AU2135699A - Pesticidal composition - Google Patents
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- AU2135699A AU2135699A AU21356/99A AU2135699A AU2135699A AU 2135699 A AU2135699 A AU 2135699A AU 21356/99 A AU21356/99 A AU 21356/99A AU 2135699 A AU2135699 A AU 2135699A AU 2135699 A AU2135699 A AU 2135699A
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- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
- A01N53/00—Biocides, pest repellants or attractants, or plant growth regulators containing cyclopropane carboxylic acids or derivatives thereof
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Description
_1~1 I _1111~ S F Ref: 457021
AUSTRALIA
PATENTS ACT 1990 COMPLETE SPECIFICATION FOR A STANDARD PATENT
ORIGINAL
9 Name and Address of Applicant: Actual Inventor(s): Address for Service: Sumltomo Chemical Company, Limited 5-33, Kitahama 4-Chome Chuo-ku Osaka 541-8550
JAPAN
Izumi Fujimoto Spruson Ferguson, Patent Attorneys Level 33 St Martins Tower, 31 Market Street Sydney, New South Wales, 2000, Australia Pesticidal Composition Invention Title: The following statement is a best method of performing it full description of this invention, including the known to me/us:- IP Australia Documents received on: C) 0.
2 3 MAR 1999 Batch No: 5845 I Pesticidal Composition Field of the Invention The present invention relates to a pesticidal composition which comprises prallethrin and a neonicotinoid compound as active ingredients.
Background of the Arts Prallethrin is a known insecticidal compound and described in The Pesticide Manual 10 th edition, page 827 (British Crop Protection Council 1994). Its chemical name is (S)-2-methyl-4-oxo-3-prop-2-ynylcyclopent-2-enyl (1R)-cis,trans-2,2dimethyl-3-(2-methylprop-l-enyl)cyclopropanecarboxylate. Neonicotinoid compounds include amidine compounds and guanidine compounds having a nitro, cyano or trifluoroacetyl group, and described in, for example, USP-5532365, USP-4742060, USP-4849432, USP-5034404, USP-5750548, USP-5304566, EP-428941A and so on.
Summary of the Invention The present invention provides a pesticidal composition that is effective for controlling harmful pests, especially arthropods.
The present composition comprises prallethrin and the neonicotinoid compound described below as active ingredients and clearly shows a synergistic effect. The neonicotinoid compounds utilized in the present invention are represented in the following formulas or A- (CH 2 N1R X-y
A-H
2 C-N Yz x-Y (2)
K>)
A-H
2 C-N YN-R 3 4-Y (3) wherein, A represents a 6-chloro-3-pyridyl, 2-chloro-5-thiazolyl, tetrahydrofuran-2-y, tetrahydrofuran-3-yl, 5-methyltetrahydrofuran-3-yl, 3-pyridyl, 6-bromo-3-pyridyl, 3cyanophenyl, 2-methyl-5-thiazolyl, 2-phenyl-5-thiazolyl or 2-bromo-5-thiazolyl group; 6R, represents a hydrogen atom, methyl, ethyl, formyl or acetyl group; 2 represents a methyl, amino, methylamino, N,N-dimnethylamino, ethylamino, N,Ndiethylamino, N-methyl-N-ethylamino, 1-pyrrolidinyl, (6-chloro-3-pyridyl)methylamino or N-methyl-N-(6-chloro-3-pyridyl)methylamino group;
R
3 represents a methyl, ethyl, propyl, propenyl or propynyl group; X represents a nitrogen atom or CH group; Y represents a cyano, nitro or trifluoroacetyl group; Z represents a NH group or sulfur atom; D represents an oxygen atom or -N(CH 3 group; :represents 0or 1; and n represents 2 or 3.
