AU2007320604B2 - Air conditioning apparatus - Google Patents

Air conditioning apparatus Download PDF

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Publication number
AU2007320604B2
AU2007320604B2 AU2007320604A AU2007320604A AU2007320604B2 AU 2007320604 B2 AU2007320604 B2 AU 2007320604B2 AU 2007320604 A AU2007320604 A AU 2007320604A AU 2007320604 A AU2007320604 A AU 2007320604A AU 2007320604 B2 AU2007320604 B2 AU 2007320604B2
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AU
Australia
Prior art keywords
refrigerant
heat exchanger
subcooling
outdoor
indoor
Prior art date
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Application number
AU2007320604A
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AU2007320604B9 (en
AU2007320604A1 (en
Inventor
Takayuki Setoguchi
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Daikin Industries Ltd
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Daikin Industries Ltd
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Publication of AU2007320604B9 publication Critical patent/AU2007320604B9/en
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Classifications

    • FMECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F25REFRIGERATION OR COOLING; COMBINED HEATING AND REFRIGERATION SYSTEMS; HEAT PUMP SYSTEMS; MANUFACTURE OR STORAGE OF ICE; LIQUEFACTION SOLIDIFICATION OF GASES
    • F25BREFRIGERATION MACHINES, PLANTS OR SYSTEMS; COMBINED HEATING AND REFRIGERATION SYSTEMS; HEAT PUMP SYSTEMS
    • F25B1/00Compression machines, plants or systems with non-reversible cycle
    • FMECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F25REFRIGERATION OR COOLING; COMBINED HEATING AND REFRIGERATION SYSTEMS; HEAT PUMP SYSTEMS; MANUFACTURE OR STORAGE OF ICE; LIQUEFACTION SOLIDIFICATION OF GASES
    • F25BREFRIGERATION MACHINES, PLANTS OR SYSTEMS; COMBINED HEATING AND REFRIGERATION SYSTEMS; HEAT PUMP SYSTEMS
    • F25B9/00Compression machines, plants or systems, in which the refrigerant is air or other gas of low boiling point
    • F25B9/002Compression machines, plants or systems, in which the refrigerant is air or other gas of low boiling point characterised by the refrigerant
    • F25B9/008Compression machines, plants or systems, in which the refrigerant is air or other gas of low boiling point characterised by the refrigerant the refrigerant being carbon dioxide
    • FMECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F25REFRIGERATION OR COOLING; COMBINED HEATING AND REFRIGERATION SYSTEMS; HEAT PUMP SYSTEMS; MANUFACTURE OR STORAGE OF ICE; LIQUEFACTION SOLIDIFICATION OF GASES
    • F25BREFRIGERATION MACHINES, PLANTS OR SYSTEMS; COMBINED HEATING AND REFRIGERATION SYSTEMS; HEAT PUMP SYSTEMS
    • F25B40/00Subcoolers, desuperheaters or superheaters
    • F25B40/02Subcoolers
    • FMECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F25REFRIGERATION OR COOLING; COMBINED HEATING AND REFRIGERATION SYSTEMS; HEAT PUMP SYSTEMS; MANUFACTURE OR STORAGE OF ICE; LIQUEFACTION SOLIDIFICATION OF GASES
    • F25BREFRIGERATION MACHINES, PLANTS OR SYSTEMS; COMBINED HEATING AND REFRIGERATION SYSTEMS; HEAT PUMP SYSTEMS
    • F25B49/00Arrangement or mounting of control or safety devices
    • F25B49/02Arrangement or mounting of control or safety devices for compression type machines, plants or systems
    • FMECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F25REFRIGERATION OR COOLING; COMBINED HEATING AND REFRIGERATION SYSTEMS; HEAT PUMP SYSTEMS; MANUFACTURE OR STORAGE OF ICE; LIQUEFACTION SOLIDIFICATION OF GASES
    • F25BREFRIGERATION MACHINES, PLANTS OR SYSTEMS; COMBINED HEATING AND REFRIGERATION SYSTEMS; HEAT PUMP SYSTEMS
    • F25B13/00Compression machines, plants or systems, with reversible cycle
    • FMECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F25REFRIGERATION OR COOLING; COMBINED HEATING AND REFRIGERATION SYSTEMS; HEAT PUMP SYSTEMS; MANUFACTURE OR STORAGE OF ICE; LIQUEFACTION SOLIDIFICATION OF GASES
    • F25BREFRIGERATION MACHINES, PLANTS OR SYSTEMS; COMBINED HEATING AND REFRIGERATION SYSTEMS; HEAT PUMP SYSTEMS
    • F25B2309/00Gas cycle refrigeration machines
    • F25B2309/06Compression machines, plants or systems characterised by the refrigerant being carbon dioxide
    • F25B2309/061Compression machines, plants or systems characterised by the refrigerant being carbon dioxide with cycle highest pressure above the supercritical pressure
    • FMECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F25REFRIGERATION OR COOLING; COMBINED HEATING AND REFRIGERATION SYSTEMS; HEAT PUMP SYSTEMS; MANUFACTURE OR STORAGE OF ICE; LIQUEFACTION SOLIDIFICATION OF GASES
    • F25BREFRIGERATION MACHINES, PLANTS OR SYSTEMS; COMBINED HEATING AND REFRIGERATION SYSTEMS; HEAT PUMP SYSTEMS
    • F25B2400/00General features or devices for refrigeration machines, plants or systems, combined heating and refrigeration systems or heat-pump systems, i.e. not limited to a particular subgroup of F25B
    • F25B2400/16Receivers
    • FMECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F25REFRIGERATION OR COOLING; COMBINED HEATING AND REFRIGERATION SYSTEMS; HEAT PUMP SYSTEMS; MANUFACTURE OR STORAGE OF ICE; LIQUEFACTION SOLIDIFICATION OF GASES
    • F25BREFRIGERATION MACHINES, PLANTS OR SYSTEMS; COMBINED HEATING AND REFRIGERATION SYSTEMS; HEAT PUMP SYSTEMS
    • F25B2600/00Control issues
    • F25B2600/17Control issues by controlling the pressure of the condenser
    • FMECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F25REFRIGERATION OR COOLING; COMBINED HEATING AND REFRIGERATION SYSTEMS; HEAT PUMP SYSTEMS; MANUFACTURE OR STORAGE OF ICE; LIQUEFACTION SOLIDIFICATION OF GASES
    • F25BREFRIGERATION MACHINES, PLANTS OR SYSTEMS; COMBINED HEATING AND REFRIGERATION SYSTEMS; HEAT PUMP SYSTEMS
    • F25B2600/00Control issues
    • F25B2600/25Control of valves
    • F25B2600/2513Expansion valves

Description

AIR CONDITIONING APPARATUS TECHNICAL FIELD The present invention relates to an air conditioning apparatus using supercritical refrigerant operating in the supercritical zone, and, at least in its preferred form(s), to an air conditioning 5 apparatus for easily regulating refrigeration performance. BACKGROUND ART A conventionally known refrigeration apparatus is configured to execute a vapor-compression refrigeration cycle by means of refrigerant circulation. The refrigeration apparatus of this type has been widely used as an air conditioning apparatus and the like. For [0 example, Patent Document 1 exemplifies a refrigeration apparatus of this type. The refrigeration apparatus is configured to execute a so-called supercritical refrigeration cycle. In the supercritical refrigeration cycle, carbon dioxide (CO 2 ) is used as refrigerant, and the high pressure of CO 2 in the refrigeration cycle is set to be equal to or greater than the critical pressure of CO 2 . <Patent Document 1> L5 Japanese Laid-open Patent Application No. JP-A-H 10-54617 According to the refrigeration apparatus using supercritical refrigerant (e.g., CO 2 refrigerant), however, refrigerant is not in a liquid state but in a supercritical state under the high pressure. This makes it difficult to store the refrigerant even if the refrigeration apparatus is provided with a receiver. Accordingly, a function for regulating the evaporation amount of refrigerant does not work well, and O performance control and COP optimum control do not appropriately function. Any discussion of documents, acts, materials, devices, articles or the like which has been included in the present specification is solely for the purpose of providing a context for the present invention. It is not to be taken as an admission that any or all of these matters form part of the prior art base or were common general knowledge in the field relevant to the present invention as it existed 25 before the priority date of each claim of this application. SUMMARY OF THE INVENTION Throughout this specification the word "comprise", or variations such as "comprises" or "comprising", will be understood to imply the inclusion of a stated element, integer or step, or group of elements, integers or steps, but not the exclusion of any other element, integer or step, or group of 30 elements, integers or steps. A first aspect of the present invention provides a refrigeration apparatus using refrigerant operating in the supercritical zone, comprising: a compressor configured to compress the refrigerant; a first heat exchanger configured to cool the high pressure refrigerant compressed by the 1 compressor; a first expansion mechanism configured to decompress the refrigerant to critical pressure or less; a subcooling heat exchanger adapted to function as a subcooler and an evaporator and 5 configured to subcool the refrigerant decompressed by the first expansion mechanism; a second expansion mechanism configured to decompress the refrigerant cooled by the subcooling heat exchanger to low pressure; a second heat exchanger configured to heat the refrigerant decompressed by the second expansion mechanism; and LO a control section configured to conduct first control to regulate the first and second expansion mechanisms for storing the refrigerant of a liquid state in the subcooling heat exchanger. The subcooling heat exchanger is preferably provided in the outlet side of the first heat exchanger functioning as a gas cooler. Moreover, the first expansion mechanism for decompressing the refrigerant to the critical pressure or less is preferably provided between the first heat exchanger .5 and the subcooling heat exchanger. In preferred embodiments, the refrigeration apparatus is capable of controlling degree of opening of the first expansion mechanism and regulating intermediate pressure of the refrigerant. Accordingly, the refrigeration apparatus is capable of storing the liquid refrigerant in the subcooling heat exchanger and regulating the amount of the refrigerant. Consequently, the refrigeration !0 apparatus is capable of optimally controlling the high pressure of the refrigerant and executing an efficient operation. The refrigeration apparatus preferably further includes subcooling information obtaining means. The subcooling information obtaining means is preferably capable of obtaining subcooling information used for calculating degree of subcooling of the refrigerant in the subcooling heat 25 exchanger. Furthermore, the control section is preferably configured to calculate the degree of subcooling based on the subcooling information. The first control is preferably conducted based on the degree of subcooling. In preferred embodiments, the refrigeration apparatus is capable of controlling the first and second expansion mechanisms for both setting the refrigerant to be in a subcooling state in the 30 subcooling heat exchanger and setting the refrigerant to be in a liquid state in the subcooling heat exchanger. Consequently, the refrigeration apparatus is capable of regulating the amount of the refrigerant. The subcooling information obtaining means is preferably composed of an inlet temperature sensor and an outlet temperature sensor. The inlet temperature sensor is preferably capable of 2 detecting refrigerant inlet temperature in the subcooling heat exchanger. The outlet temperature sensor is preferably capable of detecting refrigerant outlet temperature in the subcooling heat exchanger. In preferred embodiments, the inlet temperature sensor detects the inlet temperature of the 5 subcooling heat exchanger whereas the outlet temperature sensor detects the outlet temperature of the subcooling heat exchanger. Temperature detected by the inlet temperature sensor is equal to the saturated liquid temperature because the refrigerant is in a gas-liquid two-phase state. Accordingly, in such embodiments, the refrigeration apparatus is capable of calculating the degree of subcooling based on the obtained saturated liquid temperature and the obtained outlet temperature. LO The subcooling information obtaining means is preferably composed of an inlet pressure sensor and an outlet temperature sensor. The inlet pressure sensor is preferably capable of detecting refrigerant inlet pressure of the subcooling heat exchanger. The outlet temperature sensor is preferably capable of detecting refrigerant outlet temperature of the subcooling heat exchanger. In preferred embodiments, the inlet pressure sensor