BR112013023877A2 - catalisador, utilizável em hidrotratamento, compreendendo metais dos grupos viii e vib e preparo com o ácido cítrico e succinato de dialquila c1-c4 - Google Patents

catalisador, utilizável em hidrotratamento, compreendendo metais dos grupos viii e vib e preparo com o ácido cítrico e succinato de dialquila c1-c4

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Publication number
BR112013023877A2
BR112013023877A2 BR112013023877A BR112013023877A BR112013023877A2 BR 112013023877 A2 BR112013023877 A2 BR 112013023877A2 BR 112013023877 A BR112013023877 A BR 112013023877A BR 112013023877 A BR112013023877 A BR 112013023877A BR 112013023877 A2 BR112013023877 A2 BR 112013023877A2
Authority
BR
Brazil
Prior art keywords
catalyst
citric acid
dialkyl succinate
hydrotreating
vib
Prior art date
Application number
BR112013023877A
Other languages
English (en)
Other versions
BR112013023877B1 (pt
Inventor
Bertrand Guichard
Delphine Minoux
Jean-Pierre Dath
Laurent Simon
Valentina De Grandi
Original Assignee
IFP Energies Nouvelles
Total Raffinage Marketing
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by IFP Energies Nouvelles, Total Raffinage Marketing filed Critical IFP Energies Nouvelles
Publication of BR112013023877A2 publication Critical patent/BR112013023877A2/pt
Publication of BR112013023877B1 publication Critical patent/BR112013023877B1/pt

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    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
    • B01J31/26—Catalysts comprising hydrides, coordination complexes or organic compounds containing in addition, inorganic metal compounds not provided for in groups B01J31/02 - B01J31/24
    • B01J31/34—Catalysts comprising hydrides, coordination complexes or organic compounds containing in addition, inorganic metal compounds not provided for in groups B01J31/02 - B01J31/24 of chromium, molybdenum or tungsten
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B01J23/70—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper
    • B01J23/76—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper combined with metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36
    • B01J23/84—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper combined with metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36 with arsenic, antimony, bismuth, vanadium, niobium, tantalum, polonium, chromium, molybdenum, tungsten, manganese, technetium or rhenium
    • B01J23/85—Chromium, molybdenum or tungsten
    • B—PERFORMING OPERATIONS; TRANSPORTING
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    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
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    • B01J23/76—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper combined with metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36
    • B01J23/84—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper combined with metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36 with arsenic, antimony, bismuth, vanadium, niobium, tantalum, polonium, chromium, molybdenum, tungsten, manganese, technetium or rhenium
    • B01J23/85—Chromium, molybdenum or tungsten
    • B01J23/88—Molybdenum
    • B01J23/882—Molybdenum and cobalt
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    • B01J23/76—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper combined with metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36
    • B01J23/84—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper combined with metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36 with arsenic, antimony, bismuth, vanadium, niobium, tantalum, polonium, chromium, molybdenum, tungsten, manganese, technetium or rhenium
    • B01J23/85—Chromium, molybdenum or tungsten
    • B01J23/88—Molybdenum
    • B01J23/883—Molybdenum and nickel
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    • B01J23/90—Regeneration or reactivation
    • B01J23/94—Regeneration or reactivation of catalysts comprising metals, oxides or hydroxides of the iron group metals or copper
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    • B01J38/00—Regeneration or reactivation of catalysts, in general
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    • B01J38/50—Liquid treating or treating in liquid phase, e.g. dissolved or suspended using organic liquids
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    • C10G45/12—Refining of hydrocarbon oils using hydrogen or hydrogen-generating compounds to eliminate hetero atoms without changing the skeleton of the hydrocarbon involved and without cracking into lower boiling hydrocarbons; Hydrofinishing characterised by the catalyst used containing crystalline alumino-silicates, e.g. molecular sieves
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    • C10G2300/1037—Hydrocarbon fractions
    • C10G2300/1048—Middle distillates
    • C10G2300/1055—Diesel having a boiling range of about 230 - 330 °C
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
    • C10G2300/00—Aspects relating to hydrocarbon processing covered by groups C10G1/00 - C10G99/00
    • C10G2300/20—Characteristics of the feedstock or the products
    • C10G2300/201—Impurities
    • C10G2300/202—Heteroatoms content, i.e. S, N, O, P

