AU679472B2 - A process for activating a metal surface for conversion coating - Google Patents
A process for activating a metal surface for conversion coatingInfo
- Publication number
- AU679472B2 AU679472B2 AU55401/94A AU5540194A AU679472B2 AU 679472 B2 AU679472 B2 AU 679472B2 AU 55401/94 A AU55401/94 A AU 55401/94A AU 5540194 A AU5540194 A AU 5540194A AU 679472 B2 AU679472 B2 AU 679472B2
- Authority
- AU
- Australia
- Prior art keywords
- bath
- activating
- metal substrate
- phosphate
- coating
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Ceased
Links
- 230000003213 activating effect Effects 0.000 title claims abstract description 205
- 229910052751 metal Inorganic materials 0.000 title claims abstract description 150
- 239000002184 metal Substances 0.000 title claims abstract description 150
- 238000000034 method Methods 0.000 title claims abstract description 111
- 238000007739 conversion coating Methods 0.000 title claims description 6
- 239000000758 substrate Substances 0.000 claims abstract description 108
- 229910019142 PO4 Inorganic materials 0.000 claims abstract description 102
- 239000010452 phosphate Substances 0.000 claims abstract description 98
- NBIIXXVUZAFLBC-UHFFFAOYSA-K phosphate Chemical compound [O-]P([O-])([O-])=O NBIIXXVUZAFLBC-UHFFFAOYSA-K 0.000 claims abstract description 91
- 239000000203 mixture Substances 0.000 claims description 96
- 239000010936 titanium Substances 0.000 claims description 41
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims description 30
- RTAQQCXQSZGOHL-UHFFFAOYSA-N Titanium Chemical compound [Ti] RTAQQCXQSZGOHL-UHFFFAOYSA-N 0.000 claims description 24
- 229910052719 titanium Inorganic materials 0.000 claims description 24
- 238000007746 phosphate conversion coating Methods 0.000 claims description 19
- 238000004140 cleaning Methods 0.000 claims description 16
- 239000007795 chemical reaction product Substances 0.000 claims description 13
- 229910000838 Al alloy Inorganic materials 0.000 claims description 11
- XAGFODPZIPBFFR-UHFFFAOYSA-N aluminium Chemical compound [Al] XAGFODPZIPBFFR-UHFFFAOYSA-N 0.000 claims description 11
- XEEYBQQBJWHFJM-UHFFFAOYSA-N Iron Chemical compound [Fe] XEEYBQQBJWHFJM-UHFFFAOYSA-N 0.000 claims description 5
- 150000003609 titanium compounds Chemical class 0.000 claims description 5
- HCHKCACWOHOZIP-UHFFFAOYSA-N Zinc Chemical compound [Zn] HCHKCACWOHOZIP-UHFFFAOYSA-N 0.000 claims description 4
- 239000011701 zinc Substances 0.000 claims description 4
- 229910052725 zinc Inorganic materials 0.000 claims description 4
- -1 phosphorus compound Chemical class 0.000 claims description 3
- 229910000611 Zinc aluminium Inorganic materials 0.000 claims description 2
- 229910001297 Zn alloy Inorganic materials 0.000 claims description 2
- 229910052742 iron Inorganic materials 0.000 claims description 2
- BHEPBYXIRTUNPN-UHFFFAOYSA-N hydridophosphorus(.) (triplet) Chemical compound [PH] BHEPBYXIRTUNPN-UHFFFAOYSA-N 0.000 claims 2
- 229910052698 phosphorus Inorganic materials 0.000 claims 2
- 239000011574 phosphorus Substances 0.000 claims 2
- OAICVXFJPJFONN-UHFFFAOYSA-N Phosphorus Chemical compound [P] OAICVXFJPJFONN-UHFFFAOYSA-N 0.000 claims 1
- 150000003018 phosphorus compounds Chemical class 0.000 claims 1
- 238000000576 coating method Methods 0.000 abstract description 159
- 239000011248 coating agent Substances 0.000 abstract description 114
- 235000021317 phosphate Nutrition 0.000 description 92
- 239000013078 crystal Substances 0.000 description 62
- 239000010960 cold rolled steel Substances 0.000 description 46
- 239000000243 solution Substances 0.000 description 31
- 230000032683 aging Effects 0.000 description 29
- 230000002378 acidificating effect Effects 0.000 description 13
