BR112012015563A2 - "EMULSIFICATION OF HYDROCARBON GAS OILS TO INCREASE THE EFFECTIVENESS OF WATER-BASED HYDROGEN SULPHIDE scavengers" - Google Patents

"EMULSIFICATION OF HYDROCARBON GAS OILS TO INCREASE THE EFFECTIVENESS OF WATER-BASED HYDROGEN SULPHIDE scavengers"

Info

Publication number
BR112012015563A2
BR112012015563A2 BR112012015563A BR112012015563A BR112012015563A2 BR 112012015563 A2 BR112012015563 A2 BR 112012015563A2 BR 112012015563 A BR112012015563 A BR 112012015563A BR 112012015563 A BR112012015563 A BR 112012015563A BR 112012015563 A2 BR112012015563 A2 BR 112012015563A2
Authority
BR
Brazil
Prior art keywords
water
hydrogen sulphide
emulsification
effectiveness
increase
Prior art date
Application number
BR112012015563A
Other languages
Portuguese (pt)
Inventor
John Karas Larry
Anderson Craig
Original Assignee
General Eletric Company
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by General Eletric Company filed Critical General Eletric Company
Publication of BR112012015563A2 publication Critical patent/BR112012015563A2/en

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
    • C10G29/00—Refining of hydrocarbon oils, in the absence of hydrogen, with other chemicals
    • C10G29/20—Organic compounds not containing metal atoms
    • C10G29/22—Organic compounds not containing metal atoms containing oxygen as the only hetero atom
    • C10G29/24—Aldehydes or ketones
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01F—MIXING, e.g. DISSOLVING, EMULSIFYING OR DISPERSING
    • B01F23/00—Mixing according to the phases to be mixed, e.g. dispersing or emulsifying
    • B01F23/40—Mixing liquids with liquids; Emulsifying
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
    • C10G2300/00—Aspects relating to hydrocarbon processing covered by groups C10G1/00 - C10G99/00
    • C10G2300/20—Characteristics of the feedstock or the products
    • C10G2300/201—Impurities
    • C10G2300/207—Acid gases, e.g. H2S, COS, SO2, HCN
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
    • C10G2300/00—Aspects relating to hydrocarbon processing covered by groups C10G1/00 - C10G99/00
    • C10G2300/40—Characteristics of the process deviating from typical ways of processing
    • C10G2300/4075—Limiting deterioration of equipment

Abstract

MÉTODO PARA REMOVER SULFETO DE HIDROGÊNIO. A presente invenção refere-se a um processo de sequestro de sulfeto de hidrogênio para óleo pesado que reduz o sulfeto de hidrogênio enquanto minimiza a corrosão do equipamento de processamento. O método inclui as etapas de adicionar um sequestrante à base de água que contém um ou mais aldeídos, como glioxal, ao óleo pesado com o uso de um sistema de injeção de misturador estático e criar uma emulsão de sequestrante à base de água/óleo pesado com o uso de uma bomba de alto cisalhamento/alta velocidade. O sequestrante à base de água pode ser adicionado em uma ramificação de adição de sequestrante, sendo que a emulsão é formada na ramificação de adição e, então, é retornada ao equipamento de processamento.METHOD FOR REMOVING HYDROGEN SULPHIDE. The present invention relates to a hydrogen sulfide sequestration process for heavy oil that reduces hydrogen sulfide while minimizing corrosion of processing equipment. The method includes the steps of adding a water-based scavenger containing one or more aldehydes, such as glyoxal, to the heavy oil using a static mixer injection system and creating a water-based scavenger/heavy oil emulsion. with the use of a high shear/high speed pump. The water-based scavenger may be added in a scavenger addition branch, the emulsion being formed in the addition branch and then returned to the processing equipment.

BR112012015563A 2009-12-23 2010-10-21 "EMULSIFICATION OF HYDROCARBON GAS OILS TO INCREASE THE EFFECTIVENESS OF WATER-BASED HYDROGEN SULPHIDE scavengers" BR112012015563A2 (en)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
US12/646,432 US20110147272A1 (en) 2009-12-23 2009-12-23 Emulsification of hydrocarbon gas oils to increase efficacy of water based hydrogen sulfide scavengers
PCT/US2010/053457 WO2011087540A2 (en) 2009-12-23 2010-10-21 Emulsification of hydrocarbon gas oils to increase efficacy of water based hydrogen sulfide scavengers

Publications (1)

Publication Number Publication Date
BR112012015563A2 true BR112012015563A2 (en) 2017-09-05

Family

ID=44149590

Family Applications (1)

Application Number Title Priority Date Filing Date
BR112012015563A BR112012015563A2 (en) 2009-12-23 2010-10-21 "EMULSIFICATION OF HYDROCARBON GAS OILS TO INCREASE THE EFFECTIVENESS OF WATER-BASED HYDROGEN SULPHIDE scavengers"

Country Status (15)

Country Link
US (1) US20110147272A1 (en)
EP (1) EP2516596A2 (en)
JP (1) JP2013515818A (en)
KR (1) KR20120123348A (en)
CN (1) CN102762696A (en)
AR (1) AR079659A1 (en)
AU (1) AU2010341783A1 (en)
BR (1) BR112012015563A2 (en)
CA (1) CA2785532A1 (en)
CL (1) CL2012001711A1 (en)
MX (1) MX2012007493A (en)
RU (1) RU2012127278A (en)
SG (1) SG181925A1 (en)
TW (1) TW201137108A (en)
WO (1) WO2011087540A2 (en)

