AU688382B2 - Binders based on fat chemical reaction products - Google Patents
Binders based on fat chemical reaction productsInfo
- Publication number
- AU688382B2 AU688382B2 AU78132/94A AU7813294A AU688382B2 AU 688382 B2 AU688382 B2 AU 688382B2 AU 78132/94 A AU78132/94 A AU 78132/94A AU 7813294 A AU7813294 A AU 7813294A AU 688382 B2 AU688382 B2 AU 688382B2
- Authority
- AU
- Australia
- Prior art keywords
- reaction products
- fats
- binders
- chemical reaction
- reacting
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Ceased
Links
Classifications
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09K—MATERIALS FOR MISCELLANEOUS APPLICATIONS, NOT PROVIDED FOR ELSEWHERE
- C09K3/00—Materials not provided for elsewhere
- C09K3/10—Materials in mouldable or extrudable form for sealing or packing joints or covers
-
- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B24/00—Use of organic materials as active ingredients for mortars, concrete or artificial stone, e.g. plasticisers
- C04B24/02—Alcohols; Phenols; Ethers
- C04B24/026—Fatty alcohols
-
- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B24/00—Use of organic materials as active ingredients for mortars, concrete or artificial stone, e.g. plasticisers
- C04B24/08—Fats; Fatty oils; Ester type waxes; Higher fatty acids, i.e. having at least seven carbon atoms in an unbroken chain bound to a carboxyl group; Oxidised oils or fats
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K5/00—Use of organic ingredients
- C08K5/04—Oxygen-containing compounds
- C08K5/10—Esters; Ether-esters
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K5/00—Use of organic ingredients
- C08K5/04—Oxygen-containing compounds
- C08K5/10—Esters; Ether-esters
- C08K5/101—Esters; Ether-esters of monocarboxylic acids
- C08K5/103—Esters; Ether-esters of monocarboxylic acids with polyalcohols
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L91/00—Compositions of oils, fats or waxes; Compositions of derivatives thereof
- C08L91/005—Drying oils
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D131/00—Coating compositions based on homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by an acyloxy radical of a saturated carboxylic acid, of carbonic acid, or of a haloformic acid; Coating compositions based on derivatives of such polymers
- C09D131/02—Homopolymers or copolymers of esters of monocarboxylic acids
- C09D131/04—Homopolymers or copolymers of vinyl acetate
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09J—ADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
- C09J1/00—Adhesives based on inorganic constituents
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09J—ADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
- C09J11/00—Features of adhesives not provided for in group C09J9/00, e.g. additives
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09J—ADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
- C09J11/00—Features of adhesives not provided for in group C09J9/00, e.g. additives
- C09J11/02—Non-macromolecular additives
- C09J11/06—Non-macromolecular additives organic
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09J—ADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
- C09J11/00—Features of adhesives not provided for in group C09J9/00, e.g. additives
- C09J11/08—Macromolecular additives
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09J—ADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
- C09J125/00—Adhesives based on homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by an aromatic carbocyclic ring; Adhesives based on derivatives of such polymers
- C09J125/02—Homopolymers or copolymers of hydrocarbons
- C09J125/04—Homopolymers or copolymers of styrene
- C09J125/06—Polystyrene
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09J—ADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
- C09J127/00—Adhesives based on homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a halogen; Adhesives based on derivatives of such polymers
- C09J127/02—Adhesives based on homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a halogen; Adhesives based on derivatives of such polymers not modified by chemical after-treatment
