AU2014354984B2 - Column material for the capture of heavy metal and precious metal ions - Google Patents
Column material for the capture of heavy metal and precious metal ions Download PDFInfo
- Publication number
- AU2014354984B2 AU2014354984B2 AU2014354984A AU2014354984A AU2014354984B2 AU 2014354984 B2 AU2014354984 B2 AU 2014354984B2 AU 2014354984 A AU2014354984 A AU 2014354984A AU 2014354984 A AU2014354984 A AU 2014354984A AU 2014354984 B2 AU2014354984 B2 AU 2014354984B2
- Authority
- AU
- Australia
- Prior art keywords
- ion
- exchange
- column
- pct
- metal ions
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Active
Links
- 239000000463 material Substances 0.000 title claims abstract description 38
- 229910021645 metal ion Inorganic materials 0.000 title claims abstract description 21
- 229910001385 heavy metal Inorganic materials 0.000 title description 4
- 239000010970 precious metal Substances 0.000 title description 4
- 238000005342 ion exchange Methods 0.000 claims abstract description 56
- 239000002131 composite material Substances 0.000 claims abstract description 32
- 229920000615 alginic acid Polymers 0.000 claims abstract description 26
- 229940072056 alginate Drugs 0.000 claims abstract description 25
- 229910052751 metal Inorganic materials 0.000 claims abstract description 21
- 239000002184 metal Substances 0.000 claims abstract description 21
- 150000004770 chalcogenides Chemical class 0.000 claims abstract description 19
- 239000008187 granular material Substances 0.000 claims abstract description 18
- 238000000034 method Methods 0.000 claims abstract description 14
- 235000010443 alginic acid Nutrition 0.000 claims abstract description 10
- FHVDTGUDJYJELY-UHFFFAOYSA-N 6-{[2-carboxy-4,5-dihydroxy-6-(phosphanyloxy)oxan-3-yl]oxy}-4,5-dihydroxy-3-phosphanyloxane-2-carboxylic acid Chemical compound O1C(C(O)=O)C(P)C(O)C(O)C1OC1C(C(O)=O)OC(OP)C(O)C1O FHVDTGUDJYJELY-UHFFFAOYSA-N 0.000 claims abstract description 9
- 239000002351 wastewater Substances 0.000 claims abstract description 5
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 claims description 25
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 claims description 11
- 239000000843 powder Substances 0.000 claims description 5
- 239000004576 sand Substances 0.000 claims description 5
- 239000000377 silicon dioxide Substances 0.000 claims description 3
- 238000005065 mining Methods 0.000 claims description 2
- 238000012856 packing Methods 0.000 claims description 2
- 238000001878 scanning electron micrograph Methods 0.000 description 8
- -1 clays and zeolites Chemical class 0.000 description 7
- 150000002500 ions Chemical class 0.000 description 7
- 239000000243 solution Substances 0.000 description 7
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 5
- CSCPPACGZOOCGX-UHFFFAOYSA-N Acetone Chemical compound CC(C)=O CSCPPACGZOOCGX-UHFFFAOYSA-N 0.000 description 4
- XOJVVFBFDXDTEG-UHFFFAOYSA-N Norphytane Natural products CC(C)CCCC(C)CCCC(C)CCCC(C)C XOJVVFBFDXDTEG-UHFFFAOYSA-N 0.000 description 4
- IXPNQXFRVYWDDI-UHFFFAOYSA-N 1-methyl-2,4-dioxo-1,3-diazinane-5-carboximidamide Chemical compound CN1CC(C(N)=N)C(=O)NC1=O IXPNQXFRVYWDDI-UHFFFAOYSA-N 0.000 description 3
- 238000004458 analytical method Methods 0.000 description 3
- 238000002354 inductively-coupled plasma atomic emission spectroscopy Methods 0.000 description 3
- 239000010410 layer Substances 0.000 description 3
- 235000010413 sodium alginate Nutrition 0.000 description 3
- 239000000661 sodium alginate Substances 0.000 description 3
