AU2398771A - Organolithium polymerization initiators and use thereof in polymerization processes - Google Patents

Organolithium polymerization initiators and use thereof in polymerization processes

Info

Publication number
AU2398771A
AU2398771A AU23987/71A AU2398771A AU2398771A AU 2398771 A AU2398771 A AU 2398771A AU 23987/71 A AU23987/71 A AU 23987/71A AU 2398771 A AU2398771 A AU 2398771A AU 2398771 A AU2398771 A AU 2398771A
Authority
AU
Australia
Prior art keywords
polymerization
organolithium
processes
initiators
polymerization initiators
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired
Application number
AU23987/71A
Other languages
English (en)
Inventor
C. MORRISON and CONRAD W. KAMIENSKI ROBERT
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Lithium Corp of America Inc
Original Assignee
Lithium Corp of America Inc
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Lithium Corp of America Inc filed Critical Lithium Corp of America Inc
Publication of AU2398771A publication Critical patent/AU2398771A/en
Expired legal-status Critical Current

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F297/00—Macromolecular compounds obtained by successively polymerising different monomer systems using a catalyst of the ionic or coordination type without deactivating the intermediate polymer
    • C08F297/02—Macromolecular compounds obtained by successively polymerising different monomer systems using a catalyst of the ionic or coordination type without deactivating the intermediate polymer using a catalyst of the anionic type
    • C08F297/04—Macromolecular compounds obtained by successively polymerising different monomer systems using a catalyst of the ionic or coordination type without deactivating the intermediate polymer using a catalyst of the anionic type polymerising vinyl aromatic monomers and conjugated dienes
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J29/00—Catalysts comprising molecular sieves
    • B01J29/04—Catalysts comprising molecular sieves having base-exchange properties, e.g. crystalline zeolites
    • B01J29/06—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof
    • B01J29/064—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof containing iron group metals, noble metals or copper
    • B01J29/068—Noble metals
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07F—ACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
    • C07F1/00—Compounds containing elements of Groups 1 or 11 of the Periodic Table
    • C07F1/02—Lithium compounds
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F12/00—Homopolymers and copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by an aromatic carbocyclic ring
    • C08F12/02—Monomers containing only one unsaturated aliphatic radical
    • C08F12/04—Monomers containing only one unsaturated aliphatic radical containing one ring
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F2/00—Processes of polymerisation
    • C08F2/36—Polymerisation in solid state
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F36/00—Homopolymers and copolymers of compounds having one or more unsaturated aliphatic radicals, at least one having two or more carbon-to-carbon double bonds
    • C08F36/02—Homopolymers and copolymers of compounds having one or more unsaturated aliphatic radicals, at least one having two or more carbon-to-carbon double bonds the radical having only two carbon-to-carbon double bonds
    • C08F36/04—Homopolymers and copolymers of compounds having one or more unsaturated aliphatic radicals, at least one having two or more carbon-to-carbon double bonds the radical having only two carbon-to-carbon double bonds conjugated
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
    • Y10S—TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10S585/00—Chemistry of hydrocarbon compounds
    • Y10S585/8995—Catalyst and recycle considerations
    • Y10S585/906—Catalyst preservation or manufacture, e.g. activation before use

Landscapes

  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Health & Medical Sciences (AREA)
  • Polymers & Plastics (AREA)
  • Medicinal Chemistry (AREA)
  • Materials Engineering (AREA)
  • Engineering & Computer Science (AREA)
  • Crystallography & Structural Chemistry (AREA)
  • Inorganic Chemistry (AREA)
  • Polymerization Catalysts (AREA)
  • Addition Polymer Or Copolymer, Post-Treatments, Or Chemical Modifications (AREA)
  • Graft Or Block Polymers (AREA)
AU23987/71A 1970-01-19 1971-01-04 Organolithium polymerization initiators and use thereof in polymerization processes Expired AU2398771A (en)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
US412670A 1970-01-19 1970-01-19
USUS4126 1970-01-19

Publications (1)

Publication Number Publication Date
AU2398771A true AU2398771A (en) 1972-07-06

Family

ID=21709291

Family Applications (1)

Application Number Title Priority Date Filing Date
AU23987/71A Expired AU2398771A (en) 1970-01-19 1971-01-04 Organolithium polymerization initiators and use thereof in polymerization processes

Country Status (9)

Country Link
US (1) US3668263A (https=)
AU (1) AU2398771A (https=)
BE (1) BE761691A (https=)
CA (1) CA987332A (https=)
DE (1) DE2063642A1 (https=)
FR (1) FR2075655A5 (https=)
GB (1) GB1297331A (https=)
NL (1) NL7100697A (https=)
ZA (1) ZA708708B (https=)

