AU2021105230A4 - Synergistic stable nitrogen fertilizer and preparation method - Google Patents
Synergistic stable nitrogen fertilizer and preparation method Download PDFInfo
- Publication number
- AU2021105230A4 AU2021105230A4 AU2021105230A AU2021105230A AU2021105230A4 AU 2021105230 A4 AU2021105230 A4 AU 2021105230A4 AU 2021105230 A AU2021105230 A AU 2021105230A AU 2021105230 A AU2021105230 A AU 2021105230A AU 2021105230 A4 AU2021105230 A4 AU 2021105230A4
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- Australia
- Prior art keywords
- nitrogen
- fertilizer
- parts
- synergist
- polyglutamic acid
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
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- 239000000618 nitrogen fertilizer Substances 0.000 title claims abstract description 100
- 230000002195 synergetic effect Effects 0.000 title claims abstract description 58
- 238000002360 preparation method Methods 0.000 title claims abstract description 8
- IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 claims abstract description 236
- 229910052757 nitrogen Inorganic materials 0.000 claims abstract description 118
- XSQUKJJJFZCRTK-UHFFFAOYSA-N urea group Chemical group NC(=O)N XSQUKJJJFZCRTK-UHFFFAOYSA-N 0.000 claims abstract description 107
- 239000004202 carbamide Substances 0.000 claims abstract description 104
- 239000003337 fertilizer Substances 0.000 claims abstract description 93
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 claims abstract description 73
- 229910052799 carbon Inorganic materials 0.000 claims abstract description 73
- 239000003112 inhibitor Substances 0.000 claims abstract description 52
- FYYHWMGAXLPEAU-UHFFFAOYSA-N Magnesium Chemical compound [Mg] FYYHWMGAXLPEAU-UHFFFAOYSA-N 0.000 claims abstract description 36
- HCHKCACWOHOZIP-UHFFFAOYSA-N Zinc Chemical compound [Zn] HCHKCACWOHOZIP-UHFFFAOYSA-N 0.000 claims abstract description 36
- 239000011777 magnesium Substances 0.000 claims abstract description 36
- 229910052749 magnesium Inorganic materials 0.000 claims abstract description 36
- 239000002601 urease inhibitor Substances 0.000 claims abstract description 36
- 239000011701 zinc Substances 0.000 claims abstract description 36
- 229910052725 zinc Inorganic materials 0.000 claims abstract description 36
- NINIDFKCEFEMDL-UHFFFAOYSA-N Sulfur Chemical compound [S] NINIDFKCEFEMDL-UHFFFAOYSA-N 0.000 claims abstract description 35
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- 229910052791 calcium Inorganic materials 0.000 claims abstract description 4
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- 229910052796 boron Inorganic materials 0.000 claims abstract description 3
- 229910052742 iron Inorganic materials 0.000 claims abstract description 3
- 229910052710 silicon Inorganic materials 0.000 claims abstract description 3
- 239000010703 silicon Substances 0.000 claims abstract description 3
- 229920002643 polyglutamic acid Polymers 0.000 claims description 104
- XYXNTHIYBIDHGM-UHFFFAOYSA-N ammonium thiosulfate Chemical compound [NH4+].[NH4+].[O-]S([O-])(=O)=S XYXNTHIYBIDHGM-UHFFFAOYSA-N 0.000 claims description 62
- LXKCHCXZBPLTAE-UHFFFAOYSA-N 3,4-dimethyl-1H-pyrazole phosphate Chemical compound OP(O)(O)=O.CC1=CNN=C1C LXKCHCXZBPLTAE-UHFFFAOYSA-N 0.000 claims description 54
- 108010020346 Polyglutamic Acid Proteins 0.000 claims description 15
