BE567045A - - Google Patents
Info
- Publication number
- BE567045A BE567045A BE567045DA BE567045A BE 567045 A BE567045 A BE 567045A BE 567045D A BE567045D A BE 567045DA BE 567045 A BE567045 A BE 567045A
- Authority
- BE
- Belgium
- Prior art keywords
- sep
- solvent
- unsaturated organic
- denotes
- reaction
- Prior art date
Links
- 239000002904 solvent Substances 0.000 claims description 38
- RTZKZFJDLAIYFH-UHFFFAOYSA-N Diethyl ether Chemical compound CCOCC RTZKZFJDLAIYFH-UHFFFAOYSA-N 0.000 claims description 18
- FYYHWMGAXLPEAU-UHFFFAOYSA-N Magnesium Chemical compound [Mg] FYYHWMGAXLPEAU-UHFFFAOYSA-N 0.000 claims description 10
- 239000011777 magnesium Substances 0.000 claims description 10
- 229910052749 magnesium Inorganic materials 0.000 claims description 10
- 238000000034 method Methods 0.000 claims description 6
- 125000001931 aliphatic group Chemical group 0.000 claims description 5
- 125000005843 halogen group Chemical group 0.000 claims description 5
- 239000000203 mixture Substances 0.000 claims description 5
- 239000002202 Polyethylene glycol Substances 0.000 claims description 4
- 229920001223 polyethylene glycol Polymers 0.000 claims description 4
- 150000004292 cyclic ethers Chemical class 0.000 claims description 3
- 125000002734 organomagnesium group Chemical group 0.000 claims description 3
- 238000002360 preparation method Methods 0.000 claims description 2
- 150000002894 organic compounds Chemical class 0.000 claims 4
- WKBOTKDWSSQWDR-UHFFFAOYSA-N Bromine atom Chemical group [Br] WKBOTKDWSSQWDR-UHFFFAOYSA-N 0.000 claims 2
- KZBUYRJDOAKODT-UHFFFAOYSA-N Chlorine Chemical compound ClCl KZBUYRJDOAKODT-UHFFFAOYSA-N 0.000 claims 2
- 229910052801 chlorine Inorganic materials 0.000 claims 2
- 239000000460 chlorine Substances 0.000 claims 2
- ISWSIDIOOBJBQZ-UHFFFAOYSA-N phenol group Chemical group C1(=CC=CC=C1)O ISWSIDIOOBJBQZ-UHFFFAOYSA-N 0.000 claims 1
- 125000002496 methyl group Chemical group [H]C([H])([H])* 0.000 description 9
- OKKJLVBELUTLKV-UHFFFAOYSA-N Methanol Chemical compound OC OKKJLVBELUTLKV-UHFFFAOYSA-N 0.000 description 8
- WYURNTSHIVDZCO-UHFFFAOYSA-N Tetrahydrofuran Chemical compound C1CCOC1 WYURNTSHIVDZCO-UHFFFAOYSA-N 0.000 description 8
- FXHGMKSSBGDXIY-UHFFFAOYSA-N heptanal Chemical compound CCCCCCC=O FXHGMKSSBGDXIY-UHFFFAOYSA-N 0.000 description 7
- IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 description 6
- RDOXTESZEPMUJZ-UHFFFAOYSA-N anisole Chemical compound COC1=CC=CC=C1 RDOXTESZEPMUJZ-UHFFFAOYSA-N 0.000 description 6
- 150000001875 compounds Chemical class 0.000 description 6
- 238000010438 heat treatment Methods 0.000 description 5
- IKHGUXGNUITLKF-UHFFFAOYSA-N Acetaldehyde Chemical compound CC=O IKHGUXGNUITLKF-UHFFFAOYSA-N 0.000 description 4
- CSCPPACGZOOCGX-UHFFFAOYSA-N Acetone Chemical compound CC(C)=O CSCPPACGZOOCGX-UHFFFAOYSA-N 0.000 description 4
- QQONPFPTGQHPMA-UHFFFAOYSA-N Propene Chemical compound CC=C QQONPFPTGQHPMA-UHFFFAOYSA-N 0.000 description 4
- YLQBMQCUIZJEEH-UHFFFAOYSA-N tetrahydrofuran Natural products C=1C=COC=1 YLQBMQCUIZJEEH-UHFFFAOYSA-N 0.000 description 4
- UZKWTJUDCOPSNM-UHFFFAOYSA-N methoxybenzene Substances CCCCOC=C UZKWTJUDCOPSNM-UHFFFAOYSA-N 0.000 description 3
- 229910052757 nitrogen Inorganic materials 0.000 description 3
- NNQDMQVWOWCVEM-NSCUHMNNSA-N (e)-1-bromoprop-1-ene Chemical compound C\C=C\Br NNQDMQVWOWCVEM-NSCUHMNNSA-N 0.000 description 2
- DHXVGJBLRPWPCS-UHFFFAOYSA-N Tetrahydropyran Chemical compound C1CCOCC1 DHXVGJBLRPWPCS-UHFFFAOYSA-N 0.000 description 2
