AU683913B2 - Combined paraffin isomerization/ring opening process - Google Patents
Combined paraffin isomerization/ring opening process Download PDFInfo
- Publication number
- AU683913B2 AU683913B2 AU73670/94A AU7367094A AU683913B2 AU 683913 B2 AU683913 B2 AU 683913B2 AU 73670/94 A AU73670/94 A AU 73670/94A AU 7367094 A AU7367094 A AU 7367094A AU 683913 B2 AU683913 B2 AU 683913B2
- Authority
- AU
- Australia
- Prior art keywords
- catalyst
- hydrocarbons
- reaction zone
- process according
- hydrogen
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Ceased
Links
- 238000000034 method Methods 0.000 title claims description 75
- 230000008569 process Effects 0.000 title claims description 70
- 238000006317 isomerization reaction Methods 0.000 title claims description 60
- 238000007142 ring opening reaction Methods 0.000 title claims description 56
- 239000012188 paraffin wax Substances 0.000 title claims description 16
- 239000003054 catalyst Substances 0.000 claims description 228
- 238000006243 chemical reaction Methods 0.000 claims description 93
- 229930195733 hydrocarbon Natural products 0.000 claims description 90
- 229910052751 metal Inorganic materials 0.000 claims description 86
- 239000002184 metal Substances 0.000 claims description 86
- 150000002430 hydrocarbons Chemical class 0.000 claims description 77
- BASFCYQUMIYNBI-UHFFFAOYSA-N platinum Chemical compound [Pt] BASFCYQUMIYNBI-UHFFFAOYSA-N 0.000 claims description 72
- 229910052739 hydrogen Inorganic materials 0.000 claims description 60
- 239000001257 hydrogen Substances 0.000 claims description 57
- UFHFLCQGNIYNRP-UHFFFAOYSA-N Hydrogen Chemical compound [H][H] UFHFLCQGNIYNRP-UHFFFAOYSA-N 0.000 claims description 54
- -1 IVA metals Chemical class 0.000 claims description 35
- 239000004215 Carbon black (E152) Substances 0.000 claims description 33
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- 238000005984 hydrogenation reaction Methods 0.000 claims description 30
- 229910044991 metal oxide Inorganic materials 0.000 claims description 29
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- 125000002887 hydroxy group Chemical group [H]O* 0.000 description 4
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- 150000002736 metal compounds Chemical class 0.000 description 1
- 239000011707 mineral Substances 0.000 description 1
- PDKHNCYLMVRIFV-UHFFFAOYSA-H molybdenum;hexachloride Chemical compound [Cl-].[Cl-].[Cl-].[Cl-].[Cl-].[Cl-].[Mo] PDKHNCYLMVRIFV-UHFFFAOYSA-H 0.000 description 1
- VLAPMBHFAWRUQP-UHFFFAOYSA-L molybdic acid Chemical compound O[Mo](O)(=O)=O VLAPMBHFAWRUQP-UHFFFAOYSA-L 0.000 description 1
- 229910052901 montmorillonite Inorganic materials 0.000 description 1
- 229910052680 mordenite Inorganic materials 0.000 description 1
- IJDNQMDRQITEOD-UHFFFAOYSA-N n-butane Chemical compound CCCC IJDNQMDRQITEOD-UHFFFAOYSA-N 0.000 description 1
- 230000003472 neutralizing effect Effects 0.000 description 1
- 150000002823 nitrates Chemical class 0.000 description 1
- 231100000989 no adverse effect Toxicity 0.000 description 1
- QGLKJKCYBOYXKC-UHFFFAOYSA-N nonaoxidotritungsten Chemical compound O=[W]1(=O)O[W](=O)(=O)O[W](=O)(=O)O1 QGLKJKCYBOYXKC-UHFFFAOYSA-N 0.000 description 1
- 230000003647 oxidation Effects 0.000 description 1
- 238000007254 oxidation reaction Methods 0.000 description 1
- 230000001590 oxidative effect Effects 0.000 description 1
- 125000004430 oxygen atom Chemical group O* 0.000 description 1
