AU655506B2 - Process for fixing lead-contaminated ecologically hazardous industrial waste materials using clinoptilolite zeolite - Google Patents
Process for fixing lead-contaminated ecologically hazardous industrial waste materials using clinoptilolite zeolite Download PDFInfo
- Publication number
- AU655506B2 AU655506B2 AU26868/92A AU2686892A AU655506B2 AU 655506 B2 AU655506 B2 AU 655506B2 AU 26868/92 A AU26868/92 A AU 26868/92A AU 2686892 A AU2686892 A AU 2686892A AU 655506 B2 AU655506 B2 AU 655506B2
- Authority
- AU
- Australia
- Prior art keywords
- lead
- contaminated
- clinoptilolite
- size
- reduced
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Ceased
Links
- 239000002440 industrial waste Substances 0.000 title claims abstract description 56
- 239000000463 material Substances 0.000 title claims abstract description 45
- 238000000034 method Methods 0.000 title claims abstract description 36
- HNPSIPDUKPIQMN-UHFFFAOYSA-N dioxosilane;oxo(oxoalumanyloxy)alumane Chemical compound O=[Si]=O.O=[Al]O[Al]=O HNPSIPDUKPIQMN-UHFFFAOYSA-N 0.000 title claims abstract description 30
- JYIBXUUINYLWLR-UHFFFAOYSA-N aluminum;calcium;potassium;silicon;sodium;trihydrate Chemical compound O.O.O.[Na].[Al].[Si].[K].[Ca] JYIBXUUINYLWLR-UHFFFAOYSA-N 0.000 title claims description 40
- 229910001603 clinoptilolite Inorganic materials 0.000 title claims description 40
- 229910021536 Zeolite Inorganic materials 0.000 title claims description 25
- 239000010457 zeolite Substances 0.000 title claims description 25
- 231100001261 hazardous Toxicity 0.000 title abstract description 9
- 239000002893 slag Substances 0.000 claims abstract description 39
- 150000002500 ions Chemical class 0.000 claims abstract description 34
- 239000006227 byproduct Substances 0.000 claims abstract description 22
- 238000003723 Smelting Methods 0.000 claims abstract description 16
- 239000002002 slurry Substances 0.000 claims description 34
- 239000012633 leachable Substances 0.000 claims description 30
- 239000011398 Portland cement Substances 0.000 claims description 27
- 231100000331 toxic Toxicity 0.000 claims description 11
- 230000002588 toxic effect Effects 0.000 claims description 11
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims description 10
- 239000007787 solid Substances 0.000 claims description 8
- 239000000203 mixture Substances 0.000 claims description 7
- 238000013019 agitation Methods 0.000 claims description 3
- 239000004568 cement Substances 0.000 claims description 3
- 239000002910 solid waste Substances 0.000 claims description 3
- 239000000126 substance Substances 0.000 claims 2
- IOYNQIMAUDJVEI-BMVIKAAMSA-N Tepraloxydim Chemical group C1C(=O)C(C(=N/OC\C=C\Cl)/CC)=C(O)CC1C1CCOCC1 IOYNQIMAUDJVEI-BMVIKAAMSA-N 0.000 claims 1
- 230000002285 radioactive effect Effects 0.000 claims 1
- 238000007711 solidification Methods 0.000 claims 1
- 230000008023 solidification Effects 0.000 claims 1
- 239000003643 water by type Substances 0.000 claims 1
- 238000002386 leaching Methods 0.000 abstract description 12
- 238000005538 encapsulation Methods 0.000 abstract description 6
- 239000003795 chemical substances by application Substances 0.000 abstract description 5
- 230000008014 freezing Effects 0.000 abstract description 3
- 238000007710 freezing Methods 0.000 abstract description 3
- 238000010257 thawing Methods 0.000 abstract description 3
- 150000001768 cations Chemical class 0.000 description 7
- 238000005342 ion exchange Methods 0.000 description 7
- 239000002699 waste material Substances 0.000 description 6
