese de fischer-tropsch

Country Status (13)

Country Link
US (1) US10576444B2 (pt)
EP (1) EP3386623B1 (pt)
JP (1) JP6771033B2 (pt)
CN (1) CN108472614B (pt)
AU (1) AU2016368402B2 (pt)
BR (1) BR112018011032A2 (pt)
CA (1) CA3004932C (pt)
FI (1) FI3386623T3 (pt)
FR (1) FR3044565B1 (pt)
IL (1) IL259319B (pt)
RU (1) RU2726117C2 (pt)
WO (1) WO2017097525A1 (pt)
ZA (1) ZA201803034B (pt)

Families Citing this family (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN111514827B (zh) * 2020-04-26 2022-04-01 太原科技大学 一种合成气制甲烷的加工装置及其加工方法
CN115041106B (zh) * 2022-06-21 2023-11-07 湖北新轩宏新材料有限公司 一种制备三氯甲苯的反应器及制备方法

Family Cites Families (19)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US4963328A (en) * 1987-01-15 1990-10-16 Mobil Oil Corporation Short contact time fluid catalytic cracking apparatus
IT1292462B1 (it) * 1997-07-03 1999-02-08 Agip Petroli Composizione catalitica utile nel processo di fischer-tropsch
US6512017B1 (en) 1999-10-14 2003-01-28 Sasol Technology (Proprietary) Limited Handling of a catalyst
US20020137805A1 (en) * 2001-01-26 2002-09-26 Huang Jui-Hsin Ray Process for operating a fischer-tropsch reactor
FR2826295B1 (fr) * 2001-06-25 2003-09-26 Inst Francais Du Petrole Dispositif et procede optimisant la circulation d'une suspension dans une installation comprenant un reacteur triphasique
JP4299146B2 (ja) * 2002-02-13 2009-07-22 サソール テクノロジー（プロプライエタリー）リミテッド フィッシャー−トロプシュ反応器の始動方法
GB0226514D0 (en) * 2002-11-13 2002-12-18 Statoil Asa Fischer-tropsch catalysts
JP4388753B2 (ja) * 2003-03-13 2009-12-24 千代田化工建設株式会社 不均一系触媒を用いた酢酸の製造方法
ITMI20031776A1 (it) * 2003-09-18 2005-03-19 Enitecnologie Spa Procedimento per il caricamento di un catalizzatore in un reattore adatto a reazioni in fase eterogenea
BRPI0619491A2 (pt) * 2005-12-09 2011-10-04 Shell Int Research método para iniciar um processo em estado estacionário para produzir hidrocarbonetos a partir de gás de sìntese
US20070254968A1 (en) 2006-04-27 2007-11-01 Syntroleum Corporation Method of delivery, replacement, and removal of fischer-tropsch catalyst
CA2700126C (en) * 2007-09-27 2014-02-18 Japan Oil, Gas And Metals National Corporation Synthesis reaction system
JP5501365B2 (ja) * 2009-08-31 2014-05-21 独立行政法人石油天然ガス・金属鉱物資源機構 スラリー調製方法、スラリー調製装置、炭化水素合成反応装置、及び炭化水素合成反応システム
JP5730495B2 (ja) * 2010-03-30 2015-06-10 独立行政法人石油天然ガス・金属鉱物資源機構 フィッシャー・トロプシュ合成反応用活性化触媒の製造方法、触媒スラリーの製造方法、並びに触媒スラリーのフィッシャー・トロプッシュ合成反応器への供給方法
JP5730102B2 (ja) * 2011-03-31 2015-06-03 独立行政法人石油天然ガス・金属鉱物資源機構 気泡塔型スラリー床反応器のスタートアップ方法及びスタートアップ用溶媒並びに炭化水素油の製造方法
JP5869397B2 (ja) * 2012-03-28 2016-02-24 独立行政法人石油天然ガス・金属鉱物資源機構 気泡塔型スラリー床反応器のスタートアップ方法
FR2991991B1 (fr) * 2012-06-18 2014-06-13 IFP Energies Nouvelles Procede de synthese d'hydrocarbures a partir de gaz de synthese avec controle de la temperature de la boucle externe
JP6088214B2 (ja) * 2012-11-09 2017-03-01 独立行政法人石油天然ガス・金属鉱物資源機構 炭化水素合成反応装置のスタートアップ方法
CN103666518B (zh) * 2013-12-04 2015-10-28 中国科学院山西煤炭化学研究所 一种费托合成尾气高值化利用的方法

