AU592673B2 - Process for the production of diphenylamine - Google Patents
Process for the production of diphenylamine Download PDFInfo
- Publication number
 - AU592673B2 AU592673B2 AU79023/87A AU7902387A AU592673B2 AU 592673 B2 AU592673 B2 AU 592673B2 AU 79023/87 A AU79023/87 A AU 79023/87A AU 7902387 A AU7902387 A AU 7902387A AU 592673 B2 AU592673 B2 AU 592673B2
 - Authority
 - AU
 - Australia
 - Prior art keywords
 - percent
 - aniline
 - diphenylamine
 - catalyst
 - angstroms
 - Prior art date
 - Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
 - Ceased
 
Links
- DMBHHRLKUKUOEG-UHFFFAOYSA-N diphenylamine Chemical compound C=1C=CC=CC=1NC1=CC=CC=C1 DMBHHRLKUKUOEG-UHFFFAOYSA-N 0.000 title claims description 58
 - 238000000034 method Methods 0.000 title claims description 40
 - 238000004519 manufacturing process Methods 0.000 title description 7
 - PAYRUJLWNCNPSJ-UHFFFAOYSA-N Aniline Chemical compound NC1=CC=CC=C1 PAYRUJLWNCNPSJ-UHFFFAOYSA-N 0.000 claims description 48
 - 239000003054 catalyst Substances 0.000 claims description 25
 - PNEYBMLMFCGWSK-UHFFFAOYSA-N aluminium oxide Inorganic materials [O-2].[O-2].[O-2].[Al+3].[Al+3] PNEYBMLMFCGWSK-UHFFFAOYSA-N 0.000 claims description 13
 - 239000011148 porous material Substances 0.000 claims description 12
 - NINIDFKCEFEMDL-UHFFFAOYSA-N Sulfur Chemical compound [S] NINIDFKCEFEMDL-UHFFFAOYSA-N 0.000 claims description 8
 - 229910052717 sulfur Inorganic materials 0.000 claims description 8
 - 239000011593 sulfur Substances 0.000 claims description 8
 - 230000000052 comparative effect Effects 0.000 claims description 7
 - WTEOIRVLGSZEPR-UHFFFAOYSA-N boron trifluoride Chemical compound FB(F)F WTEOIRVLGSZEPR-UHFFFAOYSA-N 0.000 claims description 6
 - VWKLICCSBFEWSZ-UHFFFAOYSA-N aniline;trifluoroborane Chemical compound FB(F)F.NC1=CC=CC=C1 VWKLICCSBFEWSZ-UHFFFAOYSA-N 0.000 claims description 4
 - 239000000126 substance Substances 0.000 claims description 4
 - 229910015900 BF3 Inorganic materials 0.000 claims description 3
 - 238000006243 chemical reaction Methods 0.000 description 13
 - 238000002474 experimental method Methods 0.000 description 7
 - QGZKDVFQNNGYKY-UHFFFAOYSA-N Ammonia Chemical compound N QGZKDVFQNNGYKY-UHFFFAOYSA-N 0.000 description 4
 - QSHDDOUJBYECFT-UHFFFAOYSA-N mercury Chemical compound [Hg] QSHDDOUJBYECFT-UHFFFAOYSA-N 0.000 description 4
 - 229910052753 mercury Inorganic materials 0.000 description 4
 - 238000002459 porosimetry Methods 0.000 description 4
 - 229910021529 ammonia Inorganic materials 0.000 description 2
 - 239000003963 antioxidant agent Substances 0.000 description 2
 - ZOXJGFHDIHLPTG-UHFFFAOYSA-N Boron Chemical compound [B] ZOXJGFHDIHLPTG-UHFFFAOYSA-N 0.000 description 1
 - 229910000831 Steel Inorganic materials 0.000 description 1
 - 230000003078 antioxidant effect Effects 0.000 description 1
 - 229910052796 boron Inorganic materials 0.000 description 1
 - 238000010960 commercial process Methods 0.000 description 1
 - 239000013256 coordination polymer Substances 0.000 description 1
 - 238000004821 distillation Methods 0.000 description 1
 - 239000000975 dye Substances 0.000 description 1
 - 238000005265 energy consumption Methods 0.000 description 1
 - 238000005516 engineering process Methods 0.000 description 1
 - 239000002360 explosive Substances 0.000 description 1
 - 238000001030 gas--liquid chromatography Methods 0.000 description 1
 - 238000010438 heat treatment Methods 0.000 description 1
 - 239000000203 mixture Substances 0.000 description 1
 - 239000000575 pesticide Substances 0.000 description 1
 - 239000004033 plastic Substances 0.000 description 1
 - 229920003023 plastic Polymers 0.000 description 1
 - 238000007639 printing Methods 0.000 description 1
 - 239000011541 reaction mixture Substances 0.000 description 1
 - 239000003381 stabilizer Substances 0.000 description 1
 - 239000010959 steel Substances 0.000 description 1
 - 239000011269 tar Substances 0.000 description 1
 
Classifications
- 
        
- C—CHEMISTRY; METALLURGY
 - C07—ORGANIC CHEMISTRY
 - C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
 - C07C209/00—Preparation of compounds containing amino groups bound to a carbon skeleton
 - C07C209/64—Preparation of compounds containing amino groups bound to a carbon skeleton by disproportionation
 