- 238000002474 experimental method Methods 0.000 description 13
- 230000000694 effects Effects 0.000 description 12
- 239000010959 steel Substances 0.000 description 11
- CDBYLPFSWZWCQE-UHFFFAOYSA-L Sodium Carbonate Chemical compound [Na+].[Na+].[O-]C([O-])=O CDBYLPFSWZWCQE-UHFFFAOYSA-L 0.000 description 10
- 229910052782 aluminium Inorganic materials 0.000 description 9
- 101100165177 Caenorhabditis elegans bath-15 gene Proteins 0.000 description 8
- 238000007654 immersion Methods 0.000 description 8
- 239000000463 material Substances 0.000 description 7
- 239000000047 product Substances 0.000 description 7
- 238000011282 treatment Methods 0.000 description 7
- 229910000831 Steel Inorganic materials 0.000 description 6
- 239000003513 alkali Substances 0.000 description 6
- 239000008367 deionised water Substances 0.000 description 6
- 229910021641 deionized water Inorganic materials 0.000 description 6
- 239000007921 spray Substances 0.000 description 6
- 229910000851 Alloy steel Inorganic materials 0.000 description 5
- 239000011575 calcium Substances 0.000 description 5
- 239000008199 coating composition Substances 0.000 description 5
- 235000017550 sodium carbonate Nutrition 0.000 description 5
- 229910000029 sodium carbonate Inorganic materials 0.000 description 5
- 238000005507 spraying Methods 0.000 description 5
- 230000004913 activation Effects 0.000 description 4
- 230000001464 adherent effect Effects 0.000 description 4
- 238000013401 experimental design Methods 0.000 description 4
- 150000003013 phosphoric acid derivatives Chemical class 0.000 description 4
- 230000001737 promoting effect Effects 0.000 description 4
- 238000009210 therapy by ultrasound Methods 0.000 description 4
- OYPRJOBELJOOCE-UHFFFAOYSA-N Calcium Chemical compound [Ca] OYPRJOBELJOOCE-UHFFFAOYSA-N 0.000 description 3
- 229910001335 Galvanized steel Inorganic materials 0.000 description 3
- JLVVSXFLKOJNIY-UHFFFAOYSA-N Magnesium ion Chemical compound [Mg+2] JLVVSXFLKOJNIY-UHFFFAOYSA-N 0.000 description 3
- 239000002253 acid Substances 0.000 description 3
- 239000008397 galvanized steel Substances 0.000 description 3
- 239000011777 magnesium Substances 0.000 description 3
- 229910001425 magnesium ion Inorganic materials 0.000 description 3
- 238000002156 mixing Methods 0.000 description 3
- 239000001488 sodium phosphate Substances 0.000 description 3
- 239000008399 tap water Substances 0.000 description 3
- 235000020679 tap water Nutrition 0.000 description 3
- FYYHWMGAXLPEAU-UHFFFAOYSA-N Magnesium Chemical compound [Mg] FYYHWMGAXLPEAU-UHFFFAOYSA-N 0.000 description 2
- PXHVJJICTQNCMI-UHFFFAOYSA-N Nickel Chemical compound [Ni] PXHVJJICTQNCMI-UHFFFAOYSA-N 0.000 description 2
- NBIIXXVUZAFLBC-UHFFFAOYSA-N Phosphoric acid Chemical compound OP(O)(O)=O NBIIXXVUZAFLBC-UHFFFAOYSA-N 0.000 description 2
- 235000014548 Rubus moluccanus Nutrition 0.000 description 2
- QAOWNCQODCNURD-UHFFFAOYSA-N Sulfuric acid Chemical compound OS(O)(=O)=O QAOWNCQODCNURD-UHFFFAOYSA-N 0.000 description 2
- PXOYQTCIULSVDQ-UHFFFAOYSA-H [Mn++].[Ni++].[Zn++].[O-]P([O-])([O-])=O.[O-]P([O-])([O-])=O Chemical compound [Mn++].[Ni++].[Zn++].[O-]P([O-])([O-])=O.[O-]P([O-])([O-])=O PXOYQTCIULSVDQ-UHFFFAOYSA-H 0.000 description 2
- 239000007864 aqueous solution Substances 0.000 description 2
- 230000015572 biosynthetic process Effects 0.000 description 2
- 229910052791 calcium Inorganic materials 0.000 description 2
- 229910001424 calcium ion Inorganic materials 0.000 description 2
- 239000003518 caustics Substances 0.000 description 2
- 238000006243 chemical reaction Methods 0.000 description 2
- 238000005260 corrosion Methods 0.000 description 2
- 230000007797 corrosion Effects 0.000 description 2