Detailed Description of the Invention The examples of the neonicotinoid compounds of the formula in the present composition include [(6-chloro-3-pyridyl)methyl]-N 2 -cyano-N 1 methylacetamidine, N- [(6-chloro-3-pyridyl)methyl] ethyl- N'-methyl-2-nitro- 1, 1 ethylidenediamine, 1 6 -chloro- 3 -pyridyl)methyl-3-methyl-2-cyanoguanidine, 1 chloro-3-pyridyl)methyl-1 ,3-dimethyl-2-cyanoguanidine, 1-(6-chloro-3-pyridyl)methyll-ethyl-3-methyl-2-cyanoguanidine, 1 -(6-chloro-3-pyridyl)methyl-1 ,3-dimnethyl-3-(6chloro- 3 -pyridyl)methyl-2-cyanoguanidine, 1 6 -chloro-3-pyridyl)methyl-3-methyl-2nitroguanidine, 1 6 -chloro-3-pyridyl)methyl-3,3-dimethyl-2-nitroguanidine, 1 chloro-3-pyridyl)methyl-1 -methyl-2-nitroguanidine, 1-(6-chloro-3-pyridyl)methyl-1,3dimnethyl-2-nitroguanidine, 1 6 -chloro- 3 -pyridyl)methyl-3-ethyl-2-nitroguanidine, 1- 6 -chloro- 3 -pyridyl)methyl-3-(6-chdoro-3-pyridyl)methyl2-ntroguanidine, 1-(6chloro- 3 -pyridy)methyl-3-methyl-2-trifluoroacetylguanidine, 1 -(6-chloro-3to, pyridyl)methyl-1-ethyl-3-methyl-2-nitroguanidine, 1-(6-chloro-3-pyridyl)methyl-1 ,3,3trimethyl-2-nitroguanidine, l-( 6 -chloro-3-pyridyl)methyl-2-nitroguaiidine, 1-(6chloro-3-pyridyl)methyl-1-ethyl-2-nitroguanidine, 1 -(3-pyridyl)methyl-3-methyl-2nitroguanidine, l-( 6 -bromo- 3 -pyridy1)methyl-3-methylb2-nitroguanidine, 1-(2-chloro- -thiazolyl)methyl-3-methyl-2-nitroguanidine, 1 -(3-cyanophenyl)-3-methyl-2nitroguanidine, l-( 4 -chlorophenyl)methyl-3-methyl-2-nitroguanidine, 1-(6-chloro-3pyridyl)methyl-3,3-dimnethyl-1-formyl-2-nitroguanidine, l-(6-chloro-3-pyridyl)methyl- 3,3-dimethyl-l1-acetyl-2-nitroguanidine, 1 -(6-chloro-3-pyridyl)-3-methyl-2cyanoguanidine, 1 2 -cffioro- 5 -thiazolyl)methyl-3,3-dimnethyl2-ntroguapjdine, 1-(2chloro-5-thiazolyl)methyl-1 -ethyl-3-methyl-2-nitroguanidine, 1-(2-chloro-5- 4o thiazolyl)methyl- l-aeetyl-3,3-dimethyl-2-nitroguanidine, 1-(6-chloro-3-pyridyl)methyll-methyl-2-trifluoroacetylguanidine, 1 -(2-chloro-5-thiazolyl)methyl-1,3-dimethyl-2nitroguanidine, l-(2-chloro-5-thiazolyl)methyl- 1-methyl-2-nitroguanidine, thiazolyl)methyl-3-methyl-2-nitroguanidine, 1-(2-methyl-5-thiazolyl)methyl-3,3dimethyl-2-nitroguanidine, 1 2 -methyl-5-thiazolyl)methyl-3-methyl-2-nitroguanidine, l-( 2 -phenyl- 5 -thiazolyl)methyl-3-methyl-2-nitroguanidine, 1-(2-ehloro-5thiazolyl)methyb3,3..diethyl2nitroguanidine, l-( 2 -chloro-5-thiazolyl)methyl-3methyl-3-ethyl-2-nitroguanidine, l-( 2 -cfioro-5-tfiazolyl)methyl3.(l.pyrrolidinyl)2.
nitroguanidine, 1 -(2-chloro-5-thiazolyl)methyl-1 3 3 -trimethyl-2-nitroguanidine, 1 bromo-5-thiazolyl)methyl-3-methyl-2-nitroguanidine, S' 3 ,3-dimethyl-2-nitroguanidine, l-( 2 -chloro-5-thiazolyl)methyl-3-methyl-2cyanoguanidine, l-(tetrahydrofilran-3-yl)methyl-3-methyl.2-nitroguaidine and 1- (tetrahydrothran-2-yl)methyl-3-methyv2-nitroguaidine.
The examples of the neonicotinoid compounds of the formula in the present composition include 6 -chloro- 3 -pyridyl)methyl]-N-nitro-2inidazoidineimine, 3- 0~ 6 -chloro- 3 -pyridyl)methyl]-N-cyano.2-thiazolidineimine and l-[(6-ehloro-3- :pyridyl)methyl]-N-nitrotetrahydropyrimidine2-ipne.
The examples of the neonicotinoid compounds of the formula in the present composition include 3 2 -chloro- 5 -thiazolyl)methyl]-5-methyl-4-nitroiminotetrahydro.
OV, 1 ,3,5-oxadiazine, 3,5-dimethyl-1- [(6-chloro-3-pyridyl)methyl]-2- *0 nitroiminohexahydro-1,3,5-triazine, 3,5-dimethyl-1- [(2-chloro-5-thiazolyl)methyl]-2nitroiminohexahydro-1,3,5-triazine, 3 -ethyl-5-methyl-1-[(6-chloro-3-pyridyl)methyl].
2-iri io e ay r -,,-raie l5 m -ho o3 prdlty] 2 -nitroiminohexahydro-1,3,5-triazine, 3-n-propyl-5-methyl-1-[6clr chloro-S-thiazolyl)methyl]-2-nitroiniinohexahydro.4 ,3,5-triazine, 3-(2-propenyl)-5- YX methyl-l-[( 6 -chloro-3-pyridyl)methyl]p2-ntroiminohexahydro-.1 ,3,5-triazine and 3-(2- 6 -chloro-3-pyridyl)methyl j-2-nitroiminohexahydro-1,3,5triazine.