- C09J127/04—Adhesives based on homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a halogen; Adhesives based on derivatives of such polymers not modified by chemical after-treatment containing chlorine atoms
- C09J127/06—Homopolymers or copolymers of vinyl chloride
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09J—ADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
- C09J131/00—Adhesives based on homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by an acyloxy radical of a saturated carboxylic acid, of carbonic acid, or of a haloformic acid; Adhesives based on derivatives of such polymers
- C09J131/02—Homopolymers or copolymers of esters of monocarboxylic acids
- C09J131/04—Homopolymers or copolymers of vinyl acetate
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09J—ADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
- C09J191/00—Adhesives based on oils, fats or waxes; Adhesives based on derivatives thereof
- C09J191/005—Drying oils
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2666/00—Composition of polymers characterized by a further compound in the blend, being organic macromolecular compounds, natural resins, waxes or and bituminous materials, non-macromolecular organic substances, inorganic substances or characterized by their function in the composition
- C08L2666/28—Non-macromolecular organic substances
- C08L2666/34—Oxygen-containing compounds, including ammonium and metal salts
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09K—MATERIALS FOR MISCELLANEOUS APPLICATIONS, NOT PROVIDED FOR ELSEWHERE
- C09K2200/00—Chemical nature of materials in mouldable or extrudable form for sealing or packing joints or covers
- C09K2200/04—Non-macromolecular organic compounds
- C09K2200/0441—Carboxylic acids, salts, anhydrides or esters thereof
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09K—MATERIALS FOR MISCELLANEOUS APPLICATIONS, NOT PROVIDED FOR ELSEWHERE
- C09K2200/00—Chemical nature of materials in mouldable or extrudable form for sealing or packing joints or covers
- C09K2200/04—Non-macromolecular organic compounds
- C09K2200/0447—Fats, fatty oils, higher fatty acids or derivatives thereof
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09K—MATERIALS FOR MISCELLANEOUS APPLICATIONS, NOT PROVIDED FOR ELSEWHERE
- C09K2200/00—Chemical nature of materials in mouldable or extrudable form for sealing or packing joints or covers
- C09K2200/06—Macromolecular organic compounds, e.g. prepolymers
- C09K2200/0615—Macromolecular organic compounds, e.g. prepolymers obtained by reactions only involving carbon-to-carbon unsaturated bonds
- C09K2200/0632—Polystyrenes
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Engineering & Computer Science (AREA)
- Oil, Petroleum & Natural Gas (AREA)
- Materials Engineering (AREA)
- Ceramic Engineering (AREA)
- Polymers & Plastics (AREA)
- Health & Medical Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Structural Engineering (AREA)
- Life Sciences & Earth Sciences (AREA)
- Wood Science & Technology (AREA)
- Inorganic Chemistry (AREA)
- Adhesives Or Adhesive Processes (AREA)
- Fats And Perfumes (AREA)
- Working-Up Tar And Pitch (AREA)
- Polyurethanes Or Polyureas (AREA)
- Epoxy Resins (AREA)
- Compositions Of Macromolecular Compounds (AREA)
- Polyethers (AREA)
- Addition Polymer Or Copolymer, Post-Treatments, Or Chemical Modifications (AREA)
Abstract
Reaction products have more than 1,500 molecular weight and are produced by reacting: A) fats having 1 to 10, preferably 1.5 to 6 units of at least one of the functional groups -OH, -COOH, -SH, -NH2, -C=C-, an epoxide group or an acid anhydride group in the fat radical, the fat containing at least 1 % by moles of at least three-functional fats, with B) at least one mono- or multifunctional compound capable of reacting with the functional groups of the fats. The reaction products are preferably dispersed as liquids in water. These binders are suitable for coating, sealing and binding, in particular gluing, alone or combined with known glues and polymer dispersions. Glue dispersions, pressure-sensitive masses, universal glues and glue sticks may in particular be produced from these binders.