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- AZQWKYJCGOJGHM-UHFFFAOYSA-N 1,4-benzoquinone Chemical compound O=C1C=CC(=O)C=C1 AZQWKYJCGOJGHM-UHFFFAOYSA-N 0.000 claims 2
- QIGBRXMKCJKVMJ-UHFFFAOYSA-N Hydroquinone Chemical compound OC1=CC=C(O)C=C1 QIGBRXMKCJKVMJ-UHFFFAOYSA-N 0.000 claims 2
- PXIPVTKHYLBLMZ-UHFFFAOYSA-N Sodium azide Chemical compound [Na+].[N-]=[N+]=[N-] PXIPVTKHYLBLMZ-UHFFFAOYSA-N 0.000 claims 2
- YXFVVABEGXRONW-UHFFFAOYSA-N Toluene Chemical compound CC1=CC=CC=C1 YXFVVABEGXRONW-UHFFFAOYSA-N 0.000 claims 2
- OKGXJRGLYVRVNE-UHFFFAOYSA-N diaminomethylidenethiourea Chemical compound NC(N)=NC(N)=S OKGXJRGLYVRVNE-UHFFFAOYSA-N 0.000 claims 2
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- QJZYHAIUNVAGQP-UHFFFAOYSA-N 3-nitrobicyclo[2.2.1]hept-5-ene-2,3-dicarboxylic acid Chemical compound C1C2C=CC1C(C(=O)O)C2(C(O)=O)[N+]([O-])=O QJZYHAIUNVAGQP-UHFFFAOYSA-N 0.000 claims 1
- XKVUYEYANWFIJX-UHFFFAOYSA-N 5-methyl-1h-pyrazole Chemical compound CC1=CC=NN1 XKVUYEYANWFIJX-UHFFFAOYSA-N 0.000 claims 1
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- 229960001413 acetanilide Drugs 0.000 claims 1
- HSFWRNGVRCDJHI-UHFFFAOYSA-N alpha-acetylene Natural products C#C HSFWRNGVRCDJHI-UHFFFAOYSA-N 0.000 claims 1
- YMKDRGPMQRFJGP-UHFFFAOYSA-M cetylpyridinium chloride Chemical compound [Cl-].CCCCCCCCCCCCCCCC[N+]1=CC=CC=C1 YMKDRGPMQRFJGP-UHFFFAOYSA-M 0.000 claims 1
- 229960001927 cetylpyridinium chloride Drugs 0.000 claims 1
- DMSZORWOGDLWGN-UHFFFAOYSA-N ctk1a3526 Chemical compound NP(N)(N)=O DMSZORWOGDLWGN-UHFFFAOYSA-N 0.000 claims 1
- QGBSISYHAICWAH-UHFFFAOYSA-N dicyandiamide Chemical compound NC(N)=NC#N QGBSISYHAICWAH-UHFFFAOYSA-N 0.000 claims 1
- 125000002534 ethynyl group Chemical group [H]C#C* 0.000 claims 1
- KQTVWCSONPJJPE-UHFFFAOYSA-N etridiazole Chemical compound CCOC1=NC(C(Cl)(Cl)Cl)=NS1 KQTVWCSONPJJPE-UHFFFAOYSA-N 0.000 claims 1
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- 229920005610 lignin Polymers 0.000 claims 1
- HEPPIYNOUFWEPP-UHFFFAOYSA-N n-diaminophosphinothioylbutan-1-amine Chemical compound CCCCNP(N)(N)=S HEPPIYNOUFWEPP-UHFFFAOYSA-N 0.000 claims 1
- WOPHQTWCQNDMGH-UHFFFAOYSA-N n-diaminophosphinothioylcyclohexanamine Chemical compound NP(N)(=S)NC1CCCCC1 WOPHQTWCQNDMGH-UHFFFAOYSA-N 0.000 claims 1
- KMZNLGQARIPHIB-UHFFFAOYSA-N n-diaminophosphorylcyclohexanamine Chemical compound NP(N)(=O)NC1CCCCC1 KMZNLGQARIPHIB-UHFFFAOYSA-N 0.000 claims 1
- 238000005453 pelletization Methods 0.000 claims 1
- UEXCJVNBTNXOEH-UHFFFAOYSA-N phenyl acethylene Natural products C#CC1=CC=CC=C1 UEXCJVNBTNXOEH-UHFFFAOYSA-N 0.000 claims 1
- TZLVRPLSVNESQC-UHFFFAOYSA-N potassium azide Chemical compound [K+].[N-]=[N+]=[N-] TZLVRPLSVNESQC-UHFFFAOYSA-N 0.000 claims 1
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- CLZWAWBPWVRRGI-UHFFFAOYSA-N tert-butyl 2-[2-[2-[2-[bis[2-[(2-methylpropan-2-yl)oxy]-2-oxoethyl]amino]-5-bromophenoxy]ethoxy]-4-methyl-n-[2-[(2-methylpropan-2-yl)oxy]-2-oxoethyl]anilino]acetate Chemical compound CC1=CC=C(N(CC(=O)OC(C)(C)C)CC(=O)OC(C)(C)C)C(OCCOC=2C(=CC=C(Br)C=2)N(CC(=O)OC(C)(C)C)CC(=O)OC(C)(C)C)=C1 CLZWAWBPWVRRGI-UHFFFAOYSA-N 0.000 claims 1
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- 239000002253 acid Substances 0.000 description 3
- YYRMJZQKEFZXMX-UHFFFAOYSA-N calcium;phosphoric acid Chemical compound [Ca+2].OP(O)(O)=O.OP(O)(O)=O YYRMJZQKEFZXMX-UHFFFAOYSA-N 0.000 description 3
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Classifications
-
- C—CHEMISTRY; METALLURGY