detects the inlet pressure of the [5 subcooling heat exchanger whereas the outlet temperature sensor detects the outlet temperature of the subcooling heat exchanger. Accordingly, in such embodiments, the refrigeration apparatus is capable of calculating the saturated liquid temperature based on the detected inlet pressure, and is capable of calculating the degree of subcooling based on the saturated liquid temperature and the outlet temperature. O0 In a second aspect, the present invention provides a refrigeration apparatus using refrigerant operating in the supercritical zone, comprising: a compressor configured to compress the refrigerant; a first heat exchanger configured to conduct heat exchange of the refrigerant; a first expansion mechanism configured to decompress the refrigerant; 25 a subcooling heat exchanger adapted to function as a subcooler and an evaporator and configured to subcool the refrigerant; a second expansion mechanism configured to decompress the refrigerant; a second heat exchanger configured to conduct heat exchange of the refrigerant; a switch mechanism configured to be capable of switching between a first condition and a 30 second condition, the first condition causing the refrigerant evaporated in the second heat 3 exchanger to flow into the compressor and causing the refrigerant compressed in the compressor to flow into the first heat exchanger, the second condition causing the refrigerant evaporated in the first heat exchanger to flow into the compressor and causing the refrigerant compressed in the 5 compressor to flow into the second heat exchanger; and a control section configured to conduct first control and second control, the first control being configured to cause the first expansion mechanism to decompress the refrigerant from high pressure to intermediate pressure equal to or less than the supercritical pressure and cause the second expansion mechanism to 0 decompress the intermediate pressure refrigerant subcooled by the subcooling heat exchanger to low pressure for storing the refrigerant of a liquid state in the subcooling heat exchanger in the first condition switched by the switch mechanism, and the second control being configured to cause the second expansion mechanism to decompress 5 the refrigerant from high pressure to the intermediate pressure equal to or less than the supercritical pressure and cause the first expansion mechanism to decompress the intermediate pressure refrigerant subcooled by the subcooling heat exchanger to low pressure for storing the refrigerant of a liquid state in the subcooling heat exchanger in the second condition switched by the switch mechanism. 0 In preferred embodiments, the switch mechanism is capable of switching between the first condition for causing the first heat exchanger to function as a gas cooler and for causing the second heat exchanger to function as an evaporator and the second condition for causing the first heat exchanger to function as an evaporator and for causing the second heat exchanger to function as a gas cooler. When the first heat exchanger functions as a gas 25 cooler, the subcooling heat exchanger is preferably further provided in the refrigerant outlet side of the first heat exchanger. Additionally, the first expansion mechanism for decompressing the refrigerant to the critical pressure or less is further preferably provided between the first heat exchanger and the subcooling heat exchanger. On the other hand, when the second heat exchanger functions as a gas cooler, the subcooling heat exchanger is 30 preferably connected to the refrigerant outlet side of the second heat exchanger. Additionally, the second expansion mechanism for decompressing the refrigerant to the critical pressure or less is further preferably provided between the second heat exchanger and the subcooling heat exchanger. In preferred embodiments, the refrigeration apparatus is capable of regulating the
A
intermediate pressure of the refrigerant by controlling the degree of opening of the first expansion mechanism in the cooling operation whereas it is capable of regulating the intermediate pressure of the refrigerant by controlling the degree of opening of the third expansion mechanism in the heating operation. Accordingly, in such embodiments, the 5 refrigeration apparatus is capable of regulating the amount of the refrigerant by storing the liquid refrigerant into the outdoor subcooling heat exchanger (e.g., in the cooling operation) or the indoor subcooling heat exchanger (e.g., in the heating operation). Consequently, in such embodiments, the refrigeration apparatus is capable of optimally controlling the high pressure of the refrigerant. 0 The refrigeration apparatus preferably further includes subcooling information obtaining means. The subcooling information obtaining means is preferably capable of obtaining subcooling information used for calculating the degree of subcooling of the refrigerant in the subcooling heat exchanger. The control section is preferably configured to calculate the degree of subcooling based on the subcooling information. The first control or 5 the second control is preferably conducted based on the degree of subcooling. In preferred embodiments, the the subcooling information obtaining means is capable of obtaining the subcooling information, and the control section is configured to conduct the first control or the second control based on the degree of subcooling calculated based on the subcooling information. Accordingly, in such embodiments, the refrigeration 0 apparatus is capable of controlling the first and second expansion mechanisms for setting the refrigerant to be in a subcooling state in the subcooling heat exchanger and for setting the refrigerant to be in a liquid state in the subcooling heat exchanger. Consequently, in such embodiments, the refrigeration apparatus is capable of regulating the amount of the refrigerant. 25 In a third aspect, the present invention provides a refrigeration apparatus using refrigerant operating in the supercritical zone, comprising: a heat source unit including; a compressor configured to compress the refrigerant; a heat source side heat exchanger configured to conduct heat exchange 30 between the refrigerant and first fluid; a first expansion mechanism capable of decompressing the refrigerant; a heat source side auxiliary heat exchanger configured to conduct heat exchange of the refrigerant; a second expansion mechanism capable of decompressing the refrigerant; and a switch mechanism capable of switching between a first condition and a second condition, the first condition causing the refrigerant to flow into the 5 compressor after a utilization side heat exchanger conducts the heat exchange of the refrigerant and causing the refrigerant compressed by the compressor to flow into the heat source side heat exchanger, the second condition causing the refrigerant to flow into the compressor after the heat source side heat exchanger conducts the heat 0 exchange of the refrigerant and causing the refrigerant compressed by the compressor to flow into the utilization side heat exchanger; a utilization unit including the utilization side heat exchanger configured to conduct heat exchange of the refrigerant, a third expansion mechanism capable of decompressing the refrigerant, and a utilization side auxiliary heat exchanger configured to 5 conduct heat exchange of the refrigerant; and a control section configured to conduct first control, second control and third control, the first control being configured to cause the heat source side auxiliary heat exchanger to function as a subcooler and regulate the first 0 and second expansion mechanisms for storing the refrigerant of a liquid state in the heat source side auxiliary heat exchanger when temperature of the first fluid is less than the critical temperature of the refrigerant in the first condition switched by the switch mechanism, the second control being configured to cause the utilization side 25 auxiliary heat exchanger to function as a subcooler and regulate the second and third expansion mechanisms for storing the refrigerant of a liquid state in the utilization side auxiliary heat exchanger when temperature of the first fluid is equal to or greater than the critical temperature of the refrigerant in the first condition switched by the switch mechanism, and 30 the third control being configured to cause the utilization side auxiliary heat exchanger to function as a subcooler and regulate the second and third expansion mechanisms for storing the refrigerant of a liquid state in the utilization side auxiliary heat exchanger in the second condition switched by the switch mechanism. The heat source unit preferably further includes a switch mechanism (e.g., a four-way switch valve) capable of switching between a first condition and a second condition. Furthermore, the control section is preferably configured to control the first and second expansion mechanisms in the first condition switched by the switch mechanism (e.g., in the cooling operation). On the other hand, the control section is preferably configured to 5 control the second and third expansion mechanisms in the second condition switched by the switch mechanism (e.g., in the heating operation). The control section is preferably configured to conduct the third control for controlling the second and third expansion mechanisms for storing the liquid refrigerant in the utilization side subcooling heat exchanger not in the heat source side subcooling heat exchanger, for example, when the external 0 temperature is equal to or greater than the critical temperature of the refrigerant in the cooling operation. In preferred embodiments, the control section is capable of regulating the intermediate pressure of the refrigerant by controlling the first expansion mechanism in the cooling operation whereas it is capable of regulating the intermediate pressure of the 5 refrigerant by controlling the third expansion mechanism in the heating operation. Furthermore, in preferred embodiments, the control section is capable of regulating the amount of the liquid refrigerant in the heat source side subcooling heat exchanger in the cooling operation by controlling the second expansion mechanism whereas it is capable of regulating the amount of the liquid refrigerant in the utilization side subcooling heat 0 exchanger in the heating operation by controlling the second expansion mechanism. In preferred embodiments, when the refrigerant exceeds the critical point, it enters a supercritical state and thus control of the amount of the refrigerant will be difficult. Thus, it is difficult to store the refrigerant in the heat source side subcooling heat exchanger when temperature of the first fluid is equal to or greater than the critical temperature. In preferred 25 embodiments, the utilization side heat exchanger functions as an evaporator. Accordingly, temperature of the second fluid is often equal to or less than the critical temperature. It is therefore possible to store the liquid refrigerant in the utilization side subcooling heat exchanger by the control section conducting the third control for controlling the second and third expansion mechanisms. 30 The heat source unit preferably further includes heat source side subcooling information obtaining means. The heat source side subcooling information obtaining means is preferably capable of detecting first subcooling degree of the heat source side auxiliary heat exchanger. The utilization unit preferably further includes utilization side subcooling information obtaining means. The utilization side subcooling information obtaining means is preferably capable of detecting second subcooling degree of the utilization side auxiliary heat exchanger. The first control is preferably conducted based on the first subcooling degree. The second and third controls are preferably conducted based on the second subcooling degree. 