BR112012029584A2 - polímeros conjugados multicoloridos com estado oxidado altamente transmissivo. - Google Patents

polímeros conjugados multicoloridos com estado oxidado altamente transmissivo.

Info

Publication number
BR112012029584A2
BR112012029584A2 BR112012029584A BR112012029584A BR112012029584A2 BR 112012029584 A2 BR112012029584 A2 BR 112012029584A2 BR 112012029584 A BR112012029584 A BR 112012029584A BR 112012029584 A BR112012029584 A BR 112012029584A BR 112012029584 A2 BR112012029584 A2 BR 112012029584A2
Authority
BR
Brazil
Prior art keywords
units
oxidized state
highly transmissive
multicolored
unit
Prior art date
Application number
BR112012029584A
Other languages
English (en)
Inventor
Martin Amb Chad
Mei Jianguo
R Reynolds John
Shi Pengjie
Original Assignee
Univ Florida
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Univ Florida filed Critical Univ Florida
Publication of BR112012029584A2 publication Critical patent/BR112012029584A2/pt

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    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G61/00—Macromolecular compounds obtained by reactions forming a carbon-to-carbon link in the main chain of the macromolecule
    • C08G61/12—Macromolecular compounds containing atoms other than carbon in the main chain of the macromolecule
    • C08G61/122—Macromolecular compounds containing atoms other than carbon in the main chain of the macromolecule derived from five- or six-membered heterocyclic compounds, other than imides
    • C08G61/123—Macromolecular compounds containing atoms other than carbon in the main chain of the macromolecule derived from five- or six-membered heterocyclic compounds, other than imides derived from five-membered heterocyclic compounds
    • C08G61/126—Macromolecular compounds containing atoms other than carbon in the main chain of the macromolecule derived from five- or six-membered heterocyclic compounds, other than imides derived from five-membered heterocyclic compounds with a five-membered ring containing one sulfur atom in the ring
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G61/00—Macromolecular compounds obtained by reactions forming a carbon-to-carbon link in the main chain of the macromolecule
    • C08G61/12—Macromolecular compounds containing atoms other than carbon in the main chain of the macromolecule
    • C08G61/122—Macromolecular compounds containing atoms other than carbon in the main chain of the macromolecule derived from five- or six-membered heterocyclic compounds, other than imides
    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09K—MATERIALS FOR MISCELLANEOUS APPLICATIONS, NOT PROVIDED FOR ELSEWHERE
    • C09K9/00—Tenebrescent materials, i.e. materials for which the range of wavelengths for energy absorption is changed as a result of excitation by some form of energy
    • C09K9/02—Organic tenebrescent materials
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G2261/00—Macromolecular compounds obtained by reactions forming a carbon-to-carbon link in the main chain of the macromolecule
    • C08G2261/10—Definition of the polymer structure
    • C08G2261/12—Copolymers
    • C08G2261/122—Copolymers statistical
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G2261/00—Macromolecular compounds obtained by reactions forming a carbon-to-carbon link in the main chain of the macromolecule
    • C08G2261/10—Definition of the polymer structure
    • C08G2261/14—Side-groups
    • C08G2261/142—Side-chains containing oxygen
    • C08G2261/1424—Side-chains containing oxygen containing ether groups, including alkoxy
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G2261/00—Macromolecular compounds obtained by reactions forming a carbon-to-carbon link in the main chain of the macromolecule
    • C08G2261/30—Monomer units or repeat units incorporating structural elements in the main chain
    • C08G2261/32—Monomer units or repeat units incorporating structural elements in the main chain incorporating heteroaromatic structural elements in the main chain
    • C08G2261/322—Monomer units or repeat units incorporating structural elements in the main chain incorporating heteroaromatic structural elements in the main chain non-condensed
    • C08G2261/3223—Monomer units or repeat units incorporating structural elements in the main chain incorporating heteroaromatic structural elements in the main chain non-condensed containing one or more sulfur atoms as the only heteroatom, e.g. thiophene
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G2261/00—Macromolecular compounds obtained by reactions forming a carbon-to-carbon link in the main chain of the macromolecule
    • C08G2261/30—Monomer units or repeat units incorporating structural elements in the main chain
    • C08G2261/32—Monomer units or repeat units incorporating structural elements in the main chain incorporating heteroaromatic structural elements in the main chain
    • C08G2261/324—Monomer units or repeat units incorporating structural elements in the main chain incorporating heteroaromatic structural elements in the main chain condensed
    • C08G2261/3246—Monomer units or repeat units incorporating structural elements in the main chain incorporating heteroaromatic structural elements in the main chain condensed containing nitrogen and sulfur as heteroatoms
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G2261/00—Macromolecular compounds obtained by reactions forming a carbon-to-carbon link in the main chain of the macromolecule
    • C08G2261/40—Polymerisation processes
    • C08G2261/41—Organometallic coupling reactions
    • C08G2261/414—Stille reactions
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G2261/00—Macromolecular compounds obtained by reactions forming a carbon-to-carbon link in the main chain of the macromolecule
    • C08G2261/50—Physical properties
    • C08G2261/54—Physical properties electrochromatic
    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09K—MATERIALS FOR MISCELLANEOUS APPLICATIONS, NOT PROVIDED FOR ELSEWHERE
    • C09K2211/00—Chemical nature of organic luminescent or tenebrescent compounds
    • C09K2211/14—Macromolecular compounds
    • C09K2211/1441—Heterocyclic
    • C09K2211/1458—Heterocyclic containing sulfur as the only heteroatom
    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09K—MATERIALS FOR MISCELLANEOUS APPLICATIONS, NOT PROVIDED FOR ELSEWHERE
    • C09K2211/00—Chemical nature of organic luminescent or tenebrescent compounds
    • C09K2211/14—Macromolecular compounds
    • C09K2211/1441—Heterocyclic
    • C09K2211/1491—Heterocyclic containing other combinations of heteroatoms
    • G—PHYSICS
    • G02—OPTICS
    • G02F—OPTICAL DEVICES OR ARRANGEMENTS FOR THE CONTROL OF LIGHT BY MODIFICATION OF THE OPTICAL PROPERTIES OF THE MEDIA OF THE ELEMENTS INVOLVED THEREIN; NON-LINEAR OPTICS; FREQUENCY-CHANGING OF LIGHT; OPTICAL LOGIC ELEMENTS; OPTICAL ANALOGUE/DIGITAL CONVERTERS
    • G02F1/00—Devices or arrangements for the control of the intensity, colour, phase, polarisation or direction of light arriving from an independent light source, e.g. switching, gating or modulating; Non-linear optics
    • G02F1/01—Devices or arrangements for the control of the intensity, colour, phase, polarisation or direction of light arriving from an independent light source, e.g. switching, gating or modulating; Non-linear optics for the control of the intensity, phase, polarisation or colour 
    • G02F1/15—Devices or arrangements for the control of the intensity, colour, phase, polarisation or direction of light arriving from an independent light source, e.g. switching, gating or modulating; Non-linear optics for the control of the intensity, phase, polarisation or colour  based on an electrochromic effect
    • G02F1/1514—Devices or arrangements for the control of the intensity, colour, phase, polarisation or direction of light arriving from an independent light source, e.g. switching, gating or modulating; Non-linear optics for the control of the intensity, phase, polarisation or colour  based on an electrochromic effect characterised by the electrochromic material, e.g. by the electrodeposited material
    • G02F1/1516—Devices or arrangements for the control of the intensity, colour, phase, polarisation or direction of light arriving from an independent light source, e.g. switching, gating or modulating; Non-linear optics for the control of the intensity, phase, polarisation or colour  based on an electrochromic effect characterised by the electrochromic material, e.g. by the electrodeposited material comprising organic material
    • G02F1/15165—Polymers
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02E—REDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
    • Y02E10/00—Energy generation through renewable energy sources
    • Y02E10/50—Photovoltaic [PV] energy
    • Y02E10/549—Organic PV cells

