AU2012326312B2 - Froth flotation processes - Google Patents

Froth flotation processes Download PDF

Info

Publication number
AU2012326312B2
AU2012326312B2 AU2012326312A AU2012326312A AU2012326312B2 AU 2012326312 B2 AU2012326312 B2 AU 2012326312B2 AU 2012326312 A AU2012326312 A AU 2012326312A AU 2012326312 A AU2012326312 A AU 2012326312A AU 2012326312 B2 AU2012326312 B2 AU 2012326312B2
Authority
AU
Australia
Prior art keywords
salt
acid
hydrocarbyl
acids
froth flotation
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Ceased
Application number
AU2012326312A
Other languages
English (en)
Other versions
AU2012326312A1 (en
Inventor
Tarun Bhambhani
Devarayasamudram R. Nagaraj
Carmina QUINTANAR
Peter RICCIO
Alan S. Rothenberg
Bing Wang
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Cytec Technology Corp
Original Assignee
Cytec Technology Corp
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Cytec Technology Corp filed Critical Cytec Technology Corp
Publication of AU2012326312A1 publication Critical patent/AU2012326312A1/en
Application granted granted Critical
Publication of AU2012326312B2 publication Critical patent/AU2012326312B2/en
Ceased legal-status Critical Current
Anticipated expiration legal-status Critical

Links

Classifications

    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01DSEPARATION
    • B01D21/00Separation of suspended solid particles from liquids by sedimentation
    • B01D21/0084Enhancing liquid-particle separation using the flotation principle
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B03SEPARATION OF SOLID MATERIALS USING LIQUIDS OR USING PNEUMATIC TABLES OR JIGS; MAGNETIC OR ELECTROSTATIC SEPARATION OF SOLID MATERIALS FROM SOLID MATERIALS OR FLUIDS; SEPARATION BY HIGH-VOLTAGE ELECTRIC FIELDS
    • B03DFLOTATION; DIFFERENTIAL SEDIMENTATION
    • B03D1/00Flotation
    • B03D1/001Flotation agents
    • B03D1/004Organic compounds
    • B03D1/01Organic compounds containing nitrogen
    • B03D1/011Quaternary ammonium compounds
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B03SEPARATION OF SOLID MATERIALS USING LIQUIDS OR USING PNEUMATIC TABLES OR JIGS; MAGNETIC OR ELECTROSTATIC SEPARATION OF SOLID MATERIALS FROM SOLID MATERIALS OR FLUIDS; SEPARATION BY HIGH-VOLTAGE ELECTRIC FIELDS
    • B03DFLOTATION; DIFFERENTIAL SEDIMENTATION
    • B03D1/00Flotation
    • B03D1/001Flotation agents
    • B03D1/004Organic compounds
    • B03D1/012Organic compounds containing sulfur
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B03SEPARATION OF SOLID MATERIALS USING LIQUIDS OR USING PNEUMATIC TABLES OR JIGS; MAGNETIC OR ELECTROSTATIC SEPARATION OF SOLID MATERIALS FROM SOLID MATERIALS OR FLUIDS; SEPARATION BY HIGH-VOLTAGE ELECTRIC FIELDS
    • B03DFLOTATION; DIFFERENTIAL SEDIMENTATION
    • B03D1/00Flotation
    • B03D1/001Flotation agents
    • B03D1/004Organic compounds
    • B03D1/014Organic compounds containing phosphorus
    • CCHEMISTRY; METALLURGY
    • C02TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02FTREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F1/00Treatment of water, waste water, or sewage
    • C02F1/24Treatment of water, waste water, or sewage by flotation
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B03SEPARATION OF SOLID MATERIALS USING LIQUIDS OR USING PNEUMATIC TABLES OR JIGS; MAGNETIC OR ELECTROSTATIC SEPARATION OF SOLID MATERIALS FROM SOLID MATERIALS OR FLUIDS; SEPARATION BY HIGH-VOLTAGE ELECTRIC FIELDS
    • B03DFLOTATION; DIFFERENTIAL SEDIMENTATION
    • B03D1/00Flotation
    • B03D1/08Subsequent treatment of concentrated product
    • B03D1/085Subsequent treatment of concentrated product of the feed, e.g. conditioning, de-sliming
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B03SEPARATION OF SOLID MATERIALS USING LIQUIDS OR USING PNEUMATIC TABLES OR JIGS; MAGNETIC OR ELECTROSTATIC SEPARATION OF SOLID MATERIALS FROM SOLID MATERIALS OR FLUIDS; SEPARATION BY HIGH-VOLTAGE ELECTRIC FIELDS
    • B03DFLOTATION; DIFFERENTIAL SEDIMENTATION
    • B03D2201/00Specified effects produced by the flotation agents
    • B03D2201/02Collectors
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B03SEPARATION OF SOLID MATERIALS USING LIQUIDS OR USING PNEUMATIC TABLES OR JIGS; MAGNETIC OR ELECTROSTATIC SEPARATION OF SOLID MATERIALS FROM SOLID MATERIALS OR FLUIDS; SEPARATION BY HIGH-VOLTAGE ELECTRIC FIELDS
    • B03DFLOTATION; DIFFERENTIAL SEDIMENTATION
    • B03D2203/00Specified materials treated by the flotation agents; specified applications
    • B03D2203/02Ores
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B03SEPARATION OF SOLID MATERIALS USING LIQUIDS OR USING PNEUMATIC TABLES OR JIGS; MAGNETIC OR ELECTROSTATIC SEPARATION OF SOLID MATERIALS FROM SOLID MATERIALS OR FLUIDS; SEPARATION BY HIGH-VOLTAGE ELECTRIC FIELDS
    • B03DFLOTATION; DIFFERENTIAL SEDIMENTATION
    • B03D2203/00Specified materials treated by the flotation agents; specified applications
    • B03D2203/02Ores
    • B03D2203/025Precious metal ores

