AU616396B2 - Copolymers of ethylene and 1,3-butadiene - Google Patents

Copolymers of ethylene and 1,3-butadiene Download PDF

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Publication number
AU616396B2
AU616396B2 AU12234/88A AU1223488A AU616396B2 AU 616396 B2 AU616396 B2 AU 616396B2 AU 12234/88 A AU12234/88 A AU 12234/88A AU 1223488 A AU1223488 A AU 1223488A AU 616396 B2 AU616396 B2 AU 616396B2
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AU
Australia
Prior art keywords
copolymer
comonomer
ethylene
butadiene
catalyst
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Ceased
Application number
AU12234/88A
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English (en)
Other versions
AU1223488A (en
Inventor
Howard Curtis Welborn Jr.
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
ExxonMobil Chemical Patents Inc
Original Assignee
Exxon Chemical Patents Inc
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
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First worldwide family litigation filed litigation Critical https://patents.darts-ip.com/?family=26324691&utm_source=google_patent&utm_medium=platform_link&utm_campaign=public_patent_search&patent=AU616396(B2) "Global patent litigation dataset” by Darts-ip is licensed under a Creative Commons Attribution 4.0 International License.
Application filed by Exxon Chemical Patents Inc filed Critical Exxon Chemical Patents Inc
Publication of AU1223488A publication Critical patent/AU1223488A/en
Application granted granted Critical
Publication of AU616396B2 publication Critical patent/AU616396B2/en
Anticipated expiration legal-status Critical
Ceased legal-status Critical Current

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Classifications

    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F210/00—Copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
    • C08F210/16—Copolymers of ethene with alpha-alkenes, e.g. EP rubbers
    • C08F210/18—Copolymers of ethene with alpha-alkenes, e.g. EP rubbers with non-conjugated dienes, e.g. EPT rubbers
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F210/00—Copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
    • C08F210/02—Ethene
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F4/00—Polymerisation catalysts
    • C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
    • C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
    • C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
    • C08F4/62—Refractory metals or compounds thereof
    • C08F4/639—Component covered by group C08F4/62 containing a transition metal-carbon bond
    • C08F4/63912—Component covered by group C08F4/62 containing a transition metal-carbon bond in combination with an organoaluminium compound
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F4/00—Polymerisation catalysts
    • C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
    • C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
    • C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
    • C08F4/62—Refractory metals or compounds thereof
    • C08F4/639—Component covered by group C08F4/62 containing a transition metal-carbon bond
    • C08F4/63916—Component covered by group C08F4/62 containing a transition metal-carbon bond supported on a carrier, e.g. silica, MgCl2, polymer
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F4/00—Polymerisation catalysts
    • C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
    • C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
    • C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
    • C08F4/62—Refractory metals or compounds thereof
    • C08F4/639—Component covered by group C08F4/62 containing a transition metal-carbon bond
    • C08F4/6392—Component covered by group C08F4/62 containing a transition metal-carbon bond containing at least one cyclopentadienyl ring, condensed or not, e.g. an indenyl or a fluorenyl ring
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F4/00—Polymerisation catalysts
    • C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
    • C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
    • C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
    • C08F4/62—Refractory metals or compounds thereof
    • C08F4/64—Titanium, zirconium, hafnium or compounds thereof
    • C08F4/659—Component covered by group C08F4/64 containing a transition metal-carbon bond
    • C08F4/65912—Component covered by group C08F4/64 containing a transition metal-carbon bond in combination with an organoaluminium compound
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F4/00—Polymerisation catalysts
    • C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
    • C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
    • C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
    • C08F4/62—Refractory metals or compounds thereof
    • C08F4/64—Titanium, zirconium, hafnium or compounds thereof
    • C08F4/659—Component covered by group C08F4/64 containing a transition metal-carbon bond
    • C08F4/65916—Component covered by group C08F4/64 containing a transition metal-carbon bond supported on a carrier, e.g. silica, MgCl2, polymer
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F4/00—Polymerisation catalysts
    • C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
    • C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
    • C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
    • C08F4/62—Refractory metals or compounds thereof
    • C08F4/64—Titanium, zirconium, hafnium or compounds thereof
    • C08F4/659—Component covered by group C08F4/64 containing a transition metal-carbon bond
    • C08F4/6592—Component covered by group C08F4/64 containing a transition metal-carbon bond containing at least one cyclopentadienyl ring, condensed or not, e.g. an indenyl or a fluorenyl ring

Landscapes

  • Chemical & Material Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Organic Chemistry (AREA)
  • Health & Medical Sciences (AREA)
  • Addition Polymer Or Copolymer, Post-Treatments, Or Chemical Modifications (AREA)
  • Transition And Organic Metals Composition Catalysts For Addition Polymerization (AREA)
  • Materials For Medical Uses (AREA)
  • Orthopedics, Nursing, And Contraception (AREA)
  • Absorbent Articles And Supports Therefor (AREA)
  • Polyamides (AREA)
  • Medical Preparation Storing Or Oral Administration Devices (AREA)
AU12234/88A 1986-12-19 1987-12-16 Copolymers of ethylene and 1,3-butadiene Ceased AU616396B2 (en)

