BE863717A - Procede pour la preparation de perles de polymeres - Google Patents
Procede pour la preparation de perles de polymeresInfo
- Publication number
- BE863717A BE863717A BE184956A BE184956A BE863717A BE 863717 A BE863717 A BE 863717A BE 184956 A BE184956 A BE 184956A BE 184956 A BE184956 A BE 184956A BE 863717 A BE863717 A BE 863717A
- Authority
- BE
- Belgium
- Prior art keywords
- emi
- beads
- exchange resin
- loss
- resins
- Prior art date
Links
- 239000011324 bead Substances 0.000 title claims description 22
- 238000000034 method Methods 0.000 title claims description 9
- 229920000642 polymer Polymers 0.000 title description 4
- 239000011347 resin Substances 0.000 claims description 33
- 229920005989 resin Polymers 0.000 claims description 33
- 239000011049 pearl Substances 0.000 claims description 14
- 239000000178 monomer Substances 0.000 claims description 5
- 244000027321 Lychnis chalcedonica Species 0.000 claims description 4
- 238000006116 polymerization reaction Methods 0.000 claims description 4
- NWUYHJFMYQTDRP-UHFFFAOYSA-N 1,2-bis(ethenyl)benzene;1-ethenyl-2-ethylbenzene;styrene Chemical compound C=CC1=CC=CC=C1.CCC1=CC=CC=C1C=C.C=CC1=CC=CC=C1C=C NWUYHJFMYQTDRP-UHFFFAOYSA-N 0.000 claims description 2
- 239000003957 anion exchange resin Substances 0.000 claims 5
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 claims 2
- 241000317173 Perla Species 0.000 claims 2
- PPBRXRYQALVLMV-UHFFFAOYSA-N Styrene Natural products C=CC1=CC=CC=C1 PPBRXRYQALVLMV-UHFFFAOYSA-N 0.000 claims 1
- 150000001450 anions Chemical class 0.000 claims 1
- 125000003118 aryl group Chemical group 0.000 claims 1
- 239000003729 cation exchange resin Substances 0.000 claims 1
- 150000001768 cations Chemical class 0.000 claims 1
- 125000001453 quaternary ammonium group Chemical group 0.000 claims 1
- 125000003011 styrenyl group Chemical group [H]\C(*)=C(/[H])C1=C([H])C([H])=C([H])C([H])=C1[H] 0.000 claims 1
- 238000010586 diagram Methods 0.000 description 23
- 239000003431 cross linking reagent Substances 0.000 description 5
- 125000002091 cationic group Chemical group 0.000 description 4
- 239000003456 ion exchange resin Substances 0.000 description 4
- 229920003303 ion-exchange polymer Polymers 0.000 description 4
- 239000002904 solvent Substances 0.000 description 4
- 230000008961 swelling Effects 0.000 description 4
- 239000004971 Cross linker Substances 0.000 description 3
- 229920001577 copolymer Polymers 0.000 description 3
- QAOWNCQODCNURD-UHFFFAOYSA-N sulfuric acid Substances OS(O)(=O)=O QAOWNCQODCNURD-UHFFFAOYSA-N 0.000 description 3
- 229920002554 vinyl polymer Polymers 0.000 description 3
- LYCAIKOWRPUZTN-UHFFFAOYSA-N Ethylene glycol Chemical compound OCCO LYCAIKOWRPUZTN-UHFFFAOYSA-N 0.000 description 2
- PEDCQBHIVMGVHV-UHFFFAOYSA-N Glycerine Chemical compound OCC(O)CO PEDCQBHIVMGVHV-UHFFFAOYSA-N 0.000 description 2
- 239000002253 acid Substances 0.000 description 2
- 230000002378 acidificating effect Effects 0.000 description 2
- 125000000129 anionic group Chemical group 0.000 description 2
- 230000008033 biological extinction Effects 0.000 description 2
- 238000007334 copolymerization reaction Methods 0.000 description 2