5 In preferred embodiments, the heat source unit further includes second inlet pressure detection means and second outlet temperature detection means in the refrigerant inlet and the refrigerant outlet of the heat source side subcooling heat exchanger, respectively, for detecting the degree of subcooling. With the both detection means, it is possible to obtain second inlet pressure (i.e., intermediate pressure) and second outlet temperature. In such 0 embodiments, the control section is capable of calculating the degree of subcooling based on the second inlet pressure and the second outlet temperature. Consequently, the control section is capable of regulating the amount of the refrigerant by storing the liquid refrigerant in the first subcooling heat exchanger based on the degree of subcooling. The heat source side subcooling information obtaining means is preferably 5 composed of a first inlet temperature sensor and a first outlet temperature sensor. The first inlet temperature sensor is preferably capable of detecting refrigerant inlet temperature of the heat source side auxiliary heat exchanger. On the other hand, the first outlet temperature sensor is preferably capable of detecting refrigerant outlet temperature of the heat source side auxiliary heat exchanger. 0 In preferred embodiments, the first inlet temperature sensor and the first outlet temperature sensor are used in the refrigerant inlet and the refrigerant outlet of the heat source side auxiliary heat exchanger, respectively, as the heat source side subcooling information obtaining means. In such embodiments, the first inlet temperature sensor is capable of detecting the saturated liquid temperature of the refrigerant. Furthermore, it is 25 possible to calculate the first subcooling degree based on the saturated liquid temperature and the refrigerant outlet temperature detected by the first outlet temperature sensor. The utilization side subcooling information obtaining means is preferably composed of a second inlet temperature sensor and a second outlet temperature sensor. The second inlet temperature sensor is preferably capable of detecting refrigerant inlet temperature of the 30 utilization side auxiliary heat exchanger. The second outlet temperature sensor is preferably capable of detecting refrigerant outlet temperature of the utilization side auxiliary heat exchanger. In preferred embodiments, the second inlet temperature sensor and the second outlet temperature sensor are used in the refrigerant inlet and the refrigerant outlet of the utilization 0 side auxiliary heat exchanger, respectively, as the utilization side subcooling information obtaining means. In such embodiments, the second inlet temperature sensor is capable of detecting the saturated liquid temperature of the refrigerant. Furthermore, it is possible to calculate the second subcooling degree based on the saturated liquid temperature and the 5 refrigerant outlet temperature detected by the second outlet temperature sensor. Thehe refrigerant is preferably carbon dioxide (C0 2 ) refrigerant. An advantage of using CO 2 refrigerant is that the global warming potential (GWP) value of CO 2 refrigerant equals "1". This is much smaller than the GWP value of conventional refrigerant. For example, the GWP value of the fluorocarbon refrigerant is approximately hundreds to ten 0 thousand. Therefore, use of the CO 2 refrigerant is less burdening the environment and makes it possible to inhibit worsening of the global environment. In preferred embodiments, it is possible to control the degree of opening of the first expansion mechanism and regulate the intermediate pressure of the refrigerant. Accordingly, in such embodiments, the refrigeration apparatus is capable of storing the liquid refrigerant in 5 the subcooling heat exchanger, and is capable of regulating the amount of the refrigerant. Consequently, the refrigeration apparatus is capable of optimally controlling the high pressure of the refrigerant, and is capable of conducting an efficient operation. In preferred embodiments, it is possible to control the first and second expansion mechanisms for setting the refrigerant to be in a subcooling state in the subcooling heat 9 exchanger and for setting the refrigerant to be in a liquid state in the subcooling heat exchanger. Therefore, in such embodiments, the refrigeration apparatus is capable of regulating the amount of the refrigerant. In preferred embodiments, it is possible to calculate the subcooling degree based on the obtained saturated liquid temperature and the obtained outlet temperature. 25 In preferred embodiments, it is possible to calculate the saturated liquid temperature based on the detected inlet pressure. Furthermore, it is possible to calculate degree of subcooling based on the saturated liquid temperature and the outlet temperature. In preferred embodiments, it is possible to regulate the intermediate pressure of the refrigerant by controlling the degree of opening of the first expansion mechanism in the 30 cooling operation whereas it is possible to regulate the intermediate pressure of the refrigerant by controlling the degree of opening of the third expansion mechanism in the heating operation. Accordingly, in such embodiments, the refrigeration apparatus is capable of regulating the amount of the refrigerant by storing the liquid refrigerant in the outdoor subcooling heat exchanger (e.g., in the cooling operation) or the indoor subcooling heat
Q
exchanger (e.g., in the heating operation). Consequently, the refrigeration apparatus is capable of optimally controlling the high pressure of the refrigerant. In preferred embodiments, it is possible to control the first and second expansion mechanisms for setting the refrigerant to be in a subcooling state in the subcooling heat 5 exchanger and for setting the refrigerant to be in a liquid state in the subcooling heat exchanger. Accordingly, in such embodiments, the refrigeration apparatus is capable of regulating the amount of the refrigerant. In preferred embodiments, the control section is capable of regulating the intermediate pressure of the refrigerant by controlling the first expansion mechanism in the 0 cooling operation whereas it is capable of regulating the intermediate pressure of the refrigerant by controlling the third expansion mechanism in the heating operation. Furthermore, the control section is capable of regulating the amount of the liquid refrigerant of the heat source side subcooling heat exchanger in the cooling operation by controlling the second expansion mechanism whereas it is capable of regulating the amount of the liquid 5 refrigerant of the utilization side subcooling heat exchanger in the heating operation by controlling the second expansion mechanism. When the refrigerant exceeds the critical point, it enters a supercritical state and control of the amount of the refrigerant will be difficult. Accordingly, when temperature of the first fluid is equal to or greater than the critical temperature, it is difficult to store the refrigerant in the heat source side subcooling D heat exchanger. On the other hand, temperature of the second fluid is often equal to or less than the critical temperature because the utilization side heat exchanger functions as an evaporator. Therefore, the third control of the second and third expansion mechanisms by the control section makes it possible to store the liquid refrigerant in the utilization side subcooling heat exchanger. ?5 In preferred embodiments, the control section is capable of calculating degree of subcooling based on the second inlet pressure and the second outlet temperature. Therefore, the control section is capable of regulating the amount of the refrigerant by storing the liquid refrigerant in the first subcooling heat exchanger based on degree of subcooling. In preferred embodiments, the first inlet temperature sensor is capable of detecting 30 the saturated liquid temperature of the refrigerant. Furthermore, it is possible to calculate the first subcooling degree based on the saturated liquid temperature and the refrigerant outlet temperature detected by the first outlet temperature sensor. In preferred embodiments, the second inlet temperature sensor is capable of detecting the saturated liquid temperature of the refrigerant. Furthermore, it is possible to 1A calculate the second subcooling degree based on the saturated liquid temperature and the refrigerant outlet temperature detected by the second outlet temperature sensor. In preferred embodiments, use of the CO 2 refrigerant provides for less burdening of the environment and makes it possible to inhibit worsening of the global environment. 5 Preferred embodiments of the present invention preferably provide for easily regulating the circulation amount of refrigerant in an air conditioning apparatus using supercritical refrigerant. BRIEF DESCRIPTION OF THE DRAWINGS Preferred embodiments will now be described, by way of example only, with 0 reference to the accompanying drawings, in which: Fig. I is a diagram illustrating a refrigerant circuit of an air conditioning apparatus according to an embodiment of the present invention; Fig. 2 is a P-H chart for showing a two-stage expansion refrigeration cycle with CO 2 refrigerant in a preferred embodiment of an air conditioning apparatus according to the 5 present invention; Fig. 3 is a refrigerant circuit diagram of an air conditioning apparatus according to Modification (1); Fig. 4 is a refrigerant circuit diagram of an air conditioning apparatus exclusively used for a cooling operation according to Modification (5); 0 Fig. 5 is a refrigerant circuit diagram of an air conditioning apparatus exclusively used for a heating operation according to Modification (5); and Fig. 6 is a refrigerant circuit diagram of an air conditioning apparatus according to Modification (6). EXPLANATION OF THE REFERENCE NUMERALS ?5 1, la-ld air conditioning apparatus 2, 2a, 2b outdoor unit (heat source unit) 3, 3a-3c, 3d indoor unit (utilization unit) 21 compressor 23 outdoor heat exchanger (first heat exchanger, heat source side heat exchanger) 30 24 outdoor subcooling heat exchanger (subcooling heat exchanger, heat source side auxiliary heat exchanger) 31, 31a-31c indoor heat exchanger (second heat exchanger, utilization side heat exchanger) 32, 32a-32c indoor subcooling heat exchanger (utilization side auxiliary heat exchanger) 11 T I first outdoor subcooling temperature sensor (first inlet temperature sensor) T2 second outdoor subcooling temperature sensor (first outlet temperature sensor) TI first indoor subcooling temperature sensor (second inlet temperature sensor, second outlet temperature sensor) 5 T2 second indoor subcooling temperature sensor (second inlet temperature sensor, second outlet temperature sensor) V I four-way switch valve (switch mechanism) V2 first outdoor expansion valve (first expansion mechanism) V3 second outdoor expansion valve (second expansion mechanism) 0 V6, V6a-V6c indoor expansion valve (third expansion mechanism) PREFERRED EMBODIMENTS OF THE INVENTION <Structure of Air Conditioning Apparatus> Fig. 1 is a schematic configuration diagram of an air conditioning apparatus 1 according to an embodiment of the present invention. The air conditioning apparatus I is an 5 apparatus used for cooling and heating the indoor space of a building and the like by conducting a two-stage expansion refrigeration cycle operation. Carbon dioxide (C0 2 ) refrigerant (i.e., supercritical refrigerant) is used. The air conditioning apparatus 1 mainly includes an outdoor unit 2, an indoor unit 3 and a refrigerant communication pipe 4. The outdoor unit 2 functions as a heat source unit. The indoor unit 3 is connected to the outdoor o unit 2, and functions as a utilization unit. The refrigerant communication pipe 4 connects the outdoor unit 2 and the indoor unit 3. The refrigerant communication pipe 4 is composed of a liquid refrigerant communication pipe 41 and a gas refrigerant communication pipe 42. In other words, a refrigerant circuit 10 of the air conditioning apparatus I according to the present embodiment is formed by the interconnection among the outdoor unit 2, the indoor ,5 unit 3 and the refrigerant communication pipe 4. (1) Outdoor Unit The outdoor unit 2 is disposed outside a building and the like. The outdoor unit 2 is connected to the indoor unit 3 through the refrigerant communication pipe 4. The outdoor unit 2 forms a part of the refrigerant circuit 10. 