The targeted pests controlled by the present composition are, for example, the following arthropods: _i pillbugs and Isopoda (sowbugs) such as Oniscus asellus, Armadillidium vulgare (Latreille pilibug) and Porcellic scarber; Diplopoda such as Blanilus guttulatus (millepede); Chilopoda such as Geophilus carpophagus, Scutigera spp., Scolopendra subspini and Thereunema spp.; Symphyla such as Scutigerella immaculata; Thysanura (bristletails) such as Ctenolepisma villosa (oriental silverfish) and Lepisma saceharina (silverfish); Psocoptera such as Trogium pulsatorium (larger pale booklice); Collembola (snowfleas) such as Onichiurus armatus; Isoptera (termites) such as Mastotermitidae, Termopsidae Zootermopsis, Archotermopsis, Hodotermopsis, Porotemes), Kalotermitidae Kalotermes, Neotermes, Cryptotermes, Incisitermes, 1 Glyptotermes), Hodotermitidae Hodotermes, Microhodotermes, :Anacanthotermes), Rhinotermitidac Reticulitermes, Heterotermes, Coptotermes, Schedolinotermes), Serritermitidae and Termitidae Amitermes, Drepanotermes, .i Hopitalitermes, Trinervitermes, Macrotermes, Odontotermes, Microtermes, Nasutitermes, Pericapritermes, Anoplotermes); Dictyoptera (cockroaches) such as I ~Blatta orientalis (oriental cockroach), Periplaneta americana (American cockroach), a a* Periplaneta fuliginosa (smokybrown cockroach), Leucophaea maderae and Blattella germanica (German cockroach); Orthoptera such as Gryllotapa spp. (mole cricket), Acheta domesticus, Teleogryllus emma (field cricket), Locusta migratoria (asiatic locust oriental migratory locust), Melanoplus differentialis and Schistocera gregaria; go Dermaptera (earwigs) such as Labidura riparia and Forficula auricularia; Anoplura such as Phthiruspubis, Pediculus humanus, Haematopinus sulus, Linognathus spp. and Solenopotes spp.; Mailophaga such as Trichodectes spp., Tromenopon spp., Bovicola spp. and Felicola spp.; Thysanoptera (thrips) such as Frankiniella intonsa (flower thrips), onion thrips, Thrips tabaci (cotton seedling thrips) and Thripspalmi; Heteroptera such as Nezara spp., Eurygaster spp., Dysdercus intermedius, Cimex lectularis, Triatoma spp., Rhodnius prolixus, Nezara antennata (green stink bug) and Cletus puncttiger; Homoptera such as Aleurocanthus spiniferus (citrus spiny whitefly), Bemisia tabaci (sweetpotato whitefly), Trialeurodes vaporariorum (greenhouse whit efly), cotton asphid, Aphis gossypii (melon aphid), Brtevicoryne brassicae (cabbage asphid), Cryptomyzus ribis, Aphis fabae, Macrosiphum euphorbiae (potato aphid), Myzus persicae (green peach aphid), Phorodon humuli, Empoasca spp., Nephootettix cincticeps (green rice lealhopper), Lecanium corni (brown scale), Saissetia oleae (black scale), Laodelphax striatellus (small brown plant hopper), Nilaparvata lugens (brown rice planthopper), Aonidiella aurantii (red scale), Aspidiotus hederae (ivy scale), ro Pseudococcus spp., Psylla spp. and Phylloxera vastrix; Lepidoptera such as Pectinophora gossypiella (pink bollworm), Lithocolletis blancardella, Plutella xyloste (diamondback moth), Malacosoma neustria (tent catapillar), Euproctis subflava (oriental tussock moth), Lymantria dispar (gypsy moth), Bucculatrix pyrivorella (pear leafminer), Phyllocnistis citrella (citrus leafmniner), Agrotis spp., Euxca spp., Earias fS insulana, Heliothis spp., Spodoptera exigua (beet armyworm), Spodoptera litura (common cutworm), Spodoptera spp., Mamestra brassicae (cabbage armyworm), Trichoplusia ni, Carpocapsa pomonella, Pieris spp., Chilo spp., Pyrausta nubilalis, Ephestia kuehniella (Mediterranean flour moth), Galleria mellonella (greater wax moth), Tineola bisselliella (webbing clothes moth), Tenea translucens, oriental tea olo tortrix (Homona magnanima) and Totrix viridana; Coleoptera (beetles) such as Anobium punctatum, Rhizopertha dominica (lesser grain borer), Acanthoscelides obectus (bean weevil), Agelastica alni, Leptinotarsa decemlineata, Phaedon cochleariae, Diabrotica spp., Psylliodes angusticollis (solanum flea beetle), Phyllotreta striolata (striped flea beetle), Epilachna spp., Atomaria spp., Oryzaephilus surinamensis (sawtoothed grain beetle), Anthonomus spp., sitophilus spp., Otriorhynchus sulcatus (black vine weevil), Cosmopolites sordidus (banana weevil borer), Ceuthorhyncidius albosuturalis, Hypera postica (alfalfa weevil), Dermestes spp., Trogoderma spp., Atta genus unicolor (black carpet beetle), Lyctus spp., Meligethes aeneus, Ptinus spp., Gibbium psylloides, Tribolium spp., Tenebrio molitor S (yellow mealworm), Agriotes spp., Melolontha mololontha, Scolytidae