Applications Claiming Priority (3)

Application Number Priority Date Filing Date Title
US94438586A 1986-12-19 1986-12-19
US944385 1986-12-19
IN1012DE1987 IN172494B (enExample) 1986-12-19 1987-11-27

Publications (2)

Publication Number Publication Date
AU1223488A AU1223488A (en) 1988-07-15
AU616396B2 true AU616396B2 (en) 1991-10-31

Family

ID=26324691

Family Applications (1)

Application Number Title Priority Date Filing Date
AU12234/88A Ceased AU616396B2 (en) 1986-12-19 1987-12-16 Copolymers of ethylene and 1,3-butadiene

Country Status (8)

Country Link
EP (2) EP0526955A1 (enExample)
JP (1) JP2764163B2 (enExample)
AT (1) ATE111114T1 (enExample)
AU (1) AU616396B2 (enExample)
DE (1) DE3750506T2 (enExample)
ES (1) ES2058131T3 (enExample)
IN (1) IN172494B (enExample)
WO (1) WO1988004672A1 (enExample)

Families Citing this family (42)

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US5008204A (en) * 1988-02-02 1991-04-16 Exxon Chemical Patents Inc. Method for determining the compositional distribution of a crystalline copolymer
DE68911435T2 (de) * 1988-09-05 1994-04-28 Idemitsu Kosan Co Verfahren zur Herstellung eines Polymers.
DE4139261A1 (de) * 1991-11-29 1993-06-03 Basf Ag Ethylen-copolymerisate niederer dichte
US5712353A (en) * 1994-10-31 1998-01-27 Exxon Chemical Patents Inc. Gas phase polymerization process
US5763543A (en) * 1994-09-14 1998-06-09 Exxon Chemical Patents Inc. Olefin polymerization process with little or no scavenger present
US6300451B1 (en) 1994-10-24 2001-10-09 Exxon Chemical Patents Inc. Long-chain branched polymers and their production
US6239058B1 (en) * 1995-07-18 2001-05-29 Fina Technology, Inc. Process for activating a metallocene catalyst supported on silica
CA2181413A1 (en) * 1995-07-18 1998-01-18 Edwar S. Shamshoum Process for the syndiotactic propagation of olefins
IT1276070B1 (it) 1995-10-31 1997-10-24 Siac It Additivi Carburanti Processo per la preparazione di polimeri a base di etilene a basso peso molecolare
CA2192156C (en) * 1995-12-08 2006-07-11 Nobuhiro Tsujimoto Catalyst and process for producing conjugated diene polymer
US6084046A (en) * 1997-02-13 2000-07-04 Sumitomo Chemical Company, Limted Copolymer and copolymer composition
TW420693B (en) 1997-04-25 2001-02-01 Mitsui Chemicals Inc Olefin polymerization catalysts, transition metal compounds, and <alpha>-olefin/conjugated diene copolymers
DE69813958T2 (de) * 1997-07-18 2004-03-11 Mitsui Chemicals, Inc. Ungesättigte Copolymere, Verfahren zu deren Herstellung und Mischungen, die diese enthalten
JP2000063639A (ja) * 1998-08-13 2000-02-29 Mitsui Chemicals Inc α−オレフィン／共役ジエン系共重合体組成物
TW576843B (en) 1998-12-25 2004-02-21 Mitsui Chemicals Inc Olefin polymerization catalyst and process for olefin polymerization using the olefin polymerization catalyst
ITSA20010016A1 (it) * 2001-06-05 2001-09-05 Univ Degli Studi Salerno Copolimeri a base di etilene contenenti anelli ciclopropanici nella catena principale.
JP2004018696A (ja) * 2002-06-17 2004-01-22 Tosoh Corp エチレン−共役ジエン系共重合体
WO2004026923A2 (en) 2002-09-20 2004-04-01 Exxonmobil Chemical Patents Inc. Supercritical polymerization process and polymers produced therefrom
BRPI0513057A (pt) 2004-07-08 2008-04-22 Exxonmobil Chem Patents Inc produção de polìmero em condições supercrìticas
US8143352B2 (en) 2006-12-20 2012-03-27 Exxonmobil Research And Engineering Company Process for fluid phase in-line blending of polymers
US8080610B2 (en) 2007-03-06 2011-12-20 Exxonmobil Research And Engineering Company Monomer recycle process for fluid phase in-line blending of polymers
CN101855249B (zh) 2007-09-13 2013-02-13 埃克森美孚研究工程公司 在线生产增塑聚合物和增塑聚合物共混物的方法
EP2201042B1 (en) 2007-09-13 2012-06-27 ExxonMobil Research and Engineering Company In-line blending of plasticizers with a base polymer
US8138269B2 (en) 2007-12-20 2012-03-20 Exxonmobil Research And Engineering Company Polypropylene ethylene-propylene copolymer blends and in-line process to produce them
US7910679B2 (en) 2007-12-20 2011-03-22 Exxonmobil Research And Engineering Company Bulk homogeneous polymerization process for ethylene propylene copolymers
CN101945942B (zh) 2007-12-20 2012-08-08 埃克森美孚研究工程公司 生产粒料稳定的聚烯烃的在线方法
SG174602A1 (en) 2009-03-30 2011-11-28 Mitsui Chemicals Inc Copolymer of olefin and conjugated diene, and process for producing same
RU2542992C2 (ru) 2010-07-30 2015-02-27 Бриджстоун Корпорейшн Способ регулирования структуры цепи сополимера
RU2528410C1 (ru) 2010-07-30 2014-09-20 Бриджстоун Корпорейшн Сополимер, каучуковая композиция, сшитая каучуковая композиция и покрышка
BR112014018621A8 (pt) * 2012-01-30 2017-07-11 Bridgestone Corp Composição de borracha para amortecimento de vibração, composiçao de borracha reticulada para amortecimento de vibração e borracha para amortecimento de vibração
JP5893938B2 (ja) * 2012-01-30 2016-03-23 株式会社ブリヂストン 防振ゴム組成物及び防振ゴム
EP2810984B1 (en) * 2012-01-30 2016-09-14 Bridgestone Corporation Anti-vibration rubber composition, crosslinked anti-vibration rubber composition, and anti-vibration rubber
JP5893937B2 (ja) * 2012-01-30 2016-03-23 株式会社ブリヂストン 防振ゴム組成物、架橋防振ゴム組成物及び防振ゴム
FR3045613B1 (fr) 2015-12-17 2017-12-15 Michelin & Cie Copolymere d'ethylene et de butadiene de microstructure homogene
FR3045612B1 (fr) 2015-12-17 2017-12-15 Michelin & Cie Copolymere d'ethylene et de butadiene de microstructure homogene
FR3045633B1 (fr) 2015-12-22 2017-12-15 Michelin & Cie Pneumatique comprenant une composition de caoutchouc comprenant un elastomere dienique substitue
FR3065215A1 (fr) 2017-04-18 2018-10-19 Compagnie Generale Des Etablissements Michelin Synthese en continu de copolymere d'ethylene et de butadiene
FR3065216A1 (fr) 2017-04-18 2018-10-19 Compagnie Generale Des Etablissements Michelin Synthese en continu de copolymere d'ethylene et de butadiene
JP2019099719A (ja) * 2017-12-05 2019-06-24 株式会社ブリヂストン 共重合体、ゴム組成物、樹脂組成物、タイヤ及び樹脂製品
JP6983048B2 (ja) * 2017-12-05 2021-12-17 株式会社ブリヂストン 共重合体、ゴム組成物、樹脂組成物、タイヤ及び樹脂製品
KR20230109729A (ko) * 2020-11-20 2023-07-20 차이나 페트로리움 앤드 케미컬 코포레이션 에틸렌 공중합체, 이의 제조 방법, 조성물, 가교 중합체 및 타이어
JP7575928B2 (ja) * 2020-12-07 2024-10-30 株式会社ブリヂストン 共重合体、ゴム組成物及び樹脂組成物

