AU2005286952B2 - Membrane steam reformer - Google Patents

Membrane steam reformer Download PDF

Info

Publication number
AU2005286952B2
AU2005286952B2 AU2005286952A AU2005286952A AU2005286952B2 AU 2005286952 B2 AU2005286952 B2 AU 2005286952B2 AU 2005286952 A AU2005286952 A AU 2005286952A AU 2005286952 A AU2005286952 A AU 2005286952A AU 2005286952 B2 AU2005286952 B2 AU 2005286952B2
Authority
AU
Australia
Prior art keywords
membrane
hydrogen
gas
distributed combustion
tube
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Ceased
Application number
AU2005286952A
Other languages
English (en)
Other versions
AU2005286952A1 (en
Inventor
Erik Edwin Engwall
Yi Hua Ma
Ivan Petrovich Mardilovich
Andreas Nicholas Matzakos
Scott Lee Wellington
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Worcester Polytechnic Institute
Original Assignee
Worcester Polytechnic Institute
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Worcester Polytechnic Institute filed Critical Worcester Polytechnic Institute
Publication of AU2005286952A1 publication Critical patent/AU2005286952A1/en
Application granted granted Critical
Publication of AU2005286952B2 publication Critical patent/AU2005286952B2/en
Anticipated expiration legal-status Critical
Ceased legal-status Critical Current

