BR0013528A - Métodos para produção de ésteres e ácidos carboxìlicos a partir de reagentes, e, para produção de ácido acético, acetato de metila ou uma mistura dos mesmos - Google Patents
Métodos para produção de ésteres e ácidos carboxìlicos a partir de reagentes, e, para produção de ácido acético, acetato de metila ou uma mistura dos mesmosInfo
- Publication number
- BR0013528A BR0013528A BR0013528-3A BR0013528A BR0013528A BR 0013528 A BR0013528 A BR 0013528A BR 0013528 A BR0013528 A BR 0013528A BR 0013528 A BR0013528 A BR 0013528A
- Authority
- BR
- Brazil
- Prior art keywords
- production
- mixture
- esters
- reagents
- acetic acid
- Prior art date
Links
- QTBSBXVTEAMEQO-UHFFFAOYSA-N Acetic acid Chemical compound CC(O)=O QTBSBXVTEAMEQO-UHFFFAOYSA-N 0.000 title abstract 9
- 238000004519 manufacturing process Methods 0.000 title abstract 5
- 239000000203 mixture Substances 0.000 title abstract 5
- 239000003153 chemical reaction reagent Substances 0.000 title abstract 4
- XBDQKXXYIPTUBI-UHFFFAOYSA-M Propionate Chemical compound CCC([O-])=O XBDQKXXYIPTUBI-UHFFFAOYSA-M 0.000 title abstract 3
- KXKVLQRXCPHEJC-UHFFFAOYSA-N acetic acid trimethyl ester Natural products COC(C)=O KXKVLQRXCPHEJC-UHFFFAOYSA-N 0.000 title abstract 3
- 150000001735 carboxylic acids Chemical class 0.000 title abstract 3
- 150000002148 esters Chemical class 0.000 title abstract 3
- 238000000034 method Methods 0.000 title abstract 3
- 229910052751 metal Inorganic materials 0.000 abstract 3
- 239000002184 metal Substances 0.000 abstract 3
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 abstract 2
- 230000006315 carbonylation Effects 0.000 abstract 2
- 238000005810 carbonylation reaction Methods 0.000 abstract 2
- 239000003054 catalyst Substances 0.000 abstract 2
- 229910052741 iridium Inorganic materials 0.000 abstract 2
- GKOZUEZYRPOHIO-UHFFFAOYSA-N iridium atom Chemical compound [Ir] GKOZUEZYRPOHIO-UHFFFAOYSA-N 0.000 abstract 2
- 239000012808 vapor phase Substances 0.000 abstract 2
- UGFAIRIUMAVXCW-UHFFFAOYSA-N Carbon monoxide Chemical compound [O+]#[C-] UGFAIRIUMAVXCW-UHFFFAOYSA-N 0.000 abstract 1
- 125000005907 alkyl ester group Chemical group 0.000 abstract 1
- 125000005233 alkylalcohol group Chemical group 0.000 abstract 1
- 229910002091 carbon monoxide Inorganic materials 0.000 abstract 1
- 150000002170 ethers Chemical class 0.000 abstract 1
- 150000004820 halides Chemical class 0.000 abstract 1
- 239000000463 material Substances 0.000 abstract 1
- 150000002739 metals Chemical class 0.000 abstract 1
- 229910052758 niobium Inorganic materials 0.000 abstract 1
- 239000010955 niobium Substances 0.000 abstract 1
- GUCVJGMIXFAOAE-UHFFFAOYSA-N niobium atom Chemical compound [Nb] GUCVJGMIXFAOAE-UHFFFAOYSA-N 0.000 abstract 1
- 230000000737 periodic effect Effects 0.000 abstract 1
- 229910052715 tantalum Inorganic materials 0.000 abstract 1
- GUVRBAGPIYLISA-UHFFFAOYSA-N tantalum atom Chemical compound [Ta] GUVRBAGPIYLISA-UHFFFAOYSA-N 0.000 abstract 1
- 229910052720 vanadium Inorganic materials 0.000 abstract 1
- LEONUFNNVUYDNQ-UHFFFAOYSA-N vanadium atom Chemical compound [V] LEONUFNNVUYDNQ-UHFFFAOYSA-N 0.000 abstract 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C67/00—Preparation of carboxylic acid esters
- C07C67/36—Preparation of carboxylic acid esters by reaction with carbon monoxide or formates
- C07C67/37—Preparation of carboxylic acid esters by reaction with carbon monoxide or formates by reaction of ethers with carbon monoxide
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C51/00—Preparation of carboxylic acids or their salts, halides or anhydrides
- C07C51/10—Preparation of carboxylic acids or their salts, halides or anhydrides by reaction with carbon monoxide
- C07C51/12—Preparation of carboxylic acids or their salts, halides or anhydrides by reaction with carbon monoxide on an oxygen-containing group in organic compounds, e.g. alcohols