- 230000007547 defect Effects 0.000 description 2
- 239000000499 gel Substances 0.000 description 2
- -1 pentaerythritis Chemical compound 0.000 description 2
- GHMLBKRAJCXXBS-UHFFFAOYSA-N resorcinol Chemical compound OC1=CC=CC(O)=C1 GHMLBKRAJCXXBS-UHFFFAOYSA-N 0.000 description 2
- UIYCHXAGWOYNNA-UHFFFAOYSA-N vinyl sulfide Chemical compound C=CSC=C UIYCHXAGWOYNNA-UHFFFAOYSA-N 0.000 description 2
- 230000000007 visual effect Effects 0.000 description 2
- ZJQIXGGEADDPQB-UHFFFAOYSA-N 1,2-bis(ethenyl)-3,4-dimethylbenzene Chemical group CC1=CC=C(C=C)C(C=C)=C1C ZJQIXGGEADDPQB-UHFFFAOYSA-N 0.000 description 1
- YKKDJUGGSDWUKX-UHFFFAOYSA-N 1,2-bis(ethenyl)-3-ethylbenzene Chemical compound CCC1=CC=CC(C=C)=C1C=C YKKDJUGGSDWUKX-UHFFFAOYSA-N 0.000 description 1
- KHAHWKLZGBIAKT-UHFFFAOYSA-N 4-(4-methylpyrimidin-2-yl)benzaldehyde Chemical compound CC1=CC=NC(C=2C=CC(C=O)=CC=2)=N1 KHAHWKLZGBIAKT-UHFFFAOYSA-N 0.000 description 1
- NIXOWILDQLNWCW-UHFFFAOYSA-M Acrylate Chemical compound [O-]C(=O)C=C NIXOWILDQLNWCW-UHFFFAOYSA-M 0.000 description 1
- 150000007513 acids Chemical class 0.000 description 1
- 239000012736 aqueous medium Substances 0.000 description 1
- 239000008346 aqueous phase Substances 0.000 description 1
- HABAXTXIECRCKH-UHFFFAOYSA-N bis(prop-2-enyl) butanedioate Chemical compound C=CCOC(=O)CCC(=O)OCC=C HABAXTXIECRCKH-UHFFFAOYSA-N 0.000 description 1
- JKJWYKGYGWOAHT-UHFFFAOYSA-N bis(prop-2-enyl) carbonate Chemical compound C=CCOC(=O)OCC=C JKJWYKGYGWOAHT-UHFFFAOYSA-N 0.000 description 1
- FPODCVUTIPDRTE-UHFFFAOYSA-N bis(prop-2-enyl) hexanedioate Chemical compound C=CCOC(=O)CCCCC(=O)OCC=C FPODCVUTIPDRTE-UHFFFAOYSA-N 0.000 description 1
- BKXRKRANFLFTFU-UHFFFAOYSA-N bis(prop-2-enyl) oxalate Chemical compound C=CCOC(=O)C(=O)OCC=C BKXRKRANFLFTFU-UHFFFAOYSA-N 0.000 description 1
- AOESAXAWXYJFNC-UHFFFAOYSA-N bis(prop-2-enyl) propanedioate Chemical compound C=CCOC(=O)CC(=O)OCC=C AOESAXAWXYJFNC-UHFFFAOYSA-N 0.000 description 1
- MPMBRWOOISTHJV-UHFFFAOYSA-N but-1-enylbenzene Chemical compound CCC=CC1=CC=CC=C1 MPMBRWOOISTHJV-UHFFFAOYSA-N 0.000 description 1
- 238000012512 characterization method Methods 0.000 description 1
- 238000006243 chemical reaction Methods 0.000 description 1
- 239000003795 chemical substances by application Substances 0.000 description 1
- 239000002131 composite material Substances 0.000 description 1
- 239000000470 constituent Substances 0.000 description 1
- 238000005336 cracking Methods 0.000 description 1
- 238000004132 cross linking Methods 0.000 description 1
- 239000006185 dispersion Substances 0.000 description 1
- 125000004119 disulfanediyl group Chemical group *SS* 0.000 description 1
- AFOSIXZFDONLBT-UHFFFAOYSA-N divinyl sulfone Chemical compound C=CS(=O)(=O)C=C AFOSIXZFDONLBT-UHFFFAOYSA-N 0.000 description 1
- HJWBBBADPXPUPA-UHFFFAOYSA-N ethyl 3-(4-chlorophenyl)-5-methyl-1,2-oxazole-4-carboxylate Chemical compound CCOC(=O)C1=C(C)ON=C1C1=CC=C(Cl)C=C1 HJWBBBADPXPUPA-UHFFFAOYSA-N 0.000 description 1
- 239000012634 fragment Substances 0.000 description 1
- 235000011187 glycerol Nutrition 0.000 description 1
- 150000002334 glycols Chemical class 0.000 description 1