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IT1115152B (it) * 1979-03-07 1986-02-03 Anic Spa Processo per la copolimerizzazione dell'etilene con idrocarburi pluriinsaturi
DE3007725A1 (de) * 1980-02-29 1981-09-17 Hansjörg Prof. Dr. 2000 Hamburg Sinn Verfahren zur herstellung von polyethylen, polypropylen und copolymeren
DE3035358A1 (de) * 1980-09-19 1982-05-06 Bayer Ag, 5090 Leverkusen Terpolymere aus ethylen, butadien und isopren und verfahren zu ihrer herstellung
DE3127133A1 (de) * 1981-07-09 1983-01-27 Hoechst Ag, 6000 Frankfurt Verfahren zur herstellung von polyolefinen und deren copolymerisaten
ZA844157B (en) * 1983-06-06 1986-01-29 Exxon Research Engineering Co Process and catalyst for polyolefin density and molecular weight control
CA1268754A (en) * 1985-06-21 1990-05-08 Howard Curtis Welborn, Jr. Supported polymerization catalyst
GB2184368A (en) * 1985-11-27 1987-06-24 Dow Chemical Co High temperature continuous viscometry coupled with analytic temperature rising elution fractionation for evaluating crystalline and semi-crystalline polymers
IN172282B (enExample) * 1986-12-19 1993-05-29 Exxon Chemical Patents Inc

Also Published As

Publication number Publication date
ATE111114T1 (de) 1994-09-15
EP0275676B1 (en) 1994-09-07
EP0275676A1 (en) 1988-07-27
AU1223488A (en) 1988-07-15
JP2764163B2 (ja) 1998-06-11
DE3750506T2 (de) 1995-01-12
DE3750506D1 (de) 1994-10-13
ES2058131T3 (es) 1994-11-01
WO1988004672A1 (en) 1988-06-30
EP0526955A1 (en) 1993-02-10
JPH01501633A (ja) 1989-06-08
IN172494B (enExample) 1993-09-04

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