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US3862251A (en) * 1970-02-11 1975-01-21 Us Navy Organo-dilithium initiator for anionic polymerization, a novel polyisoprene, and processes for production thereof
US3954894A (en) * 1973-05-18 1976-05-04 Lithium Corporation Of America Organotrilithium polymerization initiators
US3931107A (en) * 1973-06-21 1976-01-06 Phillips Petroleum Company Polyalkoxy monovinylaromatic compound in copolymerization of a conjugated diene with a monovinyl-substituted aromatic compound
FR2313389A1 (fr) * 1975-06-06 1976-12-31 Anvar Nouveaux amorceurs de polymerisation organolithiens bi-fonctionnels et leurs applications, en particulier pour l'obtention d'elastomeres thermoplastiques
US4205016A (en) * 1975-08-01 1980-05-27 The Dow Chemical Company Multifunctional lithium containing initiator
CA1098913A (en) * 1975-08-01 1981-04-07 Lu H. Tung Multifunctional lithium containing initiator
GB1555729A (en) * 1976-06-17 1979-11-14 Charbonnages Ste Chimique Bifunctional and trifunctional organo-lithium initiators and their use
US4311818A (en) * 1976-06-17 1982-01-19 Societe Chimique Des Charbonnages-Cdf. Chimie Bi- and Trifunctional organolithium initiators and applications thereof
US4179480A (en) * 1976-11-05 1979-12-18 Phillips Petroleum Company Blends of cyclodiene-containing copolymers and block copolymers having improved high temperature green tensile strength
US4138536A (en) * 1976-12-20 1979-02-06 Phillips Petroleum Company Polymerization of 1,3-cyclodiene with vinylaromatic hydrocarbon
US4311803A (en) * 1979-05-01 1982-01-19 Phillips Petroleum Company Continuous solution polymerization process
US4297451A (en) * 1979-07-10 1981-10-27 Phillips Petroleum Company Dienyllithium initiated polymers
DE2938658A1 (de) * 1979-09-25 1981-04-09 Basf Ag, 6700 Ludwigshafen Loesungen bifunktioneller organolithiumverbindungen in nichtpolaren organischen kohlenwasserstoffen als loesungsmittel, verfahren zur herstellung solcher loesungen und deren verwendung
IT1195303B (it) * 1981-12-22 1988-10-12 Anic Spa Iniziatori anionici multifunzionali e loro impiego
JPS58154703A (ja) * 1982-03-09 1983-09-14 Daicel Chem Ind Ltd 光学活性な高分子の合成方法
DE3309748A1 (de) * 1982-07-23 1984-03-01 Veb Chemische Werke Buna, Ddr 4212 Schkopau Verfahren zur herstellung mehrfunktioneller polymerisationsinitiatoren
US4713424A (en) * 1984-11-05 1987-12-15 Phillips Petroleum Company Polymerization of olefinic hydrocarbons and complex-initiator therefor
US5149895A (en) * 1990-01-16 1992-09-22 Mobil Oil Corporation Vulcanizable liquid compositions
US5633415A (en) * 1990-01-16 1997-05-27 Mobil Oil Corporation Dispersants and dispersant viscosity index improvers from selectively hydrogenated polymers
US5210359A (en) * 1990-01-16 1993-05-11 Mobil Oil Corporation Vulcanizable liquid compositions
US5637783A (en) * 1990-01-16 1997-06-10 Mobil Oil Corporation Dispersants and dispersant viscosity index improvers from selectively hydrogenated polymers
US5780540A (en) * 1990-01-16 1998-07-14 Mobil Oil Corporation Dispersants and dispersant viscosity index improvers from selectively hydrogenated polymers
US5080835A (en) * 1990-09-21 1992-01-14 Bridgestone/Firestone, Inc. Polymetalated 1-alkyne compositions
US5147951A (en) * 1990-09-21 1992-09-15 Bridgestone/Firestone, Inc. Method for preparing ultra high molecular weight copolymers of conjugated dienes and aromatic vinyl compounds
US5272203A (en) * 1990-09-21 1993-12-21 Bridgestone/Firestone, Inc. High performance tire treads and tires
US5260370A (en) * 1990-09-21 1993-11-09 Bridgestone Corporation Oil extended ultra high molecular weight elastomers
