AU5471800A - Panel-like structure for collecting radiant energy - Google Patents
Panel-like structure for collecting radiant energy Download PDFInfo
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- AU5471800A AU5471800A AU54718/00A AU5471800A AU5471800A AU 5471800 A AU5471800 A AU 5471800A AU 54718/00 A AU54718/00 A AU 54718/00A AU 5471800 A AU5471800 A AU 5471800A AU 5471800 A AU5471800 A AU 5471800A
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- panel
- radiant energy
- major surface
- prismatic
- reflecting
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- 230000005611 electricity Effects 0.000 claims description 6
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- 238000002310 reflectometry Methods 0.000 description 5
- 230000004048 modification Effects 0.000 description 4
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- 238000000465 moulding Methods 0.000 description 3
- 230000003287 optical effect Effects 0.000 description 3
- BQCADISMDOOEFD-UHFFFAOYSA-N Silver Chemical compound [Ag] BQCADISMDOOEFD-UHFFFAOYSA-N 0.000 description 2
- 238000010521 absorption reaction Methods 0.000 description 2
- 239000004411 aluminium Substances 0.000 description 2
- XAGFODPZIPBFFR-UHFFFAOYSA-N aluminium Chemical compound [Al] XAGFODPZIPBFFR-UHFFFAOYSA-N 0.000 description 2
- 229910052782 aluminium Inorganic materials 0.000 description 2
- 239000012530 fluid Substances 0.000 description 2
- 229920001343 polytetrafluoroethylene Polymers 0.000 description 2
- 239000004810 polytetrafluoroethylene Substances 0.000 description 2
- 239000000047 product Substances 0.000 description 2
- 239000004332 silver Substances 0.000 description 2
- 229910052709 silver Inorganic materials 0.000 description 2
- 239000007787 solid Substances 0.000 description 2
- 241001270131 Agaricus moelleri Species 0.000 description 1
- NIXOWILDQLNWCW-UHFFFAOYSA-N acrylic acid group Chemical group C(C=C)(=O)O NIXOWILDQLNWCW-UHFFFAOYSA-N 0.000 description 1
- 238000003491 array Methods 0.000 description 1
- 238000006243 chemical reaction Methods 0.000 description 1
- 230000000052 comparative effect Effects 0.000 description 1
- 239000002131 composite material Substances 0.000 description 1
- 238000009833 condensation Methods 0.000 description 1
- 230000005494 condensation Effects 0.000 description 1
- 238000010276 construction Methods 0.000 description 1
- 238000000151 deposition Methods 0.000 description 1
- 238000010586 diagram Methods 0.000 description 1
- 230000005670 electromagnetic radiation Effects 0.000 description 1
- 230000007613 environmental effect Effects 0.000 description 1
- 239000005357 flat glass Substances 0.000 description 1
- 239000004811 fluoropolymer Substances 0.000 description 1
- 229920002313 fluoropolymer Polymers 0.000 description 1
- 230000004313 glare Effects 0.000 description 1
- 239000011521 glass Substances 0.000 description 1
- 238000009434 installation Methods 0.000 description 1
- 238000012423 maintenance Methods 0.000 description 1
- 230000007246 mechanism Effects 0.000 description 1
- 238000000034 method Methods 0.000 description 1
- 239000004417 polycarbonate Substances 0.000 description 1
- 229920000515 polycarbonate Polymers 0.000 description 1
- 229920001296 polysiloxane Polymers 0.000 description 1
- -1 polytetrafluoroethylene Polymers 0.000 description 1
- 230000008569 process Effects 0.000 description 1
- 230000009467 reduction Effects 0.000 description 1
- 238000007493 shaping process Methods 0.000 description 1
- 239000013589 supplement Substances 0.000 description 1
- 238000009834 vaporization Methods 0.000 description 1
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- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 1
Classifications
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- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01L—SEMICONDUCTOR DEVICES NOT COVERED BY CLASS H10
- H01L31/00—Semiconductor devices sensitive to infrared radiation, light, electromagnetic radiation of shorter wavelength or corpuscular radiation and specially adapted either for the conversion of the energy of such radiation into electrical energy or for the control of electrical energy by such radiation; Processes or apparatus specially adapted for the manufacture or treatment thereof or of parts thereof; Details thereof
- H01L31/04—Semiconductor devices sensitive to infrared radiation, light, electromagnetic radiation of shorter wavelength or corpuscular radiation and specially adapted either for the conversion of the energy of such radiation into electrical energy or for the control of electrical energy by such radiation; Processes or apparatus specially adapted for the manufacture or treatment thereof or of parts thereof; Details thereof adapted as photovoltaic [PV] conversion devices
- H01L31/054—Optical elements directly associated or integrated with the PV cell, e.g. light-reflecting means or light-concentrating means
- H01L31/0547—Optical elements directly associated or integrated with the PV cell, e.g. light-reflecting means or light-concentrating means comprising light concentrating means of the reflecting type, e.g. parabolic mirrors, concentrators using total internal reflection
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- F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
- F24—HEATING; RANGES; VENTILATING
- F24S—SOLAR HEAT COLLECTORS; SOLAR HEAT SYSTEMS
- F24S23/00—Arrangements for concentrating solar-rays for solar heat collectors
-
- F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
- F24—HEATING; RANGES; VENTILATING
- F24S—SOLAR HEAT COLLECTORS; SOLAR HEAT SYSTEMS
- F24S23/00—Arrangements for concentrating solar-rays for solar heat collectors
- F24S23/70—Arrangements for concentrating solar-rays for solar heat collectors with reflectors
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01L—SEMICONDUCTOR DEVICES NOT COVERED BY CLASS H10
- H01L31/00—Semiconductor devices sensitive to infrared radiation, light, electromagnetic radiation of shorter wavelength or corpuscular radiation and specially adapted either for the conversion of the energy of such radiation into electrical energy or for the control of electrical energy by such radiation; Processes or apparatus specially adapted for the manufacture or treatment thereof or of parts thereof; Details thereof
- H01L31/04—Semiconductor devices sensitive to infrared radiation, light, electromagnetic radiation of shorter wavelength or corpuscular radiation and specially adapted either for the conversion of the energy of such radiation into electrical energy or for the control of electrical energy by such radiation; Processes or apparatus specially adapted for the manufacture or treatment thereof or of parts thereof; Details thereof adapted as photovoltaic [PV] conversion devices
- H01L31/054—Optical elements directly associated or integrated with the PV cell, e.g. light-reflecting means or light-concentrating means
- H01L31/0543—Optical elements directly associated or integrated with the PV cell, e.g. light-reflecting means or light-concentrating means comprising light concentrating means of the refractive type, e.g. lenses