10 Next, structure of the outdoor unit 2 will be explained. The outdoor unit 2 mainly includes an outdoor side refrigerant circuit 20. The outdoor side refrigerant circuit 20 forms a part of the refrigerant circuit 10. The outdoor side refrigerant circuit 20 mainly includes a compressor 21, a four-way switch valve VI, an outdoor heat exchanger 23 functioning as a heat source side heat exchanger, a first outdoor expansion valve V2 functioning as an in expansion mechanism, an outdoor subcooling heat exchanger 24 functioning as a heat source side subcooling heat exchanger, a second outdoor expansion valve V3 functioning as an expansion mechanism, a liquid side stop valve V4 and a gas side stop valve V5. The compressor 21 is a compressor capable of changing its operation capacity. In 5 the present embodiment, the compressor 21 is a positive-displacement compressor to be driven by a motor 22. Here, rotation speed Rm of the motor 22 is controlled by an inverter. Note that only single compressor 21 is provided in the present embodiment. However, the number of the compressor 21 is not limited to this. For example, two or more compressors may be parallel-connected depending on the number of indoor units to be connected to the 0 outdoor unit 2 or the like. The four-way switch valve VI is a valve provided for causing the outdoor heat exchanger 23 to function as a gas cooler and an evaporator. The four-way switch valve VI is connected to the outdoor heat exchanger 23, the suction side of the compressor 21, the discharge side of the compressor 21 and the gas refrigerant communication pipe 42. When 5 the outdoor heat exchanger 23 is caused to function as a gas cooler, the four-way switch valve VI is configured to connect the discharge side of the compressor 21 and the outdoor heat exchanger 23, and is also configured to connect the suction side of the compressor 21 and the gas refrigerant communication pipe 42 (see a solid-line condition in Fig. 1). On the other hand, when the outdoor heat exchanger 23 is caused to function as an evaporator, the 0 four-way switch valve VI is configured to connect the outdoor heat exchanger 23 and the suction side of the compressor 21, and is also configured to connect the discharge side of the compressor 21 and the gas refrigerant communication pipe 42 (see a dashed-line condition in Fig. I ). The outdoor heat exchanger 23 is a heat exchanger allowed to function as a gas 25 cooler and an evaporator. In the present embodiment, the outdoor heat exchanger 23 is a cross-fin typed fin-and-tube heat exchanger for conducting heat exchange between the refrigerant and air functioning as a heat source. One end of the outdoor heat exchanger 23 is connected to the four-way switch valve VI while the other end thereof is connected to the outdoor subcooling heat exchanger 24 via the first outdoor expansion valve V2. 30 The first outdoor expansion valve V2 is an electric expansion valve for regulating the pressure, the flow rate and the like of refrigerant flowing through the outdoor side refrigerant circuit 20. The first outdoor expansion valve V2 is connected between the outdoor heat exchanger 23 and the outdoor subcooling heat exchanger 24. In a cooling operation, the first outdoor expansion valve V2 is configured to function as a first-stage 1Q expansion mechanism in the two-stage expansion refrigeration cycle. On the other hand, in a heating operation, the first outdoor expansion valve V2 is fully opened and causes the refrigerant to flow into the outdoor heat exchanger 23 so as not to change pressure of the refrigerant. When the first outdoor expansion valve V2 functions as the first-stage 5 expansion mechanism, it decompresses the refrigerant from high pressure Ph to intermediate pressure Pm. Here, the intermediate pressure Pm is equal to or less than critical pressure Pk of the refrigerant. However, when the external temperature is equal to or greater than 31 degrees Celsius (i.e., the critical temperature of the CO 2 refrigerant) in the cooling operation, the first outdoor expansion valve V2 is configured to be fully opened. 0 The outdoor subcooling heat exchanger 24 is a heat exchanger allowed to function as a subcooler and an evaporator. In the present embodiment, the outdoor subcooling heat exchanger 24 is a cross-fin typed fin-and-tube heat exchanger for conducting heat exchange between the refrigerant and air functioning as a heat source. One end of the outdoor subcooling heat exchanger 24 is connected to the outdoor heat exchanger 23 via the first 5 outdoor expansion valve V2 while the other end thereof is connected to the liquid refrigerant communication pipe 41 via the second outdoor expansion valve V3. However, when the external temperature is equal to or greater than 31 degrees Celsius (i.e., critical temperature of the CO 2 refrigerant) in the cooling operation, the outdoor subcooling heat exchanger 24 is configured to function as a gas cooler. In this regard, the outdoor subscooling heat 0 exchanger 24 is similar to the aforementioned outdoor heat exchanger 23. The second outdoor expansion valve V3 is an electric expansion valve for regulating the pressure, the flow rate and the like of the refrigerant flowing through the outdoor side refrigerant circuit 20. The second outdoor expansion valve V3 is connected to the liquid side of the outdoor subcooling heat exchanger 24. In both the cooling and heating 25 operations, the first outdoor expansion valve V2 is configured to function as a second-stage expansion mechanism of the two-stage expansion refrigeration cycle, and is configured to decompress the refrigerant from the intermediate pressure Pm to low pressure Pl. However, when the external temperature is equal to or greater than 31 degrees Celsius (i.e., the critical temperature of the CO 2 refrigerant) in the cooling operation, the second outdoor expansion 30 valve V3 is configured to function as the first-stage expansion mechanism of the two-stage expansion refrigeration cycle, and is configured to decompress the refrigerant from the high pressure Ph to the intermediate pressure Pm equal to or less than the critical pressure Pk of the refrigerant. Furthermore, the outdoor unit 2 includes an outdoor fan 25. The outdoor fan 25 functions as a ventilation fan for sucking outdoor air into the outdoor unit 2 and then discharging the air to the outside after the outdoor heat exchanger 23 conducts heat exchange between the sucked air and the refrigerant. The outdoor fan 25 is a fan capable of changing the flow rate of air to be supplied to the outdoor heat exchanger 23. In the present 5 embodiment, the outdoor fan 25 is a propeller fan to be driven by a motor 26, for instance. Here, the motor 26 is composed of a DC fan motor. Additionally, the outdoor unit 2 is provided with various sensors. A first outdoor subcooling temperature sensor TI is provided between the outdoor subcooling heat exchanger 24 and the first outdoor expansion valve V2. The first outdoor subcooling 0 temperature sensor TI is configured to detect temperature of the refrigerant. Additionally, a second outdoor subcooling temperature sensor T2 is provided between the outdoor subcooling heat exchanger 24 and the second outdoor expansion valve V3. The second outdoor subcooling temperature sensor T2 is configured to detect temperature of the refrigerant. In the present embodiment, each of the first and second outdoor subcooling 5 temperature sensors TI and T2 is composed of a thermistor. Moreover, the outdoor unit 2 includes an outdoor side control section 27. The outdoor side control section 27 is configured to control operations of each of the elements forming the outdoor unit 2. The outdoor side control section 27 includes a microcomputer, a memory, an inverter circuit and the like. The microcomputer is provided for controlling the 0 outdoor unit 2. The inverter circuit is configured to control the motor 22 and the like. The outdoor side control section 27 is capable of transmitting/receiving a control signal and the like to/from an after-mentioned indoor side control section 35 of the indoor unit 3 through a transmission line 51. In other words, the outdoor side control section 27, the indoor side control section 35 and the transmission line 51 connecting each of the control sections form a ?5 control section 5 for controlling the entire operation of the air conditioning apparatus 1. The elements of the control section 5 are connected for receiving detection signals from a variety of sensors (not illustrated in the figure) and for controlling the various devices 21, 25 and 33 and valves VI, V2, V3 and V6, respectively, based on the detection signals and the like. 30 (2) Indoor Unit The indoor unit 3 is installed by being embedded in or hanged down or the like from the ceiling of the indoor space of a building and the like, or by being hanged down on the wall thereof or the like. The indoor unit 3 is connected to the outdoor unit 2 through the refrigerant communication pipe 4. The indoor unit 3 forms a part of the refrigerant circuit 1!;% 10. Next, structure of the indoor unit 3 will be explained. The indoor unit 3 mainly includes an indoor side refrigerant circuit 30. The indoor side refrigerant circuit 30 forms a part of the refrigerant circuit 10. The indoor side refrigerant circuit 30 mainly includes an 5 indoor heat exchanger 31, an indoor expansion valve V6 and an indoor subcooling heat exchanger 32. The indoor heat exchanger 3 1 functions as a utilization side heat exchanger. The indoor expansion valve V6 functions as an expansion mechanism. The indoor subcooling heat exchanger 32 functions as a utilization side subcooler. The indoor heat exchanger 31 is a cross-fin typed fin-and-tube heat exchanger 0 formed by a heat transmission tube and a plurality of fins. The indoor heat exchanger 31 is configured to function as an evaporator of the refrigerant for cooling the indoor air in the cooling operation. On the other hand, the indoor heat exchanger 31 is configured to function as a gas cooler of the refrigerant for heating the indoor air in the heating operation. The indoor expansion valve V6 is an electric expansion valve for regulating the 5 pressure, the flow rate and the like of the refrigerant flowing through the indoor side refrigerant circuit 30. The indoor expansion valve V6 is connected to the liquid side of the indoor heat exchanger 31. In this regard, the indoor expansion valve V6 is similar to the aforementioned first outdoor expansion valve V2. In the cooling operation, the indoor expansion valve V6 is configured to be fully opened and causes the refrigerant to flow into D the indoor heat exchanger 3 1 so as not to change pressure of the refrigerant. On the other hand, in the heating operation, the indoor expansion valve V6 is configured to function as the first-stage expansion mechanism of the two-stage expansion refrigeration cycle. When the indoor expansion valve V6 functions as the first-stage expansion mechanism, it is configured to decompress the refrigerant from the high pressure Ph to the intermediate pressure Pm. In 5 this regard, the indoor expansion valve V6 is also similar to the first outdoor expansion valve V2. However, when the external temperature is equal to or greater than 31 degrees Celsius (i.e., the critical temperature of the CO 2 refrigerant) in the cooling operation, the indoor expansion valve V6 is configured to function as the second-stage expansion mechanism of the two-stage expansion refrigeration cycle, and is configured to decompress the refrigerant 0 from the intermediate pressure Pm to the low pressure Pl. The indoor subcooling heat exchanger 32 is a heat exchanger allowed to function as a subcooler and an evaporator. In the present embodiment, the indoor subcooling heat exchanger 32 is a cross-fin typed fin-and-tube heat exchanger for conducting heat exchange between the refrigerant and air functioning as a heat source. One end of the indoor 1 6 subcooling heat exchanger 32 is connected to the indoor heat exchanger 31 via the indoor expansion valve V6 whereas the other end thereof is connected to the liquid refrigerant communication pipe 41. However, when the external temperature is equal to or greater than 31 degrees Celsius (i.e., the critical temperature of the CO 2 refrigerant) in the cooling 5 operation, the indoor subcooling heat exchanger 32 is configured to function as an evaporator. In this regard, the indoor subcooling heat exchanger 32 is similar to the indoor heat exchanger 3 1. Furthermore, the indoor unit 3 includes an indoor fan 33. The indoor fan 33 functions as a ventilation fan for sucking the indoor air into the indoor unit 3 and 0 subsequently causing the sucked air to exchange heat with the refrigerant in the indoor heat exchanger 31 and thereafter supplying same to the indoor space as the supply air. The indoor fan 33 is a fan capable of changing the flow rate of air to be supplied to the indoor heat exchanger 31. In the present embodiment, the indoor fan 33 may be a centrifugal fan, a multi-blade fan and the like to be driven by a motor 34. Here, the motor 34 is composed of 5 a DC fan motor. Additionally, the indoor unit 3 is provided with various sensors. A first indoor subcooling temperature sensor T3 is provided between the indoor subcooling heat exchanger 32 and the indoor expansion valve V6. The first indoor subcooling temperature sensor T3 is configured to detect temperature of the refrigerant. Additionally, a second indoor D subcooling temperature sensor T4 is provided on the liquid refrigerant communication pipe 41 side of the indoor subcooling heat exchanger 32. The second indoor subcooling temperature sensor T4 is configured to detect temperature of the refrigerant. In the present embodiment, each of the first and second indoor subcooling temperature sensors T3 and T4 is composed of a thermistor. 