Landscapes

  • Chemical & Material Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Hydrology & Water Resources (AREA)
  • Engineering & Computer Science (AREA)
  • Environmental & Geological Engineering (AREA)
  • Water Supply & Treatment (AREA)
  • Organic Chemistry (AREA)
  • Manufacture And Refinement Of Metals (AREA)
  • Physical Water Treatments (AREA)
  • Coloring Foods And Improving Nutritive Qualities (AREA)
  • Pharmaceuticals Containing Other Organic And Inorganic Compounds (AREA)
  • Medicines Containing Material From Animals Or Micro-Organisms (AREA)
AU2012326312A 2011-10-18 2012-10-17 Froth flotation processes Ceased AU2012326312B2 (en)

Applications Claiming Priority (3)

Application Number Priority Date Filing Date Title
US201161548408P 2011-10-18 2011-10-18
US61/548,408 2011-10-18
PCT/US2012/060526 WO2013059259A2 (en) 2011-10-18 2012-10-17 Froth flotation processes

Publications (2)

Publication Number Publication Date
AU2012326312A1 AU2012326312A1 (en) 2014-04-24
AU2012326312B2 true AU2012326312B2 (en) 2016-09-01

Family

ID=47089191

Family Applications (1)

Application Number Title Priority Date Filing Date
AU2012326312A Ceased AU2012326312B2 (en) 2011-10-18 2012-10-17 Froth flotation processes

Country Status (14)

Country Link
US (1) US9302272B2 (ru)
EP (1) EP2768618A2 (ru)
CN (1) CN104093492B (ru)
AP (1) AP2014007573A0 (ru)
AR (1) AR089652A1 (ru)
AU (1) AU2012326312B2 (ru)
BR (1) BR112014009562A2 (ru)
CA (1) CA2852681A1 (ru)
CL (1) CL2014000986A1 (ru)
EA (1) EA033798B1 (ru)
IN (1) IN2014CN02933A (ru)
MX (1) MX2014004714A (ru)
PE (2) PE20141471A1 (ru)
WO (1) WO2013059259A2 (ru)

Families Citing this family (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
SG10202103970YA (en) * 2016-10-20 2021-06-29 Newsouth Innovations Pty Ltd Method for removing heavy metals from an aqueous solution
US11612897B2 (en) 2017-05-24 2023-03-28 Basf Se Alkylated triphenyl phosphorothionates as selective metal sulphide collectors
CL2022000850A1 (es) * 2022-04-04 2022-10-21 Oxiquim S A Composiciones de xantatos iónicos estables en solución acuosa, útiles como colectores en el proceso de flotación por espuma y su proceso de preparación.