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- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02E—REDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
- Y02E10/00—Energy generation through renewable energy sources
- Y02E10/40—Solar thermal energy, e.g. solar towers
- Y02E10/44—Heat exchange systems
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02E—REDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
- Y02E10/00—Energy generation through renewable energy sources
- Y02E10/50—Photovoltaic [PV] energy
- Y02E10/52—PV systems with concentrators
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- Engineering & Computer Science (AREA)
- Physics & Mathematics (AREA)
- Mechanical Engineering (AREA)
- General Engineering & Computer Science (AREA)
- Sustainable Energy (AREA)
- Thermal Sciences (AREA)
- Chemical & Material Sciences (AREA)
- Combustion & Propulsion (AREA)
- Life Sciences & Earth Sciences (AREA)
- Sustainable Development (AREA)
- Condensed Matter Physics & Semiconductors (AREA)
- Electromagnetism (AREA)
- General Physics & Mathematics (AREA)
- Computer Hardware Design (AREA)
- Microelectronics & Electronic Packaging (AREA)
- Power Engineering (AREA)
- Photovoltaic Devices (AREA)
- Optical Elements Other Than Lenses (AREA)
Description
WO 00/77458 PCT/US00/15726 PANEL-LIKE STRUCTURE FOR COLLECTING RADIANT ENERGY The present invention relates to structures for collecting radiant energy, more especially, (but not exclusively), solar energy and, in particular, to panel-like structures 5 suitable for use in a wide variety of locations. Solar energy is increasingly being used to supplement and, in some circumstances, replace other forms of energy in the production of electricity. However, although solar energy offers advantages from an environmental point of view it is still, for many 10 applications, too expensive to justify consideration. For maximum efficiency, the collection of solar energy for conversion into electricity is carried out using an array of photovoltaic cells which tracks the sun to ensure that, throughout the year, it is always oriented to collect the greatest amount of energy. The installation and maintenance of such an array is, however, comparatively complex. Fixed arrays are easier to install and 15 less costly but are less effective unless they are aimed in the direction of the average position of the sun (which is not always possible) or a very large area of photovoltaic cells is provided (in which case the cost of the photovoltaic cells can become prohibitively high). 20 It is recognized that one way of reducing the comparative cost of electricity produced from solar energy is to reduce the number of cells that is required to collect a given amount of solar energy. Various arrangements have been proposed with that in mind, and some examples are described in US-A-4 235 643; 4 313 023; 4 514 040; 5 419 782; and 5 466 301, and in SU-A-1 089 365. 25 In addition, a paper entitled "Ideal Prism Solar Concentrators" by D. R. Mills and J. E. Guitronich published in 1978 in "Solar Energy", Volume 21 at pages 423 to 430 describes the possibility of using simple prism units as solar concentrators, and of -1- WO 00/77458 PCT/US00/15726 combining low concentration prism units into stationary, flat-top concentrators. A related disclosure appears in AU-A-37217/78. The present invention is concerned with improving the efficiency and increasing 5 the versatility of panel-like structures used for collecting radiant energy, more especially (but by no means exclusively) structures for use in buildings, road signs and hoardings. The present invention provides a structure for collecting radiant energy, in accordance with claims 1 and 2 herein. 10 The present invention also provides a structure for collecting radiant energy in accordance with claim 9 herein. The present invention further provides a structure for collecting radiant energy, in 15 accordance with claims 16 and 17 herein. By way of example only, embodiments of the invention will be described with reference to the accompanying drawings, in which: Fig. 1 is a vertical cross-section through a panel-like structure that can be used for 20 collecting radiant energy; Fig. 2 is a diagram illustrating the location of various parts of the structure, as viewed in the direction of the arrow II in Fig. 1; Fig. 3 is a diagrammatic vertical cross-section corresponding to Fig. 1, showing various ray paths through the structure; 25 Fig. 4 is an enlarged version of part of Fig. 3, used for calculating the dimensions of parts of the structure; Figs. 5 and 6 are views, similar to Fig. 4, illustrating structures in accordance with one aspect of the present invention; Figs. 7(a) and (b) illustrate modified forms of the structure shown in Fig. 1; -2- WO 00/77458 PCT/US00/15726 Figs. 8(a) and (b) are vertical cross-sections through a structure in accordance with another aspect of the invention, in combination, respectively with a window and a graphic panel; Fig. 9 illustrates a further modification of the structure of Fig. 7(b); 5 Figs. 10(a) and (b) and 11 illustrate alternative orientations of a structure for collecting radiant energy, in accordance with a further aspect of the invention; and Figs. 12 to 14 are diagrammatic vertical cross-sections through other panel-like structures that can be used for collecting radiant energy. 10 Figs. 1 and 2 show a panel-like structure 1, suitable for use as part of a fixed construction, for collecting solar energy to be used for generating electricity. As explained in greater detail below, the structure 1 can be used in many different locations, including: on the inside surface of a window; on the outside of a building; and on road signs and hoardings. 15 The structure 1 comprises a vertical panel 2 of a light-transmitting material, having first and second major surfaces 3, 4. The first major surface 3 is planar while the second major surface 4 is profiled and comprises several elongated, generally prismatic structures 5 extending horizontally across the panel 2 one above the other. The prismatic structures 5 20 are identical, and run parallel to each other. Each prismatic structure 5 comprises mutually inclined faces 6, 7: the face 6 is a reflecting surface facing into the panel 2, and the face 7 carries a photovoltaic cell 8 which is in optical contact with the panel material to receive radiation transmitted through the latter. The photovoltaic cell 8 is in the form of a strip which covers the whole width of the face 7. Typical dimensions for the widths of the 25 faces 6 and 7 are 10mm and 3mm respectively. The panel 2 may be formed from a polymeric material, and may be a moulded structure. Suitable polymeric materials include polycarbonate, silicone, and acrylic materials, and fluoropolymers, for example Dyneonm THV fluorothermoplastic material, -3- WO UU/77458 PCT/US00/15726 available from Minnesota Mining and Manufacturing