BR112017002766A2 - adesivo para filme - Google Patents
adesivo para filmeInfo
- Publication number
- BR112017002766A2 BR112017002766A2 BR112017002766A BR112017002766A BR112017002766A2 BR 112017002766 A2 BR112017002766 A2 BR 112017002766A2 BR 112017002766 A BR112017002766 A BR 112017002766A BR 112017002766 A BR112017002766 A BR 112017002766A BR 112017002766 A2 BR112017002766 A2 BR 112017002766A2
- Authority
- BR
- Brazil
- Prior art keywords
- weight
- curable compositions
- sticker
- movie
- films
- Prior art date
Links
- 239000000203 mixture Substances 0.000 abstract 3
- RNFJDJUURJAICM-UHFFFAOYSA-N 2,2,4,4,6,6-hexaphenoxy-1,3,5-triaza-2$l^{5},4$l^{5},6$l^{5}-triphosphacyclohexa-1,3,5-triene Chemical compound N=1P(OC=2C=CC=CC=2)(OC=2C=CC=CC=2)=NP(OC=2C=CC=CC=2)(OC=2C=CC=CC=2)=NP=1(OC=1C=CC=CC=1)OC1=CC=CC=C1 RNFJDJUURJAICM-UHFFFAOYSA-N 0.000 abstract 1
- 239000004604 Blowing Agent Substances 0.000 abstract 1
- 239000004593 Epoxy Substances 0.000 abstract 1
- 239000000853 adhesive Substances 0.000 abstract 1
- 230000001070 adhesive effect Effects 0.000 abstract 1
- 239000003795 chemical substances by application Substances 0.000 abstract 1
- 239000003063 flame retardant Substances 0.000 abstract 1
- 239000004850 liquid epoxy resins (LERs) Substances 0.000 abstract 1
- 229920005992 thermoplastic resin Polymers 0.000 abstract 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
- C08J5/00—Manufacture of articles or shaped materials containing macromolecular substances
- C08J5/18—Manufacture of films or sheets
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09J—ADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
- C09J163/00—Adhesives based on epoxy resins; Adhesives based on derivatives of epoxy resins
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
- C08J9/00—Working-up of macromolecular substances to porous or cellular articles or materials; After-treatment thereof
- C08J9/0061—Working-up of macromolecular substances to porous or cellular articles or materials; After-treatment thereof characterized by the use of several polymeric components
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
- C08J9/00—Working-up of macromolecular substances to porous or cellular articles or materials; After-treatment thereof
- C08J9/0066—Use of inorganic compounding ingredients
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
- C08J9/00—Working-up of macromolecular substances to porous or cellular articles or materials; After-treatment thereof
- C08J9/04—Working-up of macromolecular substances to porous or cellular articles or materials; After-treatment thereof using blowing gases generated by a previously added blowing agent
- C08J9/12—Working-up of macromolecular substances to porous or cellular articles or materials; After-treatment thereof using blowing gases generated by a previously added blowing agent by a physical blowing agent
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
- C08J9/00—Working-up of macromolecular substances to porous or cellular articles or materials; After-treatment thereof
- C08J9/32—Working-up of macromolecular substances to porous or cellular articles or materials; After-treatment thereof from compositions containing microballoons, e.g. syntactic foams
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K3/00—Use of inorganic substances as compounding ingredients
- C08K3/02—Elements
- C08K3/04—Carbon
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K3/00—Use of inorganic substances as compounding ingredients
- C08K3/02—Elements
- C08K3/08—Metals
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L63/00—Compositions of epoxy resins; Compositions of derivatives of epoxy resins