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C67/00—Preparation of carboxylic acid esters
- C07C67/36—Preparation of carboxylic acid esters by reaction with carbon monoxide or formates
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Engineering & Computer Science (AREA)
- Oil, Petroleum & Natural Gas (AREA)
- Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
- Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)
- Catalysts (AREA)
Applications Claiming Priority (2)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| US09/383,049 US6353132B1 (en) | 1999-08-25 | 1999-08-25 | Vapor phase carbonylation process using group 5 metal promoted iridium catalyst |
| PCT/US2000/022129 WO2001014305A1 (en) | 1999-08-25 | 2000-08-11 | Vapor phase carbonylation process using promoted iridium catalyst |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| BR0013528A true BR0013528A (pt) | 2002-04-30 |
Family
ID=23511488
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| BR0013528-3A BR0013528A (pt) | 1999-08-25 | 2000-08-11 | Métodos para produção de ésteres e ácidos carboxìlicos a partir de reagentes, e, para produção de ácido acético, acetato de metila ou uma mistura dos mesmos |
Country Status (7)
| Country | Link |
|---|---|
| US (1) | US6353132B1 (https=) |
| EP (1) | EP1206433B1 (https=) |
| JP (1) | JP2003507445A (https=) |
| CN (1) | CN1188382C (https=) |
| BR (1) | BR0013528A (https=) |
| DE (1) | DE60008118T2 (https=) |
| WO (1) | WO2001014305A1 (https=) |
Families Citing this family (13)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US6617471B2 (en) * | 2001-06-20 | 2003-09-09 | Eastman Chemical Company | Method for carbonylation of lower aliphatic alcohols using tin promoted iridium catalyst |
| CA2496839A1 (en) | 2004-07-19 | 2006-01-19 | Woodland Chemical Systems Inc. | Process for producing ethanol from synthesis gas rich in carbon monoxide |
| US7465822B2 (en) | 2005-05-05 | 2008-12-16 | Bp Chemicals Ltd. | Process for carbonylation of alkyl ethers |
| US20060252959A1 (en) * | 2005-05-05 | 2006-11-09 | The Regents Of The University Of California | Process for carbonylation of alkyl ethers |
| GB0601863D0 (en) * | 2006-01-30 | 2006-03-08 | Bp Chem Int Ltd | Process |
| JP2009532483A (ja) * | 2006-04-05 | 2009-09-10 | ウッドランド バイオフュールズ インコーポレイテッド | 合成ガスを介してバイオマスをエタノールに変換するための方法 |
| US7507855B2 (en) * | 2006-12-15 | 2009-03-24 | The Regents Of The University Of California | Process for carbonylation of aliphatic alcohols and/or ester derivatives thereof |
| EP1985607A1 (en) * | 2007-04-26 | 2008-10-29 | BP Chemicals Limited | Process for the carbonylation of dimethyl ether |
| US9421522B2 (en) * | 2011-12-28 | 2016-08-23 | Eastman Chemical Company | Iridium catalysts for carbonylation |
| US10512902B2 (en) * | 2015-12-18 | 2019-12-24 | Bp Chemicals Limited | Carbonylation process using a pretreated zeolite catalyst |
| CN106111191A (zh) * | 2016-06-29 | 2016-11-16 | 兖矿水煤浆气化及煤化工国家工程研究中心有限公司 | 一种碳纳米管负载铑催化剂体系及其应用 |
| CN108067222B (zh) * | 2016-11-15 | 2020-09-22 | 中国科学院大连化学物理研究所 | 活性炭载体负载的硫促进的铱基催化剂及其制备和应用 |
| CN111195530B (zh) * | 2018-11-20 | 2021-04-23 | 中国科学院大连化学物理研究所 | 一种原子级单分散的铱基催化剂其制备方法与应用 |
Family Cites Families (22)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US3717670A (en) | 1968-08-02 | 1973-02-20 | Monsanto Co | Production of carboxylic acids and esters |
| US3772380A (en) | 1970-03-12 | 1973-11-13 | Monsanto Co | Production of carboxylic acids and esters |
| US3689533A (en) | 1971-03-15 | 1972-09-05 | Monsanto Co | Production of carboxylic acids and esters |
| US4417077A (en) | 1980-10-01 | 1983-11-22 | University Of Illinois Foundation | Heterogeneous anionic transition metal catalysts |