- C05—FERTILISERS; MANUFACTURE THEREOF
- C05G—MIXTURES OF FERTILISERS COVERED INDIVIDUALLY BY DIFFERENT SUBCLASSES OF CLASS C05; MIXTURES OF ONE OR MORE FERTILISERS WITH MATERIALS NOT HAVING A SPECIFIC FERTILISING ACTIVITY, e.g. PESTICIDES, SOIL-CONDITIONERS, WETTING AGENTS; FERTILISERS CHARACTERISED BY THEIR FORM
- C05G3/00—Mixtures of one or more fertilisers with additives not having a specially fertilising activity
-
- C—CHEMISTRY; METALLURGY
- C05—FERTILISERS; MANUFACTURE THEREOF
- C05G—MIXTURES OF FERTILISERS COVERED INDIVIDUALLY BY DIFFERENT SUBCLASSES OF CLASS C05; MIXTURES OF ONE OR MORE FERTILISERS WITH MATERIALS NOT HAVING A SPECIFIC FERTILISING ACTIVITY, e.g. PESTICIDES, SOIL-CONDITIONERS, WETTING AGENTS; FERTILISERS CHARACTERISED BY THEIR FORM
- C05G3/00—Mixtures of one or more fertilisers with additives not having a specially fertilising activity
- C05G3/90—Mixtures of one or more fertilisers with additives not having a specially fertilising activity for affecting the nitrification of ammonium compounds or urea in the soil
-
- C—CHEMISTRY; METALLURGY
- C05—FERTILISERS; MANUFACTURE THEREOF
- C05B—PHOSPHATIC FERTILISERS
- C05B1/00—Superphosphates, i.e. fertilisers produced by reacting rock or bone phosphates with sulfuric or phosphoric acid in such amounts and concentrations as to yield solid products directly
- C05B1/02—Superphosphates
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- C—CHEMISTRY; METALLURGY
- C05—FERTILISERS; MANUFACTURE THEREOF
- C05B—PHOSPHATIC FERTILISERS
- C05B17/00—Other phosphatic fertilisers, e.g. soft rock phosphates, bone meal
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- C—CHEMISTRY; METALLURGY
- C05—FERTILISERS; MANUFACTURE THEREOF
- C05C—NITROGENOUS FERTILISERS
- C05C9/00—Fertilisers containing urea or urea compounds
- C05C9/005—Post-treatment
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- C—CHEMISTRY; METALLURGY
- C05—FERTILISERS; MANUFACTURE THEREOF
- C05G—MIXTURES OF FERTILISERS COVERED INDIVIDUALLY BY DIFFERENT SUBCLASSES OF CLASS C05; MIXTURES OF ONE OR MORE FERTILISERS WITH MATERIALS NOT HAVING A SPECIFIC FERTILISING ACTIVITY, e.g. PESTICIDES, SOIL-CONDITIONERS, WETTING AGENTS; FERTILISERS CHARACTERISED BY THEIR FORM
- C05G3/00—Mixtures of one or more fertilisers with additives not having a specially fertilising activity
- C05G3/40—Mixtures of one or more fertilisers with additives not having a specially fertilising activity for affecting fertiliser dosage or release rate; for affecting solubility
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- C—CHEMISTRY; METALLURGY
- C05—FERTILISERS; MANUFACTURE THEREOF
- C05G—MIXTURES OF FERTILISERS COVERED INDIVIDUALLY BY DIFFERENT SUBCLASSES OF CLASS C05; MIXTURES OF ONE OR MORE FERTILISERS WITH MATERIALS NOT HAVING A SPECIFIC FERTILISING ACTIVITY, e.g. PESTICIDES, SOIL-CONDITIONERS, WETTING AGENTS; FERTILISERS CHARACTERISED BY THEIR FORM
- C05G3/00—Mixtures of one or more fertilisers with additives not having a specially fertilising activity
- C05G3/80—Soil conditioners
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- C—CHEMISTRY; METALLURGY
- C05—FERTILISERS; MANUFACTURE THEREOF
- C05G—MIXTURES OF FERTILISERS COVERED INDIVIDUALLY BY DIFFERENT SUBCLASSES OF CLASS C05; MIXTURES OF ONE OR MORE FERTILISERS WITH MATERIALS NOT HAVING A SPECIFIC FERTILISING ACTIVITY, e.g. PESTICIDES, SOIL-CONDITIONERS, WETTING AGENTS; FERTILISERS CHARACTERISED BY THEIR FORM
