BE373013A - - Google Patents

Info

Publication number

BE373013A

BE373013A BE373013DA BE373013A BE 373013 A BE373013 A BE 373013A BE 373013D A BE373013D A BE 373013DA BE 373013 A BE373013 A BE 373013A

Authority

BE

Belgium

Prior art keywords

cellulose

diphenyl

organic substance

benzidine

organic

Prior art date

Links

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• 239000000126 substance Substances 0.000 claims description 53
• 238000009987 spinning Methods 0.000 claims description 39
• 229920002678 cellulose Polymers 0.000 claims description 20
• 239000004305 biphenyl Substances 0.000 claims description 15
• 239000001913 cellulose Substances 0.000 claims description 15
• 239000002904 solvent Substances 0.000 claims description 14
• 239000000047 product Substances 0.000 claims description 13
• 229920002301 Cellulose acetate Polymers 0.000 claims description 12
• 239000002245 particle Substances 0.000 claims description 9
• 238000004519 manufacturing process Methods 0.000 claims description 8
• 239000003960 organic solvent Substances 0.000 claims description 7
• XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims description 7
• 238000000034 method Methods 0.000 claims description 6
• XSQUKJJJFZCRTK-UHFFFAOYSA-N urea Chemical compound NC(N)=O XSQUKJJJFZCRTK-UHFFFAOYSA-N 0.000 claims description 6
• 239000002253 acid Substances 0.000 claims description 5
• 239000012237 artificial material Substances 0.000 claims description 5
• 235000010290 biphenyl Nutrition 0.000 claims description 5
• 125000006267 biphenyl group Chemical group 0.000 claims description 5
• 238000002844 melting Methods 0.000 claims description 5
• 150000007513 acids Chemical class 0.000 claims description 4
• 239000004744 fabric Substances 0.000 claims description 4
• CZVHCFKUXGRABC-UHFFFAOYSA-N N,N'-Diacetylbenzidine Chemical compound C1=CC(NC(=O)C)=CC=C1C1=CC=C(NC(C)=O)C=C1 CZVHCFKUXGRABC-UHFFFAOYSA-N 0.000 claims description 3
• GSPPYQYDYGNLGX-UHFFFAOYSA-N N-[4-(4-benzamidophenyl)phenyl]benzamide Chemical compound C=1C=CC=CC=1C(=O)NC(C=C1)=CC=C1C(C=C1)=CC=C1NC(=O)C1=CC=CC=C1 GSPPYQYDYGNLGX-UHFFFAOYSA-N 0.000 claims description 3
• UMGDCJDMYOKAJW-UHFFFAOYSA-N Thiourea Chemical compound NC(N)=S UMGDCJDMYOKAJW-UHFFFAOYSA-N 0.000 claims description 3
• 239000004202 carbamide Substances 0.000 claims description 3
• 229920003086 cellulose ether Polymers 0.000 claims description 3
• 239000007859 condensation product Substances 0.000 claims description 3
• 150000002148 esters Chemical class 0.000 claims description 3
• ZJHHPAUQMCHPRB-UHFFFAOYSA-N urea urea Chemical compound NC(N)=O.NC(N)=O ZJHHPAUQMCHPRB-UHFFFAOYSA-N 0.000 claims description 3
• RTZKZFJDLAIYFH-UHFFFAOYSA-N diethyl ether Chemical compound CCOCC RTZKZFJDLAIYFH-UHFFFAOYSA-N 0.000 claims 4
• 239000002932 luster Substances 0.000 description 13