Xyleborus and Scolytoplatypus), Cerambycidae Monochamus, Hylotrupes, Hesperophanus, Chiorophorus, Palaeocallidium, Semanotus, Purpuricenus, Stromatium), Platypodidae Crossotarsus, Platypus), Bostrychidae Dinoderus, Bostrychus, Sinoderus), Anobiidae Ernobius, Anobium, Xyletinus, Xestobium, Ptilinus, Nicobium, o Ptilineurus) and Buprestidae; Hymenoptera such as Diprion spp., Hoplocampa spp., Lasius spp., Formica japonica, Vespa spp., and Siricidae Urocerus, Sirex); Diptera such as Aedes spp., Anopheles spp., Culex spp., Drosophila melanogaster, Musca domestica (housefly), Fannia spp., Calliphora spp., Lucilia spp., Chrysomya spp., Cuterebra spp., Gastrophilus spp., Stomoxys spp., Oestrus spp., Hypoderma spp., Tabanus spp., Bibio hortulan us, Pegomyia hyoscyami, Ceratitus capitata, Dacus dorsalis (oriental fruit fly), Tipula paludosa, Simulium spp., Eusimulium spp., Phiebotomus spp., Culicoides spp., Chrysops spp., Haematopota spp., Braula spp., Morellia spp., Glossina spp., Wohlfahrtia spp., Sarcophaga spp., Lipoptena spp., Melophagus spp. and Muscina spp.; Siphonaptera such as Xenopsylla cheopis, Ceratophyllus spp., Pulex spp. (human flea) and Ctenocephalides spp. (cat flea dog flea); Arachnida such as Scorpio maurus, Latrodectus mactans and Chiracanthium spp.; mites such as Otodectus spp., Acarus siro (grain mite), Argas spp., Ornithodoros spp., Ornithonyssus spp., Dermanyssus spp., Eriophyes spp., Chelacaropsis moorei, Dermatophagoides spp., Psoroptes equi, Chorioptes spp., Saracoptes spp., Tarsonemus 9 spp., clover mite (Bryobia praetiosa), Panonychus spp., Tetranychus spp. (spider mites), Raillietas spp., Pneumonyssus spp., Sternostorma spp., Acarapis spp., Cheyletiella spp., Myobia spp., Psorergates spp., Demodex spp., Trombicula spp., Listrophorus spp., Tyrophagus spp., Sarcoptes spp., Notoedres spp., Cytodides spp., Laminosioptes spp.; and the like.
S For the present invention, the mixing ratio of prallethrin and the neonicotinoid compounds is the ratio wherein prallethrin and the neonicotinoid compounds show a synergistic effect, and usually from 100:1 to 1:100 parts by weight, preferable within the range from 10:1 to 1:10.
The present composition may be prepared only from prallethrin and the o1 neonictinoid compounds, but for practical uses, the present composition is utilized "4 usually as a formulation that appropriately contains an inert carrier. Therefore, the present composition usually comprises solid carriers, liquid carriers, auxiliaries or the like as well as prallethrin and the neonictinoid compounds. Suitable forms of formulation include liquid formulations such as emulsifiable concentrates, oil t formulation and suspensible concentrates, dust, wettable powder, granules, paste formulation, microencapsulated formulation, foaming formulation, aerosol, liquid carbon dioxide solution and sheet formulation. The amount of prallethrin and neonicotinoid compounds incorporated depends on the formulation form, but the total S content of prallethrin and neonicotinoid compounds is usually from 0.005 to 50% by .o weight.
The above-mentioned formulations may be obtained by standard methods, for example, mixing prallethrin and neonicotinoid compounds with solid or liquid carrier(s), and optionally, adding auxiliaries such as emulsifiers or adhesives. As the carrier that is used in the situation of formulating, the following are suitable.
Suitable solid carriers include, for example, natural-occurring or synthetic minerals such as clay, kaolin, talc, bentonite, sericite, quartz, sulfur, active carbon, calcium carbonate, diatomaceous earth, pumice, calcite, sepiolite, dolomite, silica, alumina, vermiculite and perlite, as well as powdered forms of sawdust, an ear of corn, palm tree coconut shells and tobacco stems. Suitable liquid carriers include, for example, aromatic or aliphatic hydrocarbons such as xylene, toluene, alkylnaphthalene, phenylxylylethane, kerosene, gas oil, hexane and cyclohexane; halogenated hydrocarbons such as chlorobenzene, dichloromethane, dichloroethane and trichloroethane; alcohols such as methanol, ethanol, isopropyl alcohol, butanol and to hexanol; ethers such as diethyl ether, tetrahydrofuran and dioxane; esters such as ethyl acetate and butyl acetate; ketones such as acetone, methyl ethyl ketone, methyl isobutyl ketone and cyclohexanone; nitriles such as acetonitrile and isobutyronitrile; dimethylsulfoxide; amides such as N,N-dimethylformamide and N,Ndimethylacetamide; botanical oils such as soybean oil and cottonseed oil; water; and so on.