- 239000013078 crystal Substances 0.000 description 4
- 239000011734 sodium Substances 0.000 description 4
- 239000002920 hazardous waste Substances 0.000 description 3
- VTYYLEPIZMXCLO-UHFFFAOYSA-L Calcium carbonate Chemical compound [Ca+2].[O-]C([O-])=O VTYYLEPIZMXCLO-UHFFFAOYSA-L 0.000 description 2
- 235000008733 Citrus aurantifolia Nutrition 0.000 description 2
- DGAQECJNVWCQMB-PUAWFVPOSA-M Ilexoside XXIX Chemical compound C[C@@H]1CC[C@@]2(CC[C@@]3(C(=CC[C@H]4[C@]3(CC[C@@H]5[C@@]4(CC[C@@H](C5(C)C)OS(=O)(=O)[O-])C)C)[C@@H]2[C@]1(C)O)C)C(=O)O[C@H]6[C@@H]([C@H]([C@@H]([C@H](O6)CO)O)O)O.[Na+] DGAQECJNVWCQMB-PUAWFVPOSA-M 0.000 description 2
- 229910003251 Na K Inorganic materials 0.000 description 2
- ZLMJMSJWJFRBEC-UHFFFAOYSA-N Potassium Chemical compound [K] ZLMJMSJWJFRBEC-UHFFFAOYSA-N 0.000 description 2
- 235000011941 Tilia x europaea Nutrition 0.000 description 2
- 238000013459 approach Methods 0.000 description 2
- 239000004571 lime Substances 0.000 description 2
- 239000011591 potassium Substances 0.000 description 2
- 229910052700 potassium Inorganic materials 0.000 description 2
- 229910052708 sodium Inorganic materials 0.000 description 2
- 239000008399 tap water Substances 0.000 description 2
- 235000020679 tap water Nutrition 0.000 description 2
- 231100000419 toxicity Toxicity 0.000 description 2
- 230000001988 toxicity Effects 0.000 description 2
- 238000011282 treatment Methods 0.000 description 2
- UXVMQQNJUSDDNG-UHFFFAOYSA-L Calcium chloride Chemical compound [Cl-].[Cl-].[Ca+2] UXVMQQNJUSDDNG-UHFFFAOYSA-L 0.000 description 1
- 108091005462 Cation channels Proteins 0.000 description 1
- BPQQTUXANYXVAA-UHFFFAOYSA-N Orthosilicate Chemical compound [O-][Si]([O-])([O-])[O-] BPQQTUXANYXVAA-UHFFFAOYSA-N 0.000 description 1
- 239000004115 Sodium Silicate Substances 0.000 description 1
- 150000004645 aluminates Chemical class 0.000 description 1
- 229910000019 calcium carbonate Inorganic materials 0.000 description 1
- 239000001110 calcium chloride Substances 0.000 description 1
- 229910001628 calcium chloride Inorganic materials 0.000 description 1
- AXCZMVOFGPJBDE-UHFFFAOYSA-L calcium dihydroxide Chemical compound [OH-].[OH-].[Ca+2] AXCZMVOFGPJBDE-UHFFFAOYSA-L 0.000 description 1
- 239000000920 calcium hydroxide Substances 0.000 description 1
- 229910001861 calcium hydroxide Inorganic materials 0.000 description 1
- 235000011116 calcium hydroxide Nutrition 0.000 description 1
- 230000006866 deterioration Effects 0.000 description 1
- 239000008393 encapsulating agent Substances 0.000 description 1
- 230000007613 environmental effect Effects 0.000 description 1
- -1 for example Substances 0.000 description 1
- 231100000206 health hazard Toxicity 0.000 description 1
- 230000036571 hydration Effects 0.000 description 1
- 238000006703 hydration reaction Methods 0.000 description 1
- 230000003100 immobilizing effect Effects 0.000 description 1
- 230000005923 long-lasting effect Effects 0.000 description 1
- 230000007774 longterm Effects 0.000 description 1
- NTHWMYGWWRZVTN-UHFFFAOYSA-N sodium silicate Chemical compound [Na+].[Na+].[O-][Si]([O-])=O NTHWMYGWWRZVTN-UHFFFAOYSA-N 0.000 description 1
- 229910052911 sodium silicate Inorganic materials 0.000 description 1
- 239000008247 solid mixture Substances 0.000 description 1
Classifications
-
- A—HUMAN NECESSITIES
- A62—LIFE-SAVING; FIRE-FIGHTING
- A62D—CHEMICAL MEANS FOR EXTINGUISHING FIRES OR FOR COMBATING OR PROTECTING AGAINST HARMFUL CHEMICAL AGENTS; CHEMICAL MATERIALS FOR USE IN BREATHING APPARATUS