- 239000006185 dispersion Substances 0.000 description 2
- 230000003203 everyday effect Effects 0.000 description 2
- 229910052749 magnesium Inorganic materials 0.000 description 2
- 150000002739 metals Chemical class 0.000 description 2
- 239000002245 particle Substances 0.000 description 2
- 238000007789 sealing Methods 0.000 description 2
- RYFMWSXOAZQYPI-UHFFFAOYSA-K trisodium phosphate Chemical compound [Na+].[Na+].[Na+].[O-]P([O-])([O-])=O RYFMWSXOAZQYPI-UHFFFAOYSA-K 0.000 description 2
- BHPQYMZQTOCNFJ-UHFFFAOYSA-N Calcium cation Chemical compound [Ca+2] BHPQYMZQTOCNFJ-UHFFFAOYSA-N 0.000 description 1
- UXVMQQNJUSDDNG-UHFFFAOYSA-L Calcium chloride Chemical compound [Cl-].[Cl-].[Ca+2] UXVMQQNJUSDDNG-UHFFFAOYSA-L 0.000 description 1
- VYZAMTAEIAYCRO-UHFFFAOYSA-N Chromium Chemical compound [Cr] VYZAMTAEIAYCRO-UHFFFAOYSA-N 0.000 description 1
- RYGMFSIKBFXOCR-UHFFFAOYSA-N Copper Chemical compound [Cu] RYGMFSIKBFXOCR-UHFFFAOYSA-N 0.000 description 1
- KRHYYFGTRYWZRS-UHFFFAOYSA-M Fluoride anion Chemical compound [F-] KRHYYFGTRYWZRS-UHFFFAOYSA-M 0.000 description 1
- 239000004115 Sodium Silicate Substances 0.000 description 1
- 239000000654 additive Substances 0.000 description 1
- 229910000147 aluminium phosphate Inorganic materials 0.000 description 1
- 239000008346 aqueous phase Substances 0.000 description 1
- 239000002585 base Substances 0.000 description 1
- UDSAIICHUKSCKT-UHFFFAOYSA-N bromophenol blue Chemical compound C1=C(Br)C(O)=C(Br)C=C1C1(C=2C=C(Br)C(O)=C(Br)C=2)C2=CC=CC=C2S(=O)(=O)O1 UDSAIICHUKSCKT-UHFFFAOYSA-N 0.000 description 1
- 229910000019 calcium carbonate Inorganic materials 0.000 description 1
- 239000001110 calcium chloride Substances 0.000 description 1
- 229910001628 calcium chloride Inorganic materials 0.000 description 1
- 150000001768 cations Chemical class 0.000 description 1
- 238000012512 characterization method Methods 0.000 description 1
- ZCDOYSPFYFSLEW-UHFFFAOYSA-N chromate(2-) Chemical compound [O-][Cr]([O-])(=O)=O ZCDOYSPFYFSLEW-UHFFFAOYSA-N 0.000 description 1
- 229910052804 chromium Inorganic materials 0.000 description 1
- 239000011651 chromium Substances 0.000 description 1
- 239000002131 composite material Substances 0.000 description 1
- 150000001875 compounds Chemical class 0.000 description 1
- 229910052802 copper Inorganic materials 0.000 description 1
- 239000010949 copper Substances 0.000 description 1
- 230000007423 decrease Effects 0.000 description 1
- 230000002939 deleterious effect Effects 0.000 description 1
- 238000007865 diluting Methods 0.000 description 1
- BNIILDVGGAEEIG-UHFFFAOYSA-L disodium hydrogen phosphate Chemical compound [Na+].[Na+].OP([O-])([O-])=O BNIILDVGGAEEIG-UHFFFAOYSA-L 0.000 description 1
- 235000019800 disodium phosphate Nutrition 0.000 description 1
- 229910000397 disodium phosphate Inorganic materials 0.000 description 1
- 239000004519 grease Substances 0.000 description 1
- 230000003993 interaction Effects 0.000 description 1
- 150000002500 ions Chemical class 0.000 description 1
- 229910052943 magnesium sulfate Inorganic materials 0.000 description 1
- WPBNNNQJVZRUHP-UHFFFAOYSA-L manganese(2+);methyl n-[[2-(methoxycarbonylcarbamothioylamino)phenyl]carbamothioyl]carbamate;n-[2-(sulfidocarbothioylamino)ethyl]carbamodithioate Chemical compound [Mn+2].[S-]C(=S)NCCNC([S-])=S.COC(=O)NC(=S)NC1=CC=CC=C1NC(=S)NC(=O)OC WPBNNNQJVZRUHP-UHFFFAOYSA-L 0.000 description 1
- 229910001463 metal phosphate Inorganic materials 0.000 description 1
- 229910052759 nickel Inorganic materials 0.000 description 1
- 238000005457 optimization Methods 0.000 description 1
- 238000010979 pH adjustment Methods 0.000 description 1
- 238000002360 preparation method Methods 0.000 description 1