9 9 9 9. 9 Suitable auxiliaries for formulation include, for example, nonionic emulsifiers such as polyoxyethylene fatty acid esters and polyoxyethylene fatty acid alcohol ethers; ionic emulsifiers such as alkylsulfonic acid salts, alkylsulfuric acid salts and arylsulfonic acid salts; dispersing agents such as ligninsulfonic acid salts and methylcellulose; Ao adhesives such as carboxymethyl cellulose, gum arabic, polyvinyl alcohol and polyvinyl acetate; and coloring agents such as iron oxide, titanium oxide, Persian blue, alizarine dye, azo dye and phthalocyanine dye.
Moreover, the present composition may comprise active ingredients other than prallethrin and the neonicotinoid, or synergists such as piperonyl butoxide (PBO), Z octachlorodipropyl ether (S421), N-(2-ethylhexyl)bicyclo[2.2.1]hept-5-ene-2,3-
I
dicarboximide, isobornyl thiocyanatoacetate (IBTA) and N-(2-ethylhexyl)-l-isopropyl- 4-methylbicyclo[2.2.2]oct-5-ene-2,3-dicarboximide.
The present composition may be employed usually on the soil or in places wherein harmful arthropods inhabit, but may cooperate in the production of products S that controls pests by administering into a synthetic resin sheet or sheathed electric lines.
The employed amount is about from 0.001 to 10 mg/m 3 of the active ingredients (the total of prallethrin and the neonicotinoid compounds) when the present composition is utilized in a situation of household use, and for example, in the situation of controlling mosquitoes and flies indoors. Furthermore, when controlling ants or cockroaches, the active ingredients are employed at about from 0.001 to 100mg/m 3 In the case of controlling timber pests such as termites and powderpost beetles, the present invention may be employed directly onto the said pest, but said composition is usually employed on the inhabiting timber or soil of the pest. The employed amount differs upon the sort of objective harmful arthropods, formulation, employed area or rI employed method, but generally the amount of the active ingredients (prallethrin and neonicotinoid compounds) is about form 0.1 to 10,000mg/m 2
S
In addition, in the case the present composition is utilized for agricultural purposes, an amount from 0.1 to 1,000 g/ha of the active ingredients is employed onto the soil, plants, or directly onto the harmful arthropods. In that situation, the present .r0 composition is employed as emulsifiable concentrates, suspensible concentrates or wettable powders by dissolving in water usually at about from 1 to 1000ppm.
Examples Below, the present invention is described in detail with the examples.
Formulation example 1 One part by weight of Tokuseal GU-N (Tokuyama Corp. product) and 5 parts by weight of (E)-N'-[(6-chloro-3-pyridyl)methyl]acetamidine were mixed and pulverized in an centrifugal pulverizer (the powder). Separately, 1 part by weight of prallethrin was dissolved in 9 parts by weight of Solvesso 150 (Exxon product) and absorbed into 7 parts by weight of Tokuseal GU-N (the oil absorption). After mixing the oil absorption and the powder, 4 parts by weight of Sorpol 5060 (Toho Chemical product), 2 parts by weight of Demol SNB (Kao Corp. product) and 71 parts by weight of Fubasami Clay A300 (Fubasami Clay product) were added, and mixed in a mixer to obtain 100 pasts by o weight of wettable powder.
Next, the test examples are given.
a Test example 1 One half (0.5)itL of the following acetone dissolving solution wherein the concentration was adjusted to set forth a dosage given below, was applied to the back S" 4 thoracic region of a housefly (Musca domestica) which is resistant to pyrethroid and the mortality was examined 2 days later. The average of the results after repeating the example thrice are given in table 1 and table 2.
Table 1 examined compound(s) dosage gper insect) mortality Prallethrin 1.25 6.7 Compound A 1 1.25 Prallethrin Compound A 5+ 5 1 2.5 5 5+10 100 1.25 5 10 1.25 °I 66 °6 6* 6 6 6* e 6* 0* 6 6 66 "Compound (E)-N'-[(6-chloro-3-pyridyl)methyl]-N 2 -cyano-N'methylacetamidine Table 2 examined compound(s) dosage gper insect) mortality Prallethrin 1.25 6.7 Compound B 2 0.625 1.25 Prallethrin Compound B 0.625 0.625 2 1.25 1.25 0.0.625 1.25 0.3125 1.25 0.625 2.5 0.3125 2.5 1.25 0.625 2.5 1.25 100 2.5 0.625 100 "Compound 1-(tetrahydrofuran-3-yl)methyl-3-methyl-2-nitroguanidine Test example 2 Three cm of soil was packed into the central inner portion of a glass tube that has an inner diameter of 1.7cm and is 15cm long, and on one surface of the soil, 0.7mL of each aqueous solution that has the examined compound formulated to a determined 1 0 dilution (examined compound and applied concentration given in table 3).