Company, St. Paul, Minnesota, USA and polytetrafluoroethylene (PTFE). Fig. 3 illustrates the structure 1 positioned so that the vertical planar surface 3 faces 5 the direction in which the sun attains its highest altitude (i.e. due south in the northern hemisphere). Electromagnetic radiation from the sun enters the panel 2 through the surface 3, as represented by the ray paths 101 to 10', and some of that radiation (exemplified by the ray 101) will impinge directly on one of the photovoltaic cells 8 while the remainder will strike one of the reflecting faces 6 and be directed back into the panel. Radiation that is 10 reflected from a face 6 close to the apex of the respective prismatic.structure 5 will be directed to the adjacent photovoltaic cell 8, as exemplified by the ray 102 in Fig. 3, while the remainder of the reflected radiation will be directed back towards the planar surface 3, as exemplified by the rays 103 to 10'. The angle at which the rays 103 to 10' strike the surface 3 within the panel depends, for a given angle of incidence from the sun, on the 15 angle of inclination of the reflecting face 6 and the latter is selected to ensure that all of the reflected rays 103 to 10' will undergo total internal reflection (TIR) at the surface 3 and be returned yet again into the panel 2, as illustrated. This time, some of the TIR radiation will impinge on one of the photovoltaic cells 8, either directly as exemplified by the ray 10' or after one more reflection at a face 6 as exemplified by the ray 104. The remaining 20 radiation, exemplified by the ray 105, will be directed yet again to the surface 3 of the panel where it will undergo total internal reflection yet again and eventually reach a photovoltaic cell 8 by repetition(s) of the process just described (unless it encounters the edge of the panel 2 first). 25 Various configurations of the structure 1, in accordance with different aspects of the present invention, will be described below. In the description, reference will be made to the dimensions of various parts of the structure, those dimensions being as indicated in Fig. 4. -4- WU UUI / /4"5 YLT/USUU/IST7ZO To minimize the width S of the faces 7 and thus the total area of the solar cells 8 used in the structure 1 (i.e. a structure with planar faces 6, 7), the apex angle D of each prismatic structure 5 should be 900 and the angle of inclination T of each of the reflecting faces 6 to the general plane of the panel 2 (in this case, the vertical) should be as small as 5 possible consistent with ensuring that all radiation which is returned to the surface 3 of the panel 2 undergoes total internal reflection as described above. The concentration ratio of the structure (defined as the ratio of the width W in the vertical direction of one of the prismatic structures 5 to the width S of a photovoltaic cell 8) will then be at a maximum. With the angle D set at 900, it can be shown that the minimum value of the angle T is 10 determined by the expression: sin 2T = sin C .4(1 - k 2 ) - k cos C (i) where k = sin A/n C is the critical angle for the material of the panel 2 n is the refractive index of the material of the panel 2, and 15 A is the minimum sun altitude (in the vertical plane normal to the panel) at which energy is to be collected. Using expression (i) for a panel material having a refractive index of 1.5, and assuming that solar energy is to be collected at all times of the year, the minimum values shown in Table 1 below can be derived for the angle T over latitudes 400 to 600 (the values 20 being shown with the accompanying concentration ratios of the structure 1). In deriving these values, the minimum sun altitude A is taken as the altitude of the sun at noon on 21st December at each latitude. TABLE 1 Latitude Minimum Angle T Concentration ratio W/S 400 12.230 4.72 450 13.810 4.19 500 15.420 3.76 -5- WO UU/77458 PCT/US00/15726 550 17.060 3.40 600 18.720 3.11 A fixed panel-like structure of the type described above with reference to Figs. 1 and 2 can, through an appropriate selection of the angle T, collect substantially more (typically over three times as much) photovoltaic energy per unit area of photovoltaic cell 5 than a plane panel of the same materials. Even if the angle T does not have the minimum possible value for the particular latitude at which the panel is used, an advantageous amount of solar energy can still be collected. As an example of the above, if a structure as shown in Figs 1 and 2 is formed from 10 a material having a refractive index n of 1.5 and with the angle T equal to 15.750 and is located (facing due south) at latitude 500 north then, assuming that the reflectivity of the faces 6 is 100% and that substantially all of the radiation directed to a face 7 actually enters the associated photovoltaic cell 8, it can be expected that the structure could show a net gain of about 3.6 (i.e. it could collect about 3.6 times as much solar energy per unit 15 area as a plane photovoltaic cell potted in a material having a refractive index of 1.5). Moreover, that increase in the amount of energy collected remains comparatively constant throughout the day and throughout the year. The concentration ratio W/S of the structure shown in Fig. 1 varies with the index 20 of refraction of the material of the panel 2 and, in particular, can be increased at any given latitude by employing a material having a greater index of refraction. That is illustrated by the following table, for latitude 500. TABLE 2 Refractive Facet Angle Concentration Index T ratio W/S -6- WO 00/77458 PCT/US00/15726 1.4 16.920 3.43 1.5 15.420 3.76 1.6 14.210 4.07 It is also possible, in accordance with one aspect of the present invention, to achieve an increase in the concentration ratio W/S by modifying the shape of the prismatic structures 5, in particular the shape of the reflecting surfaces 6, as will now be described 5 with reference to Figs. 5 and 6. Fig. 5 is a view similar to Fig. 4, illustrating that the reflecting faces 6 of the prismatic structures 5 need not be completely planar. Each of the reflecting faces has an initial planar section 11 but comprises also a curved section 12 which commences at the 10 point indicated by the reference P and joins the planar section to the apex of the prismatic structure 5 (and to the associated face 7). The point P is the location, in the face 6 of Fig. 4, at which a reflected ray from the sun at minimum altitude A grazes the edge 13 of the face 7. The position of the point P defines the width W 1 in the vertical direction of the planar section 11 of the reflecting face 6, which is given by the expression 15 W, = W/I 1 +(tan T) tan (B+2T) }. The section 12 follows a parabolic curve (shown continued in dotted lines beyond the apex of the prismatic structure) having the following characteristics: the focus of the parabola is located at the edge 13 of the face 7; the axis 14 of the parabola (also shown in dotted lines) is parallel to the initial path of a ray within the panel 2 when the sun is at the minimum altitude A (see above); and the origin-focus 20 distance a of the parabola (i.e. the length of the axis 14 shown in Fig. 5) is given by the expression a = 0.5{M + 4(M 2 + N 2 )} (ii) where M = L sin B L= (W, tan T)/tan B - W + W, -7- WO 00/77458 PCT/US00/15726 N = (W, tan T)/Sin B - L cos B By shaping the reflecting face 6 as shown in Fig. 5, the widths of the photovoltaic cell 8 can be reduced (for a given width W of the prismatic structure 5) while still ensuring that 5 all radiation incident on the reflecting face 6 below the point P (i.e. the parabolic section 12) will be directed onto the photovoltaic cell. Radiation that is incident on the reflecting face 6 above the point P (i.e. the planar section 11) will be directed back to the front face 3 of the structure 1 and will be totally internally reflected at that face as described above with reference to Fig. 3. The effect of reducing the width S of the photovoltaic cell is to 10 increase the concentration ratio of the structure, and the greatest effect is achieved by arranging the face 7 to lie along the axis 14 of the parabolic curve 12. In that case, the width of the photovoltaic cell 8 will be as small as possible but, nevertheless, will receive all radiation incident on the parabolic section 12 of the reflecting surface. However, it may be more practical (from a manufacturing viewpoint) to arrange the face 7 at 900 to the 15 front face 3 of the panel 2 as shown in Fig. 5 although the concentration ratio of the structure will be slightly lower. Fig. 6 illustrates an alternative prismatic structure 5, in which the parabolic section 12 of Fig. 5 is replaced by two mutually-inclined planar sections 15', 152 one of which 20 (15') is a continuation of the planar section 11 of the reflecting face 6. The planar sections 15', 152 together provide a shape that corresponds substantially to that of the parabolic section 12 and necessitate some adjustment in the width and orientation of the face 7 carrying the photovoltaic cell 8 but the planar section 11 of the reflecting face 6 (above the point P) remains unchanged. The configuration illustrated in Fig. 6 offers a slightly lower 25 concentration ratio for the panel 2 than that of Fig. 5 but, unlike the Fig. 5 configuration, does not result in all of the minimum angle radiation (i.e. radiation incident on the front face 3 at the angle A) reflected from the lower part of the face 6 being brought to a focus on the edge 13 of the photovoltaic cell 8 when the sun is at the minimum altitude A: instead, some of that radiation will now be directed to other areas of the photovoltaic cell. -8- WO 00/77458 PCT/US00/15726 If desired, the parabolic section 12 of Fig. 5 could be replaced by more than two mutually inclined planar sections (one being a continuation of the section 11, in the manner of section 151 in Fig. 6), likewise providing a shape that corresponds substantially to that of the parabolic section. 5 In each of the configurations described above, the photovoltaic cells 8 may be any suitable type in the form of a strip, and are located on the faces 7 so that they are in optical contact with the material of the panel 2. In the case in which the panel 2 is formed by moulding, the required optical contact could, for example, be achieved by making the 10 photovoltaic cells an integral part of the moulded product. The reflecting surface on the faces 6 of the panels 2 can be formed by depositing a reflective material on those sections or by attaching a pre-formed reflective material to those sections. Advantageously, the reflecting surface has a reflectivity of at least 90% 15 and an example of a suitable pre-formed material is a silver reflective film available, under the trade designation "Silverlux", from Minnesota Mining and Manufacturing Company of St. Paul, Minnesota, USA. That material may be laminated to the panel 2 after the latter has been formed or, in the case in which the panel is formed by moulding, may be an integral part of the moulded product. Examples of other pre-formed reflective materials 20 suitable for use on the faces 6 of a panel are described in US-A-5 882 774 and WO 97/01774. Further examples are reflective films available, under the trade designations "ECP 305A" and "SA-85P" from Minnesota Mining and Manufacturing Company; a silvered film on aluminium available, under the trade designation "EVERBRITE 95", from Alcoa of Sidney, Ohio, USA; a silver film available, under the trade designation 25 "SPECULAR PLUS", from MSC Laminates & Composites Inc., of Elk Grove Village, Illinois, USA; and aluminium reflective sheeting available, under the trade designation "MIRO 4" from Alanod Aluminium-Veredlung GmbH & Co, of Ennepetal, Germany. -9- WO 00/77458 PCTI/USUoI/15726 An alternative form of the panel of Fig. 1, in which the reflective material 16 is spaced apart from the faces 6, is illustrated in Fig. 7(a). The reflective material 16 is shown positioned parallel to the respective face 6 but space apart from it by an air gap 17 which is closed at both ends by the adjacent photovoltaic cell 8. In this case, the presence of the air 5 gap 17 will cause some of the radiation incident on the face 6 (represented by the ray 18) to be totally internally reflected and thus directed back into the panel without any absorption losses. The remaining radiation incident on the face 6 (represented by the ray 181) will be directed back into the panel either by partial reflection at this face ( as indicated by the ray 182) or by reflection, with absorption losses, at the material 16 (as 10 indicated by the ray 183). In Fig. 7(a), the air gap 17 could be replaced by a solid layer of a material having a low index of refraction in comparison to the material of the panel 2. In that case, the solid layer will provide support for the reflective material 16. Although the arrangement shown 15 in Fig. 7(a) does not offer an appreciable advantage over the arrangements of Figs. 1 to 6 if the material 16 has a very high reflectivity, it will give an improved performance if the reflectivity of the material 16 is less good. In some circumstances, it is possible to omit completely the reflective material 20 associated with the faces 6 of the panel of Fig. 1, as illustrated in Fig. 7(b). In that case, only radiation (exemplified by the ray 19) that undergoes total internal reflection at the faces 6 will be redirected into the panel 2 and may eventually impact one of the photovoltaic cells 8: the remainder of the radiation (other than that which falls directly on the photovoltaic cells) will simply pass out of the panel 2 through the faces 6 and be lost, 25 as indicated by the ray 191. Through a suitable choice of the angle T (see Fig. 3), in accordance with: n sin (C-T) = sin A (iii) (where n, A and C are as defined above) it can, if desired, be ensured that all solar radiation falling on the faces 6 undergoes total internal reflection, although the -10- WO 00/77458 PCT/US00/15726 concentration ratio W/S of the structure 1 will be lower. On the other hand, because of the