Families Citing this family (12)

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MX351425B (en) 2011-09-23 2017-10-13 Lonza Ag Process and composition for the removal of hydrogen sulfide from industrial process fluids.
WO2013049027A1 (en) * 2011-09-27 2013-04-04 General Electric Company Hydrogen sulfide scavenger compositions, methods for making and processes for removing hydrogen sulfide from liquid hydrocarbon media
WO2014031537A2 (en) * 2012-08-21 2014-02-27 Lonza, Inc. Method of scavenging hydrogen sulfide and/or sulfhydryl compounds
RU2687079C2 (en) * 2014-03-17 2019-05-07 Курарей Ко., Лтд. Composition for removing sulfur-containing compounds
KR20170110079A (en) * 2015-01-29 2017-10-10 주식회사 쿠라레 Composition for removing sulfur-containing compounds
CA3001767C (en) * 2015-10-14 2021-04-20 Haldor Topsoe A/S A process for removing sulphur compounds from process streams
JPWO2018062254A1 (en) 2016-09-27 2019-08-15 株式会社クラレ Metal corrosion control method
CN109952141A (en) 2016-11-22 2019-06-28 株式会社可乐丽 For removing the composition of sulfur-containing compound
US10513662B2 (en) * 2017-02-02 2019-12-24 Baker Hughes, A Ge Company, Llc Functionalized aldehydes as H2S and mercaptan scavengers
CN108732940B (en) * 2017-04-24 2021-05-07 西门子（中国）有限公司 Method and system for optimizing top circulating oil flow of catalytic cracking fractionator for gasoline and diesel cutting process
EP3999617A1 (en) 2019-07-17 2022-05-25 BL Technologies, Inc. Method of removal and conversion of amines in a refinery desalter
CN112710812B (en) * 2020-11-17 2023-02-24 中国石油天然气股份有限公司 Integrated process for detecting and treating toxic gas in crude oil produced by oil field

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US4344842A (en) * 1979-05-31 1982-08-17 Irwin Fox Reactive iron oxide agents for scavenging hydrogen sulfide from hydrocarbon liquids
US4680127A (en) * 1985-12-13 1987-07-14 Betz Laboratories, Inc. Method of scavenging hydrogen sulfide
US5284635A (en) * 1989-09-05 1994-02-08 Societe Francaise Hoechst Process for the elimination of hydrogen sulfide by using water-in-oil emulsions
US5397708A (en) * 1993-05-13 1995-03-14 Nalco Chemical Company Method for detection of sulfides
DE4342620C1 (en) * 1993-12-14 1995-07-06 Starck H C Gmbh Co Kg Process for the production of metal hydroxides
US5674377A (en) * 1995-06-19 1997-10-07 Nalco/Exxon Energy Chemicals, L.P. Method of treating sour gas and liquid hydrocarbon
US5744024A (en) * 1995-10-12 1998-04-28 Nalco/Exxon Energy Chemicals, L.P. Method of treating sour gas and liquid hydrocarbon
US6063346A (en) * 1998-06-05 2000-05-16 Intevep, S. A. Process for scavenging hydrogen sulfide and mercaptan contaminants from a fluid
GB9915214D0 (en) * 1999-06-29 1999-09-01 Bp Exploration Operating Microemulsions
GB0031710D0 (en) * 2000-12-27 2001-02-07 Dyno Oil Field Chemicals Process for the reduction or elimination of hydrogen sulphide
US7314545B2 (en) * 2004-01-09 2008-01-01 Lyondell Chemical Technology, L.P. Desulfurization process
EA012104B1 (en) * 2004-10-01 2009-08-28 Пропуре Ас Multi fluid injection mixer
US7267477B1 (en) * 2004-10-07 2007-09-11 Broad Reach Companies, Llc Fluid blending utilizing either or both passive and active mixing
US7576136B2 (en) * 2005-06-07 2009-08-18 Ge Betz, Inc. Emulsified feedstock for hydrocarbon process units that incorporate spray atomization
US8162048B2 (en) * 2008-09-09 2012-04-24 Tetra Technologies, Inc. Method of delivering frac fluid and additives

Also Published As

Publication number Publication date
MX2012007493A (en) 2012-08-03
WO2011087540A2 (en) 2011-07-21
EP2516596A2 (en) 2012-10-31
CN102762696A (en) 2012-10-31
US20110147272A1 (en) 2011-06-23
SG181925A1 (en) 2012-07-30
KR20120123348A (en) 2012-11-08
AU2010341783A1 (en) 2012-07-19
CA2785532A1 (en) 2011-07-21
JP2013515818A (en) 2013-05-09
TW201137108A (en) 2011-11-01
CL2012001711A1 (en) 2013-04-12
RU2012127278A (en) 2014-01-27
AR079659A1 (en) 2012-02-08
WO2011087540A3 (en) 2011-11-17

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Legal Events

Date Code Title Description
B08F Application dismissed because of non-payment of annual fees [chapter 8.6 patent gazette]
B08K Patent lapsed as no evidence of payment of the annual fee has been furnished to inpi [chapter 8.11 patent gazette]
B350 Update of information on the portal [chapter 15.35 patent gazette]