- C05G5/00—Fertilisers characterised by their form
- C05G5/10—Solid or semi-solid fertilisers, e.g. powders
- C05G5/12—Granules or flakes
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- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02P—CLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
- Y02P60/00—Technologies relating to agriculture, livestock or agroalimentary industries
- Y02P60/20—Reduction of greenhouse gas [GHG] emissions in agriculture, e.g. CO2
- Y02P60/21—Dinitrogen oxide [N2O], e.g. using aquaponics, hydroponics or efficiency measures
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- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Life Sciences & Earth Sciences (AREA)
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- Soil Sciences (AREA)
- Fertilizers (AREA)
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AU (1) | AU2021105230A4 (de) |
BE (1) | BE1028364B1 (de) |
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LU (1) | LU500810B1 (de) |
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CN115136778A (zh) * | 2022-08-10 | 2022-10-04 | 四川农业大学 | 一种秸秆、生物或者化学硝化抑制剂与氮肥的配施方法 |
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CN112209784A (zh) * | 2020-11-02 | 2021-01-12 | 中国科学院沈阳应用生态研究所 | 一种增效稳定性复合肥肥料及制备方法 |
CN113443937A (zh) * | 2021-07-16 | 2021-09-28 | 青岛农业大学 | 一种调节梨园土壤酸碱性的稳定性水溶肥及其应用 |
CN114451165B (zh) * | 2022-02-24 | 2022-12-13 | 河南农业大学 | 用于调控烟草生长的氮素增效剂及其使用方法和应用 |
CN115521789B (zh) * | 2022-09-22 | 2024-05-24 | 中科吉安生态环境研究院 | 提高农田土壤硝态氮同化能力的生物调理剂及制备方法 |
WO2024076491A1 (en) * | 2022-10-03 | 2024-04-11 | Verdesian Life Sciences U.S., Llc | Compositions for enhancing nitrogen fertilizers by incorporating anti-oxidant moieties and methods for use thereof |
CN116023183A (zh) * | 2022-12-30 | 2023-04-28 | 中振智农科技有限公司 | 一种提高水稻肥料利用率的复合型增效剂及其制备方法 |
CN117142899B (zh) * | 2023-08-18 | 2024-05-07 | 安徽卓砺农业科技有限公司 | 一种生物基肥料增效剂及其制备方法 |
CN117185876A (zh) * | 2023-09-05 | 2023-12-08 | 新洋丰农业科技股份有限公司 | 一种提高番茄抗寒性的稳定性水溶氮肥及其制备方法 |
CN117534528A (zh) * | 2023-11-21 | 2024-02-09 | 宁夏大彩生物科技有限公司 | 一种绿色环保复合肥料 |
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CN1312238A (zh) * | 2000-03-08 | 2001-09-12 | 云南爱地生物技术研究所 | 氨基酸螯合肥生产新工艺 |
CN101434503A (zh) * | 2007-11-16 | 2009-05-20 | 中国科学院沈阳应用生态研究所 | 增效缓释尿素肥料及制备方法 |
CN101434504B (zh) * | 2007-11-16 | 2012-05-30 | 中国科学院沈阳应用生态研究所 | 增效缓释氮素肥料及制备方法 |
CN101434502B (zh) * | 2007-11-16 | 2012-05-30 | 中国科学院沈阳应用生态研究所 | 一种增效缓释氮素肥料及制备方法 |
CN102786367A (zh) * | 2007-11-16 | 2012-11-21 | 中国科学院沈阳应用生态研究所 | 增效缓释尿素肥料及其制备方法 |
CN102786346B (zh) * | 2007-11-16 | 2014-08-06 | 中国科学院沈阳应用生态研究所 | 一种增效缓释尿素肥料及其制备方法 |
CN101450880B (zh) * | 2007-12-07 | 2012-06-06 | 中国科学院沈阳应用生态研究所 | 氮素肥料复合增效剂及制备方法 |
CN104961591B (zh) * | 2015-07-10 | 2018-02-16 | 云南威鑫农业科技股份有限公司 | 一种缓释增效生物肥及其制备方法 |
CN106966816A (zh) * | 2017-05-17 | 2017-07-21 | 贵州天宝丰原生态农业科技有限公司 | 马铃薯专用复合肥、制备方法及施用方法 |
CN107011066A (zh) * | 2017-05-17 | 2017-08-04 | 贵州天宝丰原生态农业科技有限公司 | 玉米专用复合肥、制备方法及施肥方法 |
CN109400371A (zh) * | 2018-12-05 | 2019-03-01 | 中国科学院沈阳应用生态研究所 | 一种碳耦合型稳定性复合肥肥料及制备方法 |
CN109232137A (zh) * | 2018-12-05 | 2019-01-18 | 中国科学院沈阳应用生态研究所 | 一种碳耦合型稳定性氮肥肥料及制备方法 |
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CN115136778A (zh) * | 2022-08-10 | 2022-10-04 | 四川农业大学 | 一种秸秆、生物或者化学硝化抑制剂与氮肥的配施方法 |
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BE1028364B1 (de) | 2022-01-04 |
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