Landscapes

  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Health & Medical Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Polyoxymethylene Polymers And Polymers With Carbon-To-Carbon Bonds (AREA)

Abstract

polímeros conjugados multicoloridos com estado oxidado altamente transmissivo. a presente invenção refere-se a copolímeros conjugados randômicos compreendendo uma pluralidade de uma ou mais unidades de repetição doadoras diferentes (d) e uma pluralidade de pelo menos uma unidade de repetição aceptora (a). pelo menos uma das unidades d tem um substituintes solubilizante, estatisticamente uma porção de unidades a de repetição que são separadas entre si somente por uma unidade d e uma pluralidade de unidade a é adjacente a um as unidades d que têm os substituintes solubilizam. os copolímeros conjugados randômicos são pretos ou coloridos no estado neutro e altamente transmissivos no estado oxidado. os copolímeros conjugados randômicos têm estrutura -[(d)~ x~a]~ n~-, em que x > 1 e n (x+1) <242> 10 ou estrutura -[(da)~ x~-(d<39> a<39>)~ y~]~ n~-, em que d representa aquela unidade d substituída e d<39> representa outras unidades d e em que x <242> 1, y <242> 1 e 2n (x+y) <242> 10. outras modalidades da invenção são dirigidas à formação de copolímeros conjugados randômicos -[(d)~ x~a]~ n~- ou -[(da)~ x~-(d<39> a<39>)~ y~]~ n~- por polimerização de condensação entre monômeros contendo grupos reativos complementares.
BR112012029584A 2010-05-21 2011-05-19 polímeros conjugados multicoloridos com estado oxidado altamente transmissivo. BR112012029584A2 (pt)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
US34709110P 2010-05-21 2010-05-21
PCT/US2011/037138 WO2012021195A2 (en) 2010-05-21 2011-05-19 Multi-colored conjugated polymers with highly transmissive oxidized state

Publications (1)

Publication Number Publication Date
BR112012029584A2 true BR112012029584A2 (pt) 2019-09-24

Family

ID=44973012

Family Applications (1)

Application Number Title Priority Date Filing Date
BR112012029584A BR112012029584A2 (pt) 2010-05-21 2011-05-19 polímeros conjugados multicoloridos com estado oxidado altamente transmissivo.

