MX2012007493A - Emulsification of hydrocarbon gas oils to increase efficacy of water based hydrogen sulfide scavengers. - Google Patents

Emulsification of hydrocarbon gas oils to increase efficacy of water based hydrogen sulfide scavengers.

Info

Publication number
MX2012007493A
MX2012007493A MX2012007493A MX2012007493A MX2012007493A MX 2012007493 A MX2012007493 A MX 2012007493A MX 2012007493 A MX2012007493 A MX 2012007493A MX 2012007493 A MX2012007493 A MX 2012007493A MX 2012007493 A MX2012007493 A MX 2012007493A
Authority
MX
Mexico
Prior art keywords
hydrogen sulfide
emulsification
water based
hydrocarbon gas
gas oils
Prior art date
Application number
MX2012007493A
Other languages
Spanish (es)
Inventor
Larry John Karas
Craig Anderson
Original Assignee
Gen Electric
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Gen Electric filed Critical Gen Electric
Publication of MX2012007493A publication Critical patent/MX2012007493A/en

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
    • C10G29/00—Refining of hydrocarbon oils, in the absence of hydrogen, with other chemicals
    • C10G29/20—Organic compounds not containing metal atoms
    • C10G29/22—Organic compounds not containing metal atoms containing oxygen as the only hetero atom
    • C10G29/24—Aldehydes or ketones
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01F—MIXING, e.g. DISSOLVING, EMULSIFYING OR DISPERSING
    • B01F23/00—Mixing according to the phases to be mixed, e.g. dispersing or emulsifying
    • B01F23/40—Mixing liquids with liquids; Emulsifying
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
    • C10G2300/00—Aspects relating to hydrocarbon processing covered by groups C10G1/00 - C10G99/00
    • C10G2300/20—Characteristics of the feedstock or the products
    • C10G2300/201—Impurities
    • C10G2300/207—Acid gases, e.g. H2S, COS, SO2, HCN
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
    • C10G2300/00—Aspects relating to hydrocarbon processing covered by groups C10G1/00 - C10G99/00
    • C10G2300/40—Characteristics of the process deviating from typical ways of processing
    • C10G2300/4075—Limiting deterioration of equipment

Landscapes

  • Chemical & Material Sciences (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Engineering & Computer Science (AREA)
  • General Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Production Of Liquid Hydrocarbon Mixture For Refining Petroleum (AREA)

Abstract

A hydrogen sulfide scavenging process for heavy oil that reduces hydrogen sulfide while minimizing corrosion to processing equipment. The method includes the steps of adding an aqueous-based scavenger containing one or more aldehydes, such as giyoxal, Io the heavy oil using a static mixer injection system and creating an aqueous-based scavenger/heavy oil emulsion using a high shear/high velocity pump. The aqueous- based scavenger may be added in a scavenger addition branch, with the emulsion being formed in the addition branch and then returned to the processing equipment.
MX2012007493A 2009-12-23 2010-10-21 Emulsification of hydrocarbon gas oils to increase efficacy of water based hydrogen sulfide scavengers. MX2012007493A (en)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
US12/646,432 US20110147272A1 (en) 2009-12-23 2009-12-23 Emulsification of hydrocarbon gas oils to increase efficacy of water based hydrogen sulfide scavengers
PCT/US2010/053457 WO2011087540A2 (en) 2009-12-23 2010-10-21 Emulsification of hydrocarbon gas oils to increase efficacy of water based hydrogen sulfide scavengers

Publications (1)

Publication Number Publication Date
MX2012007493A true MX2012007493A (en) 2012-08-03

Family

ID=44149590

Family Applications (1)

Application Number Title Priority Date Filing Date
MX2012007493A MX2012007493A (en) 2009-12-23 2010-10-21 Emulsification of hydrocarbon gas oils to increase efficacy of water based hydrogen sulfide scavengers.

Country Status (15)

Country Link
US (1) US20110147272A1 (en)
EP (1) EP2516596A2 (en)
JP (1) JP2013515818A (en)
KR (1) KR20120123348A (en)
CN (1) CN102762696A (en)
AR (1) AR079659A1 (en)
AU (1) AU2010341783A1 (en)
BR (1) BR112012015563A2 (en)
CA (1) CA2785532A1 (en)
CL (1) CL2012001711A1 (en)
MX (1) MX2012007493A (en)
RU (1) RU2012127278A (en)
SG (1) SG181925A1 (en)
TW (1) TW201137108A (en)
WO (1) WO2011087540A2 (en)