- 238000013019 agitation Methods 0.000 description 2
- 150000001299 aldehydes Chemical class 0.000 description 2
- 125000000484 butyl group Chemical group [H]C([*])([H])C([H])([H])C([H])([H])C([H])([H])[H] 0.000 description 2
- 239000003153 chemical reaction reagent Substances 0.000 description 2
- NKDDWNXOKDWJAK-UHFFFAOYSA-N dimethoxymethane Chemical compound COCOC NKDDWNXOKDWJAK-UHFFFAOYSA-N 0.000 description 2
- 150000002170 ethers Chemical class 0.000 description 2
- 125000004051 hexyl group Chemical group [H]C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])* 0.000 description 2
- PNDPGZBMCMUPRI-UHFFFAOYSA-N iodine Chemical compound II PNDPGZBMCMUPRI-UHFFFAOYSA-N 0.000 description 2
- 125000001449 isopropyl group Chemical group [H]C([H])([H])C([H])(*)C([H])([H])[H] 0.000 description 2
- 150000002576 ketones Chemical class 0.000 description 2
- 238000010992 reflux Methods 0.000 description 2
- LXULSIHXSIQYAG-UHFFFAOYSA-N 1-bromo-1-ethoxyprop-1-ene Chemical class C(C)OC(=CC)Br LXULSIHXSIQYAG-UHFFFAOYSA-N 0.000 description 1
- IOKIELYKONFEPP-UHFFFAOYSA-N 1-bromohex-1-yne Chemical group CCCCC#CBr IOKIELYKONFEPP-UHFFFAOYSA-N 0.000 description 1
- NNQDMQVWOWCVEM-UHFFFAOYSA-N 1-bromoprop-1-ene Chemical compound CC=CBr NNQDMQVWOWCVEM-UHFFFAOYSA-N 0.000 description 1
- DURPTKYDGMDSBL-UHFFFAOYSA-N 1-butoxybutane Chemical compound CCCCOCCCC DURPTKYDGMDSBL-UHFFFAOYSA-N 0.000 description 1
- BPPVUXSMLBXYGG-UHFFFAOYSA-N 4-[3-(4,5-dihydro-1,2-oxazol-3-yl)-2-methyl-4-methylsulfonylbenzoyl]-2-methyl-1h-pyrazol-3-one Chemical compound CC1=C(C(=O)C=2C(N(C)NC=2)=O)C=CC(S(C)(=O)=O)=C1C1=NOCC1 BPPVUXSMLBXYGG-UHFFFAOYSA-N 0.000 description 1
- ZCYVEMRRCGMTRW-UHFFFAOYSA-N 7553-56-2 Chemical compound [I] ZCYVEMRRCGMTRW-UHFFFAOYSA-N 0.000 description 1
- 241001091551 Clio Species 0.000 description 1
- AQZGPSLYZOOYQP-UHFFFAOYSA-N Diisoamyl ether Chemical compound CC(C)CCOCCC(C)C AQZGPSLYZOOYQP-UHFFFAOYSA-N 0.000 description 1
- ZAFNJMIOTHYJRJ-UHFFFAOYSA-N Diisopropyl ether Chemical compound CC(C)OC(C)C ZAFNJMIOTHYJRJ-UHFFFAOYSA-N 0.000 description 1
- 239000007818 Grignard reagent Substances 0.000 description 1
- XCUKEVQQRWNPOY-UHFFFAOYSA-M [Br-].CCCCC#C[Mg+] Chemical compound [Br-].CCCCC#C[Mg+] XCUKEVQQRWNPOY-UHFFFAOYSA-M 0.000 description 1
- 125000003118 aryl group Chemical group 0.000 description 1
- 125000004429 atom Chemical group 0.000 description 1
- 238000009835 boiling Methods 0.000 description 1
- 125000004432 carbon atom Chemical group C* 0.000 description 1
- 238000009833 condensation Methods 0.000 description 1
- 230000005494 condensation Effects 0.000 description 1
- 239000013078 crystal Substances 0.000 description 1
- 125000004122 cyclic group Chemical group 0.000 description 1
- 125000000524 functional group Chemical group 0.000 description 1
- 150000004795 grignard reagents Chemical class 0.000 description 1
- 229910052736 halogen Inorganic materials 0.000 description 1
- 150000002366 halogen compounds Chemical class 0.000 description 1
- 239000008240 homogeneous mixture Substances 0.000 description 1
- 229910052740 iodine Inorganic materials 0.000 description 1
- 239000011630 iodine Substances 0.000 description 1
- 150000002605 large molecules Chemical class 0.000 description 1
- 229920002521 macromolecule Polymers 0.000 description 1
- QSHDDOUJBYECFT-UHFFFAOYSA-N mercury Chemical compound [Hg] QSHDDOUJBYECFT-UHFFFAOYSA-N 0.000 description 1
- 229910052753 mercury Inorganic materials 0.000 description 1