- 239000011253 protective coating Substances 0.000 description 1
- 238000007761 roller coating Methods 0.000 description 1
- 239000011734 sodium Substances 0.000 description 1
- 229910000030 sodium bicarbonate Inorganic materials 0.000 description 1
- FQENQNTWSFEDLI-UHFFFAOYSA-J sodium diphosphate Chemical compound [Na+].[Na+].[Na+].[Na+].[O-]P([O-])(=O)OP([O-])([O-])=O FQENQNTWSFEDLI-UHFFFAOYSA-J 0.000 description 1
- 235000011008 sodium phosphates Nutrition 0.000 description 1
- 235000019830 sodium polyphosphate Nutrition 0.000 description 1
- 229940048086 sodium pyrophosphate Drugs 0.000 description 1
- NTHWMYGWWRZVTN-UHFFFAOYSA-N sodium silicate Chemical compound [Na+].[Na+].[O-][Si]([O-])=O NTHWMYGWWRZVTN-UHFFFAOYSA-N 0.000 description 1
- 229910052911 sodium silicate Inorganic materials 0.000 description 1
- 235000019794 sodium silicate Nutrition 0.000 description 1
- 235000019832 sodium triphosphate Nutrition 0.000 description 1
- 238000000527 sonication Methods 0.000 description 1
- 238000003756 stirring Methods 0.000 description 1
- 239000004094 surface-active agent Substances 0.000 description 1
- 235000019818 tetrasodium diphosphate Nutrition 0.000 description 1
- 239000001577 tetrasodium phosphonato phosphate Substances 0.000 description 1
- 235000019801 trisodium phosphate Nutrition 0.000 description 1
- 229910000406 trisodium phosphate Inorganic materials 0.000 description 1
- 238000010337 ultrasonic energy treatment Methods 0.000 description 1
- 239000011800 void material Substances 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C23—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; CHEMICAL SURFACE TREATMENT; DIFFUSION TREATMENT OF METALLIC MATERIAL; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL; INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION IN GENERAL
- C23C—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; SURFACE TREATMENT OF METALLIC MATERIAL BY DIFFUSION INTO THE SURFACE, BY CHEMICAL CONVERSION OR SUBSTITUTION; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL
- C23C22/00—Chemical surface treatment of metallic material by reaction of the surface with a reactive liquid, leaving reaction products of surface material in the coating, e.g. conversion coatings, passivation of metals
- C23C22/78—Pretreatment of the material to be coated
- C23C22/80—Pretreatment of the material to be coated with solutions containing titanium or zirconium compounds
-
- C—CHEMISTRY; METALLURGY
- C23—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; CHEMICAL SURFACE TREATMENT; DIFFUSION TREATMENT OF METALLIC MATERIAL; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL; INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION IN GENERAL
- C23C—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; SURFACE TREATMENT OF METALLIC MATERIAL BY DIFFUSION INTO THE SURFACE, BY CHEMICAL CONVERSION OR SUBSTITUTION; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL
- C23C22/00—Chemical surface treatment of metallic material by reaction of the surface with a reactive liquid, leaving reaction products of surface material in the coating, e.g. conversion coatings, passivation of metals
- C23C22/78—Pretreatment of the material to be coated
Landscapes
- Chemical & Material Sciences (AREA)
- Metallurgy (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
- Mechanical Engineering (AREA)
- General Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Chemical Treatment Of Metals (AREA)
- Preventing Corrosion Or Incrustation Of Metals (AREA)
- Other Surface Treatments For Metallic Materials (AREA)
- Materials For Medical Uses (AREA)
- Cleaning And De-Greasing Of Metallic Materials By Chemical Methods (AREA)