simplicity of the structure when the reflective material is omitted, it may be acceptable in certain circumstances to use a panel having a lower concentration ratio despite the losses due to radiation passing out of the panel through the faces 6. By way of example, reference 5 can be made again to the specific structure (mentioned above) of the type shown in Figs. 1 and 2 (i.e. a structure formed from a material having a refractive index of 1.5 and with the angle T equal to 15.7540, and located facing due south at latitude 50'N). As stated above, if the reflectivity of the faces 6 is 100%, it can be expected that such a structure would show a constant net gain of about 3.6. If, for comparison, the reflective material is then 10 removed from the faces 6 so that the structure becomes of the type shown in Fig. 7(b), the net gain will remain substantially the same in mid-summer but will be lower at other times of the year (varying from a comparatively constant value of about 0.54 throughout the day in mid-winter to an average daily value of about 2.85 (with wide variations) around the vernal and autumnal equinoxes). 15 The alternative panel 2 of Fig. 7(b) can be used to advantage on the inside of window glass 20 as illustrated in Fig. 8(a). In that case, in addition to collecting solar energy which passes through the glass, the panel 2 will eliminate direct glare from the sun (due to the presence of the photovoltaic cells 8) while still allowing an observer 21 inside 20 the building to see through the window (via the surfaces 6) to the ground outside. Fig. 8(b) illustrates that the panel 2 of Fig. 7(b) can also be used to advantage in front of a graphic panel 30 which is intended to be viewed from below (i.e. by an observer 31 positioned to look up towards the graphic panel 30). The graphic panel 30 will be 25 visible to the observer through the planar faces 6 of the panel 2 but the latter will, nevertheless, also function to collect solar energy which may, in turn, be used to generate electricity to store in a battery for illuminating the graphic panel (which may, for example, be a back-lit sign). The panel 30 may be located on the outside of a building, or it may be any other form of vertical panel such as an advertising hoarding or a road sign. Since the -11- WO 00/77458 PCT/US00/15726 front face of the graphic panel 30 will be protected by the panel 2, it is possible to construct the graphic panel from materials which, otherwise, would not be able to withstand the effects of the weather. 5 Fig. 9 illustrates a modification to the panel 2 of Fig. 7(b), for use in eliminating distortion of an image that is viewed through the panel. The modification comprises the provision, adjacent the profiled face 4 of the panel 2, of a second panel 33 formed from the same material as the first panel to compensate for the refraction of light rays passing through the latter. The face 35 of the second panel 33 adjacent the panel 2 has a profile 10 which is complementary to that of the face 4, and there is a small air gap 37 between the two faces to ensure that the amount of radiation directed to the photovoltaic cells 8 remains unchanged. To an observer 38 looking through the panels, however, the assembly 2, 33 functions as if it were a parallel plate and any distortion of the view that might have been apparent in the absence of the second panel 33 is eliminated. 15 In the above description, it is assumed that the panel 2 is positioned so that the vertical front face 3 faces in the geographical direction in which the sun attains its highest altitude (i.e. due south in the northern hemisphere). The panel 2 can also be used to advantage (i.e. without a substantial reduction in the amount of solar radiation that it can 20 collect) when rotated up to about 450 to the east or west provided that the structure is rotated in its own plane at the same time and the angle T is increased slightly to ensure the collection of solar energy when the sun is at minimum altitude. In other words, the front face 3 remains vertical but the prismatic structures 5 no longer run horizontally. This is illustrated in Figs. 10(a) and (b) which are diagrammatic views from the front and from 25 above, respectively, of a south-facing panel 22, a south-east-facing panel 23, and a south west-facing panel 24. The panels 23 and 24 have been rotated clockwise and anti clockwise, respectively, relative to the panel 21 as seen in Fig. 9(a). In one practical example, a panel of the type shown in Figs. 1 and 2, formed from a material having a refractive index of 1.5, is used in a vertical orientation facing 30 east of south at a latitude -12- WO 00/77458 PCT/US00/15726 of 50'N. The panel is rotated clockwise through an angle R of 24.940 (as viewed in the direction of the arrow II in Fig. 1) and the angle of inclination T of the reflecting facets is set at 17.70 (giving a concentration ratio W/S of 3.29). The same panel will, of course, function satisfactorily facing 300 west of south at the same latitude, but should be rotated 5 through 24.940 in an anti-clockwise, rather than a clockwise, direction. Other practical examples are summarized in Table 3 below. In each case, the panel (which is of the type shown in Figs. 1 and 2) is formed from a material having a refractive index of 1.5 and is used in a vertical orientation at a latitude of 50'N. Panel facing: Rotation R Facet Angle T Concentration Ratio w/s 100 east/west of south 9.580 16.1 3.6 200 east/west of south 16.090 16.55 3.51 400 east/west of south 31.690 19.3 3.02 10 Any of the other panels described above (i.e. with reference to Figs. 5 to 9) can also be used with advantage in the manner illustrated in Fig. 10. In each case, the panel is rotated in its own plane so that the prismatic structures 5 are inclined to the horizontal, and the angle T is increased to ensure collection of solar energy when the sun is at minimum 15 altitude. It has also been assumed in the above description that the panel 2 is vertical. The same structure will, however, also function in a non-vertical orientation, for example on the inclined (pitched) roof of a house or as part of a collector array on the ground, and may 20 still offer advantages in comparison with a conventional plane, non-tracking, solar panel oriented in the optimum direction. The optimum direction is the direction of the average position of the sun (taken to be the position of the sun at mid-day on the equinox), and a panel 25 that is oriented in that way is shown in Fig. 11 with the average position of the -13- WO 00/77458 PCT/US00/15726 sun being indicated at 26. At latitude 500, the optimum aim altitude for the panel 25 would be 400. A structure of the type shown in Fig. 1, used at this latitude and oriented in this way can, provided it is adapted to receive minimum angle radiation from the sun (i.e. radiation from the December sun), collect twice as much solar energy over the course of a 5 year as a plane panel for the same area of photovoltaic cells. The net gain is, moreover, comparatively