- A62D3/00—Processes for making harmful chemical substances harmless or less harmful, by effecting a chemical change in the substances
- A62D3/30—Processes for making harmful chemical substances harmless or less harmful, by effecting a chemical change in the substances by reacting with chemical agents
- A62D3/33—Processes for making harmful chemical substances harmless or less harmful, by effecting a chemical change in the substances by reacting with chemical agents by chemical fixing the harmful substance, e.g. by chelation or complexation
-
- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B28/00—Compositions of mortars, concrete or artificial stone, containing inorganic binders or the reaction product of an inorganic and an organic binder, e.g. polycarboxylate cements
- C04B28/02—Compositions of mortars, concrete or artificial stone, containing inorganic binders or the reaction product of an inorganic and an organic binder, e.g. polycarboxylate cements containing hydraulic cements other than calcium sulfates
-
- A—HUMAN NECESSITIES
- A62—LIFE-SAVING; FIRE-FIGHTING
- A62D—CHEMICAL MEANS FOR EXTINGUISHING FIRES OR FOR COMBATING OR PROTECTING AGAINST HARMFUL CHEMICAL AGENTS; CHEMICAL MATERIALS FOR USE IN BREATHING APPARATUS
- A62D2101/00—Harmful chemical substances made harmless, or less harmful, by effecting chemical change
- A62D2101/40—Inorganic substances
- A62D2101/43—Inorganic substances containing heavy metals, in the bonded or free state
-
- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B2111/00—Mortars, concrete or artificial stone or mixtures to prepare them, characterised by specific function, property or use
- C04B2111/00474—Uses not provided for elsewhere in C04B2111/00
- C04B2111/00767—Uses not provided for elsewhere in C04B2111/00 for waste stabilisation purposes
- C04B2111/00784—Uses not provided for elsewhere in C04B2111/00 for waste stabilisation purposes for disposal only
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02W—CLIMATE CHANGE MITIGATION TECHNOLOGIES RELATED TO WASTEWATER TREATMENT OR WASTE MANAGEMENT
- Y02W30/00—Technologies for solid waste management
- Y02W30/50—Reuse, recycling or recovery technologies
- Y02W30/91—Use of waste materials as fillers for mortars or concrete
Landscapes
- Chemical & Material Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Ceramic Engineering (AREA)
- Engineering & Computer Science (AREA)
- Inorganic Chemistry (AREA)
- Materials Engineering (AREA)
- Business, Economics & Management (AREA)
- Emergency Management (AREA)
- Health & Medical Sciences (AREA)
- Toxicology (AREA)
- General Health & Medical Sciences (AREA)
- General Chemical & Material Sciences (AREA)
- Structural Engineering (AREA)
- Organic Chemistry (AREA)
- Processing Of Solid Wastes (AREA)
- Solid-Sorbent Or Filter-Aiding Compositions (AREA)
- Silicates, Zeolites, And Molecular Sieves (AREA)
- Fire-Extinguishing Compositions (AREA)
Applications Claiming Priority (5)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| US76116391A | 1991-09-11 | 1991-09-11 | |
| US761163 | 1991-09-11 | ||
| US941392 | 1992-09-08 | ||
| US07/941,392 US5234498A (en) | 1991-09-11 | 1992-09-08 | Process for fixing lead-contaminated ecologically hazardous industrial waste materials using clinoptilolite zeolite |
| PCT/US1992/007665 WO1993004995A1 (en) | 1991-09-11 | 1992-09-10 | Process for fixing lead-contaminated ecologically hazardous industrial waste materials using clinoptilolite zeolite |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| AU2686892A AU2686892A (en) | 1993-04-05 |