Applications Claiming Priority (5)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
DE4335672 | 1993-10-20 | ||
DE4335672 | 1993-10-20 | ||
DE4430875 | 1994-08-31 | ||
DE4430875A DE4430875A1 (en) | 1993-10-20 | 1994-08-31 | binder |
PCT/EP1994/003351 WO1995011284A2 (en) | 1993-10-20 | 1994-10-12 | Binders based on fat chemical reaction products |
Publications (2)
Publication Number | Publication Date |
---|---|
AU7813294A AU7813294A (en) | 1995-05-08 |
AU688382B2 true AU688382B2 (en) | 1998-03-12 |
Family
ID=25930542
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
AU78132/94A Ceased AU688382B2 (en) | 1993-10-20 | 1994-10-12 | Binders based on fat chemical reaction products |
Country Status (13)
Country | Link |
---|---|
EP (1) | EP0724613B1 (en) |
JP (1) | JPH09504045A (en) |
CN (1) | CN1133606A (en) |
AT (1) | ATE213503T1 (en) |
AU (1) | AU688382B2 (en) |
CA (1) | CA2174502A1 (en) |
CZ (1) | CZ113496A3 (en) |
DK (1) | DK0724613T3 (en) |
ES (1) | ES2173125T3 (en) |
HU (1) | HU217178B (en) |
PL (1) | PL184822B1 (en) |
SK (1) | SK25796A3 (en) |
WO (1) | WO1995011284A2 (en) |
Families Citing this family (14)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
DE19624148A1 (en) | 1995-06-22 | 1997-01-02 | Henkel Kgaa | Adhesive, sealing and coating compsn. based on styrene] copolymer |
PT1038910E (en) * | 1995-08-11 | 2004-11-30 | Henkel Kgaa | COLOFONIUM RESINS SOLUTIONS |
DE19755535A1 (en) * | 1997-12-13 | 1999-06-17 | Henkel Kgaa | Binder based on oleochemical reaction products |
DE10015913A1 (en) * | 1999-04-16 | 2000-10-19 | Henkel Kgaa | Adducts used as binders for adhesives or as tackifiers are obtained from unsaturated natural fats or oils by ene or Diels-Alder reactions followed by radical or oxidative treatment |
US7686877B2 (en) * | 2005-05-18 | 2010-03-30 | Ciba Corporation | Pigmented tinting concentrates comprising a diels alder humectant |
JP5520066B2 (en) * | 2009-03-02 | 2014-06-11 | ローム アンド ハース カンパニー | Bio-based polyol |
BR112013003759A2 (en) * | 2010-08-18 | 2016-05-31 | Avery Dennison Corp | pressure sensitive adhesives based on renewable sources and related methods |
TWI473868B (en) * | 2011-09-29 | 2015-02-21 | Ind Tech Res Inst | Adhesive composition, glue and manufacturing method for the same and adhesive tape |
CO6650065A1 (en) * | 2011-10-03 | 2013-04-15 | Indupalma Ltda | Processes for obtaining a polyol from palm oil, polyols obtained from said processes, products derived from said polyol and their method of preparation |
MX356868B (en) | 2012-04-09 | 2018-06-18 | Avery Dennison Corp | Pressure sensitive adhesives based on renewable resources, uv curing and related methods. |
CN106396608B (en) * | 2016-08-30 | 2019-03-22 | 福建省泉州市契合工贸有限公司 | Ceramics and preparation method thereof with abrasive rubber surface layer |
CN106928866A (en) * | 2017-01-22 | 2017-07-07 | 广西玉林市禹力音响配件有限公司 | A kind of bulging paper glue special and preparation method thereof |
EP3917986A1 (en) * | 2019-01-29 | 2021-12-08 | !OBAC Limited | Magnetic flooring system adhesive composition |
WO2024128009A1 (en) * | 2022-12-15 | 2024-06-20 | Dic株式会社 | Adhesive composition, multilayer body and packaging material |
Citations (3)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