constant throughout the year. At lower aim altitudes (i.e. less than 400) the amount of solar energy collected by the Fig. 1 type of structure over the course of a year can be increased even further but exhibits wider variations throughout the year, with the highest gain relative to the conventional panel 25 of Fig. 11 being achieved in the winter 10 months. Any of the other panels described above, with reference to Figs. 5 to 9, can also be used in a non-vertical orientation. Figs. 12 and 13 illustrate further modifications of the structure shown in Fig. 1. The panel-like structure 27 shown in Fig. 12 comprises, effectively, a single one only of 15 the prismatic structures of Fig. 1. In this case, the geometry of the structure is selected to ensure that at least part of the radiation that is reflected from the face 6 will reach the photovoltaic cell 8 directly while another part will reach the solar cell after total internal reflection at the front face 3. The structure illustrated in Fig. 12 comprises a series of single prismatic structures 27, each of the type shown in Fig. 11, assembled one adjacent 20 another to form a larger panel. It will be appreciated that any of the other prismatic structures described above with reference to Figs. 5 to 8 could also be used in the manner illustrated in Figs. 12 and 13. Any of the panel structures described above could be laminated to a transparent 25 panel in the manner illustrated in Fig. 8(a). The transparent panel need not be a window in a building but could, for example, serve the purpose of protecting the panel from the environment or against physical damage when it is used in an exposed situation. -14- WO 00/77458 PCT/US00/15726 In the above description with reference to the drawings, it has been assumed that the radiant energy collectors are in the form of photovoltaic cells. Other forms of energy collector could be used, however, including heat collectors. Fig. 14, for example, shows a panel structure of the type shown in Fig. 1, in which the photovoltaic cells 8 are replaced 5 by heat-collecting tubes 28. If the panel is a moulded structure, the tubes 28 may be incorporated during the moulding operation. The tubes 28 may contain water or another suitable fluid to transport heat, or they may be heat pipes (i.e. pipes that transfer heat through repeated vaporization and condensation of a fluid). 10 In the above description of panels that comprise a plurality of prismatic structures, it has been assumed that the prismatic structures are identical. That is not essential, however, provided that the various mechanisms by which radiation is directed to the collectors 8, 28 in the panel are still present. It is also not essential for the front face 3 of the panel to be exactly planar: in some circumstances, it may be desirable to provide the 15 panel with a front face which is structured (although on a significantly smaller scale than the rear face 4), for example to reduce radiation loses through partial reflection at the front face. It may also, in some circumstances, be desirable to give a degree of curvature to the whole panel, for example to match the curvature of a face (such as a building facade) on which the panel is mounted. The curvature could be in the horizontal and/or the vertical 20 direction. -15-
Claims (34)
1. A structure for collecting radiant energy, comprising a panel of material having a first major surface through which radiant energy can enter the panel, and an opposed second major surface; the second major surface being profiled and comprising at least one 5 elongated generally prismatic structure one part of which comprises a reflecting surface facing into the panel and another part of which comprises a radiant energy collector; wherein the prismatic structure is so shaped that: (i) a part of the radiant energy that enters the panel through the first major surface is reflected from the reflecting surface to impinge directly on the radiant energy collector; 10 (ii) another part of the radiant energy that enters the panel through the first major surface is reflected from the reflecting surface to impinge on the radiant energy collector following total internal reflection at the first major surface of the panel; and (iii) another part of the radiant energy which enters the panel through the first major surface impinges directly on the radiant energy collector; 15 and wherein at least part of the reflecting surface has the shape of, or a shape that substantially corresponds to, part of a parabolic reflector so arranged that all radiant energy incident on that shaped part of the reflecting surface is reflected directly to the radiant energy collector. 20
2. A structure for collecting radiant energy, comprising a panel of material having a first major surface through which radiant energy can enter the panel, and an opposed second major surface; the second major surface being profiled and comprising a plurality of elongated generally prismatic structures one part of each of which comprises a reflecting surface facing into the panel, and another part of each of which comprises a 25 radiant energy collector; wherein the prismatic structures are so shaped that: (i) a part of the radiant energy that enters the panel through the first major surface is reflected from the reflecting surfaces to impinge directly on the radiant energy collectors; -16- WO 00/77458 PCT/US00/15726 (ii) another part of the radiant energy that enters the panel through the first major surface is reflected from the reflecting surfaces to impinge on some, at least, of the radiant energy collectors following total internal reflection at the first major surface of the panel; and 5 (iii) another part of the radiant energy that enters the panel through the first major surface impinges directly on the radiant energy collectors; and wherein at least part of each reflecting surface has the shape of, or a shape that substantially corresponds to, part of a parabolic reflector so arranged that all radiant energy incident on that shaped part of the reflecting surface is reflected directly to the radiant 10 energy collector of the respective prismatic structure.
3. A structure as claimed in claim 2, in which the prismatic structures are generally identical and are arranged parallel to each other. 15
4. A structure as claimed in any one of claims 1 to 3, in which another part of the reflecting surface of the/each prismatic structure is a planar reflecting surface.
5. A structure as claimed in any one of claims 1 to 4, in which the shaped part of the reflecting surface of the/each prismatic structure comprises a plurality of mutually-inclined 20 planar reflecting surfaces forming a shape that substantially corresponds to part of a parabolic reflector.
6. A structure as claimed in claim 5, in which the reflecting surface of the/each prismatic structure forms a first face of the prismatic structure, and the associated radiant 25 energy collector is located in a second face adjoining the shaped part of the reflecting surface.