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| PCT/US1993/010243 WO1995012011A1 (en) | 1993-10-26 | 1993-10-26 | A process for activating a metal surface for conversion coating |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| AU5540194A AU5540194A (en) | 1995-05-22 |
| AU679472B2 true AU679472B2 (en) | 1997-07-03 |
Family
ID=22237103
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| AU55401/94A Ceased AU679472B2 (en) | 1993-10-26 | 1993-10-26 | A process for activating a metal surface for conversion coating |
Country Status (10)
Families Citing this family (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN111474092B (zh) * | 2020-04-27 | 2023-04-07 | 安徽工业大学 | 一种研究蒸气在细颗粒表面核化特性的实验方法 |
Citations (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| SU1036680A1 (ru) * | 1982-04-28 | 1983-08-23 | Предприятие П/Я Г-4855 | Способ получени фосфата титана |
| US4529451A (en) * | 1983-01-03 | 1985-07-16 | Detrex Chemical Industries, Inc. | Zinc phosphate coated metal and process of producing same |
Family Cites Families (7)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US2456947A (en) * | 1944-12-21 | 1948-12-21 | Westinghouse Electric Corp | Corrosion resistant coating for metal surfaces |
| US4311157A (en) * | 1980-02-26 | 1982-01-19 | Rock Oil Corporation | Sonic treating apparatus |
| AU2448684A (en) * | 1983-03-02 | 1984-09-06 | Parker Chemical Company | Metal treatment before phosphate coating |
| US4531978A (en) * | 1983-04-11 | 1985-07-30 | Detrex Chemical Industries, Inc. | Method of forming chromate conversion coatings on aluminum surfaces and the coating formed thereby |
| JPS61170576A (ja) * | 1985-01-23 | 1986-08-01 | Kawasaki Steel Corp | 耐食性および色調外観の優れた亜鉛めつき系クロメ−ト処理鋼板の製造法 |
| JPH0394075A (ja) * | 1989-09-04 | 1991-04-18 | Nippon Parkerizing Co Ltd | 表面調整処理方法 |
| US5176755A (en) * | 1990-02-14 | 1993-01-05 | Armco Inc. | Plastic powder coated metal strip |
-
1993
- 1993-10-26 JP JP7508344A patent/JPH09504052A/ja active Pending
- 1993-10-26 WO PCT/US1993/010243 patent/WO1995012011A1/en active IP Right Grant
- 1993-10-26 AU AU55401/94A patent/AU679472B2/en not_active Ceased
- 1993-10-26 DE DE69326085T patent/DE69326085T2/de not_active Expired - Fee Related
- 1993-10-26 AT AT94900395T patent/ATE183554T1/de not_active IP Right Cessation
- 1993-10-26 ES ES94900395T patent/ES2137348T3/es not_active Expired - Lifetime
- 1993-10-26 BR BR9307897A patent/BR9307897A/pt not_active Application Discontinuation
- 1993-10-26 EP EP94900395A patent/EP0725844B1/en not_active Expired - Lifetime
-
1994
- 1994-10-17 ZA ZA948135A patent/ZA948135B/xx unknown
- 1994-10-26 CN CN94117580A patent/CN1106072A/zh active Pending
Patent Citations (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| SU1036680A1 (ru) * | 1982-04-28 | 1983-08-23 | Предприятие П/Я Г-4855 | Способ получени фосфата титана |
| US4529451A (en) * | 1983-01-03 | 1985-07-16 | Detrex Chemical Industries, Inc. | Zinc phosphate coated metal and process of producing same |
Also Published As
| Publication number | Publication date |
|---|---|
| EP0725844B1 (en) | 1999-08-18 |
| CN1106072A (zh) | 1995-08-02 |
| WO1995012011A1 (en) | 1995-05-04 |
| JPH09504052A (ja) | 1997-04-22 |
| ES2137348T3 (es) | 1999-12-16 |
| BR9307897A (pt) | 1996-09-10 |
| ATE183554T1 (de) | 1999-09-15 |
| EP0725844A4 (enrdf_load_stackoverflow) | 1996-09-11 |
| EP0725844A1 (en) | 1996-08-14 |
| AU5540194A (en) | 1995-05-22 |
| DE69326085T2 (de) | 2000-04-13 |
| ZA948135B (en) | 1995-06-26 |
| DE69326085D1 (de) | 1999-09-23 |
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Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| MK14 | Patent ceased section 143(a) (annual fees not paid) or expired |