- 230000036961 partial effect Effects 0.000 description 1
- 238000005453 pelletization Methods 0.000 description 1
- 150000003057 platinum Chemical class 0.000 description 1
- 150000003058 platinum compounds Chemical class 0.000 description 1
- FHMDYDAXYDRBGZ-UHFFFAOYSA-N platinum tin Chemical compound [Sn].[Pt] FHMDYDAXYDRBGZ-UHFFFAOYSA-N 0.000 description 1
- 239000002574 poison Substances 0.000 description 1
- 231100000614 poison Toxicity 0.000 description 1
- 231100000572 poisoning Toxicity 0.000 description 1
- 230000000607 poisoning effect Effects 0.000 description 1
- 239000011148 porous material Substances 0.000 description 1
- 239000000843 powder Substances 0.000 description 1
- 239000002244 precipitate Substances 0.000 description 1
- 230000008707 rearrangement Effects 0.000 description 1
- 238000011160 research Methods 0.000 description 1
- 230000000717 retained effect Effects 0.000 description 1
- 238000012552 review Methods 0.000 description 1
- WUAPFZMCVAUBPE-UHFFFAOYSA-N rhenium atom Chemical compound [Re] WUAPFZMCVAUBPE-UHFFFAOYSA-N 0.000 description 1
- 239000012266 salt solution Substances 0.000 description 1
- 238000007086 side reaction Methods 0.000 description 1
- 229910052709 silver Inorganic materials 0.000 description 1
- 239000004332 silver Substances 0.000 description 1
- XMVONEAAOPAGAO-UHFFFAOYSA-N sodium tungstate Chemical compound [Na+].[Na+].[O-][W]([O-])(=O)=O XMVONEAAOPAGAO-UHFFFAOYSA-N 0.000 description 1
- 125000004434 sulfur atom Chemical group 0.000 description 1
- 150000003464 sulfur compounds Chemical class 0.000 description 1
- 150000003467 sulfuric acid derivatives Chemical class 0.000 description 1
- 238000003786 synthesis reaction Methods 0.000 description 1
- 229910052713 technetium Inorganic materials 0.000 description 1
- 150000003568 thioethers Chemical class 0.000 description 1
- FAKFSJNVVCGEEI-UHFFFAOYSA-J tin(4+);disulfate Chemical compound [Sn+4].[O-]S([O-])(=O)=O.[O-]S([O-])(=O)=O FAKFSJNVVCGEEI-UHFFFAOYSA-J 0.000 description 1
- HPGGPRDJHPYFRM-UHFFFAOYSA-J tin(iv) chloride Chemical compound Cl[Sn](Cl)(Cl)Cl HPGGPRDJHPYFRM-UHFFFAOYSA-J 0.000 description 1
- 229910001930 tungsten oxide Inorganic materials 0.000 description 1
- CMPGARWFYBADJI-UHFFFAOYSA-L tungstic acid Chemical compound O[W](O)(=O)=O CMPGARWFYBADJI-UHFFFAOYSA-L 0.000 description 1
- LSGOVYNHVSXFFJ-UHFFFAOYSA-N vanadate(3-) Chemical compound [O-][V]([O-])([O-])=O LSGOVYNHVSXFFJ-UHFFFAOYSA-N 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C5/00—Preparation of hydrocarbons from hydrocarbons containing the same number of carbon atoms
- C07C5/22—Preparation of hydrocarbons from hydrocarbons containing the same number of carbon atoms by isomerisation
- C07C5/2206—Catalytic processes not covered by C07C5/23 - C07C5/31
- C07C5/226—Catalytic processes not covered by C07C5/23 - C07C5/31 with metals
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C5/00—Preparation of hydrocarbons from hydrocarbons containing the same number of carbon atoms
- C07C5/02—Preparation of hydrocarbons from hydrocarbons containing the same number of carbon atoms by hydrogenation
- C07C5/13—Preparation of hydrocarbons from hydrocarbons containing the same number of carbon atoms by hydrogenation with simultaneous isomerisation
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C2521/00—Catalysts comprising the elements, oxides or hydroxides of magnesium, boron, aluminium, carbon, silicon, titanium, zirconium or hafnium