Subsequently, 4% agar was inserted onto both surfaces of the soil, 50 worker Formosan subterranean termites (Coptotermes formosanus) and 5 soldier Formosan subterranean termites were deposited into side of the inner part of the tube wherein no compound was applied, and the tunneled soil condition by the termites was examined a week later. The t1 example was repeated thrice. The results are given in table 3.
Within the results of table 3, A represents a condition wherein the termites tunneled through the surface of the soil of the treated side and the non-treated side, B represents a condition wherein the surface of the soil of the treated side was tunneled through and the agar was tunneled halfway, C represents a condition wherein the surface S of the soil of the treated side was incompletely tunneled through and the agar had no visible tunneling.
Table 3 *00* 0 0 0 examined compound(s) concentration of results application (ppm) composition C 3 Prallethrin 5EC5 1 0 0 2 0 CCC Compound B 2 Prallethrin 5EC 5 2 0 5 0 CCC Compound D 4 Prallethrin 5EC 2 0 5 0 CCC Composition C' 3 1 2 5 AAA Compound B' 2 2 0 ACA Compound D 4 2 0 AAA Prallethrin 5EC 2 0 AAA 6 2. 5 AAA *2 "Compound B" 1-(tetrahydrofuran-3-yl)methyl-3-methyl-2-nitroguanidine *3 "Composition C" 20% flowable of 1-[(6-chloro-3-pyridyl)methyl]-N-nitro-2to imidazolidineimine (Nihon Bayer Agrochem product Hachikusan FL) *4 Compound 3-[(2-chloro-5-thiazolyl)methyl]-5-methyl-4nitroiminotetrahydro-1, 3, "Prallethrin 5 EC": emulsifiable concentrate of 5% prallethrin, 85% xylene and Sorpol SM 200
Claims (8)
1. A pesticidal composition comprising prallethrin and a neonicotinoid compound given in the following formula or R C2n KDi A- (CH 2 N.R 2 A-H 2 C-N Y Z A-H 2 C-N YN-11 3 x-Y W-Y Y- (3) wherein, A represents a 6-chloro-3-pyridyl, 2-chloro-5-thiazolyl, tetrahydrofuran-2-yl, tetrahydrofiiran-3-yl, 5-methyltetrahydrofuran-3-yl, 3-pyridyl, 6-bromo-3-pyridyl, 3- cyanophenyl, 2-methyl-5-thiazolyl, 2-phenyl-5-thiazolyl or 2-bromo-5-thiazolyl group; R, represents a hydrogen atom, methyl, ethyl, formyl or acetyl group; R 2 represents a methyl, amino, methylamino, N,N-dimethylamino, ethylamino, N,N-diethylamino, N- methyl-N-ethylamino, 1-pyrroidinyl, (6-chloro-3-pyridyl)methylamino or N-methyl-N- (6-chloro-3-pyridyl)methylamino group; R 3 represents a methyl, ethyl, propyl, propenyl easeor propynyl group; X represents a nitrogen atom or CHI group; Y represents a cyano, nitro or trifluoroacetyl group; Z represents a NH group or sulfur atom; D represents an :0 :oxygen atom or -N(CH 3 group; m represents 0 or 1; and n represents 2 or 3, as active ingredients.
2. A pesticidal composition according to claim 1, wherein A is a 6-chloro-3-pyridyl, tetrahydrofuran-2-yl, tetrahydrofuran-3-yl or methyltetrahydroftiran-3-yl group; R, represents a hydrogen atom or methyl group; R 2 represents a methyl or methylanino group; R 3 represents a methyl group; X is a nitrogen atom or CH group; Y is a cyano or nitro group; Z is a NH group or sulfur atom; D is a oxygen atom or -N(CH 3 group; m is 1; and n is 2.
3. A pesticidal composition according to claim 1, wherin an amount of prallethrin and a neonicotinoid compound is at a weight ratio from 100:1 to 1:100.
4. A pesticidal composition according to claim 1, wherin the neonicotinoid compound is (E)-N'-[(6-chloro-3-pyridyl)methyl]-N 2 -cyano-N'-methylacetamidine. A pesticidal composition according to claim 1, wherin the neonicotinoid compound is 1-(tetrahydrofuran-3-yl)methyl-3-methyl-2-nitroguanidine.