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L81/00—Compositions of macromolecular compounds obtained by reactions forming in the main chain of the macromolecule a linkage containing sulfur with or without nitrogen, oxygen or carbon only; Compositions of polysulfones; Compositions of derivatives of such polymers
- C08L81/06—Polysulfones; Polyethersulfones
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09K—MATERIALS FOR MISCELLANEOUS APPLICATIONS, NOT PROVIDED FOR ELSEWHERE
- C09K21/00—Fireproofing materials
- C09K21/02—Inorganic materials
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
- C08J2203/00—Foams characterized by the expanding agent
- C08J2203/22—Expandable microspheres, e.g. Expancel®
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
- C08J2205/00—Foams characterised by their properties
- C08J2205/04—Foams characterised by their properties characterised by the foam pores
- C08J2205/052—Closed cells, i.e. more than 50% of the pores are closed
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
- C08J2363/00—Characterised by the use of epoxy resins; Derivatives of epoxy resins
- C08J2363/02—Polyglycidyl ethers of bis-phenols
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
- C08J2363/00—Characterised by the use of epoxy resins; Derivatives of epoxy resins
- C08J2363/04—Epoxynovolacs
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
- C08J2400/00—Characterised by the use of unspecified polymers
- C08J2400/22—Thermoplastic resins
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
- C08J2400/00—Characterised by the use of unspecified polymers
- C08J2400/26—Elastomers
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
- C08J2463/00—Characterised by the use of epoxy resins; Derivatives of epoxy resins
- C08J2463/02—Polyglycidyl ethers of bis-phenols
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
- C08J2471/00—Characterised by the use of polyethers obtained by reactions forming an ether link in the main chain; Derivatives of such polymers
- C08J2471/08—Polyethers derived from hydroxy compounds or from their metallic derivatives
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
- C08J2481/00—Characterised by the use of macromolecular compounds obtained by reactions forming in the main chain of the macromolecule a linkage containing sulfur with or without nitrogen, oxygen, or carbon only; Polysulfones; Derivatives of such polymers
- C08J2481/06—Polysulfones; Polyethersulfones
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Engineering & Computer Science (AREA)
- Polymers & Plastics (AREA)
- Health & Medical Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Materials Engineering (AREA)
- Manufacturing & Machinery (AREA)
- Inorganic Chemistry (AREA)
- Adhesives Or Adhesive Processes (AREA)
- Manufacture Of Porous Articles, And Recovery And Treatment Of Waste Products (AREA)
- Epoxy Resins (AREA)
- Compositions Of Macromolecular Compounds (AREA)
- Adhesive Tapes (AREA)
Applications Claiming Priority (2)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| US201462036300P | 2014-08-12 | 2014-08-12 | |
| PCT/US2015/044857 WO2016025597A1 (en) | 2014-08-12 | 2015-08-12 | Film adhesive |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| BR112017002766A2 true BR112017002766A2 (pt) | 2017-12-19 |
Family
ID=53969443
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| BR112017002766A BR112017002766A2 (pt) | 2014-08-12 | 2015-08-12 | adesivo para filme |
Country Status (8)
| Country | Link |
|---|---|
| US (1) | US20170218237A1 (enExample) |
| EP (1) | EP3180393B2 (enExample) |
| JP (1) | JP2017530214A (enExample) |
| KR (1) | KR20170041820A (enExample) |
| CN (1) | CN106574100A (enExample) |
| BR (1) | BR112017002766A2 (enExample) |
