BE563417A - - Google Patents
Info
- Publication number
- BE563417A BE563417A BE563417DA BE563417A BE 563417 A BE563417 A BE 563417A BE 563417D A BE563417D A BE 563417DA BE 563417 A BE563417 A BE 563417A
- Authority
- BE
- Belgium
- Prior art keywords
- catalyst
- alcohol
- emi
- polyethylene
- added
- Prior art date
Links
- 239000003054 catalyst Substances 0.000 claims description 29
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 claims description 23
- 239000004698 Polyethylene Substances 0.000 claims description 19
- -1 polyethylene Polymers 0.000 claims description 19
- 229920000573 polyethylene Polymers 0.000 claims description 19
- 238000006116 polymerization reaction Methods 0.000 claims description 17
- 238000000034 method Methods 0.000 claims description 14
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 claims description 13
- 229910052760 oxygen Inorganic materials 0.000 claims description 13
- 239000001301 oxygen Substances 0.000 claims description 13
- 238000006243 chemical reaction Methods 0.000 claims description 11
- VGGSQFUCUMXWEO-UHFFFAOYSA-N Ethene Chemical compound C=C VGGSQFUCUMXWEO-UHFFFAOYSA-N 0.000 claims description 10
- 239000005977 Ethylene Substances 0.000 claims description 10
- 150000001336 alkenes Chemical class 0.000 claims description 7
- 239000000203 mixture Substances 0.000 claims description 6
- XJDNKRIXUMDJCW-UHFFFAOYSA-J titanium tetrachloride Chemical compound Cl[Ti](Cl)(Cl)Cl XJDNKRIXUMDJCW-UHFFFAOYSA-J 0.000 claims description 5
- 239000007789 gas Substances 0.000 claims description 4
- 229910052751 metal Inorganic materials 0.000 claims description 4
- 239000002184 metal Substances 0.000 claims description 4
- 125000002524 organometallic group Chemical group 0.000 claims description 4
- 239000004215 Carbon black (E152) Substances 0.000 claims description 3
- 229930195733 hydrocarbon Natural products 0.000 claims description 3
- 150000002430 hydrocarbons Chemical class 0.000 claims description 3
- 230000000737 periodic effect Effects 0.000 claims description 3
- 239000011541 reaction mixture Substances 0.000 claims description 3
- 150000003608 titanium Chemical class 0.000 claims description 3
- UGFAIRIUMAVXCW-UHFFFAOYSA-N Carbon monoxide Chemical compound [O+]#[C-] UGFAIRIUMAVXCW-UHFFFAOYSA-N 0.000 claims description 2
- 229910002091 carbon monoxide Inorganic materials 0.000 claims description 2
- 150000002739 metals Chemical class 0.000 claims description 2
- LRHPLDYGYMQRHN-UHFFFAOYSA-N N-Butanol Chemical compound CCCCO LRHPLDYGYMQRHN-UHFFFAOYSA-N 0.000 claims 2
- QAOWNCQODCNURD-UHFFFAOYSA-N Sulfuric acid Chemical compound OS(O)(=O)=O QAOWNCQODCNURD-UHFFFAOYSA-N 0.000 claims 2
- KPZGRMZPZLOPBS-UHFFFAOYSA-N 1,3-dichloro-2,2-bis(chloromethyl)propane Chemical compound ClCC(CCl)(CCl)CCl KPZGRMZPZLOPBS-UHFFFAOYSA-N 0.000 claims 1
- 230000000052 comparative effect Effects 0.000 claims 1
- 230000003247 decreasing effect Effects 0.000 claims 1
- YNLAOSYQHBDIKW-UHFFFAOYSA-M diethylaluminium chloride Chemical compound CC[Al](Cl)CC YNLAOSYQHBDIKW-UHFFFAOYSA-M 0.000 claims 1
- 238000001035 drying Methods 0.000 claims 1
- 238000005984 hydrogenation reaction Methods 0.000 claims 1
- BDERNNFJNOPAEC-UHFFFAOYSA-N propan-1-ol Chemical compound CCCO BDERNNFJNOPAEC-UHFFFAOYSA-N 0.000 claims 1
- 230000035484 reaction time Effects 0.000 claims 1