Links

Classifications

    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J8/00—Chemical or physical processes in general, conducted in the presence of fluids and solid particles; Apparatus for such processes
    • B01J8/008—Details of the reactor or of the particulate material; Processes to increase or to retard the rate of reaction
    • B01J8/009—Membranes, e.g. feeding or removing reactants or products to or from the catalyst bed through a membrane
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01D—SEPARATION
    • B01D53/00—Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols
    • B01D53/22—Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols by diffusion
    • B01D53/228—Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols by diffusion characterised by specific membranes
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01D—SEPARATION
    • B01D67/00—Processes specially adapted for manufacturing semi-permeable membranes for separation processes or apparatus
    • B01D67/0039—Inorganic membrane manufacture
    • B01D67/0069—Inorganic membrane manufacture by deposition from the liquid phase, e.g. electrochemical deposition
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01D—SEPARATION
    • B01D67/00—Processes specially adapted for manufacturing semi-permeable membranes for separation processes or apparatus
    • B01D67/0081—After-treatment of organic or inorganic membranes
    • B01D67/0088—Physical treatment with compounds, e.g. swelling, coating or impregnation
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01D—SEPARATION
    • B01D69/00—Semi-permeable membranes for separation processes or apparatus characterised by their form, structure or properties; Manufacturing processes specially adapted therefor
    • B01D69/10—Supported membranes; Membrane supports
    • B01D69/108—Inorganic support material
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01D—SEPARATION
    • B01D69/00—Semi-permeable membranes for separation processes or apparatus characterised by their form, structure or properties; Manufacturing processes specially adapted therefor
    • B01D69/12—Composite membranes; Ultra-thin membranes
    • B01D69/1214—Chemically bonded layers, e.g. cross-linking
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01D—SEPARATION
    • B01D71/00—Semi-permeable membranes for separation processes or apparatus characterised by the material; Manufacturing processes specially adapted therefor
    • B01D71/02—Inorganic material
    • B01D71/022—Metals
    • B01D71/0223—Group 8, 9 or 10 metals
    • B01D71/02231—Palladium
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01D—SEPARATION
    • B01D71/00—Semi-permeable membranes for separation processes or apparatus characterised by the material; Manufacturing processes specially adapted therefor
    • B01D71/02—Inorganic material
    • B01D71/022—Metals
    • B01D71/0223—Group 8, 9 or 10 metals
    • B01D71/02232—Nickel
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01D—SEPARATION
    • B01D71/00—Semi-permeable membranes for separation processes or apparatus characterised by the material; Manufacturing processes specially adapted therefor
    • B01D71/02—Inorganic material
    • B01D71/024—Oxides
    • B01D71/025—Aluminium oxide
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J19/00—Chemical, physical or physico-chemical processes in general; Their relevant apparatus
    • B01J19/24—Stationary reactors without moving elements inside
    • B01J19/2475—Membrane reactors
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B3/00—Hydrogen; Gaseous mixtures containing hydrogen; Separation of hydrogen from mixtures containing it; Purification of hydrogen; Reversible storage of hydrogen
    • C01B3/02—Production of hydrogen; Production of gaseous mixtures containing hydrogen
    • C01B3/32—Production of hydrogen; Production of gaseous mixtures containing hydrogen by reaction of gaseous or liquid organic compounds with gasifying agents, e.g. water, carbon dioxide or air
    • C01B3/34—Production of hydrogen; Production of gaseous mixtures containing hydrogen by reaction of gaseous or liquid organic compounds with gasifying agents, e.g. water, carbon dioxide or air by reaction of hydrocarbons with gasifying agents
    • C01B3/38—Production of hydrogen; Production of gaseous mixtures containing hydrogen by reaction of gaseous or liquid organic compounds with gasifying agents, e.g. water, carbon dioxide or air by reaction of hydrocarbons with gasifying agents using catalysts
    • C01B3/384—Production of hydrogen; Production of gaseous mixtures containing hydrogen by reaction of gaseous or liquid organic compounds with gasifying agents, e.g. water, carbon dioxide or air by reaction of hydrocarbons with gasifying agents using catalysts with external heating of the catalyst
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B3/00—Hydrogen; Gaseous mixtures containing hydrogen; Separation of hydrogen from mixtures containing it; Purification of hydrogen; Reversible storage of hydrogen
    • C01B3/50—Separation of hydrogen or hydrogen-containing gases from gaseous mixtures, e.g. purification
    • C01B3/501—Separation of hydrogen or hydrogen-containing gases from gaseous mixtures, e.g. purification by diffusion
    • C01B3/503—Separation of hydrogen or hydrogen-containing gases from gaseous mixtures, e.g. purification by diffusion characterised by membranes
    • C01B3/505—Membranes containing palladium
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01D—SEPARATION
    • B01D2325/00—Details relating to properties of membranes
    • B01D2325/20—Specific permeability or cut-off range
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01D—SEPARATION
    • B01D2325/00—Details relating to properties of membranes
    • B01D2325/32—Melting point or glass-transition temperatures
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B2203/00—Integrated processes for the production of hydrogen or synthesis gas
    • C01B2203/02—Processes for making hydrogen or synthesis gas
    • C01B2203/0205—Processes for making hydrogen or synthesis gas containing a reforming step
    • C01B2203/0227—Processes for making hydrogen or synthesis gas containing a reforming step containing a catalytic reforming step
    • C01B2203/0233—Processes for making hydrogen or synthesis gas containing a reforming step containing a catalytic reforming step the reforming step being a steam reforming step
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B2203/00—Integrated processes for the production of hydrogen or synthesis gas
    • C01B2203/04—Integrated processes for the production of hydrogen or synthesis gas containing a purification step for the hydrogen or the synthesis gas
    • C01B2203/0405—Purification by membrane separation
    • C01B2203/041—In-situ membrane purification during hydrogen production
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B2203/00—Integrated processes for the production of hydrogen or synthesis gas
    • C01B2203/04—Integrated processes for the production of hydrogen or synthesis gas containing a purification step for the hydrogen or the synthesis gas
    • C01B2203/0465—Composition of the impurity
    • C01B2203/047—Composition of the impurity the impurity being carbon monoxide
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B2203/00—Integrated processes for the production of hydrogen or synthesis gas
    • C01B2203/04—Integrated processes for the production of hydrogen or synthesis gas containing a purification step for the hydrogen or the synthesis gas
    • C01B2203/0465—Composition of the impurity
    • C01B2203/0475—Composition of the impurity the impurity being carbon dioxide
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B2203/00—Integrated processes for the production of hydrogen or synthesis gas
    • C01B2203/04—Integrated processes for the production of hydrogen or synthesis gas containing a purification step for the hydrogen or the synthesis gas
    • C01B2203/0465—Composition of the impurity
    • C01B2203/048—Composition of the impurity the impurity being an organic compound
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B2203/00—Integrated processes for the production of hydrogen or synthesis gas
    • C01B2203/04—Integrated processes for the production of hydrogen or synthesis gas containing a purification step for the hydrogen or the synthesis gas
    • C01B2203/0465—Composition of the impurity
    • C01B2203/0495—Composition of the impurity the impurity being water
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B2203/00—Integrated processes for the production of hydrogen or synthesis gas
    • C01B2203/80—Aspect of integrated processes for the production of hydrogen or synthesis gas not covered by groups C01B2203/02 - C01B2203/1695
    • C01B2203/86—Carbon dioxide sequestration
    • F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F23—COMBUSTION APPARATUS; COMBUSTION PROCESSES
    • F23C—METHODS OR APPARATUS FOR COMBUSTION USING FLUID FUEL OR SOLID FUEL SUSPENDED IN  A CARRIER GAS OR AIR 
    • F23C2900/00—Special features of, or arrangements for combustion apparatus using fluid fuels or solid fuels suspended in air; Combustion processes therefor
    • F23C2900/99001—Cold flame combustion or flameless oxidation processes
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02E—REDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
    • Y02E20/00—Combustion technologies with mitigation potential
    • Y02E20/34—Indirect CO2mitigation, i.e. by acting on non CO2directly related matters of the process, e.g. pre-heating or heat recovery
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02P—CLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
    • Y02P30/00—Technologies relating to oil refining and petrochemical industry