- 229940005550 sodium alginate Drugs 0.000 description 3
- 229910052718 tin Inorganic materials 0.000 description 3
- XLYOFNOQVPJJNP-ZSJDYOACSA-N Heavy water Chemical compound [2H]O[2H] XLYOFNOQVPJJNP-ZSJDYOACSA-N 0.000 description 2
- 230000015572 biosynthetic process Effects 0.000 description 2
- 239000003795 chemical substances by application Substances 0.000 description 2
- 238000013461 design Methods 0.000 description 2
- 238000001914 filtration Methods 0.000 description 2
- 239000012530 fluid Substances 0.000 description 2
- 239000011521 glass Substances 0.000 description 2
- 238000001095 inductively coupled plasma mass spectrometry Methods 0.000 description 2
- 239000011229 interlayer Substances 0.000 description 2
- 229910052749 magnesium Inorganic materials 0.000 description 2
- 229910052748 manganese Inorganic materials 0.000 description 2
- 239000000203 mixture Substances 0.000 description 2
- 238000012986 modification Methods 0.000 description 2
- 230000004048 modification Effects 0.000 description 2
- BWHMMNNQKKPAPP-UHFFFAOYSA-L potassium carbonate Chemical compound [K+].[K+].[O-]C([O-])=O BWHMMNNQKKPAPP-UHFFFAOYSA-L 0.000 description 2
- 238000000634 powder X-ray diffraction Methods 0.000 description 2
- 230000008569 process Effects 0.000 description 2
- 238000005067 remediation Methods 0.000 description 2
- 238000004611 spectroscopical analysis Methods 0.000 description 2
- 229910052717 sulfur Inorganic materials 0.000 description 2
- 125000004434 sulfur atom Chemical group 0.000 description 2
- 238000003786 synthesis reaction Methods 0.000 description 2
- 229910002483 Cu Ka Inorganic materials 0.000 description 1
- 101000666896 Homo sapiens V-type immunoglobulin domain-containing suppressor of T-cell activation Proteins 0.000 description 1
- 241000985284 Leuciscus idus Species 0.000 description 1
- 102100038282 V-type immunoglobulin domain-containing suppressor of T-cell activation Human genes 0.000 description 1
- 239000007864 aqueous solution Substances 0.000 description 1
- 125000004429 atom Chemical group 0.000 description 1
- 229910052791 calcium Inorganic materials 0.000 description 1
- 150000001768 cations Chemical class 0.000 description 1
- 150000001875 compounds Chemical class 0.000 description 1
- 239000003651 drinking water Substances 0.000 description 1
- 235000020188 drinking water Nutrition 0.000 description 1
- 238000000921 elemental analysis Methods 0.000 description 1
- 238000002149 energy-dispersive X-ray emission spectroscopy Methods 0.000 description 1
- 238000005516 engineering process Methods 0.000 description 1
- 230000007613 environmental effect Effects 0.000 description 1
- 238000002474 experimental method Methods 0.000 description 1
- IJJVMEJXYNJXOJ-UHFFFAOYSA-N fluquinconazole Chemical compound C=1C=C(Cl)C=C(Cl)C=1N1C(=O)C2=CC(F)=CC=C2N=C1N1C=NC=N1 IJJVMEJXYNJXOJ-UHFFFAOYSA-N 0.000 description 1
- 239000010439 graphite Substances 0.000 description 1
- 229910002804 graphite Inorganic materials 0.000 description 1
- 230000036541 health Effects 0.000 description 1
- 238000001027 hydrothermal synthesis Methods 0.000 description 1
- 238000009616 inductively coupled plasma Methods 0.000 description 1
- 238000002386 leaching Methods 0.000 description 1
- 150000002739 metals Chemical class 0.000 description 1
- 239000004570 mortar (masonry) Substances 0.000 description 1
- 230000008520 organization Effects 0.000 description 1
- 239000002245 particle Substances 0.000 description 1
- 238000000053 physical method Methods 0.000 description 1