• 239000000463 material Substances 0.000 description 8
• CSCPPACGZOOCGX-UHFFFAOYSA-N acetone Chemical compound CC(C)=O CSCPPACGZOOCGX-UHFFFAOYSA-N 0.000 description 6
• 230000002238 attenuated Effects 0.000 description 6
• RZVHIXYEVGDQDX-UHFFFAOYSA-N Anthraquinone Chemical compound C1=CC=C2C(=O)C3=CC=CC=C3C(=O)C2=C1 RZVHIXYEVGDQDX-UHFFFAOYSA-N 0.000 description 5
• 235000010980 cellulose Nutrition 0.000 description 4
• 230000000694 effects Effects 0.000 description 4
• 150000004056 anthraquinones Chemical class 0.000 description 3
• 230000001112 coagulant Effects 0.000 description 3
• 150000001875 compounds Chemical class 0.000 description 3
• 230000003292 diminished Effects 0.000 description 3
• 239000006185 dispersion Substances 0.000 description 3
• 238000000578 dry spinning Methods 0.000 description 3
• 238000010348 incorporation Methods 0.000 description 3
• 238000002360 preparation method Methods 0.000 description 3
• UJOBWOGCFQCDNV-UHFFFAOYSA-N Carbazole Chemical compound C1=CC=C2C3=CC=CC=C3NC2=C1 UJOBWOGCFQCDNV-UHFFFAOYSA-N 0.000 description 2
• ZQPPMHVWECSIRJ-KTKRTIGZSA-N Oleic acid Chemical compound CCCCCCCC\C=C/CCCCCCCC(O)=O ZQPPMHVWECSIRJ-KTKRTIGZSA-N 0.000 description 2
• QTBSBXVTEAMEQO-UHFFFAOYSA-M acetate Chemical compound CC([O-])=O QTBSBXVTEAMEQO-UHFFFAOYSA-M 0.000 description 2
• 239000000835 fiber Substances 0.000 description 2
• 238000000227 grinding Methods 0.000 description 2
• 239000007788 liquid Substances 0.000 description 2
• 239000003921 oil Substances 0.000 description 2
• 235000019198 oils Nutrition 0.000 description 2
• 238000001556 precipitation Methods 0.000 description 2
• 239000000725 suspension Substances 0.000 description 2
• 238000002166 wet spinning Methods 0.000 description 2
• KJGPMAHVCDFRBN-UHFFFAOYSA-N 2,6-dichloroanthracene-9,10-dione Chemical compound ClC1=CC=C2C(=O)C3=CC(Cl)=CC=C3C(=O)C2=C1 KJGPMAHVCDFRBN-UHFFFAOYSA-N 0.000 description 1
• AFPRJLBZLPBTPZ-UHFFFAOYSA-N Acenaphthoquinone Chemical compound C1=CC(C(C2=O)=O)=C3C2=CC=CC3=C1 AFPRJLBZLPBTPZ-UHFFFAOYSA-N 0.000 description 1
• MWPLVEDNUUSJAV-UHFFFAOYSA-N Anthracene Chemical compound C1=CC=CC2=CC3=CC=CC=C3C=C21 MWPLVEDNUUSJAV-UHFFFAOYSA-N 0.000 description 1
• 229920002955 Art silk Polymers 0.000 description 1
• HFACYLZERDEVSX-UHFFFAOYSA-N Benzidine Chemical class C1=CC(N)=CC=C1C1=CC=C(N)C=C1 HFACYLZERDEVSX-UHFFFAOYSA-N 0.000 description 1
• 229920000742 Cotton Polymers 0.000 description 1
• FTWUXYZHDFCGSV-UHFFFAOYSA-N N,N'-diphenyloxamide Chemical compound C=1C=CC=CC=1NC(=O)C(=O)NC1=CC=CC=C1 FTWUXYZHDFCGSV-UHFFFAOYSA-N 0.000 description 1
• 239000000020 Nitrocellulose Substances 0.000 description 1
• 239000005642 Oleic acid Substances 0.000 description 1
• YNPNZTXNASCQKK-UHFFFAOYSA-N Phenanthrene Chemical compound C1=CC=C2C3=CC=CC=C3C=CC2=C1 YNPNZTXNASCQKK-UHFFFAOYSA-N 0.000 description 1
• 229920000297 Rayon Polymers 0.000 description 1