- 238000007670 refining Methods 0.000 claims 1
- 230000009466 transformation Effects 0.000 claims 1
- JRZJOMJEPLMPRA-UHFFFAOYSA-N olefin Natural products CCCCCCCC=C JRZJOMJEPLMPRA-UHFFFAOYSA-N 0.000 description 3
- 230000015572 biosynthetic process Effects 0.000 description 2
- 229920000642 polymer Polymers 0.000 description 2
- 229920000098 polyolefin Polymers 0.000 description 2
- NINIDFKCEFEMDL-UHFFFAOYSA-N Sulfur Chemical compound [S] NINIDFKCEFEMDL-UHFFFAOYSA-N 0.000 description 1
- 230000003213 activating effect Effects 0.000 description 1
- HSFWRNGVRCDJHI-UHFFFAOYSA-N alpha-acetylene Natural products C#C HSFWRNGVRCDJHI-UHFFFAOYSA-N 0.000 description 1
- AZDRQVAHHNSJOQ-UHFFFAOYSA-N alumane Chemical class [AlH3] AZDRQVAHHNSJOQ-UHFFFAOYSA-N 0.000 description 1
- 229910052782 aluminium Inorganic materials 0.000 description 1
- XAGFODPZIPBFFR-UHFFFAOYSA-N aluminium Chemical compound [Al] XAGFODPZIPBFFR-UHFFFAOYSA-N 0.000 description 1
- 238000010924 continuous production Methods 0.000 description 1
- 239000002283 diesel fuel Substances 0.000 description 1
- 230000008030 elimination Effects 0.000 description 1
- 238000003379 elimination reaction Methods 0.000 description 1
- 125000002534 ethynyl group Chemical group [H]C#C* 0.000 description 1
- 230000002349 favourable effect Effects 0.000 description 1
- 239000012535 impurity Substances 0.000 description 1
- 230000005087 leaf formation Effects 0.000 description 1
- QQONPFPTGQHPMA-UHFFFAOYSA-N propylene Natural products CC=C QQONPFPTGQHPMA-UHFFFAOYSA-N 0.000 description 1
- 125000004805 propylene group Chemical group [H]C([H])([H])C([H])([*:1])C([H])([H])[*:2] 0.000 description 1
- 229910052717 sulfur Inorganic materials 0.000 description 1
- 239000011593 sulfur Substances 0.000 description 1
- 125000000383 tetramethylene group Chemical group [H]C([H])([*:1])C([H])([H])C([H])([H])C([H])([H])[*:2] 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F10/00—Homopolymers and copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
Landscapes
- Chemical & Material Sciences (AREA)
- Health & Medical Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Organic Chemistry (AREA)
- Transition And Organic Metals Composition Catalysts For Addition Polymerization (AREA)
- Addition Polymer Or Copolymer, Post-Treatments, Or Chemical Modifications (AREA)
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| DER20247A DE1195496B (de) | 1956-12-22 | 1956-12-22 | Verfahren zur Polymerisation von AEthylen |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| BE563417A true BE563417A (en, 2012) |
Family
ID=7400625
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| BE563417D BE563417A (en, 2012) | 1956-12-22 |
Country Status (4)
| Country | Link |
|---|---|
| BE (1) | BE563417A (en, 2012) |
| DE (1) | DE1195496B (en, 2012) |
| FR (1) | FR1188360A (en, 2012) |
| NL (2) | NL107937C (en, 2012) |
Families Citing this family (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US3168588A (en) * | 1960-09-14 | 1965-02-02 | Exxon Research Engineering Co | Polymerized ethylene lubricating oils from alkanol modified catalysts |
| FR2152503B1 (en, 2012) * | 1971-09-07 | 1977-04-01 | Monsanto Co |
Family Cites Families (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| DE1012460B (de) * | 1953-11-17 | 1957-07-18 | Dr Dr E H Karl Ziegler | Verfahren zur Herstellung von hochmolekularen Polyaethylenen |