25 Moreover, the indoor unit 3 is provided with the indoor side control section 35 for controlling operations of each of the elements forming the indoor unit 3. The indoor side control section 35 includes a microcomputer, a memory and the like provided for controlling the indoor unit 3. The indoor side control section 35 is capable of transmitting/receiving a control signal and the like to/from a remote controller (not illustrated in the figure) for 30 independently operating a corresponding indoor unit 3 from other units. Additionally, the indoor side control section 35 is capable of transmitting/receiving, etc. a control signal and the like to/from the outdoor unit 2 through the transmission line 51. (3) Refrigerant Communication Pipe When the air conditioning apparatus I is installed in an installation place of a 17 building and the like, the refrigerant communication pipe 4 is attached to the air conditioning apparatus I in the installation site. Any suitable refrigerant communication pipes 4 of a variety of lengths and diameters may be used depending on an installation condition (e.g., an installation site and a combination of the outdoor unit 2 and the indoor unit 3). 5 <Operation of Air Conditioning Apparatus> Next, operations of the air conditioning apparatus I of the present embodiment will be explained. The air conditioning apparatus 1 of the present embodiment is configured to be operated in two operation modes depending on operation loads of the indoor unit 3 necessary D for cooling/heating the indoor space. One of the operation modes is a cooling operation for causing the indoor unit 3 to cool the indoor space while the other of the operation modes is a heating operation for causing the indoor unit 3 to heat the indoor space. Operations of the air conditioning apparatus 1 in each of the operation modes will be hereinafter explained. 5 (1) Cooling Operation First, the cooling operation will be explained with reference to Figs. I and 2. In the cooling operation, the four-way switch valve VI in the outdoor side refrigerant circuit 20 of the outdoor unit 2 is switched to the solid-line condition illustrated in Fig. 1. Accordingly, the outdoor heat exchanger 23 is configured to function as a gas cooler, and the indoor heat D exchanger 3 1 is configured to function as an evaporator. When the compressor 21, the outdoor fan 25 and the indoor fan 33 are activated under the condition of the refrigerant circuit 10, gas refrigerant of the low pressure P is inhaled into the compressor 21 and is compressed to the high pressure Ph therein. The compressed gas refrigerant of the high pressure Ph flows into the outdoor heat exchanger 23. ,5 The outdoor heat exchanger 23 herein functions as a gas cooler. The outdoor heat exchanger 23 releases heat into the outdoor air supplied by the outdoor fan 25 for cooling the refrigerant. Subsequently, the first outdoor expansion valve V2 decompresses the gas refrigerant from the high pressure Ph to the intermediate pressure Pm equal to or less than the critical pressure Pk of the refrigerant. When the refrigerant is decompressed to the 30 intermediate pressure Pm, it enters a gas-liquid two-phase state and flows into the outdoor subcooling heat exchanger 24. The refrigerant is further cooled in the outdoor subcooling heat exchanger 24 and changes into liquid refrigerant. Thus the refrigerant enters a subcooling state. The outdoor subcooling heat exchanger 24 stores the liquid refrigerant, and the second outdoor expansion valve V3 controls the amount of the liquid refrigerant 1Q stored in the outdoor subcooling heat exchanger 24. The amount of the liquid refrigerant stored in the outdoor subcooling heat exchanger 24 is controlled based on degree of subcooling of the refrigerant. The degree of subcooling of refrigerant is calculated based on temperatures detected by the first and second outdoor subcooling temperature sensors TI and 5 T2. The second outdoor expansion valve V3 herein decompresses the subcooling-state refrigerant to approximately the sucking pressure of the compressor 21. Thus the decompressed refrigerant changes into gas-liquid two-phase state refrigerant of the low pressure P1. Subsequently, the refrigerant of the low pressure P is transported to the indoor unit D 3 through the liquid side stop valve V4 and the liquid refrigerant communication pipe 41. In the indoor unit 3, the indoor subcooling heat exchanger 32 and the indoor heat exchanger 31 conduct heat exchange between the indoor air and the transported liquid refrigerant of the low pressure P1. Then, the liquid refrigerant of the low pressure P1 evaporates and changes into gas refrigerant of the low pressure P1. At this time, the indoor expansion valve V6 is fully 5 opened. The gas refrigerant of the low pressure P1 is transported to the outdoor unit 2 through the gas refrigerant communication pipe 42. Then, it is again inhaled into the compressor 21 through the gas side stop valve V5. When the external temperature is 31 degrees Celsius or more (i.e., the critical temperature of the CO 2 refrigerant), another control, which is different from the 3 aforementioned control, will be executed. The following is an explanation thereof. First, the first outdoor expansion valve V2 is fully opened, and the outdoor heat exchanger 23 and the outdoor subcooling heat exchanger 24 are caused to function as gas coolers. Next, the second outdoor expansion valve V3 decompresses the refrigerant of the high pressure Ph cooled by the outdoor heat exchanger 23 and the outdoor subcooling heat exchanger 24 to the 5 intermediate pressure Pm equal to or less than the critical pressure Pk of the refrigerant. After the refrigerant is decompressed to the intermediate pressure Pm, it is transported to the indoor unit 3. The refrigerant is herein further cooled by the indoor subcooling heat exchanger 32 and changes into liquid refrigerant. Thus it enters a subcooling state. The indoor subcooling heat exchanger 32 stores the liquid refrigerant, and the indoor expansion 0 valve V6 controls the amount of the liquid refrigerant stored in the indoor subcooling heat exchanger 32. The amount of the liquid refrigerant stored in the indoor subcooling heat exchanger 32 is controlled based on degree of subcooling of the refrigerant. The degree of subcooling of the refrigerant is calculated based on temperatures detected by the first and second indoor subcooling temperature sensors T3 and T4. The indoor expansion valve V6
I
decompresses the subcooling-state refrigerant to approximately the sucking pressure of the compressor 21. Accordingly, it changes into gas-liquid two-phase state refrigerant of the low pressure Pl. Then, the indoor heat exchanger 31 conducts heat exchange between the indoor air and the refrigerant of the low pressure Pl. The refrigerant evaporates and changes 5 into gas refrigerant of the low pressure Pl. The gas refrigerant of the low pressure P is transported to the outdoor unit 2 through the gas refrigerant communication pipe 42. Then, the gas refrigerant is again inhaled into the compressor 21 through the gas side stop valve V5. (2) Heating Operation In the heating operation, the four-way switch valve VI of the outdoor side D refrigerant circuit 20 of the outdoor unit 2 is switched to the dashed-line condition in Fig. I. Accordingly, the outdoor heat exchanger 23 is configured to function as an evaporator whereas the indoor heat exchanger 31 is configured to function as a gas cooler. When the compressor 21, the outdoor fan 25 and the indoor fan 33 are activated under the condition of the refrigerant circuit 10, gas refrigerant of the low pressure PI is 5 inhaled into the compressor 21 and is compressed therein. The gas refrigerant of the low pressure P accordingly changes into gas refrigerant of the high pressure Ph, and is transported to the gas refrigerant communication pipe 42 through the four-way switch valve VI and the gas side stop valve V5. After the gas refrigerant of the high pressure Ph is transported to the gas refrigerant ) communication pipe 42, it is transported to the indoor unit 3. Subsequently, the gas refrigerant of the high pressure Ph transported to the indoor unit 3 is further transported to the indoor heat exchanger 3 1. The indoor heat exchanger 31 conducts heat exchange between the indoor air and the refrigerant for cooling the refrigerant. Accordingly, the refrigerant changes into liquid refrigerant of the high pressure Ph. Subsequently, when the liquid 5 refrigerant passes through the indoor expansion valve V6, it is decompressed to the intermediate pressure Pm in accordance with degree of opening of the indoor expansion valve V6. When the refrigerant is decompressed to the intermediate pressure Pm, it changes into gas-liquid two-phase state refrigerant, and flows into the indoor subcooling heat exchanger 32. The indoor subcooling heat exchanger 32 further cools the refrigerant. The refrigerant 0 thus changes into subcooling-state liquid refrigerant. The indoor subcooling heat exchanger 32 stores the liquid refrigerant, and the second outdoor expansion valve V3 controls the amount of the liquid refrigerant stored in the indoor subcooling heat exchanger 32. The amount of the liquid refrigerant stored in the indoor subcooling heat exchanger 32 is controlled based on degree of subcooling of the refrigerant. The degree of subcooling of the On~ refrigerant is calculated based on temperatures detected by the first and second indoor subcooling temperature sensors T3 and T4. The subcooling-state refrigerant is subsequently transported to the outdoor unit 2 through the liquid refrigerant communication pipe 41. The refrigerant is transported to the 5 second outdoor expansion valve V3 through the liquid side stop valve V4. The second outdoor expansion valve V3 decompresses the refrigerant to approximately the sucking pressure of the compressor 21. The refrigerant thus changes into gas-liquid two-phase state refrigerant of the low pressure Pl. The outdoor subcooling heat exchanger 24 and the outdoor heat exchanger 23 conduct heat exchange between the external air and the ) decompressed refrigerant of the low pressure Pl. Accordingly the refrigerant evaporates and changes into gas refrigerant of the low pressure Pl. At this time, the first outdoor expansion valve V2 is fully opened. The gas refrigerant of the low pressure P is again inhaled into the compressor 21 through the four-way switch valve VI. <Two-stage Expansion Refrigeration Cycle> 5 Fig. 2 illustrates the refrigeration cycle under the supercritical condition with a P-H chart (Mollier diagram). In the present embodiment, the CO 2 refrigerant (i.e., the supercritical refrigerant) is used as refrigerant. Moreover, the present embodiment adopts the two-stage expansion refrigeration cycle configured to expand the refrigerant in two stages with two expansion mechanisms. As described above, the refrigerant circuit 10 is mainly ) composed of the compressor 21, the outdoor heat exchanger 23, the first outdoor