BR112013002329A2 - catalisadores de metátese estáveis e altamente ajustáveis - Google Patents

catalisadores de metátese estáveis e altamente ajustáveis

Info

Publication number
BR112013002329A2
BR112013002329A2 BR112013002329A BR112013002329A BR112013002329A2 BR 112013002329 A2 BR112013002329 A2 BR 112013002329A2 BR 112013002329 A BR112013002329 A BR 112013002329A BR 112013002329 A BR112013002329 A BR 112013002329A BR 112013002329 A2 BR112013002329 A2 BR 112013002329A2
Authority
BR
Brazil
Prior art keywords
highly adjustable
stable
present
metathesis catalysts
catalysts
Prior art date
Application number
BR112013002329A
Other languages
English (en)
Inventor
Christophe Crevisy
Frederic Caijo
Marc Maudut
Original Assignee
Centre Nat Rech Scient
Ecole Nationale Superieure De Chimie De Rennes
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Centre Nat Rech Scient, Ecole Nationale Superieure De Chimie De Rennes filed Critical Centre Nat Rech Scient
Publication of BR112013002329A2 publication Critical patent/BR112013002329A2/pt

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07F—ACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
    • C07F15/00—Compounds containing elements of Groups 8, 9, 10 or 18 of the Periodic Table
    • C07F15/0006—Compounds containing elements of Groups 8, 9, 10 or 18 of the Periodic Table compounds of the platinum group
    • C07F15/0046—Ruthenium compounds
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
    • B01J31/02—Catalysts comprising hydrides, coordination complexes or organic compounds containing organic compounds or metal hydrides
    • B01J31/12—Catalysts comprising hydrides, coordination complexes or organic compounds containing organic compounds or metal hydrides containing organo-metallic compounds or metal hydrides
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
    • B01J31/16—Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes
    • B01J31/22—Organic complexes
    • B01J31/2204—Organic complexes the ligands containing oxygen or sulfur as complexing atoms
    • B01J31/2208—Oxygen, e.g. acetylacetonates
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
    • B01J31/16—Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes
    • B01J31/22—Organic complexes
    • B01J31/2265—Carbenes or carbynes, i.e.(image)
    • B01J31/2269—Heterocyclic carbenes
    • B01J31/2273—Heterocyclic carbenes with only nitrogen as heteroatomic ring members, e.g. 1,3-diarylimidazoline-2-ylidenes
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
    • B01J31/16—Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes
    • B01J31/22—Organic complexes
    • B01J31/2265—Carbenes or carbynes, i.e.(image)
    • B01J31/2278—Complexes comprising two carbene ligands differing from each other, e.g. Grubbs second generation catalysts
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C67/00—Preparation of carboxylic acid esters
    • C07C67/30—Preparation of carboxylic acid esters by modifying the acid moiety of the ester, such modification not being an introduction of an ester group
    • C07C67/333—Preparation of carboxylic acid esters by modifying the acid moiety of the ester, such modification not being an introduction of an ester group by isomerisation; by change of size of the carbon skeleton
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07D—HETEROCYCLIC COMPOUNDS
    • C07D207/00—Heterocyclic compounds containing five-membered rings not condensed with other rings, with one nitrogen atom as the only ring hetero atom
    • C07D207/02—Heterocyclic compounds containing five-membered rings not condensed with other rings, with one nitrogen atom as the only ring hetero atom with only hydrogen or carbon atoms directly attached to the ring nitrogen atom
    • C07D207/18—Heterocyclic compounds containing five-membered rings not condensed with other rings, with one nitrogen atom as the only ring hetero atom with only hydrogen or carbon atoms directly attached to the ring nitrogen atom having one double bond between ring members or between a ring member and a non-ring member
    • C07D207/20—Heterocyclic compounds containing five-membered rings not condensed with other rings, with one nitrogen atom as the only ring hetero atom with only hydrogen or carbon atoms directly attached to the ring nitrogen atom having one double bond between ring members or between a ring member and a non-ring member with only hydrogen atoms, hydrocarbon or substituted hydrocarbon radicals, directly attached to ring carbon atoms
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2231/00—Catalytic reactions performed with catalysts classified in B01J31/00
    • B01J2231/50—Redistribution or isomerisation reactions of C-C, C=C or C-C triple bonds
    • B01J2231/54—Metathesis reactions, e.g. olefin metathesis
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2531/00—Additional information regarding catalytic systems classified in B01J31/00
    • B01J2531/80—Complexes comprising metals of Group VIII as the central metal
    • B01J2531/82—Metals of the platinum group
    • B01J2531/821—Ruthenium