7. A structure as claimed in claim 6, in which the second face of the/each prismatic structure is located perpendicular to the first major surface of the panel. -17- WO 00/77458 PCT/US00/15726
8. A structure as claimed in any one of the preceding claims, in which each reflecting surface comprises a light-reflective material in direct contact with, or adjacent, the respective prismatic structure. 5
9. A structure for collecting radiant energy, comprising a panel of material having a first major surface through which radiant energy can enter the panel, and an opposed second major surface; the second major surface being profiled and comprising a plurality of elongated generally prismatic structures extending generally parallel to one another over 10 the panel, one part of each prismatic structure comprising a reflecting surface facing into the panel, and another part comprising a radiant energy collector; wherein the prismatic structures are so shaped that: (i) a part of the radiant energy that enters the panel through the first major surface is reflected from the reflecting surfaces to impinge directly on the radiant energy 15 collectors; (ii) another part of the radiant energy that enters the panel through the first major surface is reflected from the reflecting surfaces to impinge on some, at least, of the radiant energy collectors following total internal reflection at the first major surface of the panel; and 20 (iii) another part of the radiant energy that enters the panel through the first major surface impinges directly on the radiant energy collectors; and wherein the panel faces in a geographical direction other than that in which the sun attains its highest altitude and is positioned with the prismatic structures extending in a direction inclined to the horizontal. 25
10. A structure as claimed in claim 9, in which each reflecting surface forms a first face of the respective prismatic structure, and the associated radiant energy collector is located in an adjoining second face. -18- WO 00/77458 PCT/US00/15726
11. A structure as claimed in claim 10, in which the first and second faces are planar faces and are inclined at 900 to each other.
12. A structure as claimed in claim 10, in which the second face is located 5 perpendicular to the first major surface of the panel.
13. A structure as claimed in anyone of claims 9 to 12, in which each reflecting surface comprises a light-reflective material in direct contact with, or adjacent, the respective prismatic structure. 10
14. A structure as claimed in claim 13, in which the reflecting surface is located behind, and spaced apart from, the respective prismatic structure in the direction away from the first major surface of the panel.
15 15. A structure as claimed in claim 9 or claim 10, in which at least part of each reflecting surface has the shape of, or a shape that substantially corresponds to, part of a parabolic reflector so arranged that all radiant energy incident on that shaped part of the reflecting surface is reflected directly to the radiant energy collector of the respective prismatic structure. 20
16. A structure for collecting radiant energy, comprising a panel of material having a first major surface through which radiant energy can enter the panel, and an opposed second major surface; the second major surface being profiled and comprising at least one elongated generally prismatic structure one part of which comprises a radiant energy 25 collector; wherein the prismatic structure is so shaped that: (i) a part of the radiant energy that enters the panel through the first major surface passes directly through the panel; -19- WO 00/77458 PCT/US00/15726 (ii) another part of the radiant energy that enters the panel through the first major surface impinges on the radiant energy collector, either directly or following total internal reflection at least at the second major surface of the panel. 5
17. A structure for collecting radiant energy, comprising a panel of material having a first major surface through which radiant energy can enter the panel, and an opposed second major surface; the second major surface being profiled and comprising a plurality of elongated generally prismatic structure one part of each of which comprises a radiant energy collector; wherein the prismatic structures are so shaped that: 10 (i) a part of the radiant energy that enters the panel through the first major surface passes directly through the panel; (ii) another part of the radiant energy that enters the panel through the first major surface impinges on the radiant energy collectors either directly or following total internal reflection at the second major surface of the panel. 15
18. A structure as claimed in claim 17, in which the prismatic structures are generally identical and are arranged parallel to each other.
19. A structure as claimed in any one of claims 16 to 18, in which the panel is 20 positioned with the/each prismatic structure extending in a direction inclined to the horizontal.
20. A structure as claimed in any one of claims 16 to 19, in which the/each prismatic structure comprises a pair of mutually-inclined faces one of which includes the associated 25 radiant energy collector.
21. A structure as claimed in claim 20, in which the mutually-inclined faces are inclined at 900 to each other. -20- WO 00/77458 PCT/US00/15726
22. A structure as claimed in any one of claims 16 to 21, in which the panel is located in front of a surface whereby the surface is visible, through the panel, to an observer positioned in front of the first major surface. 5
23. A structure as claimed in claim 22, in which the surface comprises graphics visible through the panel.
24. A structure as claimed in claim 22 or claim 23, in which energy collected by the radiant energy collector(s) is used to generate electricity for illuminating the surface. 10
25. A structure as claimed in any one of claims 16 to 21, in which the panel is located on the inside surface of a window.
26. A structure as claimed in any one of claims 16 to 25, including a second panel 15 positioned adjacent the second major surface of the first-mentioned panel; wherein the surface of the second panel adjacent the second major surface of the first-mentioned panel has a profile complementary thereto.
27. A structure as claimed in any one of the preceding claims, in which the radiant 20 energy collector comprises a photovoltaic cell or a heat-collector.
28. A structure as claimed in any one of the preceding claims, in which the panel is formed from a polymeric material. 25
29. A structure as claimed in any one of the preceding claims, in which the panel comprises a moulded assembly.
30. A structure as claimed in any one of the preceding claims, in which the first major surface is planar. -21- WO 00/77458 PCT/US00/15726
31. A structure as claimed in any one of the preceding claims, in which the panel is positioned so that the first major surface is substantially vertical. 5
32. A structure as claimed in claim 1 or claim 2, substantially as described herein with reference to, and as shown in, Fig. 5 or Fig. 6 of the accompanying drawings.
33. A structure as claimed in claim 9, substantially as described herein with reference to, and as shown in, Fig. 10 in combination with Figs. 1 to 4, or any one of Figs. 5 to 9 of 10 the accompanying drawings.