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  • Chemical & Material Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Organic Chemistry (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • Materials Engineering (AREA)
  • General Chemical & Material Sciences (AREA)
  • Crystallography & Structural Chemistry (AREA)
  • Inorganic Chemistry (AREA)
  • Catalysts (AREA)
  • Production Of Liquid Hydrocarbon Mixture For Refining Petroleum (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)

Abstract

resumo patente de invenção: "catalisador, utilizável em hidrotratamento, compreendendo metais dos grupos viii e vib e preparo com o ácido cítrico e succinato de dialquila c1-c4". a presente invenção refere-se a um catalisador que compreende um suporte amorfo à base de alumina, um succinato de dialquila c1-c4, o ácido cítrico e eventualmente o ácido acético, o fósforo e uma função hidrodesidrogenante, compreendendo pelo menos um elemento do grupo viii e pelo menos um elemento do grupo vtb, catalisador, cujo espectro raman compreende as faixas as mais intensas características dos heterpopoliânions de keggin (974 e/ou 990 cm-1), o succinato de dialquila c1-c4 e o ácido cítrico (notadamente 785 e 956 cm-1). a invenção se refere também ao processo de preparo desse catalisador no qual um precursor catalítico no estado seco, calcinado ou regenerado contendo os elementos da função hidrodesidrogenante, eventualmente o fósforo, é impregnado por uma solução de impregnação, compreendendo pelo menos um succinato de dialquila c1-c4, o ácido cítrico, e, eventualmente pelo menos um composto de fósforo e eventualmente o ácido acético, depois é secado. a invenção se refere também à utilização desse catalisador em qualquer processo de hidrotratamento.
BR112013023877-1A 2011-03-18 2012-02-10 Catalisador, processos de preparo do mesmo e de hidrotratamento de cargas hidrocarbonadas BR112013023877B1 (pt)

Applications Claiming Priority (3)

Application Number Priority Date Filing Date Title
EP11/00.840 2011-03-18
FR1100840A FR2972648B1 (fr) 2011-03-18 2011-03-18 Catalyseur utilisable en hydrotraitement comprenant des metaux des groupes viii et vib et preparation avec de l'acide citrique et du succinate de dialkyle c1-c4
PCT/FR2012/000052 WO2012127128A1 (fr) 2011-03-18 2012-02-10 Catalyseur utilisable en hydrotraitement comprenant des metaux des groupes viii et vib et preparation avec de l'acide citrique et du succinate de dialkyle c1-c4

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BR112013023877A2 true BR112013023877A2 (pt) 2016-12-13
BR112013023877B1 BR112013023877B1 (pt) 2019-07-02

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BR (1) BR112013023877B1 (pt)
CA (1) CA2825958C (pt)
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FR (1) FR2972648B1 (pt)
WO (1) WO2012127128A1 (pt)
ZA (1) ZA201305844B (pt)

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CN103501902B (zh) 2017-10-27
FR2972648B1 (fr) 2013-04-26
DK2686105T3 (en) 2017-03-27
CA2825958C (fr) 2019-04-02
BR112013023877B1 (pt) 2019-07-02
US11351529B2 (en) 2022-06-07
CN103501902A (zh) 2014-01-08
EP2686105A1 (fr) 2014-01-22
EP2686105B1 (fr) 2016-12-14
FR2972648A1 (fr) 2012-09-21
WO2012127128A1 (fr) 2012-09-27
RU2013146532A (ru) 2015-04-27
JP5933684B2 (ja) 2016-06-15
JP2014514142A (ja) 2014-06-19
WO2012127128A8 (fr) 2013-09-12
CA2825958A1 (fr) 2012-09-27
ZA201305844B (en) 2014-04-30
US20140076780A1 (en) 2014-03-20

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