- 229910052700 potassium Inorganic materials 0.000 description 1
- 229910000027 potassium carbonate Inorganic materials 0.000 description 1
- 235000015320 potassium carbonate Nutrition 0.000 description 1
- 229910001414 potassium ion Inorganic materials 0.000 description 1
- 238000002360 preparation method Methods 0.000 description 1
- QQONPFPTGQHPMA-UHFFFAOYSA-N propylene Natural products CC=C QQONPFPTGQHPMA-UHFFFAOYSA-N 0.000 description 1
- 125000004805 propylene group Chemical group [H]C([H])([H])C([H])([*:1])C([H])([H])[*:2] 0.000 description 1
- 230000005855 radiation Effects 0.000 description 1
- 238000012552 review Methods 0.000 description 1
- 230000007480 spreading Effects 0.000 description 1
- 238000003756 stirring Methods 0.000 description 1
- 239000002699 waste material Substances 0.000 description 1
- 239000010457 zeolite Substances 0.000 description 1
- 229910052725 zinc Inorganic materials 0.000 description 1
Classifications
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J39/00—Cation exchange; Use of material as cation exchangers; Treatment of material for improving the cation exchange properties
- B01J39/02—Processes using inorganic exchangers
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01D—SEPARATION
- B01D15/00—Separating processes involving the treatment of liquids with solid sorbents; Apparatus therefor
- B01D15/08—Selective adsorption, e.g. chromatography
- B01D15/26—Selective adsorption, e.g. chromatography characterised by the separation mechanism
- B01D15/36—Selective adsorption, e.g. chromatography characterised by the separation mechanism involving ionic interaction, e.g. ion-exchange, ion-pair, ion-suppression or ion-exclusion
- B01D15/361—Ion-exchange
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J39/00—Cation exchange; Use of material as cation exchangers; Treatment of material for improving the cation exchange properties
- B01J39/08—Use of material as cation exchangers; Treatment of material for improving the cation exchange properties
- B01J39/09—Inorganic material
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J47/00—Ion-exchange processes in general; Apparatus therefor
- B01J47/018—Granulation; Incorporation of ion-exchangers in a matrix; Mixing with inert materials
-
- C—CHEMISTRY; METALLURGY
- C02—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F1/00—Treatment of water, waste water, or sewage
- C02F1/28—Treatment of water, waste water, or sewage by sorption
- C02F1/288—Treatment of water, waste water, or sewage by sorption using composite sorbents, e.g. coated, impregnated, multi-layered
-
- C—CHEMISTRY; METALLURGY
- C02—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F1/00—Treatment of water, waste water, or sewage
- C02F1/42—Treatment of water, waste water, or sewage by ion-exchange
-
- C—CHEMISTRY; METALLURGY
- C02—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F1/00—Treatment of water, waste water, or sewage
- C02F1/42—Treatment of water, waste water, or sewage by ion-exchange
- C02F2001/425—Treatment of water, waste water, or sewage by ion-exchange using cation exchangers
-
- C—CHEMISTRY; METALLURGY
- C02—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F2101/00—Nature of the contaminant
- C02F2101/006—Radioactive compounds
-
- C—CHEMISTRY; METALLURGY
- C02—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F2101/00—Nature of the contaminant
- C02F2101/10—Inorganic compounds
- C02F2101/20—Heavy metals or heavy metal compounds
-
- C—CHEMISTRY; METALLURGY