6. A pesticidal composition according to claim 1, wherin the neonicotinoid compound is 1-[(6-chloro-3-pyridyl)methyl]-N-nitro-2-imidazoldineinine. A pesticidal composition according to claim 1, wherin. the neonicotinoid 9 compound is 3-[(2-chloro-5-thiazolyl)methyl]-5-methyl-4-nitroimiinotetrahydro-1, 3, so oxadiazine. A method for controlling pests which comprises applying an effective amount of 4* prallethrin and a neonicotinoid compound given in the following formula or 46 0. (0H 2 )n #09.R,D *goA- (CH 2 N, R 2 A-H 2 C-N Z A-H 2 C-N N-R 3 6 .x-Y x-Y (3) wherein, A represents a 6-chloro-3-pyridyl, 2-chloro-5-thiazolyl, tetrahydrofuran-2-yi, tetrahydrofuran-3-yl, 5-methyltetrahydrofuran-3-yl, 3-pyridyl, 6-bromo-3-pyridyl, 3- cyanophenyl, 2-methyl-5-thiazolyl, 2-phenyl-5-thiazolyl or 2-bromo-5-thiazolyl group; R, represents a hydrogen atom, methyl, ethyl, formyl or acetyl group; R 2 represents a methyl, amino, methylamino, N,N-dimethylamiino, ethylamino, N,N-diethylamino, N- methyl-N-ethylamino, 1-pyrrolidinyl, (6-chloro-3-pyridyl)methylamino or N-methyl-N- (6-chloro-3-pyridyl)methylamino group; R 3 represents a methyl, ethyl, propyl, propenyl or propynyl group; X represents a nitrogen atom or CH group; Y represents a cyano, nitro or trifluoroacetyl group; Z represents a NH group or sulfur atom; D represents an oxygen atom or -N(CH 3 group; m represents 0 or 1; and n represents 2 or 3, to a pest or the locus where a pest inhabits.
9. A method according to claim 8, wherin an amount of prallcthrin and a neonicotinoid compound is at a weight ratio from 100:1 to 1:100. A method according to claim 9, wherin the neonicotinoid compound is selected from the group consisting of (E)-N 1 [(6-chloro-3-pyridyl)methyl]-N 2 -cyano-N 1 :%see 0 methylacetamidine, 1-(tetrahydrofuran-3-yl)methyl-3-mcthyl-2-nitroguanidine, .00 6 gochloro-3-pyridyl)methyl]-N-nitro-2-imidazolidineimine and 3- thiazolyl)methyl]-5-methyl-4-nitroiminotetrahydro-1, 3, I 17 methyl, amino, methylamino, N,N-dimethylamino, ethylamino, N,N-diethylamino, N- methyl-N-ethylamino, 1-pyrrolidinyl, (6-chloro-3-pyridyl)methylamino or N-methyl-N-(6- chloro-3-pyridyl)methylamino group; R 3 represents a methyl, ethyl, propyl, propenyl or propynyl group; X represents a nitrogen atom or CH group; Y represents a cyano, nitro or trifluoroacetyl group; Z represents a NH group or sulfur atom; D represents an oxygen atom or -N(CH 3 group; m represents 0 or 1; and n represents 2 or 3, to a pest or the locus where a pest inhabits. 9. A method according to claim 8, wherein an amount of prallethrin and a neonicotinoid compound is at a weight ratio from 100:1 to 1:100.
10. A method according to claim 9, wherein the neonicotinoid compound is selected from the group consisting of (E)-N1-[(6-chloro-3-pyridyl)methyl]-N 2 -cyano-N 1 methylacetamidine, 1-(tetrahydrofuran-3-yl)methyl-3-methyl-2-nitroguanidine, chloro-3-pyridyl)methyl]-N-nitro-2-imidazolidineimine and 3-[(2-chloro-5- thiazolyl)methyl]-5-methyl-4-nitroiminotetrahydro-1, 3,
11. A pesticidal composition comprising prallethrin and a neonicotinoid, substantially as hereinbefore described with reference to any one of the examples. 0000 Dated 23 March, 1999 Sumitomo Chemical Company, Limited 0:006: 0* 0 S.i Patent Attorneys for the Applicant/Nominated Person 20 SPRUSON FERGUSON 0 S 5* S 0 *0000 00 [N:/libxx]01 1 18:GMM
Applications Claiming Priority (2)
Application Number | Priority Date | Filing Date | Title |
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JP09756598A JP4196427B2 (en) | 1998-04-09 | 1998-04-09 | Harmful arthropod control composition |
JP10-097565 | 1998-04-09 |
Publications (2)
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AU2135699A true AU2135699A (en) | 1999-10-28 |
AU739438B2 AU739438B2 (en) | 2001-10-11 |
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AU21356/99A Ceased AU739438B2 (en) | 1998-04-09 | 1999-03-23 | Pesticidal composition |
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US (3) | US6255340B1 (en) |
JP (1) | JP4196427B2 (en) |
AU (1) | AU739438B2 (en) |
ID (1) | ID22405A (en) |
TW (1) | TW478925B (en) |
Families Citing this family (13)
Publication number | Priority date | Publication date | Assignee | Title |