expansion valve V2, the outdoor subcooling heat exchanger 24, the second outdoor expansion valve V3, the indoor subcooling heat exchanger 32, the indoor expansion valve V6 and the indoor heat exchanger 3 1. Points A, B, C, D, E and F in Fig. 2 illustrate states of refrigerant at the corresponding points in Fig. I in the cooling operation. On the other hand, points (A), (B), 5 (E), (F), (G) and (H) in Fig. 2 illustrate states of refrigerant at the corresponding points of Fig. I in the heating operation. Note that the two-stage expansion cycle in the cooling operation (i.e., when the external temperature is equal to or less than the critical temperature of the CO 2 refrigerant) will be hereinafter explained with reference to Figs. I and 2. Note it is possible to explain the two-stage expansion cycle in the heating operation by replacing the points C, D, 0 E and F with the points H, G, F and E, respectively. In the refrigerant circuit 10, the compressor 21 compresses the refrigerant and the compressed refrigerant changes into high-temperature refrigerant of the high pressure Ph (A -+ B). At this time, the gas refrigerant, C0 2 , enters a supercritical state. Note the term "supercritical state" means a state of material under temperature and pressure equal to or 0 1 greater than the critical point K. Supercritical-state material has both gas diffusivity and liquid solubility. In Fig. 2, the supercritical state of the refrigerant is shown in the area positioned rightward of a critical temperature isothermal curve Tk at the critical pressure Pk or greater. When the refrigerant (material) enters a supercritical state, there is no distinction 5 between gas phase and liquid phase. Additionally, the term "gas phase" is a state of the refrigerant shown by the area positioned rightward of a saturated vapor curve Sv at the critical pressure Pk or less. On the other hand, the term "liquid phase" is a state of the refrigerant shown by the area positioned leftward of both a saturated liquid curve Sl and the critical temperature isothermal curve Tk. After the refrigerant enters a supercritical state of 0 high temperature and high pressure by the compression of the compressor 21, the outdoor heat exchanger 23 functioning as a gas cooler releases heat of the supercritical-state refrigerant. Accordingly, the refrigerant changes into low-temperature refrigerant of the high pressure Ph (B -+ C). At this time, the refrigerant is in a supercritical state. Therefore, the refrigerant operates with sensible heat change (i.e., temperature change) in the 5 interior of the outdoor hear exchanger 23. After the outdoor heat exchanger 23 releases heat of the refrigerant, the refrigerant expands in conjunction with opening of the first outdoor expansion valve V2. Accordingly, the refrigerant of the high pressure Ph is decompressed to the intermediate pressure Pm (C -- D). Subsequently, the refrigerant decompressed by the first outdoor expansion valve V2 to the intermediate pressure Pm flows into the outdoor D subcooling heat exchanger 24 without changing its pressure. The outdoor subcooling heat exchanger 24 further cools the refrigerant. Accordingly, the refrigerant enters a subcooling state (D -+ E). Moreover, the second outdoor expansion valve V3 further expands the subcooling-state refrigerant. Thus the refrigerant changes into refrigerant of the low pressure P1 (E - F). The refrigerant of the low pressure Pl passes through the liquid .5 refrigerant communication pipe 41, absorbs heat and evaporates in the indoor subcooling heat exchanger 32 and the indoor heat exchanger 31. Furthermore, the evaporated refrigerant passes through the gas refrigerant communication pipe 42, and returns to the compressor 21 (F - A). <Characteristics> 30 (1) In the present embodiment, the outdoor unit 2 further includes the four-way switch valve VI capable of switching the operation modes between the cooling operation and the heating operation. Moreover, the control section 5 is configured to control the first and second outdoor expansion valves V2 and V3 when the four-way switch valve VI is switched 99 into the solid-line condition in Fig. I (i.e., the cooling operation). On the other hand, the control section 5 is configured to control the second outdoor expansion valve V3 and the indoor expansion valve V6 when the four-way switch valve VI is switched into the dashed-line condition in Fig. I (i.e., the heating operation). When the external temperature 5 is equal to or greater than the critical temperature of the refrigerant in the cooling operation, the control section 5 is configured to control the second outdoor expansion valve V3 and the indoor expansion valve V6 for storing the liquid refrigerant in the indoor subcooling heat exchanger 32 without storing it in the outdoor subcooling heat exchanger 24. Therefore, the control section 5 is capable of regulating the intermediate pressure of D the refrigerant by controlling the first outdoor expansion valve V2 in the cooling operation. On the other hand, the control section 5 is capable of regulating the intermediate pressure of the refrigerant by controlling the indoor expansion valve V6 in the heating operation. Moreover, the control section 5 is capable of regulating the amount of the liquid refrigerant in the outdoor subcooling heat exchanger 24 by controlling the second outdoor expansion valve 5 V3 in the cooling operation. On the other hand, the control section 5 is capable of regulating the amount of the liquid refrigerant in the indoor subcooling heat exchanger 32 in the heating operation. When the refrigerant exceeds the critical point, it enters a supercritical state. It is thus difficult to control the amount of the refrigerant in this condition. By the same token, it is difficult to store the refrigerant in the outdoor subcooling ) heat exchanger 24 when the external temperature is equal to or greater than 31 degrees Celsius (i.e., the critical temperature of the refrigerant). Furthermore, temperature of the indoor air is often equal to or less than 31 degrees Celsius (i.e., the critical temperature of the
CO
2 refrigerant) because the indoor heat exchanger 3 1 functions as an evaporator. Therefore, it is possible to store the liquid refrigerant in the indoor subcooling heat exchanger 5 32 by the control section 5 controlling both the second outdoor expansion valve V3 and the indoor expansion valve V6. (2) In the present embodiment, the outdoor unit 2 includes the first and second outdoor subcooling temperature sensors TI and T2 at the refrigerant inlet and the refrigerant outlet of 0 the outdoor subcooling heat exchanger 24 for detecting degree of subcooling. It is possible to obtain the intermediate pressure Pm and the outlet temperature of the outdoor subcooling heat exchanger 24 with the temperature sensors TI and T2 when the external temperature is less than 31 degrees Celsius in the cooling operation. Moreover, the indoor unit 3 includes the first and second indoor subcooling temperature sensors T3 and T4 at the refrigerant inlet and the refrigerant outlet of the indoor subcooling heat exchanger 32 for detecting degree of subcooling. It is possible to obtain the intermediate pressure Pm and the outlet temperature of the indoor subcooling heat exchanger 32 with the temperature sensors T3 and T4 both in the heating operation and in the cooling operation when the external temperature is equal to 5 or greater than 31 degrees Celsius. Therefore, the control section 5 is capable of calculating degree of subcooling based on the intermediate pressure Pm and the outlet temperature of the outdoor subcooling heat exchanger 24 or that of the indoor subcooling heat exchanger 32. Consequently, the control section 5 is capable of storing the liquid refrigerant in the outdoor subcooling heat exchanger 0 24 or the indoor subcooling heat exchanger 32 functioning as a subcooling heat exchanger based on degree of subcooling of the refrigerant, and is capable of regulating the amount of the refrigerant. (3) In the present embodiment, the CO 2 refrigerant is used as refrigerant. The global 5 warming potential (GWP) value of the CO 2 refrigerant equals to 1. The value is much lower than conventional refrigerant such as fluorocarbon refrigerant having the GWP value of approximately hundreds to ten thousand. Therefore, use of the CO 2 refrigerant less burdening the environment makes it possible to inhibit worsening of the global environment. o <Modifications> (1) The air conditioning apparatus 1 of the present embodiment is a so-called pair-type air conditioning device, and single indoor unit 3 is connected to single outdoor unit 2. However, the air conditioning apparatus I is not limited to the structure. For example, the 25 air conditioning apparatus may be a multi-type air conditioning apparatus Ia, and a plurality of indoor units may be connected to single outdoor unit. As illustrated in Fig. 3, for instance, three indoor units 3a, 3b and 3c may be parallel-connected to single outdoor unit 2. Elements of the indoor units 3a, 3b and 3c in Fig. 3 correspond to those of the indoor unit 3 explained in the present embodiment, respectively. Additionally, "a", "b" and "c" are added 30 at the end of reference numerals of the elements of the indoor units 3a, 3b and 3c. For example, the indoor fan 33 of the indoor unit 3 corresponds to the indoor fans 33a, 33b and 33c of the indoor units 3a, 3b and 3c, respectively. The indoor unit 3 has the same structure as the indoor units 3a, 3b and 3c. In the example of Fig. 3, three indoor units 3a to 3c are connected to the outdoor unit 2. However, the number of the indoor units is not limited to 0 A this. For example, any suitable number (e.g., two, four or five) of the indoor units may be connected to the outdoor unit 2. The air conditioning apparatus la of the present modification is provided with a plurality of the indoor units 3a to 3c. Accordingly, when different operation loads are 5 applied to the indoor units 3a to 3c in their installation places, the air conditioning apparatus la allows the indoor units 3a to 3c to independently operate for coping with the respective operational loads. Therefore, when operational loads vary in places, the air conditioning apparatus ]a is capable of more efficiently operating compared to an air conditioning apparatus with single indoor unit. 3 (2) In the air conditioning apparatus of the present embodiment, the outdoor unit 2 is provided with the first outdoor expansion valve V2 as an expansion mechanism while the indoor unit 3 is provided with the indoor expansion valve V6 as an expansion mechanism. However, the expansion mechanisms are not limited to the expansion valves. For example, expansion devices may be used as the expansion mechanisms. (3) In the air conditioning apparatus of the present embodiment, temperature sensors are respectively provided at the inlet and the outlet of the outdoor subcooling heat exchanger 24 and at the inlet and the outlet of the indoor subcooling heat exchanger 32 for calculating ) degree of subcooling of the refrigerant. However, the sensors provided at the refrigerant inlet side of the subcooling heat exchangers 24 and 32 are not limited to the temperature sensors. For example, pressure sensors may be provided therein. Specifically, pressure sensors may be used instead of the first outdoor subcooling temperature sensor TI disposed in the refrigerant flow directional inlet side of the outdoor subcooling heat exchanger 24 5 functioning as a subcooler in the cooling operation and the first indoor subcooling temperature sensor T3 disposed in the refrigerant flow directional inlet side of the indoor subcooling heat exchanger 32 functioning as a subcooler in the heating operation. However, when the external temperature is equal to or greater than 31 degrees Celsius in the cooling operation, not the outdoor subcooling heat exchanger 24 but the indoor subcooling heat 0 exchanger 32 functions as a subcooler. Therefore, the sensor disposed at the refrigerant flow directional outlet side of the indoor subcooling heat exchanger 32 (i.e., the first indoor subcooling temperature sensor T3) has to be a temperature sensor in this case. In the present embodiment, it is thus possible to only replace the first outdoor subcooling temperature sensor TI with a pressure sensor.