- C02—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F2103/00—Nature of the water, waste water, sewage or sludge to be treated
- C02F2103/10—Nature of the water, waste water, sewage or sludge to be treated from quarries or from mining activities
-
- C—CHEMISTRY; METALLURGY
- C02—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F2103/00—Nature of the water, waste water, sewage or sludge to be treated
- C02F2103/34—Nature of the water, waste water, sewage or sludge to be treated from industrial activities not provided for in groups C02F2103/12 - C02F2103/32
Landscapes
- Chemical & Material Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Organic Chemistry (AREA)
- Inorganic Chemistry (AREA)
- Analytical Chemistry (AREA)
- Life Sciences & Earth Sciences (AREA)
- Hydrology & Water Resources (AREA)
- Engineering & Computer Science (AREA)
- Environmental & Geological Engineering (AREA)
- Water Supply & Treatment (AREA)
- Solid-Sorbent Or Filter-Aiding Compositions (AREA)
- Treatment Of Water By Ion Exchange (AREA)
Applications Claiming Priority (3)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| US201361909669P | 2013-11-27 | 2013-11-27 | |
| US61/909,669 | 2013-11-27 | ||
| PCT/US2014/066882 WO2015080976A1 (en) | 2013-11-27 | 2014-11-21 | Column material for the capture of heavy metal and precious metal ions |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| AU2014354984A1 AU2014354984A1 (en) | 2016-05-05 |
| AU2014354984B2 true AU2014354984B2 (en) | 2018-06-21 |
Family
ID=53181721
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| AU2014354984A Active AU2014354984B2 (en) | 2013-11-27 | 2014-11-21 | Column material for the capture of heavy metal and precious metal ions |
Country Status (6)
| Country | Link |
|---|---|
| US (1) | US10549270B2 (cg-RX-API-DMAC7.html) |
| EP (1) | EP3074128B1 (cg-RX-API-DMAC7.html) |
| JP (1) | JP6517799B2 (cg-RX-API-DMAC7.html) |
| AU (1) | AU2014354984B2 (cg-RX-API-DMAC7.html) |
| CA (1) | CA2927398C (cg-RX-API-DMAC7.html) |
| WO (1) | WO2015080976A1 (cg-RX-API-DMAC7.html) |
Families Citing this family (6)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US9227186B2 (en) | 2012-10-04 | 2016-01-05 | Northwestern University | Synthesis of layered metal sulfide ion-exchangers |
| US10549270B2 (en) | 2013-11-27 | 2020-02-04 | Northwestern University | Column material for the capture of heavy metal and precious metal ions |
| WO2017083467A1 (en) | 2015-11-10 | 2017-05-18 | Northwestern University | Composite materials containing organic polymer-encapsulated metal organic frameworks |
| CN109012621B (zh) * | 2016-12-07 | 2021-03-02 | 天津市金鳞水处理科技有限公司 | 一种重金属离子吸附和检测型复合水凝胶纤维 |
| CN106745592B (zh) * | 2016-12-07 | 2019-04-26 | 天津市金鳞水处理科技有限公司 | 一种具有重金属离子吸附和检测功能的复合絮凝剂及其制备方法 |
| CN108236913B (zh) * | 2016-12-27 | 2020-06-09 | 中国科学院宁波城市环境观测研究站 | 一种磁性硫属复合吸附剂的制备方法 |
Citations (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US20090095684A1 (en) * | 2007-10-10 | 2009-04-16 | Northwestern University | Chalcogenide compounds with a clay-like cation-exchange capacity and methods of use |
Family Cites Families (17)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US4040917A (en) | 1975-07-02 | 1977-08-09 | Exxon Research And Engineering Company | Preparation of intercalated chalcogenides |
| US4125687A (en) | 1977-06-27 | 1978-11-14 | Bell Telephone Laboratories, Incorporated | Rechargeable nonaqueous cell with chalcogenide electrode |
| US4340496A (en) | 1979-03-02 | 1982-07-20 | Varian Associates, Inc. | Anion exchange chromatographic composition for separation of polyfunctional compounds |