- C07C2521/06—Silicon, titanium, zirconium or hafnium; Oxides or hydroxides thereof
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C2523/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group C07C2521/00
- C07C2523/14—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group C07C2521/00 of germanium, tin or lead
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C2523/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group C07C2521/00
- C07C2523/38—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group C07C2521/00 of noble metals
- C07C2523/40—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group C07C2521/00 of noble metals of the platinum group metals
- C07C2523/42—Platinum
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C2523/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group C07C2521/00
- C07C2523/38—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group C07C2521/00 of noble metals
- C07C2523/54—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group C07C2521/00 of noble metals combined with metals, oxides or hydroxides provided for in groups C07C2523/02 - C07C2523/36
- C07C2523/56—Platinum group metals
- C07C2523/62—Platinum group metals with gallium, indium, thallium, germanium, tin or lead
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
- Catalysts (AREA)
- Production Of Liquid Hydrocarbon Mixture For Refining Petroleum (AREA)
- Agricultural Chemicals And Associated Chemicals (AREA)
- Compositions Of Macromolecular Compounds (AREA)
Applications Claiming Priority (5)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| US095882 | 1993-07-22 | ||
| US08/095,885 US5382731A (en) | 1993-07-22 | 1993-07-22 | Combined paraffin isomerization/ring opening process |
| US095885 | 1993-07-22 | ||
| US08/095,882 US5345026A (en) | 1993-07-22 | 1993-07-22 | Ring opening process |
| PCT/US1994/008131 WO1995003262A1 (en) | 1993-07-22 | 1994-07-19 | Combined paraffin isomerization/ring opening process |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| AU7367094A AU7367094A (en) | 1995-02-20 |
| AU683913B2 true AU683913B2 (en) | 1997-11-27 |
Family
ID=26790716
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| AU73670/94A Ceased AU683913B2 (en) | 1993-07-22 | 1994-07-19 | Combined paraffin isomerization/ring opening process |
Country Status (7)
Families Citing this family (10)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| RU2176233C1 (ru) * | 2000-06-08 | 2001-11-27 | Открытое Акционерное Общество "Научно-Производственное Предприятие Нефтехим" | Способ изомеризации легких парафиновых углеводородов c4-c6 |
| RU2171827C1 (ru) * | 2000-11-23 | 2001-08-10 | Открытое Акционерное Общество "Научно-Производственное Предприятие Нефтехим" | Способ изомеризации легких парафиновых углеводородов c4-c6 |
| RU2196124C1 (ru) * | 2002-01-24 | 2003-01-10 | Общество с ограниченной ответственностью "Научно-внедренческая фирма "Катализатор" | Способ изомеризации легких парафиновых углеводородов с4-с6 |
| RU2264256C1 (ru) * | 2004-02-25 | 2005-11-20 | Институт Катализа Им. Г.К. Борескова Сибирского Отделения Российской Академии Наук | Катализатор, способ его приготовления и способ изомеризации н-парафинов с использованием этого катализатора |
| RU2264255C1 (ru) * | 2004-02-25 | 2005-11-20 | Институт Катализа Им. Г.К. Борескова Сибирского Отделения Российской Академии Наук | Катализатор, способ его приготовления и способ изомеризации н-бутана с использованием этого катализатора |