Also Published As

Publication number Publication date
CN108472614A (zh) 2018-08-31
WO2017097525A1 (fr) 2017-06-15
FR3044565A1 (fr) 2017-06-09
RU2018122962A (ru) 2020-01-10
JP6771033B2 (ja) 2020-10-21
CA3004932C (fr) 2023-08-08
ZA201803034B (en) 2019-02-27
RU2726117C2 (ru) 2020-07-09
US20180369776A1 (en) 2018-12-27
AU2016368402B2 (en) 2020-10-22
CA3004932A1 (fr) 2017-06-15
FI3386623T3 (fi) 2024-01-26
FR3044565B1 (fr) 2017-12-01
IL259319B (en) 2021-09-30
CN108472614B (zh) 2021-04-13
US10576444B2 (en) 2020-03-03
JP2019504751A (ja) 2019-02-21
RU2018122962A3 (pt) 2020-01-27
EP3386623B1 (fr) 2023-10-25
AU2016368402A1 (en) 2018-07-12
IL259319A (en) 2018-07-31
EP3386623A1 (fr) 2018-10-17

Similar Documents

Publication Publication Date Title
BR112018070241A2 (pt) processo, aparelho, controlador e sistema para gerar produtos de petróleo
BR112017008648A2 (pt) processo contínuo para a preparação de óxido de propileno e composição
BR112015012012A2 (pt) processo para oligomerização de etileno
BR112016006226A2 (pt) soluções líquidas que contêm nanobolha
UY37748A (es) Sistema y método para la separación criogénica de un material vegetal
BR112018011032A2 (pt) carregamento de um catalisador em uma coluna de bolhas para a síntese de fischer-tropsch
WO2014151448A3 (en) An improved integrated process to produce 2,3,3,3-tetrafluoropropene
AR100112A1 (es) Disposición de hidrogenación para compuesto aromático
WO2013184207A3 (en) Emergency and back-up cooling of nuclear fuel and reactors
BR112018010229A2 (pt) sistema catalisador e processo para a produção de glicóis
BR112017016225A2 (pt) método para administrar biocida à água industrial em um processo de água industrial, e, reator para gerar um biocida oxidante e distribuir o biocida oxidante para uma corrente de líquido.
BR112013024770A2 (pt) sistema de controle de temperatura, aparelho de reação de síntese de hidrocarboneto, sistema de reação de síntese de hidrocarboneto, e processo de controle de temperatura
MY166852A (en) Separation of components from a multi-component hydrocarbon stream
GB2540282A (en) Methods and processes to recycle base oil fluids from spent invert emulsion drilling fluids
BR112015017802A2 (pt) processo e dispositivo para produção de combustível para uma turbina de gás
MY180942A (en) Method for separating polymer solution and water
Gutiérrez et al. Kinetics of biofuel generation from deodorizer distillates derived from the physical refining of olive oil and squalene recovery
ES2600037T3 (es) Procedimiento para la preparación de 2,2-difluoroetilamina a partir de 2,2-difluoro-1-cloroetano y amoniaco
GB2551666A (en) Pneumatic agitated ionic liquid alkylation using vaporization to remove reaction heat
BR112016018101A2 (pt) Processo e planta para a produção de olefinas
MX2019015256A (es) Proceso para la disolucion continua de un solido en un medio de reaccion.
BR112017023068A2 (pt) sistema de pintura de dois componentes
Matsuda et al. Excess molar enthalpies of the binary system carbon dioxide+ butyl levulinate at 298.15 and 303.15 K and 5.0–7.0 MPa
WO2015019313A3 (en) Method and retort vessel for enabling continuous thermal or thermo-catalytic degradation of mixed waste plastic feedstock
BR112018012474A2 (pt) método e aparelho para preparar aditivo para coque

Legal Events

Date Code Title Description
B06U Preliminary requirement: requests with searches performed by other patent offices: procedure suspended [chapter 6.21 patent gazette]
B07A Application suspended after technical examination (opinion) [chapter 7.1 patent gazette]
B350 Update of information on the portal [chapter 15.35 patent gazette]
B09B Patent application refused [chapter 9.2 patent gazette]
B09B Patent application refused [chapter 9.2 patent gazette]

Free format text: MANTIDO O INDEFERIMENTO UMA VEZ QUE NAO FOI APRESENTADO RECURSO DENTRO DO PRAZO LEGAL