Families Citing this family (13)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
DK2758347T3 (en) 2011-09-23 2017-03-27 Lonza Ag PROCEDURE FOR REMOVING HYDROGEN SULFIDE FROM INDUSTRIAL PROCESS FLUIDS
WO2013049027A1 (en) * 2011-09-27 2013-04-04 General Electric Company Hydrogen sulfide scavenger compositions, methods for making and processes for removing hydrogen sulfide from liquid hydrocarbon media
CA2880283C (en) * 2012-08-21 2020-07-21 Lonza, Inc. Method of scavenging hydrogen sulfide and/or sulfhydryl compounds
KR20160135191A (en) * 2014-03-17 2016-11-25 주식회사 쿠라레 Composition for removal of sulphur-containing compounds
CA2974070A1 (en) 2015-01-29 2016-08-04 Kuraray Co., Ltd. Composition for removing sulfur-containing compounds
EP3362535B1 (en) 2015-10-14 2020-05-06 Haldor Topsøe A/S A process for removing sulphur compounds from process streams
JPWO2018062254A1 (en) 2016-09-27 2019-08-15 株式会社クラレ Metal corrosion control method
CN109952141A (en) 2016-11-22 2019-06-28 株式会社可乐丽 For removing the composition of sulfur-containing compound
US10513662B2 (en) * 2017-02-02 2019-12-24 Baker Hughes, A Ge Company, Llc Functionalized aldehydes as H2S and mercaptan scavengers
CN108732940B (en) * 2017-04-24 2021-05-07 西门子（中国）有限公司 Method and system for optimizing top circulating oil flow of catalytic cracking fractionator for gasoline and diesel cutting process
US11926797B2 (en) 2019-07-17 2024-03-12 Bl Technologies, Inc. Method of removal and conversion of amines in a refinery desalter
CN112710812B (en) * 2020-11-17 2023-02-24 中国石油天然气股份有限公司 Integrated process for detecting and treating toxic gas in crude oil produced by oil field
WO2024081958A2 (en) * 2022-10-14 2024-04-18 Solugen, Inc. Compositions to control level of undesirable materials

Family Cites Families (15)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US4344842A (en) * 1979-05-31 1982-08-17 Irwin Fox Reactive iron oxide agents for scavenging hydrogen sulfide from hydrocarbon liquids
US4680127A (en) * 1985-12-13 1987-07-14 Betz Laboratories, Inc. Method of scavenging hydrogen sulfide
US5284635A (en) * 1989-09-05 1994-02-08 Societe Francaise Hoechst Process for the elimination of hydrogen sulfide by using water-in-oil emulsions
US5397708A (en) * 1993-05-13 1995-03-14 Nalco Chemical Company Method for detection of sulfides
DE4342620C1 (en) * 1993-12-14 1995-07-06 Starck H C Gmbh Co Kg Process for the production of metal hydroxides
US5674377A (en) * 1995-06-19 1997-10-07 Nalco/Exxon Energy Chemicals, L.P. Method of treating sour gas and liquid hydrocarbon
US5744024A (en) * 1995-10-12 1998-04-28 Nalco/Exxon Energy Chemicals, L.P. Method of treating sour gas and liquid hydrocarbon
US6063346A (en) * 1998-06-05 2000-05-16 Intevep, S. A. Process for scavenging hydrogen sulfide and mercaptan contaminants from a fluid
GB9915214D0 (en) * 1999-06-29 1999-09-01 Bp Exploration Operating Microemulsions
GB0031710D0 (en) * 2000-12-27 2001-02-07 Dyno Oil Field Chemicals Process for the reduction or elimination of hydrogen sulphide
US7314545B2 (en) * 2004-01-09 2008-01-01 Lyondell Chemical Technology, L.P. Desulfurization process
JP4913058B2 (en) * 2004-10-01 2012-04-11 プロピュア・アクティーゼルスカブ Multi-fluid injection mixer
US7267477B1 (en) * 2004-10-07 2007-09-11 Broad Reach Companies, Llc Fluid blending utilizing either or both passive and active mixing
US7576136B2 (en) * 2005-06-07 2009-08-18 Ge Betz, Inc. Emulsified feedstock for hydrocarbon process units that incorporate spray atomization
US8162048B2 (en) * 2008-09-09 2012-04-24 Tetra Technologies, Inc. Method of delivering frac fluid and additives

Also Published As

Publication number Publication date
CN102762696A (en) 2012-10-31
EP2516596A2 (en) 2012-10-31
RU2012127278A (en) 2014-01-27
CL2012001711A1 (en) 2013-04-12
KR20120123348A (en) 2012-11-08
AU2010341783A1 (en) 2012-07-19
SG181925A1 (en) 2012-07-30
US20110147272A1 (en) 2011-06-23
AR079659A1 (en) 2012-02-08
WO2011087540A3 (en) 2011-11-17
BR112012015563A2 (en) 2017-09-05
JP2013515818A (en) 2013-05-09
TW201137108A (en) 2011-11-01
CA2785532A1 (en) 2011-07-21
WO2011087540A2 (en) 2011-07-21

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