| WO2007008097A1 (fr) * | 2005-07-11 | 2007-01-18 | Institut Kataliza Imeni G.K. Boreskova Sibirskogo Otdeleniya Rosiiskoi Akademii Nauk | Catalyseur, procede de fabrication correspondant et procede d'isomerisation d'hydrocarbures utilisant ce catalyseur |
| RU2402377C1 (ru) * | 2009-06-23 | 2010-10-27 | Министерство Промышленности И Торговли Российской Федерации | Способ приготовления оксидного катализатора изомеризации легких бензиновых фракций |
| EP3132005B1 (en) | 2014-03-26 | 2021-12-01 | Neste Oyj | Method for thermal conversion of ketoacids and hydrotreatment to hydrocarbons |
| EP2924097B1 (en) | 2014-03-26 | 2019-10-16 | Neste Oyj | Method for catalytic conversion of ketoacids and hydrotreatment to hydrocarbons |
| RU2693464C1 (ru) * | 2018-11-12 | 2019-07-03 | Федеральное государственное бюджетное учреждение науки "Федеральный исследовательский центр "Институт катализа им. Г.К. Борескова Сибирского отделения Российской академии наук" (ИК СО РАН, Институт катализа СО РАН) | Катализатор изомеризации н-бутана в изобутан, способ его приготовления и процесс получения изобутана с использованием данного катализатора |
Citations (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US4098683A (en) * | 1975-11-03 | 1978-07-04 | Uop Inc. | Process for hydrodesulfurizing or hydrogenating a hydrocarbon distillate |
| US4783575A (en) * | 1987-12-17 | 1988-11-08 | Uop Inc. | Isomerization with cyclic hydrocarbon conversion |
| US5334792A (en) * | 1992-10-09 | 1994-08-02 | Mobil Oil Corporation | Combined paraffin isomerization/ring opening process for c5+naphtha |
Family Cites Families (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| GB2211756A (en) * | 1987-10-30 | 1989-07-12 | Shell Int Research | Process for the preparation of paraffinic hydrocarbons and of a catalyst for said process |
-
1994
- 1994-07-19 ES ES94922624T patent/ES2141245T3/es not_active Expired - Lifetime
- 1994-07-19 DE DE69422814T patent/DE69422814T2/de not_active Expired - Fee Related
- 1994-07-19 WO PCT/US1994/008131 patent/WO1995003262A1/en active IP Right Grant
- 1994-07-19 DK DK94922624T patent/DK0710221T3/da active
- 1994-07-19 AU AU73670/94A patent/AU683913B2/en not_active Ceased
- 1994-07-19 EP EP94922624A patent/EP0710221B1/en not_active Expired - Lifetime
- 1994-08-06 TW TW83107223A patent/TW247904B/zh active
Patent Citations (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US4098683A (en) * | 1975-11-03 | 1978-07-04 | Uop Inc. | Process for hydrodesulfurizing or hydrogenating a hydrocarbon distillate |
| US4783575A (en) * | 1987-12-17 | 1988-11-08 | Uop Inc. | Isomerization with cyclic hydrocarbon conversion |
| US5334792A (en) * | 1992-10-09 | 1994-08-02 | Mobil Oil Corporation | Combined paraffin isomerization/ring opening process for c5+naphtha |
Also Published As
| Publication number | Publication date |
|---|---|
| WO1995003262A1 (en) | 1995-02-02 |
| DK0710221T3 (da) | 2000-04-17 |
| EP0710221B1 (en) | 2000-01-26 |
| EP0710221A4 (GUID-C5D7CC26-194C-43D0-91A1-9AE8C70A9BFF.html) | 1996-06-19 |
| DE69422814T2 (de) | 2000-10-12 |
| EP0710221A1 (en) | 1996-05-08 |
| TW247904B (GUID-C5D7CC26-194C-43D0-91A1-9AE8C70A9BFF.html) | 1995-05-21 |
| ES2141245T3 (es) | 2000-03-16 |
| DE69422814D1 (de) | 2000-03-02 |
| AU7367094A (en) | 1995-02-20 |
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