EP0690075B1 (en) 1994-06-27 1999-05-06 Shell Internationale Researchmaatschappij B.V. Process for the preparation of block copolymers using difunctional anionic polymerisation initiators
TW322493B (https=) * 1994-06-27 1997-12-11 Shell Int Research
US5464914A (en) * 1994-06-29 1995-11-07 The Dow Chemical Company Preparation of a low polydisperse polymer
DE19516563A1 (de) * 1995-05-05 1996-11-07 Basf Ag Verfahren zur Herstellung von Styrol-Oligomeren und deren Verwendung als Schmiermittel in Thermoplasten
US6306962B1 (en) 1999-09-30 2001-10-23 The Dow Chemical Company Flow carbonate polymer blends
US6380304B1 (en) 1999-09-30 2002-04-30 The Dow Chemical Company Mass polymerized rubber-modified monovinylidene aromatic copolymer compositions
US6380303B1 (en) 2000-02-24 2002-04-30 The Dow Chemical Company Flow carbonate polymer blends
US20010046938A1 (en) * 2000-03-04 2001-11-29 Halasa Adel Farhan Synthesis of dilithium initiator
CN101045756B (zh) * 2006-03-30 2011-01-12 北京化工大学 一种阴离子聚合用多官能团有机碱金属引发剂的制备方法
MX2009013127A (es) * 2007-06-07 2010-01-15 Albemarle Corp Polimeros bromados de bajo peso molecular y su uso en formulaciones termoplasticas.
US8993684B2 (en) 2008-06-06 2015-03-31 Albemarle Corporation Low molecular weight brominated polymers, processes for their manufacture and their use in thermoplastic formulations
BRPI0915818A2 (pt) * 2008-07-09 2015-08-04 Basf Se Mistura pesticida, composição pesticida, método para controlar fungos nocivos fitopatogênicos, para proteger plantas de fungos nocivos fitopatogênicos, para controlar insetos, aracnídeos ou nematódeos, para proteger plantas do ataque ou infestação por insetos, acarídeos ou nematódeos, e para a proteção de semente, semente, e, uso de uma mistura.
JO3423B1 (ar) * 2008-12-02 2019-10-20 Albemarle Corp مؤخرات لهب معالجة بالبروم و مواد مشتقه منها
KR20110100216A (ko) * 2008-12-02 2011-09-09 알베마를 코포레이션 분지형 또는 별모양 분지형 스티렌 폴리머, 텔로머, 및 부가물, 그의 합성, 그의 브롬화, 및 그의 용도
CN102224122B (zh) * 2008-12-02 2014-09-03 雅宝公司 甲苯和苯乙烯衍生的调聚物分布物及由其制备的溴化阻燃剂
US8642821B2 (en) * 2008-12-02 2014-02-04 Albemarle Corporation Bromination of telomer mixtures derived from toluene and styrene
US8753554B2 (en) 2009-05-01 2014-06-17 Albemarle Corporation Pelletized low molecular weight brominated aromatic polymer compositions
JO3059B1 (ar) 2009-05-01 2017-03-15 Albemarle Corp معالجة بالبروم لتراكيب بوليمرات عطرية ذات وزن جزيئي منخفض
BRPI1015023A2 (pt) 2009-06-30 2019-07-09 Bridgestone Corp iniciadores e processos para polimerização aniônica.
JP6388577B2 (ja) * 2012-06-26 2018-09-12 イネオス・スタイロリューション・ヨーロッパ・ゲゼルシャフト・ミット・ベシュレンクテル・ハフツング ビニル芳香族のポリマー並びにビニル芳香族−ジエンブロックコポリマーの製造方法

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US3308170A (en) * 1963-08-28 1967-03-07 Nat Distillers Chem Corp Substantially linear polydiene alcohols having majority of hydroxy groups terminal by preparing polydiene in hydrocarbon and then using ether medium during epoxide addition
US3402159A (en) * 1963-12-20 1968-09-17 Phillips Petroleum Co Process for polymerizing butadiene and styrene terminated in short blocks of polystyrene
US3301840A (en) * 1964-09-17 1967-01-31 Phillips Petroleum Co Preparation of polymers of conjugated dienes using organolithium/polar compound catalyst systems
US3492369A (en) * 1965-05-24 1970-01-27 Phillips Petroleum Co Graft polymerizing by first lithiating in the presence of polar compounds
US3452111A (en) * 1966-12-09 1969-06-24 Lithium Corp Stabilization of secondary alkyllithiums

Also Published As

Publication number Publication date
CA987332A (en) 1976-04-13
ZA708708B (en) 1971-10-27
US3668263A (en) 1972-06-06
FR2075655A5 (https=) 1971-10-08
DE2063642A1 (de) 1971-07-29
GB1297331A (https=) 1972-11-22
BE761691A (fr) 1971-07-01
NL7100697A (https=) 1971-07-21

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