- 239000012046 mixed solvent Substances 0.000 description 1
- RRRODBVLAIUQDT-UHFFFAOYSA-N oct-3-yn-2-ol Chemical compound CCCCC#CC(C)O RRRODBVLAIUQDT-UHFFFAOYSA-N 0.000 description 1
- 150000002901 organomagnesium compounds Chemical class 0.000 description 1
- -1 phenolic ethers Chemical class 0.000 description 1
- 239000002244 precipitate Substances 0.000 description 1
- 239000000047 product Substances 0.000 description 1
- 239000012429 reaction media Substances 0.000 description 1
- 238000011084 recovery Methods 0.000 description 1
- 239000007858 starting material Substances 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07F—ACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
- C07F3/00—Compounds containing elements of Groups 2 or 12 of the Periodic Table
- C07F3/02—Magnesium compounds
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Catalysts (AREA)
Publications (1)
| Publication Number | Publication Date |
|---|---|
| BE567045A true BE567045A (enrdf_load_stackoverflow) |
Family
ID=186937
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| BE567045D BE567045A (enrdf_load_stackoverflow) |
Country Status (1)
| Country | Link |
|---|---|
| BE (1) | BE567045A (enrdf_load_stackoverflow) |
-
0
- BE BE567045D patent/BE567045A/fr unknown
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| FR2464246A1 (fr) | Procede de preparation de composes fluorocarbonyles a partir d'ethers fluores | |
| CH635054A5 (fr) | Procede de monoetherification selective de la pyrocatechine. | |
| EP0149407B1 (fr) | Procédé de préparation de bromobenzaldehydes hydroxy et/ou alkoxy substitués | |
| BE567045A (enrdf_load_stackoverflow) | ||
| EP0049186B1 (fr) | Procédé de préparation de fluorobenzonitriles | |
| CH365720A (fr) | Procédé de préparation de dérivés organomagnésiens | |
| BE427306A (fr) | Procédé de préparation de produits de condensation du formaldéhyde | |
| EP0190523A1 (fr) | Procédé de préparation de composés porteurs d'un groupe difluorométhylène ou trifluorométhyle | |
| EP0013995B1 (fr) | Procédé pour la préparation de cétones macrocycliques acétyleniques | |
| EP0035927B1 (fr) | Procédé de préparation de chloroalkoxybenzènes | |
| CA1306860C (fr) | Compositions a base d'ether chlorofluore et de solvant | |
| EP0051527A1 (fr) | Procédé pour la synthèse de composés hydrogénés et/ou fluorés du type polyoxyéthylène-alkyl-éther, composés de ce type et application à titre d'agents tensio-actifs non ioniques | |
| LU84129A1 (fr) | Procede d'halogenation en meta de n-(o,o'-dialkyl phenyl)alaninates et homologues | |
| FR2463115A1 (fr) | Procede de production de fluorure d'o-iodacyle contenant un groupe icf2cf2o, par mise en oeuvre de tetrafluoroethylene | |
| BE558202A (enrdf_load_stackoverflow) | ||
| CH366042A (fr) | Procédé de préparation de dérivés magnésiens acétyléniques | |
| BE460921A (enrdf_load_stackoverflow) | ||
| EP0256903A1 (fr) | Composition à base de chlorure de méthylène - son utilisation pour le dégraissage des métaux | |
| EP0105008B1 (fr) | Procédé d'élimination d'agents nitrosants de composés aromatiques nitrés | |
| BE559876A (enrdf_load_stackoverflow) | ||
| CH618158A5 (enrdf_load_stackoverflow) | ||
| CH374987A (fr) | Procédé de préparation de cétones a-éthyléniques | |
| BE634817A (enrdf_load_stackoverflow) | ||
| FR2537138A1 (fr) | Procede de preparation de derives de l'acide 2-thiophene acetique | |
| FR2693456A1 (fr) | Réactif de perfluoroalcoylation et procédé utilisant ce réactif. |