• 210000002268 Wool Anatomy 0.000 description 1
• FJWGYAHXMCUOOM-QHOUIDNNSA-N [(2S,3R,4S,5R,6R)-2-[(2R,3R,4S,5R,6S)-4,5-dinitrooxy-2-(nitrooxymethyl)-6-[(2R,3R,4S,5R,6S)-4,5,6-trinitrooxy-2-(nitrooxymethyl)oxan-3-yl]oxyoxan-3-yl]oxy-3,5-dinitrooxy-6-(nitrooxymethyl)oxan-4-yl] nitrate Chemical compound O([C@@H]1O[C@@H]([C@H]([C@H](O[N+]([O-])=O)[C@H]1O[N+]([O-])=O)O[C@H]1[C@@H]([C@@H](O[N+]([O-])=O)[C@H](O[N+]([O-])=O)[C@@H](CO[N+]([O-])=O)O1)O[N+]([O-])=O)CO[N+](=O)[O-])[C@@H]1[C@@H](CO[N+]([O-])=O)O[C@@H](O[N+]([O-])=O)[C@H](O[N+]([O-])=O)[C@H]1O[N+]([O-])=O FJWGYAHXMCUOOM-QHOUIDNNSA-N 0.000 description 1
• 238000006640 acetylation reaction Methods 0.000 description 1
• 125000001797 benzyl group Chemical group [H]C1=C([H])C([H])=C(C([H])=C1[H])C([H])([H])* 0.000 description 1
• 230000015572 biosynthetic process Effects 0.000 description 1
• FERIUCNNQQJTOY-UHFFFAOYSA-M butyrate Chemical compound CCCC([O-])=O FERIUCNNQQJTOY-UHFFFAOYSA-M 0.000 description 1
• 239000003153 chemical reaction reagent Substances 0.000 description 1
• 239000000701 coagulant Substances 0.000 description 1
• 239000000084 colloidal system Substances 0.000 description 1
• 230000000875 corresponding Effects 0.000 description 1
• 239000002270 dispersing agent Substances 0.000 description 1
• 238000004090 dissolution Methods 0.000 description 1
• 238000005886 esterification reaction Methods 0.000 description 1
• 125000001495 ethyl group Chemical group [H]C([H])([H])C([H])([H])* 0.000 description 1
• 238000001914 filtration Methods 0.000 description 1
• 238000005755 formation reaction Methods 0.000 description 1
• 238000009940 knitting Methods 0.000 description 1
• 239000000944 linseed oil Substances 0.000 description 1
• 235000021388 linseed oil Nutrition 0.000 description 1
• 230000001404 mediated Effects 0.000 description 1
• BDAGIHXWWSANSR-UHFFFAOYSA-M methanoate Chemical compound [O-]C=O BDAGIHXWWSANSR-UHFFFAOYSA-M 0.000 description 1
• 125000002496 methyl group Chemical group [H]C([H])([H])* 0.000 description 1
• 238000002156 mixing Methods 0.000 description 1
• 239000000203 mixture Substances 0.000 description 1
• 229920001220 nitrocellulos Polymers 0.000 description 1
• 230000000414 obstructive Effects 0.000 description 1
• 235000021313 oleic acid Nutrition 0.000 description 1
• 239000004006 olive oil Substances 0.000 description 1
• 235000008390 olive oil Nutrition 0.000 description 1
• 230000001376 precipitating Effects 0.000 description 1
• XBDQKXXYIPTUBI-UHFFFAOYSA-M propionate Chemical compound CCC([O-])=O XBDQKXXYIPTUBI-UHFFFAOYSA-M 0.000 description 1
• 230000001681 protective Effects 0.000 description 1
• 230000005070 ripening Effects 0.000 description 1
• QAOWNCQODCNURD-UHFFFAOYSA-N sulfuric acid Substances OS(O)(=O)=O QAOWNCQODCNURD-UHFFFAOYSA-N 0.000 description 1
• 238000009941 weaving Methods 0.000 description 1