| US4612387A (en) | 1982-01-04 | 1986-09-16 | Air Products And Chemicals, Inc. | Production of carboxylic acids and esters |
| DE3463257D1 (en) | 1983-03-25 | 1987-05-27 | Texaco Development Corp | A process for producing carboxylic acids by carbonylation of alkanols over a carbon catalyst |
| US4625050A (en) | 1983-06-23 | 1986-11-25 | Chevron Research Company | Ether homologation to esters and alcohols using a heterogeneous sulfided catalyst |
| DE3323654A1 (de) | 1983-07-01 | 1985-01-03 | Basf Ag, 6700 Ludwigshafen | Verfahren zur herstellung von essigsaeure und methylacetat |
| US5144068A (en) | 1984-05-03 | 1992-09-01 | Hoechst Celanese Corporation | Methanol carbonylation process |
| EP0203286B1 (de) | 1985-03-27 | 1988-09-14 | Hoechst Aktiengesellschaft | Trägerkatalysator und Verfahren zur Herstellung von Monocarbonsäureanhydriden |
| DE3643894A1 (de) | 1986-12-22 | 1988-06-23 | Degussa | Rhodium-haltige organopolysiloxan-ammoniumverbindungen, verfahren zu ihrer herstellung und verwendung |
| US5185462A (en) | 1987-01-08 | 1993-02-09 | Bp Chemicals Limited | Production of carboxylic acids and esters thereof |
| GB8807284D0 (en) | 1988-03-26 | 1988-04-27 | Bp Chem Int Ltd | Chemical process |
| US5218140A (en) | 1988-08-02 | 1993-06-08 | Union Carbide Chemicals & Plastics Technology Corporation | Carbonylation reaction and catalyst therefor |
| GB9013116D0 (en) | 1990-06-12 | 1990-08-01 | British Petroleum Co Plc | Carbonylation of methanol |
| US5488143A (en) | 1992-06-30 | 1996-01-30 | Korea Institute Of Science And Technology | Processes for the carbonylation of methanol to form acetic acid, methyl acetate and acetic anhydride |
| GB9223170D0 (en) | 1992-11-05 | 1992-12-16 | British Petroleum Co Plc | Process for preparing carboxylic acids |
| US5773642A (en) * | 1994-05-13 | 1998-06-30 | Acetex Chimie | Process for the preparation of carboxylic acids or the corresponding esters in the presence of a soluble catalyst based on iridium and iodides |
| US5510524A (en) | 1995-02-21 | 1996-04-23 | Bp Chemicals Limited | Process for the production of a carboxylic acid |
| US5696284A (en) | 1995-06-21 | 1997-12-09 | Bp Chemicals Limited | Process for the carbonylation of alkyl alcohols and/or reactive derivatives thereof |
| GB9517184D0 (en) | 1995-08-22 | 1995-10-25 | Bp Chem Int Ltd | Process |
| US5900505A (en) * | 1997-02-04 | 1999-05-04 | Eastman Chemical Company | Heterogeneous vapor phase carbonylation process |
-
1999
- 1999-08-25 US US09/383,049 patent/US6353132B1/en not_active Expired - Lifetime
-
2000
- 2000-08-11 BR BR0013528-3A patent/BR0013528A/pt not_active IP Right Cessation
- 2000-08-11 DE DE60008118T patent/DE60008118T2/de not_active Expired - Lifetime
- 2000-08-11 EP EP00954016A patent/EP1206433B1/en not_active Expired - Lifetime
- 2000-08-11 JP JP2001518398A patent/JP2003507445A/ja active Pending
- 2000-08-11 CN CNB008120153A patent/CN1188382C/zh not_active Expired - Fee Related
- 2000-08-11 WO PCT/US2000/022129 patent/WO2001014305A1/en not_active Ceased
Also Published As
| Publication number | Publication date |
|---|---|
| US6353132B1 (en) | 2002-03-05 |
| WO2001014305A1 (en) | 2001-03-01 |
| EP1206433A1 (en) | 2002-05-22 |
| EP1206433B1 (en) | 2004-02-04 |
| CN1371350A (zh) | 2002-09-25 |
| DE60008118T2 (de) | 2004-07-08 |
| DE60008118D1 (de) | 2004-03-11 |
| CN1188382C (zh) | 2005-02-09 |
| JP2003507445A (ja) | 2003-02-25 |
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Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| B08F | Application fees: application dismissed [chapter 8.6 patent gazette] |
Free format text: REFERENTE A 4A, 5A, 6A E 7A ANUIDADES. |
|
| B08K | Patent lapsed as no evidence of payment of the annual fee has been furnished to inpi [chapter 8.11 patent gazette] |
Free format text: REFERENTE AO DESPACHO 8.6 PUBLICADO NA RPI 1927 DE 11/12/2007. |