| CH356913A (de) * | 1954-06-08 | 1961-09-15 | Montedison Spa | Verfahren zur Polymerisation von olefinisch ungesättigten Kohlenwasserstoffen |
-
0
- NL NL213703D patent/NL213703A/xx unknown
- BE BE563417D patent/BE563417A/fr unknown
- NL NL107937D patent/NL107937C/xx active
-
1956
- 1956-12-22 DE DER20247A patent/DE1195496B/de active Pending
-
1957
- 1957-12-14 FR FR1188360D patent/FR1188360A/fr not_active Expired
Also Published As
| Publication number | Publication date |
|---|---|
| NL107937C (en, 2012) | |
| DE1195496B (de) | 1965-06-24 |
| FR1188360A (fr) | 1959-09-22 |
| NL213703A (en, 2012) |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| EP0373999B1 (fr) | Procédé de polymérisation en phase gazeuse de l'éthylène permettant la fabrication de polyéthylène linéaire de distribution étroite de masse moléculaire | |
| CA2156843A1 (fr) | Procede de production d'olefines alpha legeres de purete amelioree par oligomerisation de l'ethylene | |
| FR2503715A1 (fr) | Catalyseur de polymerisation d'olefines, son procede de production et son utilisation | |
| FR2549073A1 (fr) | Procede pour preparer des copolymeres d'ethylene et d'a-olefines a chaine longue | |
| BE563417A (en, 2012) | ||
| EP0232643B1 (fr) | Procédé de traitement de catalyseurs sphériques de polymérisation des oléfines. Application du catalyseur obtenu à la polymérisation des oléfines | |
| BE1017695A3 (fr) | Procede de production de polymere de propylene en utilisant un compose d'alcoxysilane contenant un groupement trialkylsilyle dans la structure moleculaire. | |
| EP0116248B1 (fr) | Procédé continu amélioré de fabrication d'homopolymères ou de copolymères de l'éthylène | |
| EP0370864B1 (fr) | Procédé de polymérisation de l'éthylène permettant d'obtenir un polymère de distribution large de masses moleculaires, procédé de traitement de la composante catalytique | |
| FR2530645A1 (fr) | Procede de production de polyethylene lineaire basse densite et produit obtenu | |
| JPS5910361B2 (ja) | オレフイン重合方法 | |
| FR2462452A1 (fr) | Procede de copolymerisation sequencee d'ethylene et de propylene et produit obtenu | |
| EP0559885B1 (fr) | Catalyseurs et procede de preparation de catalyseurs utilisables pour la polymerisation de l'ethylene | |
| EP0143716A2 (fr) | Procédé perfectionné de polymérisation et copolymérisation de l'étylène à pressions et températures élevées en présence de catalyseurs type ziegler | |
| EP0003716A1 (fr) | Procédé de polymérisation d'oléfines, système catalytique utilisé et sa préparation | |
| FR2491058A1 (fr) | Procede ameliore de synthese catalytique du methane par reaction de l'hydrogene avec le monoxyde de carbone | |
| EP0554139A1 (fr) | Procédé de polymérisation de l'éthylène permettant d'obtenir un polymère de distribution large de masses moléculaires, procédé de traitement de la composante catalytique | |
| BE583699A (en, 2012) | ||
| BE569476A (en, 2012) | ||
| FR2686595A1 (fr) | Procede de fabrication de mgcl2, mgo de repartition granulometrique etroite. application de ce compose comme support de composante catalytique de polymerisation des olefines. | |
| BE656914A (fr) | Procede de preparation de composes d'aluminium-trialcoyle. | |
| BE588611A (en, 2012) | ||
| BE579209A (en, 2012) | ||
| BE559842A (en, 2012) | ||
| BE701409A (en, 2012) |