- PCHJSUWPFVWCPO-UHFFFAOYSA-N gold Chemical compound [Au] PCHJSUWPFVWCPO-UHFFFAOYSA-N 0.000 description 1
- 239000010931 gold Substances 0.000 description 1
- 229910052737 gold Inorganic materials 0.000 description 1
- WGCNASOHLSPBMP-UHFFFAOYSA-N hydroxyacetaldehyde Natural products OCC=O WGCNASOHLSPBMP-UHFFFAOYSA-N 0.000 description 1
- 238000005286 illumination Methods 0.000 description 1
- 238000005342 ion exchange Methods 0.000 description 1
- 230000001788 irregular Effects 0.000 description 1
- 239000000463 material Substances 0.000 description 1
- 239000000203 mixture Substances 0.000 description 1
- UCUUFSAXZMGPGH-UHFFFAOYSA-N penta-1,4-dien-3-one Chemical compound C=CC(=O)C=C UCUUFSAXZMGPGH-UHFFFAOYSA-N 0.000 description 1
- WXZMFSXDPGVJKK-UHFFFAOYSA-N pentaerythritol Chemical compound OCC(CO)(CO)CO WXZMFSXDPGVJKK-UHFFFAOYSA-N 0.000 description 1
- 239000012071 phase Substances 0.000 description 1
- 239000002243 precursor Substances 0.000 description 1
- 239000003760 tallow Substances 0.000 description 1
- 238000002076 thermal analysis method Methods 0.000 description 1
- NZHHDFRSEQSGLN-ZRDIBKRKSA-N tris(prop-2-enyl) (e)-prop-1-ene-1,2,3-tricarboxylate Chemical compound C=CCOC(=O)C\C(C(=O)OCC=C)=C/C(=O)OCC=C NZHHDFRSEQSGLN-ZRDIBKRKSA-N 0.000 description 1
- 125000000391 vinyl group Chemical group [H]C([*])=C([H])[H] 0.000 description 1
Classifications
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J39/00—Cation exchange; Use of material as cation exchangers; Treatment of material for improving the cation exchange properties
- B01J39/08—Use of material as cation exchangers; Treatment of material for improving the cation exchange properties
- B01J39/16—Organic material
- B01J39/18—Macromolecular compounds
- B01J39/20—Macromolecular compounds obtained by reactions only involving unsaturated carbon-to-carbon bonds
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F212/00—Copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by an aromatic carbocyclic ring
- C08F212/02—Monomers containing only one unsaturated aliphatic radical
- C08F212/04—Monomers containing only one unsaturated aliphatic radical containing one ring
- C08F212/06—Hydrocarbons
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Health & Medical Sciences (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Addition Polymer Or Copolymer, Post-Treatments, Or Chemical Modifications (AREA)
- Polymerisation Methods In General (AREA)
- Compositions Of Macromolecular Compounds (AREA)
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| US76612077A | 1977-02-07 | 1977-02-07 |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| BE863717A true BE863717A (fr) | 1978-08-07 |
Family
ID=25075463
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| BE184956A BE863717A (fr) | 1977-02-07 | 1978-02-07 | Procede pour la preparation de perles de polymeres |
Country Status (4)
| Country | Link |
|---|---|
| JP (1) | JPS53124184A (enExample) |
| BE (1) | BE863717A (enExample) |
| IN (1) | IN148422B (enExample) |
| ZA (1) | ZA78562B (enExample) |