| CA (1) | CA2957758A1 (enExample) |
| WO (1) | WO2016025597A1 (enExample) |
Families Citing this family (7)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| EP3170877B1 (en) | 2015-11-19 | 2020-11-18 | 3M Innovative Properties Company | Structural adhesive with improved failure mode |
| CN111601860B (zh) * | 2018-02-09 | 2022-12-20 | Dic株式会社 | 胶粘带、物品和物品的制造方法 |
| CA3093194A1 (en) | 2018-03-08 | 2019-09-12 | Zephyros, Inc. | Honeycomb core splice adhesive with improved fire retardancy |
| US12202933B2 (en) | 2018-08-06 | 2025-01-21 | Zephyros, Inc. | High elastic modulus structural foam materials with improved strain to failure |
| CN110211762A (zh) * | 2019-06-05 | 2019-09-06 | 珠海天基探测技术有限公司 | 一种电流互感器柔性软磁铁芯 |
| EP3798255A1 (en) | 2019-09-27 | 2021-03-31 | 3M Innovative Properties Company | Expandable structural adhesive film for dissimilar metal bonding |
| EP4107223A1 (en) | 2020-02-18 | 2022-12-28 | Zephyros Inc. | Low density flame retardant two-component composition for structural void filling |
Family Cites Families (39)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US3574644A (en) | 1965-03-22 | 1971-04-13 | Dow Chemical Co | Method of rendering normally flamable materials flame resistant |
| US4663065A (en) | 1982-09-15 | 1987-05-05 | Hercules Incorporated | Elastomer insulation compositions for rocket motors |
| US4459398A (en) * | 1983-05-27 | 1984-07-10 | General Motors Corporation | High strength one-part epoxy adhesive composition |
| CA2112410C (en) | 1991-06-26 | 2003-12-09 | Norman E. Blank | Reactive hot-melt adhesive |
| DE69224937T2 (de) | 1991-07-01 | 1998-10-22 | Gen Electric | Polycarbonat-Polysiloxan-Blockcopolymere |
| JP3431944B2 (ja) | 1992-03-19 | 2003-07-28 | 東ソー株式会社 | 難燃性ポリオレフィン系樹脂組成物 |
| FR2703689B1 (fr) | 1993-04-09 | 1995-06-16 | Minnesota Mining & Mfg | Composition epoxyde ignifuge pratiquement exempte d'halogene. |
| EP0976780B1 (en) | 1997-01-16 | 2003-06-11 | Sekisui Chemical Co., Ltd. | Fire-resistant sheetlike molding, fire-resistant laminate for covering steel, fire-resistant structure for wall, and method for constructing fire-resistant steel and fire-resistant wall |
| US6451876B1 (en) | 2000-10-10 | 2002-09-17 | Henkel Corporation | Two component thermosettable compositions useful for producing structural reinforcing adhesives |
| US7473715B2 (en) * | 2001-05-02 | 2009-01-06 | Zephyros, Inc. | Two component (epoxy/amine) structural foam-in-place material |
| JP4768938B2 (ja) * | 2001-08-28 | 2011-09-07 | 積水化学工業株式会社 | エポキシ樹脂発泡体 |
| EP1456286B1 (en) | 2001-12-21 | 2012-06-13 | Henkel AG & Co. KGaA | Expandable epoxy resin-based systems modified with thermoplastic polymers |
| US7119149B2 (en) | 2003-01-03 | 2006-10-10 | Henkel Kommanditgesellschaft Auf | High expansion two-component structural foam |
| US7125461B2 (en) * | 2003-05-07 | 2006-10-24 | L & L Products, Inc. | Activatable material for sealing, baffling or reinforcing and method of forming same |
| JP2005133054A (ja) | 2003-10-30 | 2005-05-26 | Nippon Jitsupaa Chiyuubingu Kk | Emi対策製品用のノンハロゲン難燃性を有する合成樹脂組成物及びその塗工方法 |
| EP1616924A1 (en) | 2004-07-13 | 2006-01-18 | Huntsman Advanced Materials (Switzerland) GmbH | Fire retardant composition |
| EP1674518A1 (en) | 2004-12-23 | 2006-06-28 | 3M Innovative Properties Company | Fire-retardant low-density epoxy composition |
| JP2006225544A (ja) * | 2005-02-18 | 2006-08-31 | Nagase Chemtex Corp | エポキシ樹脂接着剤 |
| US20070104958A1 (en) | 2005-08-24 | 2007-05-10 | Dow Global Technologies, Inc. | Epoxy based reinforcing patches with encapsulated physical blowing agents |
| JP4826729B2 (ja) * | 2005-10-17 | 2011-11-30 | 株式会社スリーボンド | 加熱膨張性シート状接着剤組成物 |
| GB0610695D0 (en) | 2006-05-31 | 2006-07-12 | L & L Products Inc | Improvements in or relating to honeycomb structures |