GB907782A (en) * | 1958-03-11 | 1962-10-10 | Berger Jensen & Nicholson Ltd | Improvements in or relating to stoving surface coating compositions |
EP0256467A2 (en) * | 1986-08-18 | 1988-02-24 | Henkel Kommanditgesellschaft auf Aktien | Low molecular weight polycondensates and their use in aqueous adhesive dispersions |
WO1991001980A2 (en) * | 1989-08-09 | 1991-02-21 | Battelle-Institut E.V. | Process for preparing plastics from raw fats and oils |
Family Cites Families (5)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
FR1132976A (en) * | 1954-06-25 | 1957-03-19 | Exxon Research Engineering Co | Process for improving the properties of synthetic drying oils |
NL292342A (en) * | 1962-05-07 | |||
DE3347045A1 (en) * | 1983-12-24 | 1985-07-04 | Henkel KGaA, 4000 Düsseldorf | TWO COMPONENT POLYURETHANE ADHESIVE |
DE4019087C3 (en) * | 1989-06-29 | 2001-01-18 | Frische Gmbh | Novel plastics based on fatty acids |
WO1991002016A1 (en) * | 1989-08-09 | 1991-02-21 | Battelle-Institut E.V. | New monomeric units obtained from hydroxy fatty acids, for manufacturing plastics |
-
1994
- 1994-10-12 EP EP94928891A patent/EP0724613B1/en not_active Revoked
- 1994-10-12 AU AU78132/94A patent/AU688382B2/en not_active Ceased
- 1994-10-12 ES ES94928891T patent/ES2173125T3/en not_active Expired - Lifetime
- 1994-10-12 AT AT94928891T patent/ATE213503T1/en not_active IP Right Cessation
- 1994-10-12 WO PCT/EP1994/003351 patent/WO1995011284A2/en not_active Application Discontinuation
- 1994-10-12 CZ CZ961134A patent/CZ113496A3/en unknown
- 1994-10-12 CN CN94193822A patent/CN1133606A/en active Pending
- 1994-10-12 DK DK94928891T patent/DK0724613T3/en active
- 1994-10-12 CA CA002174502A patent/CA2174502A1/en not_active Abandoned
- 1994-10-12 PL PL94314104A patent/PL184822B1/en not_active IP Right Cessation
- 1994-10-12 SK SK257-96A patent/SK25796A3/en unknown
- 1994-10-12 JP JP7511278A patent/JPH09504045A/en active Pending
- 1994-10-12 HU HU9601007A patent/HU217178B/en not_active IP Right Cessation
Patent Citations (3)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
GB907782A (en) * | 1958-03-11 | 1962-10-10 | Berger Jensen & Nicholson Ltd | Improvements in or relating to stoving surface coating compositions |
EP0256467A2 (en) * | 1986-08-18 | 1988-02-24 | Henkel Kommanditgesellschaft auf Aktien | Low molecular weight polycondensates and their use in aqueous adhesive dispersions |
WO1991001980A2 (en) * | 1989-08-09 | 1991-02-21 | Battelle-Institut E.V. | Process for preparing plastics from raw fats and oils |
Also Published As
Publication number | Publication date |
---|---|
ES2173125T3 (en) | 2002-10-16 |
HUT74048A (en) | 1996-10-28 |
AU7813294A (en) | 1995-05-08 |
WO1995011284A3 (en) | 1995-06-01 |
SK25796A3 (en) | 1997-07-09 |
DK0724613T3 (en) | 2002-05-13 |
WO1995011284A2 (en) | 1995-04-27 |
HU9601007D0 (en) | 1996-06-28 |
PL314104A1 (en) | 1996-08-19 |
CZ113496A3 (en) | 1996-07-17 |
PL184822B1 (en) | 2002-12-31 |
HU217178B (en) | 1999-12-28 |
EP0724613B1 (en) | 2002-02-20 |
CN1133606A (en) | 1996-10-16 |
CA2174502A1 (en) | 1995-04-27 |
EP0724613A1 (en) | 1996-08-07 |
ATE213503T1 (en) | 2002-03-15 |
JPH09504045A (en) | 1997-04-22 |
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Legal Events
Date | Code | Title | Description |
---|---|---|---|
MK14 | Patent ceased section 143(a) (annual fees not paid) or expired |