| US5531936A (en) | 1994-08-31 | 1996-07-02 | Board Of Trustees Operating Michigan State University | Alkali metal quaternary chalcogenides and process for the preparation thereof |
| AU6670098A (en) | 1997-02-21 | 1998-09-09 | Engelhard Corporation | Composite material based on zeolite and active carbon, preparation and use thereof in water treatment |
| CA2293691C (en) | 1997-06-09 | 2006-11-07 | Hw Process Technologies, Inc. | Method for separating and isolating precious metals from non precious metals dissolved in solutions |
| JP3045148B2 (ja) * | 1997-07-01 | 2000-05-29 | サムソン ジェネラル ケミカルズ カンパニー リミテッド | アルギン酸ゲル水処理剤及びその製造方法 |
| US20030200839A1 (en) | 1998-03-27 | 2003-10-30 | Jenkins Alexander E. | Recovery of precious metals and copper from copper/gold ores using resin technology |
| US6616860B1 (en) | 1999-02-16 | 2003-09-09 | Agency Of Industrial Science And Technology | Biopolymer composite ion-exchanger with high cesium selectivity and its manufacturing method |
| US6919030B2 (en) | 1999-10-01 | 2005-07-19 | Hannah Technologies Limited Partnership | Process for recovering cyanide from copper-containing feed material |
| US20080145305A1 (en) | 2006-10-26 | 2008-06-19 | Board Of Trustees Of Michigan State University | Process for the removal of metals using an open framework chalcogenide |
| US20090057228A1 (en) * | 2007-08-29 | 2009-03-05 | Siemens Water Technologies Corp. | System and method of filtering using stratified activated carbon |
| US9868637B2 (en) | 2008-06-11 | 2018-01-16 | Avantbio Corporation | Bromine-facilitated synthesis of fluoro-sulfur compounds |
| US9056263B2 (en) | 2010-05-25 | 2015-06-16 | Northwestern University | Chalcogenide compounds for the remediation of nuclear and heavy metal wastes |
| US9227186B2 (en) | 2012-10-04 | 2016-01-05 | Northwestern University | Synthesis of layered metal sulfide ion-exchangers |
| US9731227B2 (en) * | 2013-10-10 | 2017-08-15 | Nano And Advanced Materials Institute Limited | Household water filter element for removing radioactive substances |
| US10549270B2 (en) | 2013-11-27 | 2020-02-04 | Northwestern University | Column material for the capture of heavy metal and precious metal ions |
-
2014
- 2014-11-20 US US14/548,952 patent/US10549270B2/en active Active
- 2014-11-21 AU AU2014354984A patent/AU2014354984B2/en active Active
- 2014-11-21 WO PCT/US2014/066882 patent/WO2015080976A1/en not_active Ceased
- 2014-11-21 EP EP14866622.5A patent/EP3074128B1/en active Active
- 2014-11-21 JP JP2016529458A patent/JP6517799B2/ja active Active
- 2014-11-21 CA CA2927398A patent/CA2927398C/en active Active
Patent Citations (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US20090095684A1 (en) * | 2007-10-10 | 2009-04-16 | Northwestern University | Chalcogenide compounds with a clay-like cation-exchange capacity and methods of use |
Also Published As
| Publication number | Publication date |
|---|---|
| EP3074128A4 (en) | 2017-08-02 |
| EP3074128B1 (en) | 2021-07-28 |
| JP2017500189A (ja) | 2017-01-05 |
| CA2927398A1 (en) | 2015-06-04 |
| WO2015080976A1 (en) | 2015-06-04 |
| CA2927398C (en) | 2021-08-31 |
| JP6517799B2 (ja) | 2019-05-22 |
| EP3074128A1 (en) | 2016-10-05 |
| AU2014354984A1 (en) | 2016-05-05 |
| US10549270B2 (en) | 2020-02-04 |
| US20150144568A1 (en) | 2015-05-28 |
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Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| FGA | Letters patent sealed or granted (standard patent) |