Citations (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US3203968A (en) * 1959-06-03 1965-08-31 Sebba Felix Ion flotation method
WO2008019451A1 (en) * 2006-08-17 2008-02-21 Ab Tall (Holdings) Pty Ltd Collectors and flotation methods
US20100021370A1 (en) * 2008-07-25 2010-01-28 Devarayasamudram Ramachandran Nagaraj Flotation Reagents and Flotation Processes Utilizing Same

Family Cites Families (74)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CA771181A (en) 1967-11-07 Du Pont Of Canada Limited Dithiocarbamate ore collector agents
CA808222A (en) 1969-03-11 Du Pont Of Canada Limited Ore flotation process and collector agents
US2134706A (en) 1931-02-24 1938-11-01 Peter C Reilly Process of flotation and agent therefor
US1949956A (en) 1931-03-02 1934-03-06 Peter C Reilly Ore flotation and flotation reagent
US2043192A (en) * 1934-05-09 1936-06-02 American Cyanamid Co Flotation reagent
US2074699A (en) 1934-06-02 1937-03-23 Du Pont Flotation process
US2063629A (en) 1935-02-19 1936-12-08 Du Pont Esters of the thio acids of phosphorus
US2267307A (en) 1936-12-17 1941-12-23 Armour & Co Concentrating ores
US2201535A (en) * 1937-08-07 1940-05-21 Benjamin R Harris Lipophilic-hydrophilic derivatives of thio compounds
US2185968A (en) 1937-11-01 1940-01-02 Armour & Co Process of concentrating ores and flotation agents therefor
US2120217A (en) * 1937-12-18 1938-06-07 Benjamin R Harris Ore flotation
US2221377A (en) * 1938-10-10 1940-11-12 Emulsol Corp Substituted ammonium salts of sulphocarboxylic acid esters
US2278020A (en) 1939-11-03 1942-03-31 Armour & Co Process of separating chalcocite ore
US2293470A (en) * 1940-03-07 1942-08-18 American Cyanamid Co Froth flotation of siliceous material
US2330587A (en) 1940-11-06 1943-09-28 American Cyanamid Co Flotation reagent and process
US2389718A (en) 1943-01-07 1945-11-27 American Cyanamid Co Disubstituted dithiophosphates
US2812332A (en) 1955-04-01 1957-11-05 Goodrich Co B F Quaternary ammonium xanthates
US2919025A (en) * 1956-04-04 1959-12-29 American Cyanamid Co Flotation reagent composition
US3103492A (en) 1958-07-30 1963-09-10 Lubricating composition
US2991430A (en) 1959-06-03 1961-07-04 Charles M Allred Automatic r-f level control
FR1352145A (fr) * 1961-10-03 1964-05-13 Armour & Co Procédé de flottation d'ions
US3214018A (en) * 1962-10-08 1965-10-26 Feldspar Corp Froth flotation of micaceous minerals
US3737458A (en) * 1963-03-13 1973-06-05 Exxon Product of alpha monolithiated amine and carbonyl compounds
SE302754B (ru) * 1963-12-06 1968-08-05 American Cyanamid Co
US3476553A (en) * 1965-02-10 1969-11-04 Armour & Co Precipitate flotation process
US3425550A (en) 1966-07-22 1969-02-04 Armour Ind Chem Co Flotation separation of metallic sulfide ores
US3671612A (en) 1968-04-05 1972-06-20 Knapsack Ag Process for the manufacture of ammonium dialkyldithiophosphates
GB1051269A (ru) * 1969-05-16
US3570772A (en) * 1969-08-22 1971-03-16 American Cyanamid Co Di(4-5 carbon branched primary alkyl) dithiophosphate promoters for the flotation of copper middlings
GB1295914A (ru) * 1970-01-16 1972-11-08
FI56216C (fi) 1971-03-25 1981-10-02 Tampella Oy Ab Siktanordning
GB1353976A (en) 1971-08-27 1974-05-22 Exxon Research Engineering Co Lubricating oil compositions
US3788467A (en) 1972-04-27 1974-01-29 American Cyanamid Co Flotation process for recovering molybdenum
US3845862A (en) 1973-01-04 1974-11-05 Continental Oil Co Concentration of oxide copper ores by flotation separation
US4040950A (en) 1974-08-01 1977-08-09 American Cyanamid Company Concentration of ore by flotation with solutions of aqueous dithiophosphates and thionocarbamate as collector
US3925218A (en) 1974-08-01 1975-12-09 American Cyanamid Co Concentration of ore by flotation with solutions of aqueous dithiophosphates and thionocarbamate as collector
US3971836A (en) 1974-08-16 1976-07-27 Minerec Corporation Amine-stabilized dialkyl dithiophosphates
US4036746A (en) 1974-08-16 1977-07-19 Minerec Corporation Flotation with amine-stabilized dialkyl dithiophosphates
US4022686A (en) * 1975-03-13 1977-05-10 Sumitomo Metal Mining Co., Limited Flotation process for copper ores and copper smelter slags