| CA2665551A1 (en) | 2006-10-06 | 2008-04-17 | Henkel Ag & Co. Kgaa | Pumpable epoxy paste adhesives resistant to wash-off |
| US8097119B2 (en) | 2007-04-11 | 2012-01-17 | Dow Global Technologies Llc | Heat-resistant structural epoxy resins |
| PT2160435E (pt) | 2007-06-12 | 2012-02-08 | Zephyros Inc | Material adesivo endurecido |
| EP2205692B1 (en) | 2007-10-30 | 2020-02-19 | Henkel AG & Co. KGaA | Epoxy paste adhesives resistant to wash-off |
| EP2256163B1 (en) * | 2008-03-25 | 2018-11-14 | Toray Industries, Inc. | Epoxy resin composition, fiber-reinforced composite material and method for producing the same |
| GB0806434D0 (en) | 2008-04-09 | 2008-05-14 | Zephyros Inc | Improvements in or relating to structural adhesives |
| US7763350B2 (en) | 2008-07-01 | 2010-07-27 | Ppg Industries Ohio, Inc. | Coated articles demonstrating heat reduction and noise reduction properties |
| US20100004369A1 (en) † | 2008-07-01 | 2010-01-07 | Ppg Industries Ohio, Inc. | Low density viscoelastic composition having damping properties |
| CN102177013B (zh) | 2008-07-29 | 2014-07-23 | 陶氏环球技术有限责任公司 | 用于汽车空腔中的加强和能量耗散的增韧可膨胀环氧树脂 |
| GB0905362D0 (en) | 2009-03-30 | 2009-05-13 | 3M Innovative Properties Co | Fire resistant epoxy resin based core filler material developing low exothermic heat |
| DE102009026548A1 (de) * | 2009-05-28 | 2011-03-24 | Henkel Ag & Co. Kgaa | Klebefolie oder Klebeband auf Basis von Epoxiden |
| DE102009046157A1 (de) | 2009-10-29 | 2011-05-05 | Henkel Ag & Co. Kgaa | Vormischung und Verfahren zur Herstellung einer thermisch expandierbaren und härtbaren Epoxid-basierten Masse |
| DE102010028586A1 (de) | 2010-05-05 | 2011-11-10 | Henkel Ag & Co. Kgaa | 1K-Epoxidharzzusammensetzung mit verringerter Toxizität |
| GB201007793D0 (en) | 2010-05-10 | 2010-06-23 | Zephyros Inc | Improvements in or relating to structural adhesives |
| GB201102672D0 (en) | 2011-02-15 | 2011-03-30 | Zephyros Inc | Improved structural adhesives |
| CN104136516B (zh) | 2012-03-23 | 2016-06-01 | 陶氏环球技术有限责任公司 | 阻燃结构环氧树脂粘合剂以及粘合金属构件的方法 |
| ES2588362T3 (es) * | 2012-08-23 | 2016-11-02 | 3M Innovative Properties Company | Película adhesiva estructural |
| EP2727664B1 (en) | 2012-11-05 | 2015-06-10 | 3M Innovative Properties Company | Method for making a hemmed structure of metal panels |
-
2015
- 2015-08-12 WO PCT/US2015/044857 patent/WO2016025597A1/en not_active Ceased
- 2015-08-12 KR KR1020177006306A patent/KR20170041820A/ko not_active Withdrawn
- 2015-08-12 EP EP15754082.4A patent/EP3180393B2/en active Active
- 2015-08-12 BR BR112017002766A patent/BR112017002766A2/pt not_active Application Discontinuation
- 2015-08-12 CN CN201580042028.4A patent/CN106574100A/zh active Pending
- 2015-08-12 US US15/500,703 patent/US20170218237A1/en not_active Abandoned
- 2015-08-12 CA CA2957758A patent/CA2957758A1/en not_active Abandoned
- 2015-08-12 JP JP2017507790A patent/JP2017530214A/ja active Pending
Also Published As
| Publication number | Publication date |
|---|---|
| EP3180393A1 (en) | 2017-06-21 |
| WO2016025597A1 (en) | 2016-02-18 |
| EP3180393B2 (en) | 2024-10-16 |
| CA2957758A1 (en) | 2016-02-18 |
| JP2017530214A (ja) | 2017-10-12 |
| CN106574100A (zh) | 2017-04-19 |
| KR20170041820A (ko) | 2017-04-17 |
| EP3180393B1 (en) | 2021-09-29 |
| US20170218237A1 (en) | 2017-08-03 |
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Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| B06U | Preliminary requirement: requests with searches performed by other patent offices: procedure suspended [chapter 6.21 patent gazette] | ||
| B11B | Dismissal acc. art. 36, par 1 of ipl - no reply within 90 days to fullfil the necessary requirements |