Landscapes

  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Inorganic Chemistry (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
  • Catalysts (AREA)
  • Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)

Abstract

catalisadores de metátese estáveis e altamente ajustáveis. a presente invenção refere-se a compostos cataliticamente ativos da fórmula geral (1) que são altamente ajustáveis, bem como a um método para sua preparação e sua utilização em qualquer tipo de reação de metátese. os novos compostos da presente invenção compreendem sítios de ativação que possibilitam uma concepção de catalisador específico. em particular, cadeias laterais e ligantes possibilitam atividades eficaz e um controle da especificidade dos catalisadores da presente invenção.
BR112013002329A 2010-07-30 2010-07-30 catalisadores de metátese estáveis e altamente ajustáveis BR112013002329A2 (pt)

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
PCT/EP2010/004668 WO2012013208A1 (en) 2010-07-30 2010-07-30 Novel stable and highly tunable metathesis catalysts

Publications (1)

Publication Number Publication Date
BR112013002329A2 true BR112013002329A2 (pt) 2016-05-24

Family

ID=42797431

Family Applications (1)

Application Number Title Priority Date Filing Date
BR112013002329A BR112013002329A2 (pt) 2010-07-30 2010-07-30 catalisadores de metátese estáveis e altamente ajustáveis

Country Status (7)

Country Link
US (1) US8835628B2 (pt)
EP (1) EP2598511B1 (pt)
JP (1) JP2013532667A (pt)
CN (1) CN103221417A (pt)
BR (1) BR112013002329A2 (pt)
CA (1) CA2806754C (pt)
WO (1) WO2012013208A1 (pt)

Families Citing this family (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN104169322B (zh) * 2012-03-16 2016-08-31 日本瑞翁株式会社 开环易位聚合物氢化物的制造方法及树脂组合物
FR3063290A1 (fr) 2017-02-24 2018-08-31 Stratoz Procede de synthese de pheromones
EP3720885B1 (de) * 2017-12-08 2021-12-01 ARLANXEO Deutschland GmbH Verfahren zur herstellung von nitrilkautschuken mit ruthenium-komplexkatalysatoren
JP7417554B2 (ja) 2018-07-23 2024-01-18 アランセオ・ドイチュランド・ゲーエムベーハー ニトリルゴムをメタセシスするための触媒の使用

Family Cites Families (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
AU8477301A (en) 2000-08-10 2002-02-25 Trustees Boston College Recyclable metathesis catalysts
PL199412B1 (pl) 2002-10-15 2008-09-30 Boehringer Ingelheim Int Nowe kompleksy rutenu jako (pre)katalizatory reakcji metatezy, pochodne 2-alkoksy-5-nitrostyrenu jako związki pośrednie i sposób ich wytwarzania
EP2886549A1 (en) 2005-07-04 2015-06-24 Zannan Scitech Co., Ltd. Ruthenium complex ligand, ruthenium complex and the use of the complex as a catalyst in olefin metathesis reactions
DE102006043704A1 (de) 2006-09-18 2008-03-27 Umicore Ag & Co. Kg Neue Metathesekatalysatoren
CN106083579A (zh) * 2006-10-13 2016-11-09 埃莱文斯可更新科学公司 通过烯烃复分解由内烯烃合成末端烯烃的方法
FR2909382B1 (fr) 2006-11-30 2009-01-23 Enscr Complexes catalytiques a base de ruthenium et utilisation de tels complexes pour la metathese d'olefines

Also Published As

Publication number Publication date
EP2598511B1 (en) 2018-07-04
US8835628B2 (en) 2014-09-16
JP2013532667A (ja) 2013-08-19
EP2598511A1 (en) 2013-06-05
US20130197218A1 (en) 2013-08-01
WO2012013208A8 (en) 2012-03-22
CA2806754C (en) 2020-04-07
CN103221417A (zh) 2013-07-24
CA2806754A1 (en) 2012-02-02
WO2012013208A1 (en) 2012-02-02

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Legal Events

Date Code Title Description
B11A Dismissal acc. art.33 of ipl - examination not requested within 36 months of filing
B11Y Definitive dismissal - extension of time limit for request of examination expired [chapter 11.1.1 patent gazette]