CA1062818A (en) 1976-01-30 1979-09-18 Reichel A.G. Tenbergen Flotation process
CA1105156A (en) 1978-10-11 1981-07-14 William A. Rickelton Flotation of sulfide minerals
US4215067A (en) * 1978-12-29 1980-07-29 Standard Oil Company (Indiana) Process for the preparation of zinc salts of dihydrocarbyldithiophosphoric acids
US4472288A (en) 1980-08-29 1984-09-18 Chevron Research Company Lubricant composition containing alkali metal borate and an oil-soluble amine salt of a phosphorus compound
US4530758A (en) 1982-05-17 1985-07-23 Thiotech, Inc. Ore flotation method
ZA832287B (en) 1982-05-17 1983-12-28 Thiotech Inc Ore flotation method
US4601818A (en) * 1983-03-30 1986-07-22 Phillips Petroleum Company Ore flotation
US4575431A (en) 1984-05-30 1986-03-11 Chevron Research Company Lubricant composition containing a mixture of neutralized phosphates
US4699712A (en) 1984-06-20 1987-10-13 Thiotech, Inc. Ore dressing method
US4584097A (en) * 1984-08-17 1986-04-22 American Cyanamid Company Neutral hydrocarboxycarbonyl thionocarbamate sulfide collectors
US4595493A (en) * 1984-08-17 1986-06-17 American Cyanamid Company Process for the flotation of base metal sulfide minerals in acid, neutral or mildly alkaline circuits
US4684459A (en) 1985-11-29 1987-08-04 The Dow Chemical Company Collector compositions for the froth flotation of mineral values
US4830739A (en) 1985-02-20 1989-05-16 Berol Kemi Ab Process and composition for the froth flotation beneficiation of iron minerals from iron ores
DE3517154A1 (de) 1985-05-11 1986-11-13 Henkel KGaA, 4000 Düsseldorf Verwendung von tensidgemischen als hilfsmittel fuer die flotation von nichtsulfidischen erzen
US4793852A (en) * 1985-10-28 1988-12-27 The Dow Chemical Company Process for the recovery of non-ferrous metal sulfides
US4853110A (en) * 1986-10-31 1989-08-01 Exxon Research And Engineering Company Method for separating arsenic and/or selenium from shale oil
CA1299777C (en) 1986-11-21 1992-04-28 Elias M. Klein Recovery of platinum-group metals and other metal valuables
EP0298392A3 (de) * 1987-07-07 1991-01-09 Henkel Kommanditgesellschaft auf Aktien Verfahren zur Gewinnung von Mineralen aus sulfidischen aus Erzen durch Flotation und Mittel zu seiner Durchführung
US4879022A (en) * 1987-07-14 1989-11-07 The Lubrizol Corporation Ore flotation process and use of mixed hydrocarbyl dithiophosphoric acids and salts thereof
EP0368956A4 (en) * 1988-04-25 1990-09-26 National Starch And Chemical Corporation Quaternary ammonium dithiocarbamate compounds
US5147572A (en) 1990-06-15 1992-09-15 The Lubrizol Corporation Flotation composition using a mixture of collectors
MX9602812A (es) * 1994-01-18 1997-06-28 Du Pont Sales de amonio polimericas, reticuladas.
GB9403604D0 (en) * 1994-02-25 1994-04-13 Exxon Chemical Patents Inc Manufacture of dihydrocarbyl dithiophosphates
US5929408A (en) * 1996-09-26 1999-07-27 Cytec Technology Corp. Compositions and methods for ore beneficiation
MY125825A (en) 1998-08-20 2006-08-30 Shell Int Research Lubricating oil composition useful in hydraulic fluids
JP4565529B2 (ja) 2000-03-08 2010-10-20 ミヨシ油脂株式会社 金属捕集剤
JP2003064347A (ja) 2001-08-24 2003-03-05 Sanken:Kk 有害金属捕捉剤
JP2005513259A (ja) 2001-12-12 2005-05-12 ウラジミール・ラジク 優先浮選剤および浮遊選鉱方法
US6820746B2 (en) 2002-10-15 2004-11-23 Cytec Technology Corp. Process for the beneficiation of sulfide minerals
US6732867B2 (en) 2002-10-15 2004-05-11 Cytec Technology Corp. Beneficiation of sulfide minerals
JP2004217797A (ja) 2003-01-15 2004-08-05 Ethyl Japan Kk 長寿命で熱安定性に優れたギア油組成物
US7299930B2 (en) 2003-11-27 2007-11-27 Procesos Mineros E Industries Conosur S.A. Collecting agent comprising ammoniated compounds (primary, secondary, tertiary amines), for use in the process of grinding and/or floating copper, molybdenum, zinc, and other contained mineral ores
PT2117718T (pt) * 2007-02-07 2017-08-16 Cytec Tech Corp Novos coletores de ditiocarbamato e seu uso na beneficiação de corpos minerais metálicos
CN101816981B (zh) * 2010-03-16 2012-12-19 武汉理工大学 一种环境友好型胺类阳离子捕收剂及其使用方法
CN102502905A (zh) * 2011-11-15 2012-06-20 沈阳创达技术交易市场有限公司 污水处理药剂