| AU655506B2 true AU655506B2 (en) | 1994-12-22 |
Family
ID=27116936
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| AU26868/92A Ceased AU655506B2 (en) | 1991-09-11 | 1992-09-10 | Process for fixing lead-contaminated ecologically hazardous industrial waste materials using clinoptilolite zeolite |
Country Status (8)
| Country | Link |
|---|---|
| EP (1) | EP0556385B1 (enExample) |
| JP (1) | JPH06502801A (enExample) |
| AT (1) | ATE161246T1 (enExample) |
| AU (1) | AU655506B2 (enExample) |
| CA (1) | CA2095931C (enExample) |
| DE (1) | DE69223605T2 (enExample) |
| ES (1) | ES2110526T3 (enExample) |
| WO (1) | WO1993004995A1 (enExample) |
Families Citing this family (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JP4991979B2 (ja) * | 2005-03-17 | 2012-08-08 | 大谷 智子 | 産業廃棄物のガラス製品 |
| NL2027369B1 (en) | 2021-01-22 | 2022-08-05 | Pkb Top Holding B V | Immobilizing chemical species |
Citations (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US4116705A (en) * | 1973-06-01 | 1978-09-26 | Stablex Ag | Detoxification |
| AU637168B2 (en) * | 1989-12-18 | 1993-05-20 | Aardelite Holding B.V. | Method for reducing the leachability of granular material and granular material obtained using this method |
Family Cites Families (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPS58151356A (ja) * | 1982-03-03 | 1983-09-08 | 水澤化学工業株式会社 | 水硬性セメント組成物 |
| US4537710A (en) * | 1983-10-31 | 1985-08-27 | The United States Of America As Represented By The United States Department Of Energy | Method of storing radioactive wastes using modified tobermorite |
| JPH03207483A (ja) * | 1990-01-08 | 1991-09-10 | Kiyoya Nishimura | 有害産業廃棄物のコンクリート固化処理処分法 |
| IL97895A0 (en) * | 1990-05-09 | 1992-06-21 | Zeofuels Res Pty Ltd | Modified clinoptilolite and its use as an ion exchange material |
| US5242503A (en) * | 1990-12-17 | 1993-09-07 | Westinghouse Electric Corp. | Method of restoring contaminated solids using ion exchange powder contact |
-
1992
- 1992-09-10 DE DE69223605T patent/DE69223605T2/de not_active Expired - Fee Related
- 1992-09-10 ES ES92920927T patent/ES2110526T3/es not_active Expired - Lifetime
- 1992-09-10 CA CA002095931A patent/CA2095931C/en not_active Expired - Fee Related
- 1992-09-10 AT AT92920927T patent/ATE161246T1/de not_active IP Right Cessation
- 1992-09-10 JP JP5505500A patent/JPH06502801A/ja active Pending
- 1992-09-10 EP EP19920920927 patent/EP0556385B1/en not_active Expired - Lifetime
- 1992-09-10 WO PCT/US1992/007665 patent/WO1993004995A1/en not_active Ceased
- 1992-09-10 AU AU26868/92A patent/AU655506B2/en not_active Ceased
Patent Citations (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US4116705A (en) * | 1973-06-01 | 1978-09-26 | Stablex Ag | Detoxification |
| AU637168B2 (en) * | 1989-12-18 | 1993-05-20 | Aardelite Holding B.V. | Method for reducing the leachability of granular material and granular material obtained using this method |
Also Published As
| Publication number | Publication date |
|---|---|
| DE69223605D1 (de) | 1998-01-29 |
| ATE161246T1 (de) | 1998-01-15 |
| WO1993004995A1 (en) | 1993-03-18 |
| EP0556385A4 (enExample) | 1995-01-25 |
| ES2110526T3 (es) | 1998-02-16 |
| EP0556385A1 (en) | 1993-08-25 |
| CA2095931A1 (en) | 1993-03-12 |
| JPH06502801A (ja) | 1994-03-31 |
| EP0556385B1 (en) | 1997-12-17 |
| AU2686892A (en) | 1993-04-05 |
| CA2095931C (en) | 1999-05-25 |
| DE69223605T2 (de) | 1998-07-02 |
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Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| MK14 | Patent ceased section 143(a) (annual fees not paid) or expired |