Families Citing this family (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPS5830687A (ja) * | 1981-08-17 | 1983-02-23 | Kyowa Gas Chem Ind Co Ltd | プラスチツクシンチレ−タ |
| JPS6050361B2 (ja) * | 1981-08-21 | 1985-11-08 | 三菱化学株式会社 | 陽イオン交換樹脂の製造法 |
| KR940000789B1 (ko) * | 1987-10-08 | 1994-01-31 | 이데미쓰 고산 가부시끼가이샤 | 스티렌계 중합체 및 그 제조방법 |
-
1978
- 1978-01-31 ZA ZA00780562A patent/ZA78562B/xx unknown
- 1978-02-06 IN IN97/DEL/78A patent/IN148422B/en unknown
- 1978-02-06 JP JP1223378A patent/JPS53124184A/ja active Granted
- 1978-02-07 BE BE184956A patent/BE863717A/fr not_active IP Right Cessation
Also Published As
| Publication number | Publication date |
|---|---|
| JPS6126564B2 (enExample) | 1986-06-21 |
| JPS53124184A (en) | 1978-10-30 |
| ZA78562B (en) | 1979-08-29 |
| IN148422B (enExample) | 1981-02-21 |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| JP3939651B2 (ja) | バイオセンサー用の多孔質高分子膜を製造するためのスクリーン印刷可能なペースト材 | |
| DE2833998A1 (de) | Kontaktlinse | |
| Baker et al. | Macromolecular disorder in linear polyamides. Relation of structure to physical properties of copolyamides | |
| Chen et al. | Chemoenzymic Synthesis and Characterization of Poly (. alpha.-methyl galactoside 6-acrylate) Hydrogels | |
| CN112266502A (zh) | 一种多重响应纳米纤维素复合膜及其制备方法 | |
| EP0130872B1 (fr) | Procédé de fabrication de polyvynilbutyral et produits obtenus | |
| US9260683B2 (en) | Molecularly imprinted polymer for wine, method of preparing, and use of same | |
| Dech et al. | Amphiphilic polymer conetworks derived from aqueous solutions for biocatalysis in organic solvents | |
| BE863717A (fr) | Procede pour la preparation de perles de polymeres | |
| Haas et al. | Changing mechanical properties of photopolymerized, dityrosine-crosslinked protein-based hydrogels | |
| US2271468A (en) | Water soluble polyvinyl alcohol softened with beta-hydroxy-alkyl ammounium salt | |
| US2486190A (en) | Imidized polyacrylamides | |
| Mozafarpour et al. | Improvement the barrier and mechanical properties of whey protein isolate film using fructan obtained from Serish (Eremurus spectabilis) root as a novel polysaccharide | |
| US7495036B2 (en) | Polymeric compositions and their production and uses | |
| Stainsby | The fractionation of gelatin by coacervation | |
| Ochi et al. | Preparation of hydrogel capsules with thermoresponsive interpenetrating polymer network using concentric two-fluid nozzles | |
| Feng et al. | The effect of novel solvent formula of primer containing functional monomer on improving the durability of dentin adhesion | |
| Zeng et al. | Molecular chain properties of poly (N-isopropyl acrylamide) | |
| Sadeghi et al. | Comparison of physicomechanical properties of films prepared from organic solutions and aqueous dispersion of Eudragit RL | |
| CN114858792A (zh) | 一种有机胺类气体响应结构色肉类新鲜度指示标签及其制备方法和应用 | |
| US2350851A (en) | Polyamide articles | |
| JPH0625231B2 (ja) | 光学素子用共重合体の製造法 | |
| US5286777A (en) | Preparing a dye-containing polymer | |
| US1836946A (en) | Plastic film or sheet containing cellulose nitrate | |
| US10662271B2 (en) | Droplets distributed in an aqueous medium |
Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| RE | Patent lapsed |
Owner name: ROHM AND HAAS CY Effective date: 19950228 |