Patent Citations (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US3203968A (en) * 1959-06-03 1965-08-31 Sebba Felix Ion flotation method
WO2008019451A1 (en) * 2006-08-17 2008-02-21 Ab Tall (Holdings) Pty Ltd Collectors and flotation methods
US20100021370A1 (en) * 2008-07-25 2010-01-28 Devarayasamudram Ramachandran Nagaraj Flotation Reagents and Flotation Processes Utilizing Same

Also Published As

Publication number Publication date
MX2014004714A (es) 2014-09-25
WO2013059259A2 (en) 2013-04-25
WO2013059259A3 (en) 2013-11-28
EA033798B1 (ru) 2019-11-26
AR089652A1 (es) 2014-09-10
EA201490816A1 (ru) 2014-08-29
CN104093492B (zh) 2017-05-10
PE20190646A1 (es) 2019-05-06
US20130092604A1 (en) 2013-04-18
AP2014007573A0 (en) 2014-04-30
BR112014009562A2 (pt) 2017-06-13
AU2012326312A1 (en) 2014-04-24
IN2014CN02933A (ru) 2015-07-03
CL2014000986A1 (es) 2014-09-05
US9302272B2 (en) 2016-04-05
PE20141471A1 (es) 2014-10-17
EP2768618A2 (en) 2014-08-27
CA2852681A1 (en) 2013-04-25
CN104093492A (zh) 2014-10-08

Similar Documents

Publication Publication Date Title
US9302274B2 (en) Collector compositions and methods of using the same
AU2012326313B2 (en) Froth flotation processes
US10478829B2 (en) Collector compositions and methods of using same in mineral flotation processes
AU2016204138B2 (en) Sulfide flotation aid
AU2013293041B2 (en) Monothiophosphate containing collectors and methods
AU2012326312B2 (en) Froth flotation processes
US6820746B2 (en) Process for the beneficiation of sulfide minerals
CA2501079C (en) Process for the beneficiation of sulfide minerals
CA1216975A (en) Flotation reagents
RU2705280C1 (ru) Способ флотационного отделения сфалерита и минералов меди от сульфидов железа

Legal Events

Date Code Title Description
FGA Letters patent sealed or granted (standard patent)
MK14 Patent ceased section 143(a) (annual fees not paid) or expired