Country Status (8)

Country Link
US (1) US8450449B2 (pt)
EP (1) EP2571920A4 (pt)
JP (1) JP5748843B2 (pt)
CN (1) CN102906153A (pt)
BR (1) BR112012029584A2 (pt)
CA (1) CA2797406C (pt)
RU (1) RU2012151578A (pt)
WO (1) WO2012021195A2 (pt)

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US9893294B2 (en) 2010-11-22 2018-02-13 The Regents Of The University Of California Organic small molecule semiconducting chromophores for use in organic electronic devices
KR101259865B1 (ko) * 2011-11-21 2013-05-02 광주과학기술원 저밴드갭의 공중합체 및 이의 제조방법
WO2014018472A1 (en) * 2012-07-23 2014-01-30 The University Of Connecticut Electrochromic copolymers from precursors, method of making, and use thereof
US10323178B2 (en) 2014-05-16 2019-06-18 The University Of Connecticut Color tuning of electrochromic devices using an organic dye
WO2016081787A2 (en) 2014-11-19 2016-05-26 Biltmore Technologies, Inc. Controlled color and opacity-changing coating system
CN105504233B (zh) * 2016-01-04 2018-09-07 京东方科技集团股份有限公司 电致变色聚合物及其制备方法和包含其的组件
US9975989B2 (en) * 2016-05-04 2018-05-22 Furcifer Inc. Multicolored electrochromic polymer compositions and methods of making and using the same
CN107880253B (zh) * 2017-11-23 2019-09-20 深圳市光羿科技有限公司 一种黑色电致变色高分子材料及其制备方法和应用
JP7238793B2 (ja) * 2017-12-25 2023-03-14 株式会社レゾナック 固体電解コンデンサ製造用分散液組成物及び固体電解コンデンサの製造方法
CN111217990A (zh) * 2020-01-20 2020-06-02 西安交通大学 基于不同取代吡嗪受体单元的d-a共聚物给体材料及应用
CN117280279A (zh) * 2021-10-14 2023-12-22 安比莱特 含有吡咯衍生物和噻吩的电致变色聚合物
US11879098B2 (en) 2022-02-09 2024-01-23 Ambilight Inc. High transparency electrochromic polymers
US11874578B2 (en) 2022-02-09 2024-01-16 Ambilight Inc. High transparency electrochromic polymers
US20230257504A1 (en) * 2022-02-16 2023-08-17 Gentex Corporation Electrochromic block copolymers and devices made with such copolymers

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US7256923B2 (en) * 2001-06-25 2007-08-14 University Of Washington Switchable window based on electrochromic polymers
ES2382652T3 (es) * 2001-11-21 2012-06-12 University Of Florida Polímeros electrocrómicos y dispositivos electrocrómicos poliméricos
WO2007008978A2 (en) * 2005-07-11 2007-01-18 University Of Connecticut Electrochromic devices utilizing very low band gap conjugated polymers: preparation and use
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Also Published As

Publication number Publication date
JP2013526648A (ja) 2013-06-24
EP2571920A4 (en) 2014-01-29
CA2797406C (en) 2018-06-26
WO2012021195A3 (en) 2012-04-26
CN102906153A (zh) 2013-01-30
JP5748843B2 (ja) 2015-07-15
CA2797406A1 (en) 2012-02-16
US8450449B2 (en) 2013-05-28
RU2012151578A (ru) 2014-06-27
US20110288253A1 (en) 2011-11-24
WO2012021195A2 (en) 2012-02-16
EP2571920A2 (en) 2013-03-27

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Legal Events

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B08F Application dismissed because of non-payment of annual fees [chapter 8.6 patent gazette]
B08K Patent lapsed as no evidence of payment of the annual fee has been furnished to inpi [chapter 8.11 patent gazette]

Free format text: EM VIRTUDE DO ARQUIVAMENTO PUBLICADO NA RPI 2543 DE 01-10-2019 E CONSIDERANDO AUSENCIA DE MANIFESTACAO DENTRO DOS PRAZOS LEGAIS, INFORMO QUE CABE SER MANTIDO O ARQUIVAMENTO DO PEDIDO DE PATENTE, CONFORME O DISPOSTO NO ARTIGO 12, DA RESOLUCAO 113/2013.