Moreover, pressure sensors may be further provided at the refrigerant flow directional inlet sides of the subcooling heat exchangers 24 and 32, respectively, in addition to temperature sensors. (4) 5 In the air conditioning apparatus I of the present embodiment, the outdoor air is used as a heat source. However, the heat source is not limited to the outdoor air. For example, water and the like may be used as a heat source. (5) The air conditioning apparatus of the present embodiment includes the four-way D switch valve VI in the outdoor unit 2, and is capable of executing both the cooling and heating operations. However, the air conditioning apparatus of the present invention is not limited to the structure. For example, as illustrated in Figs 4 and 5, the air conditioning apparatus may be an air conditioning apparatus I b exclusively used for the cooling operation without any four-way switch valves or an air conditioning apparatus Ic exclusively used for 5 the heating operation without any four-way switch valves. Specifically, the air conditioning apparatus lb exclusively used for the cooling operation in Fig. 4 is configured to control the first and second outdoor expansion valves V2 and V3 for storing the liquid refrigerant in the outdoor subcooling heat exchanger 24. On the other hand, the air conditioning apparatus Ic exclusively used for the heating operation in D Fig. 5 is configured to control the first and second outdoor expansion valves V2 and V3 for storing the liquid refrigerant in the outdoor subcooling heat exchanger 24. In this regard, the air conditioning apparatus Ic in Fig. 5 is similar to the air conditioning apparatus lb in Fig. 4. (6) 5 In the air conditioning apparatus of the present embodiment, the outdoor unit 2 is provided with the outdoor subcooling heat exchanger 24 whereas the indoor unit 3 is provided with the indoor subcooling heat exchanger 32. Furthermore, the refrigerant circuit 10 is provided with two devices functioning as subcooling heat exchangers. However, structure of the air conditioning apparatus is not limited to this. As illustrated in Fig. 6, for 30 instance, an air conditioning apparatus Id may be provided with single device configured to function as a subcooling heat exchanger. Specifically, in the air conditioning apparatus Id of Fig. 6, only an outdoor unit 2 is provided with an outdoor subcooling heat exchanger 24. The outdoor unit 2 is further provided with first and second outdoor expansion valves V2 and V3 so as to sandwich the outdoor subcooling heat exchanger 24 therebetween. In both the cooling and heating operations, the air conditioning apparatus Id is configured to control the first and second outdoor expansion valves V2 and V3 for storing the liquid refrigerant in the outdoor subcooling heat exchanger 24. 5 INDUSTRIAL APPLICABILITY The air conditioning apparatus of preferred embodiments of the present invention is capable of optimally controlling high pressure of refrigerant by regulating the circulation amount of refrigerant. Additionally, the air conditioning apparatus is useful as an air conditioning apparatus and the like using supercritical refrigerant operating in the ) supercritical zone for easily regulating the circulation amount of supercritical refrigerant.

Claims (12)

1. A refrigeration apparatus using refrigerant operating in the supercritical zone, comprising: a compressor configured to compress the refrigerant; 5 a first heat exchanger configured to cool the high pressure refrigerant compressed by the compressor; a first expansion mechanism configured to decompress the refrigerant to critical pressure or less; a subcooling heat exchanger adapted to function as a subcooler and an evaporator LO and configured to subcool the refrigerant decompressed by the first expansion mechanism; a second expansion mechanism configured to decompress the refrigerant cooled by the subcooling heat exchanger to low pressure; a second heat exchanger configured to heat the refrigerant decompressed by the second expansion mechanism; and 15 a control section configured to conduct first control to regulate the first and second expansion mechanisms for storing the refrigerant of a liquid state in the subcooling heat exchanger.
2. The refrigeration apparatus according to claim 1, further comprising subcooling information obtaining means configured to obtain ?O subcooling information used for calculating degree of subcooling of the refrigerant in the subcooling heat exchanger, and wherein the control section is configured to calculate the degree of subcooling based on the subcooling information, and the first control is conducted based on the degree of subcooling. 25
3. The refrigeration apparatus according to claim 2, wherein the subcooling information obtaining means is composed of an inlet temperature sensor capable of detecting refrigerant inlet temperature of the subcooling heat exchanger and an outlet temperature sensor capable of detecting refrigerant outlet temperature of the subcooling heat exchanger.
4. The refrigeration apparatus according to claim 2, wherein the subcooling information 30 obtaining means is composed of an inlet pressure sensor capable of detecting refrigerant inlet pressure of the subcooling heat exchanger and an outlet temperature sensor capable of detecting refrigerant outlet temperature of the subcooling heat exchanger.
5. A refrigeration apparatus using refrigerant operating in the supercritical zone, comprising: 28 a compressor configured to compress the refrigerant; a first heat exchanger configured to conduct heat exchange of the refrigerant; a first expansion mechanism configured to decompress the refrigerant; a subcooling heat exchanger adapted to function as a subcooler and an evaporator 5 and configured to subcool the refrigerant; a second expansion mechanism configured to decompress the refrigerant; a second heat exchanger configured to conduct heat exchange of the refrigerant; a switch mechanism configured to be capable of switching between a first condition and a second condition, 10 the first condition causing the refrigerant evaporated in the second heat exchanger to flow into the compressor and causing the refrigerant compressed in the compressor to flow into the first heat exchanger, the second condition causing the refrigerant evaporated in the first heat exchanger to flow into the compressor and causing the refrigerant compressed in the 15 compressor to flow into the second heat exchanger; and a control section configured to conduct first control and second control, the first control being configured to cause the first expansion mechanism to decompress the refrigerant from high pressure to intermediate pressure equal to or less than the supercritical pressure and cause the second expansion mechanism to 20 decompress the intermediate pressure refrigerant subcooled by the subcooling heat exchanger to low pressure for storing the refrigerant of a liquid state in the subcooling heat exchanger in the first condition switched by the switch mechanism, and the second control being configured to cause the second expansion 25 mechanism to decompress the refrigerant from high pressure to the intermediate pressure equal to or less than the supercritical pressure and cause the first expansion mechanism to decompress the intermediate pressure refrigerant subcooled by the subcooling heat exchanger to low pressure for storing the refrigerant of a liquid state in the subcooling heat exchanger in the second condition switched by the switch 30 mechanism.
6. The refrigeration apparatus according to claim 5, further comprising subcooling information obtaining means configured to obtain subcooling information used for calculating degree of subcooling of the refrigerant in the subcooling heat exchanger, and 29 wherein the control section is configured to calculate the degree of subcooling based on the subcooling information, and the first control or the second control is conducted based on the degree of subcooling. 5
7. A refrigeration apparatus using refrigerant operating in the supercritical zone, comprising: a heat source unit including; a compressor configured to compress the refrigerant; a heat source side heat exchanger configured to conduct heat exchange LO between the refrigerant and first fluid; a first expansion mechanism capable of decompressing the refrigerant; a heat source side auxiliary heat exchanger configured to conduct heat exchange of the refrigerant; a second expansion mechanism capable of decompressing the [5 refrigerant; and a switch mechanism capable of switching between a first condition and a second condition, the first condition causing the refrigerant to flow into the compressor after a utilization side heat exchanger conducts the heat ?0 exchange of the refrigerant and causing the refrigerant compressed by the compressor to flow into the heat source side heat exchanger, the second condition causing the refrigerant to flow into the compressor after the heat source side heat exchanger conducts the heat exchange of the refrigerant and causing the refrigerant compressed by the 25 compressor to flow into the utilization side heat exchanger; a utilization unit including the utilization side heat exchanger configured to conduct heat exchange of the refrigerant, a third expansion mechanism capable of decompressing the refrigerant, and a utilization side auxiliary heat exchanger configured to conduct heat exchange of the refrigerant; and 30 a control section configured to conduct first control, second control and third control, the first control being configured to cause the heat source side auxiliary heat exchanger to function as a subcooler and regulate the first and second expansion mechanisms for storing the refrigerant of a liquid 30 state in the heat source side auxiliary heat exchanger when temperature of the first fluid is less than the critical temperature of the refrigerant in the first condition switched by the switch mechanism, the second control being configured to cause the utilization side 5 auxiliary heat exchanger to function as a subcooler and regulate the second and third expansion mechanisms for storing the refrigerant of a liquid state in the utilization side auxiliary heat exchanger when temperature of the first fluid is equal to or greater than the critical temperature of the refrigerant in the first condition switched by the switch mechanism, and L0 the third control being configured to cause the utilization side auxiliary heat exchanger to function as a subcooler and regulate the second and third expansion mechanisms for storing the refrigerant of a liquid state in the utilization side auxiliary heat exchanger in the second condition switched by the switch mechanism. L5
8. The refrigeration apparatus according to claim 7, wherein the heat source unit further includes heat source side subcooling information obtaining means capable of detecting first subcooling degree of the heat source side auxiliary heat exchanger, the utilization unit further includes utilization side subcooling information obtaining 0 means capable of detecting second subcooling degree of the utilization side auxiliary heat exchanger, the first control is conducted based on the first subcooling degree, and the second and third controls are conducted based on the second subcooling degree.