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EP1146786A2 (en) * | 1998-11-06 | 2001-10-24 | Colorado State University Research Foundation | Method and device for attracting insects |
US6978572B1 (en) * | 1998-11-06 | 2005-12-27 | Colorado State University Research Foundation | Method and device for attracting insects |
GR1003957B (en) * | 2000-08-28 | 2002-08-06 | Syngenta Participations Ag | Control of wood-destroying pests with Thiamethoxam |
US20020103233A1 (en) * | 2000-11-30 | 2002-08-01 | Arther Robert G. | Compositions for enhanced acaricidal activity |
JP4604392B2 (en) * | 2001-05-16 | 2011-01-05 | 住友化学株式会社 | Method for preventing damage to textile products by pests and agent therefor |
DE10301906A1 (en) * | 2003-01-17 | 2004-07-29 | Bayer Healthcare Ag | Arthropod repellent, especially useful for repelling ticks, fleas, mosquitoes and fleas from humans or animals, contains combination of pyrethroid or pyrethrin and nicotinic agonist |
KR100859547B1 (en) * | 2003-12-12 | 2008-09-22 | 바이엘 크롭사이언스 아게 | Synergistic insecticidal mixtures |
MXPA06007728A (en) * | 2004-01-09 | 2006-09-01 | Fmc Corp | Insecticidal compositions for control of general household pests. |
EP1727432A1 (en) * | 2004-03-25 | 2006-12-06 | Fmc Corporation | Liquid termiticide compositions of pyrethroids and a neonicitinoids |
BRPI0513244B1 (en) | 2004-07-13 | 2015-05-19 | Nippon Soda Co | Clathrate compound, method for controlling the concentration of aqueous solution of agricultural chemical active ingredient, agricultural chemical formulation and agricultural active composition |
DE102006014488A1 (en) * | 2006-03-29 | 2007-10-04 | Bayer Cropscience Ag | Combination useful for controlling animal pests comprises a 4-pyridylmethylamino-2(5H)-furanone derivative and an N-heterocyclylmethylamine derivative |
US20090318393A1 (en) * | 2008-06-23 | 2009-12-24 | Shalaby Shalaby W | Film-forming liquid formulations for controlled release of pesticides |
EP2201841A1 (en) * | 2008-12-29 | 2010-06-30 | Bayer CropScience AG | Synergistic insecticidal mixtures |
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DE3681465D1 (en) | 1985-02-04 | 1991-10-24 | Nihon Bayer Agrochem K.K., Tokio/Tokyo, Jp | |
JPH0717621B2 (en) | 1986-03-07 | 1995-03-01 | 日本バイエルアグロケム株式会社 | New heterocyclic compound |
IE71183B1 (en) | 1988-12-27 | 1997-01-29 | Takeda Chemical Industries Ltd | Guanidine derivatives their production and insecticides |
US5304566A (en) | 1989-10-06 | 1994-04-19 | Nippon Soda Co., Ltd | Pyridine compounds which have useful insecticidal utility |
US6187773B1 (en) | 1989-11-10 | 2001-02-13 | Agro-Kanesho Co., Ltd. | Hexahydrotriazine compounds and insecticides |
AU658903B2 (en) * | 1991-10-17 | 1995-05-04 | Sumitomo Chemical Company, Limited | Snake-controlling agent |
US5434181A (en) | 1993-10-26 | 1995-07-18 | Mitsui Toatsu Chemicals, Inc. | Furanyl insecticide |
US5750548A (en) | 1994-01-24 | 1998-05-12 | Novartis Corp. | 1- N-(halo-3-pyridylmethyl)!-N-methylamino-1-alklamino-2-nitroethylene derivatives for controlling fleas in domestic animals |
JP2000509379A (en) * | 1996-04-29 | 2000-07-25 | ノバルティス アクチェンゲゼルシャフト | Pesticide composition |
JP2000007508A (en) * | 1998-06-26 | 2000-01-11 | Sumitomo Chem Co Ltd | Insect pest repellent |
-
1998
- 1998-04-09 JP JP09756598A patent/JP4196427B2/en not_active Expired - Lifetime
-
1999
- 1999-03-15 TW TW088103913A patent/TW478925B/en not_active IP Right Cessation
- 1999-03-23 AU AU21356/99A patent/AU739438B2/en not_active Ceased
- 1999-04-07 ID IDP990309D patent/ID22405A/en unknown
- 1999-04-07 US US09/287,121 patent/US6255340B1/en not_active Expired - Lifetime
-
2000
- 2000-08-15 US US09/637,702 patent/US6391327B1/en not_active Expired - Lifetime
- 2000-08-15 US US09/637,697 patent/US6284782B1/en not_active Expired - Lifetime
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TW478925B (en) | 2002-03-11 |
JP4196427B2 (en) | 2008-12-17 |
US6284782B1 (en) | 2001-09-04 |
JPH11292723A (en) | 1999-10-26 |
US6255340B1 (en) | 2001-07-03 |
ID22405A (en) | 1999-10-14 |
US6391327B1 (en) | 2002-05-21 |
AU739438B2 (en) | 2001-10-11 |
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