 
Landscapes
- Chemical & Material Sciences (AREA)
 - Organic Chemistry (AREA)
 - Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
 - Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)
 - Catalysts (AREA)
 
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title | 
|---|---|---|---|
| US06/903,354 US4814504A (en) | 1986-09-03 | 1986-09-03 | Process for the production of diphenylamine | 
Publications (2)
| Publication Number | Publication Date | 
|---|---|
| AU7902387A AU7902387A (en) | 1989-04-06 | 
| AU592673B2 true AU592673B2 (en) | 1990-01-18 | 
Family
ID=25417361
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date | 
|---|---|---|---|
| AU79023/87A Ceased AU592673B2 (en) | 1986-09-03 | 1987-09-28 | Process for the production of diphenylamine | 
Country Status (6)
| Country | Link | 
|---|---|
| US (1) | US4814504A (instruction) | 
| EP (1) | EP0308552B1 (instruction) | 
| JP (1) | JPH01102046A (instruction) | 
| AU (1) | AU592673B2 (instruction) | 
| IN (1) | IN171241B (instruction) | 
| ZA (1) | ZA877208B (instruction) | 
Families Citing this family (7)
| Publication number | Priority date | Publication date | Assignee | Title | 
|---|---|---|---|---|
| US4760186A (en) * | 1986-09-15 | 1988-07-26 | Monsanto Company | Preparation of substituted aromatic amines | 
| CN1043313C (zh) * | 1994-06-29 | 1999-05-12 | 中国石油化工总公司抚顺石油化工研究院 | 一种由苯胺合成二苯胺的催化剂及其制备方法 | 
| DE19756158A1 (de) * | 1997-12-17 | 1999-06-24 | Bayer Ag | Herstellung von sekundären Diarylaminen | 
| RU2158178C1 (ru) * | 1999-04-09 | 2000-10-27 | Товарищество с ограниченной ответственностью научно-внедренческое предприятие "ХИМТЕХ" | Раствор катализатора для конденсации анилина в дифениламин и способ его получения | 
| US6069279A (en) * | 1999-06-14 | 2000-05-30 | Simon; Mark W. | Preparation of substituted aromatic amines | 
| RU2274636C1 (ru) * | 2005-02-02 | 2006-04-20 | Государственное образовательное учреждение высшего профессионального образования Томский политехнический университет | Способ гетерофазного получения дифениламина | 
| US9752092B2 (en) | 2015-10-30 | 2017-09-05 | Chevron Oronite Company Llc | Lubricating oil compositions containing amidine antioxidants | 
Citations (1)
| Publication number | Priority date | Publication date | Assignee | Title | 
|---|---|---|---|---|
| EP0260651A2 (en) * | 1986-09-19 | 1988-03-23 | The B.F. GOODRICH Company | Process for the preparation of a composition of parabutylated and octylated, ortho-ethylated diphenylamines | 
Family Cites Families (6)
| Publication number | Priority date | Publication date | Assignee | Title | 
|---|---|---|---|---|
| CH357407A (fr) * | 1956-09-21 | 1961-10-15 | American Cyanamid Co | Procédé pour la fabrication continue en phase vapeur de diphénylamine | 
| FR1231215A (fr) * | 1959-04-10 | 1960-09-27 | Cfmc | Nouveau procédé de préparation de la diphénylamine | 
| US3118944A (en) * | 1959-08-07 | 1964-01-21 | American Cyanamid Co | Vapor phase process for the manufacture of diphenylamine | 
| GB1402707A (en) * | 1971-10-07 | 1975-08-13 | Ici Ltd | Preparation of diphenylamines | 
| JPS573668A (en) * | 1980-06-11 | 1982-01-09 | Yoshida Masafumi | Game method | 
| DE4218170C1 (instruction) * | 1992-06-02 | 1993-05-27 | Siemens Ag, 8000 Muenchen, De | 
- 
        1986
        
- 1986-09-03 US US06/903,354 patent/US4814504A/en not_active Expired - Lifetime
 
 - 
        1987
        
- 1987-09-23 EP EP87308420A patent/EP0308552B1/en not_active Expired - Lifetime
 - 1987-09-23 IN IN843/DEL/87A patent/IN171241B/en unknown
 - 1987-09-24 ZA ZA877208A patent/ZA877208B/xx unknown
 - 1987-09-28 AU AU79023/87A patent/AU592673B2/en not_active Ceased
 - 1987-10-14 JP JP62257491A patent/JPH01102046A/ja active Granted
 
 
Patent Citations (1)
| Publication number | Priority date | Publication date | Assignee | Title | 
|---|---|---|---|---|
| EP0260651A2 (en) * | 1986-09-19 | 1988-03-23 | The B.F. GOODRICH Company | Process for the preparation of a composition of parabutylated and octylated, ortho-ethylated diphenylamines | 
Also Published As
| Publication number | Publication date | 
|---|---|
| JPH0420423B2 (instruction) | 1992-04-02 | 
| EP0308552B1 (en) | 1991-05-22 | 
| AU7902387A (en) | 1989-04-06 | 
| ZA877208B (en) | 1988-04-21 | 
| EP0308552A1 (en) | 1989-03-29 | 
| JPH01102046A (ja) | 1989-04-19 | 
| US4814504A (en) | 1989-03-21 | 
| IN171241B (instruction) | 1992-08-22 | 
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