34. A structure as claimed in claim 16 or claim 17, substantially as described herein with reference to, and as shown in, Fig. 7(b) or Fig. 8(a) or Fig. 8(b) or Fig. 9 of the accompanying drawings. 15 -22-
Applications Claiming Priority (3)
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GB9913466 | 1999-06-10 | ||
GBGB9913466.0A GB9913466D0 (en) | 1999-06-10 | 1999-06-10 | Panel-like structure for collecting radiant energy |
PCT/US2000/015726 WO2000077458A1 (en) | 1999-06-10 | 2000-06-08 | Panel-like structure for collecting radiant energy |
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AU5471800A true AU5471800A (en) | 2001-01-02 |
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AU54718/00A Abandoned AU5471800A (en) | 1999-06-10 | 2000-06-08 | Panel-like structure for collecting radiant energy |
Country Status (8)
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EP (1) | EP1185829A1 (en) |
JP (1) | JP2003502843A (en) |
CN (1) | CN1354828A (en) |
AU (1) | AU5471800A (en) |
BR (1) | BR0011397A (en) |
GB (1) | GB9913466D0 (en) |
MX (1) | MXPA01012586A (en) |
WO (1) | WO2000077458A1 (en) |
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US7270870B2 (en) * | 2004-06-04 | 2007-09-18 | Saint Gobain Performance Plastics Corporation | Multi-layer polymer film |
US7804021B2 (en) * | 2007-02-23 | 2010-09-28 | Lintec Corporation | Light transmissible solar cell module, process for manufacturing same, and solar cell panel thereof |
EP2286051A4 (en) * | 2008-04-02 | 2012-05-02 | Morgan Solar Inc | Solar panel window |
JP2012514323A (en) * | 2008-12-31 | 2012-06-21 | ピタゴラス ソーラー インコーポレイテッド | Solar prism concentrator |
CN102742031A (en) * | 2009-10-21 | 2012-10-17 | 毕达哥拉斯太阳公司 | Window |
DE102010007763A1 (en) * | 2010-02-12 | 2011-08-18 | Fraunhofer-Gesellschaft zur Förderung der angewandten Forschung e.V., 80686 | Photovoltaic device and its use |
CN103155176A (en) * | 2010-06-07 | 2013-06-12 | 森普留斯公司 | Photovoltaic devices with off-axis image display |
JP5649740B2 (en) | 2010-11-19 | 2015-01-07 | サン−ゴバン パフォーマンス プラスティックス コーポレイション | Bushing, composite, and method of forming a bushing |
DE102012102752A1 (en) | 2011-12-26 | 2013-06-27 | Kaustik-Solar Gmbh | Apparatus and method for photovoltaic absorption of incident light |
JP2016500448A (en) * | 2012-12-03 | 2016-01-12 | トロピグラス テクノロジーズ リミテッド | Spectral selectivity panel |
US10355156B2 (en) * | 2013-01-21 | 2019-07-16 | Holomedia, Llc | Light-concentrating mechanism, photovoltaic power generation device, window structure, and window glass |
DE102014208237A1 (en) * | 2014-04-30 | 2015-11-05 | Siemens Aktiengesellschaft | Concentrator photovoltaic module with variable display, arrangement of a plurality of such concentrator photovoltaic modules and method for operating the concentrator photovoltaic module |
JP7036587B2 (en) * | 2017-12-26 | 2022-03-15 | 矢崎エナジーシステム株式会社 | Solar energy utilization device |
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AU522513B2 (en) * | 1977-06-24 | 1982-06-10 | Unisearch Limited | Solar concentrator & radiation distributor |
US4235643A (en) | 1978-06-30 | 1980-11-25 | Exxon Research & Engineering Co. | Solar cell module |
DE2907424A1 (en) * | 1979-02-26 | 1980-08-28 | Eberhard Floegel | Light concentrator for solar panel - has internal reflectors to transmit light from large input area to small focussing panel |
US4313023A (en) | 1979-02-28 | 1982-01-26 | Exxon Research & Engineering Co. | Solar cell module |
IT1150272B (en) | 1982-03-11 | 1986-12-10 | Siv Soc Italiana Vetro | PRISM REFRACTOR SUITABLE FOR CONCENTRATING SOLAR ENERGY, ON AN APPROPRIATE COLLECTION PLAN, REMAINING IN A FIXED POSITION OVER TIME |
SU1089365A1 (en) | 1982-10-28 | 1984-04-30 | Всесоюзный Научно-Исследовательский Проектно-Конструкторский И Технологический Институт Источников Тока | Solar radiation concentrator |
JPS62266879A (en) * | 1986-05-14 | 1987-11-19 | Agency Of Ind Science & Technol | Solar energy conversion panel |
DE3718844A1 (en) * | 1987-06-05 | 1988-12-22 | Koester Helmut | Device for supplying and simultaneously acquiring solar energy |
US5646397A (en) * | 1991-10-08 | 1997-07-08 | Unisearch Limited | Optical design for photo-cell |
JPH06275859A (en) * | 1993-03-24 | 1994-09-30 | Omron Corp | Condensing device for solar cell |
US5419782A (en) | 1993-05-11 | 1995-05-30 | Texas Instruments Incorporated | Array of solar cells having an optically self-aligning, output-increasing, ambient-protecting coating |
US5882774A (en) | 1993-12-21 | 1999-03-16 | Minnesota Mining And Manufacturing Company | Optical film |
JP2568983B2 (en) * | 1994-04-12 | 1997-01-08 | 信号器材株式会社 | High-intensity pattern light-emitting display device using back-incident light method |
US5466301A (en) | 1994-06-29 | 1995-11-14 | Texas Instruments Incorporated | Solar cell having an output-increasing, protective cover |
US6080467A (en) | 1995-06-26 | 2000-06-27 | 3M Innovative Properties Company | High efficiency optical devices |
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1999
- 1999-06-10 GB GBGB9913466.0A patent/GB9913466D0/en not_active Ceased
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- 2000-06-08 CN CN00808694A patent/CN1354828A/en active Pending
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- 2000-06-08 JP JP2001503470A patent/JP2003502843A/en active Pending
- 2000-06-08 EP EP00939665A patent/EP1185829A1/en not_active Withdrawn
- 2000-06-08 MX MXPA01012586A patent/MXPA01012586A/en unknown
- 2000-06-08 WO PCT/US2000/015726 patent/WO2000077458A1/en not_active Application Discontinuation
- 2000-06-08 AU AU54718/00A patent/AU5471800A/en not_active Abandoned
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CN1354828A (en) | 2002-06-19 |
GB9913466D0 (en) | 1999-08-11 |
BR0011397A (en) | 2002-03-05 |
JP2003502843A (en) | 2003-01-21 |
WO2000077458A1 (en) | 2000-12-21 |
EP1185829A1 (en) | 2002-03-13 |
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