9. The refrigeration apparatus according to claim 8, wherein the heat source side subcooling 25 information obtaining means is composed of a first inlet temperature sensor capable of detecting refrigerant inlet temperature of the heat source side auxiliary heat exchanger and a first outlet temperature sensor capable of detecting refrigerant outlet temperature of the heat source side auxiliary heat exchanger.
10. The refrigeration apparatus according to claim 8 or claim 9, wherein the utilization side 30 subcooling information obtaining means is composed of a second inlet temperature sensor capable of detecting refrigerant inlet temperature of the utilization side auxiliary heat exchanger and a second outlet temperature sensor capable of detecting refrigerant outlet temperature of the utilization side auxiliary heat exchanger.
11. The refrigeration apparatus according to any of claims 1 to 10, wherein the refrigerant is 31 carbon dioxide (CO 2 ) refrigerant.
12. A refrigeration apparatus using refrigerant operating in the supercritical zone, said apparatus substantially as hereinbefore described with reference to any one embodiment, as that embodiment is shown in the accompanying drawings. 32
AU2007320604A 2006-11-13 2007-11-07 Air conditioning apparatus Ceased AU2007320604B9 (en)

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Families Citing this family (15)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JP5570739B2 (en) * 2009-02-25 2014-08-13 三菱重工業株式会社 Multi-type air conditioner, outdoor unit thereof, and control method thereof
JP5523817B2 (en) * 2009-12-25 2014-06-18 三洋電機株式会社 Refrigeration equipment
KR20110092147A (en) * 2010-02-08 2011-08-17 삼성전자주식회사 Air conditioner and control method thereof
JP5724476B2 (en) * 2011-03-10 2015-05-27 株式会社富士通ゼネラル Refrigeration cycle equipment
CN102840720A (en) * 2011-06-21 2012-12-26 叶必武 Pressure adjustment device of vehicle air conditioner
JP6412702B2 (en) * 2014-03-06 2018-10-24 東プレ株式会社 Refrigeration apparatus and method of operating refrigeration apparatus
JP6657613B2 (en) * 2015-06-18 2020-03-04 ダイキン工業株式会社 Air conditioner
CN105627470B (en) * 2015-12-30 2018-07-03 同济大学 A kind of air-conditioner set based on supercooling reheating
CN108195007A (en) * 2018-01-15 2018-06-22 杭州微光电子股份有限公司 The air-conditioning system of Temperature and Humidity Control and Btu utilization
CN108870689B (en) * 2018-07-17 2020-01-07 珠海格力电器股份有限公司 Pressure control method and system of air conditioning unit
US20220018571A1 (en) * 2018-12-07 2022-01-20 Daikin Industries, Ltd. Air-conditioner
US11137156B2 (en) * 2019-05-31 2021-10-05 Trane International Inc Refrigerant charge management with subcooling control
JP7343764B2 (en) * 2019-09-30 2023-09-13 ダイキン工業株式会社 air conditioner
CN112944708A (en) * 2021-02-05 2021-06-11 湖南汽车工程职业学院 Vehicle-mounted air conditioner carbon dioxide refrigerant determination method and capture system
JPWO2023105607A1 (en) * 2021-12-07 2023-06-15

Citations (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JP2000205670A (en) * 1999-01-11 2000-07-28 Sanden Corp Vapor compression type refrigeration cycle
JP2001004235A (en) * 1999-06-22 2001-01-12 Sanden Corp Steam compression refrigeration cycle
JP2002168536A (en) * 2000-11-29 2002-06-14 Mitsubishi Heavy Ind Ltd Air conditioner
JP2004100979A (en) * 2002-09-05 2004-04-02 Matsushita Electric Ind Co Ltd Heat pump device
JP2005226950A (en) * 2004-02-16 2005-08-25 Mitsubishi Electric Corp Refrigerating air conditioner

Family Cites Families (43)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPS6334459A (en) * 1986-07-29 1988-02-15 株式会社東芝 Air conditioner
JP2997487B2 (en) * 1989-12-13 2000-01-11 株式会社日立製作所 Refrigeration apparatus and method for indicating amount of refrigerant in refrigeration apparatus
JPH06103130B2 (en) * 1990-03-30 1994-12-14 株式会社東芝 Air conditioner
JP2909190B2 (en) * 1990-11-02 1999-06-23 株式会社東芝 Air conditioner
US5109677A (en) * 1991-02-21 1992-05-05 Gary Phillippe Supplemental heat exchanger system for heat pump
US5431026A (en) * 1994-03-03 1995-07-11 General Electric Company Refrigerant flow rate control based on liquid level in dual evaporator two-stage refrigeration cycles
CN1135341C (en) * 1994-05-30 2004-01-21 三菱电机株式会社 Refrigerating circulating system and refrigerating air conditioning device
EP0854329B1 (en) * 1994-07-21 2002-06-05 Mitsubishi Denki Kabushiki Kaisha Refrigeration air-conditioner using a non-azeotrope refrigerant and having a control-information detecting apparatus
JP3341500B2 (en) * 1994-11-25 2002-11-05 株式会社日立製作所 Refrigeration apparatus and operating method thereof
JP3655681B2 (en) * 1995-06-23 2005-06-02 三菱電機株式会社 Refrigerant circulation system
JP3331102B2 (en) * 1995-08-16 2002-10-07 株式会社日立製作所 Refrigeration cycle capacity control device
JP3582185B2 (en) * 1995-10-24 2004-10-27 ダイキン工業株式会社 Heat transfer device
WO1997015789A1 (en) * 1995-10-24 1997-05-01 Daikin Industries, Ltd. Air conditioner
EP0837291B1 (en) * 1996-08-22 2005-01-12 Denso Corporation Vapor compression type refrigerating system
JPH10197171A (en) * 1996-12-27 1998-07-31 Daikin Ind Ltd Refrigerator and its manufacture
JPH11211250A (en) * 1998-01-21 1999-08-06 Denso Corp Supercritical freezing cycle
US6073454A (en) * 1998-07-10 2000-06-13 Spauschus Associates, Inc. Reduced pressure carbon dioxide-based refrigeration system
JP4045654B2 (en) * 1998-07-15 2008-02-13 株式会社日本自動車部品総合研究所 Supercritical refrigeration cycle
US6510698B2 (en) * 1999-05-20 2003-01-28 Mitsubishi Denki Kabushiki Kaisha Refrigeration system, and method of updating and operating the same
US6343482B1 (en) * 2000-10-31 2002-02-05 Takeshi Endo Heat pump type conditioner and exterior unit
JP2003028542A (en) * 2001-07-16 2003-01-29 Daikin Ind Ltd Refrigeration unit
ES2443644T3 (en) * 2002-03-18 2014-02-20 Daikin Industries, Ltd. Air conditioning system
EP1498668B1 (en) * 2002-03-29 2013-11-06 Daikin Industries, Ltd. Heat source unit of air conditioner and air conditioner
JP3714304B2 (en) * 2002-07-10 2005-11-09 ダイキン工業株式会社 Refrigeration equipment
WO2004013550A1 (en) * 2002-08-02 2004-02-12 Daikin Industries, Ltd. Refrigeration equipment
WO2004013549A1 (en) * 2002-08-02 2004-02-12 Daikin Industries, Ltd. Refrigeration equipment
KR100447204B1 (en) * 2002-08-22 2004-09-04 엘지전자 주식회사 Multi-type air conditioner for cooling/heating the same time and method for controlling the same
US7493775B2 (en) * 2002-10-30 2009-02-24 Mitsubishi Denki Kabushiki Kaisha Air conditioner
JP4069733B2 (en) * 2002-11-29 2008-04-02 三菱電機株式会社 Air conditioner
JP4208620B2 (en) * 2003-03-27 2009-01-14 三洋電機株式会社 Refrigerant cycle equipment
KR100496376B1 (en) * 2003-03-31 2005-06-22 한명범 Improvement system of energy efficiency for use in a refrigeration cycle
JP3858015B2 (en) * 2003-09-30 2006-12-13 三洋電機株式会社 Refrigerant circuit and heat pump water heater
US7096679B2 (en) * 2003-12-23 2006-08-29 Tecumseh Products Company Transcritical vapor compression system and method of operating including refrigerant storage tank and non-variable expansion device
JP4269323B2 (en) * 2004-03-29 2009-05-27 三菱電機株式会社 Heat pump water heater
BRPI0511969B1 (en) * 2004-06-11 2018-11-27 Daikin Ind Ltd air conditioner
JP3781046B2 (en) * 2004-07-01 2006-05-31 ダイキン工業株式会社 Air conditioner
NL1026728C2 (en) * 2004-07-26 2006-01-31 Antonie Bonte Improvement of cooling systems.
US7159408B2 (en) * 2004-07-28 2007-01-09 Carrier Corporation Charge loss detection and prognostics for multi-modular split systems
JP4459776B2 (en) * 2004-10-18 2010-04-28 三菱電機株式会社 Heat pump device and outdoor unit of heat pump device
JP2006283989A (en) * 2005-03-31 2006-10-19 Sanyo Electric Co Ltd Cooling/heating system
DE602007001038D1 (en) * 2006-01-31 2009-06-18 Sanyo Electric Co air conditioning
KR101199382B1 (en) * 2006-02-17 2012-11-09 엘지전자 주식회사 Air-conditioner and Controlling Method for the same
US20070251256A1 (en) * 2006-03-20 2007-11-01 Pham Hung M Flash tank design and control for heat pumps

Patent Citations (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JP2000205670A (en) * 1999-01-11 2000-07-28 Sanden Corp Vapor compression type refrigeration cycle
JP2001004235A (en) * 1999-06-22 2001-01-12 Sanden Corp Steam compression refrigeration cycle
JP2002168536A (en) * 2000-11-29 2002-06-14 Mitsubishi Heavy Ind Ltd Air conditioner
JP2004100979A (en) * 2002-09-05 2004-04-02 Matsushita Electric Ind Co Ltd Heat pump device
JP2005226950A (en) * 2004-02-16 2005-08-25 Mitsubishi Electric Corp Refrigerating air conditioner

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