Landscapes

  • Chemical & Material Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Inorganic Chemistry (AREA)
  • Organic Chemistry (AREA)
  • Engineering & Computer Science (AREA)
  • Combustion & Propulsion (AREA)
  • Manufacturing & Machinery (AREA)
  • General Health & Medical Sciences (AREA)
  • Health & Medical Sciences (AREA)
  • Electrochemistry (AREA)
  • Analytical Chemistry (AREA)
  • General Chemical & Material Sciences (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • Hydrogen, Water And Hydrids (AREA)
  • Separation Using Semi-Permeable Membranes (AREA)
AU2005286952A 2004-09-21 2005-09-19 Membrane steam reformer Ceased AU2005286952B2 (en)

Applications Claiming Priority (3)

Application Number Priority Date Filing Date Title
US61168304P 2004-09-21 2004-09-21
US60/611,683 2004-09-21
PCT/US2005/033289 WO2006034100A1 (en) 2004-09-21 2005-09-19 Membrane steam reformer

Publications (2)

Publication Number Publication Date
AU2005286952A1 AU2005286952A1 (en) 2006-03-30
AU2005286952B2 true AU2005286952B2 (en) 2009-06-11

Family

ID=35658943

Family Applications (1)

Application Number Title Priority Date Filing Date
AU2005286952A Ceased AU2005286952B2 (en) 2004-09-21 2005-09-19 Membrane steam reformer

Country Status (7)

Country Link
EP (1) EP1789171A1 (https=)
JP (1) JP2008513338A (https=)
AU (1) AU2005286952B2 (https=)
CA (1) CA2580585A1 (https=)
NO (1) NO20071530L (https=)
TW (1) TW200619136A (https=)
WO (1) WO2006034100A1 (https=)

Families Citing this family (25)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US7531215B2 (en) * 2005-11-15 2009-05-12 Praxair Technology, Inc. Hydrogen transport membrane fabrication method
FR2898518B1 (fr) * 2006-03-17 2009-01-16 Inst Francais Du Petrole Reacteur echangeur a combustion interne pour reaction endothermique en lit fixe
AU2008236737A1 (en) 2007-04-05 2008-10-16 Worcester Polytechnic Institute Composite structures with porous anodic oxide layers and methods of fabrication
JP4990044B2 (ja) * 2007-06-26 2012-08-01 独立行政法人産業技術総合研究所 酸素分離膜、およびその製造方法
JP4993496B2 (ja) * 2007-10-24 2012-08-08 独立行政法人産業技術総合研究所 酸素分離膜、及びその製造方法
JP5173931B2 (ja) * 2009-05-20 2013-04-03 大日本印刷株式会社 水素選択透過膜およびその製造方法
US8652239B2 (en) 2010-05-03 2014-02-18 Worcester Polytechnic Institute High permeance sulfur tolerant Pd/Cu alloy membranes
KR101763609B1 (ko) * 2014-08-13 2017-08-02 한국과학기술연구원 폴리벤지이미다졸계 고분자 막을 지지체로 하는 팔라듐 도금 분리막 및 그 제조 방법
CN106430095B (zh) * 2016-08-29 2018-08-07 东营科尔特化工科技有限公司 一种甲乙酮装置副产氢气物料脱杂质的方法
CN112919409A (zh) * 2019-12-06 2021-06-08 中国科学院大连化学物理研究所 一种金属膜分离器及应用
US11492255B2 (en) 2020-04-03 2022-11-08 Saudi Arabian Oil Company Steam methane reforming with steam regeneration
US11322766B2 (en) 2020-05-28 2022-05-03 Saudi Arabian Oil Company Direct hydrocarbon metal supported solid oxide fuel cell
US11639290B2 (en) 2020-06-04 2023-05-02 Saudi Arabian Oil Company Dry reforming of methane with carbon dioxide at elevated pressure
US11492254B2 (en) 2020-06-18 2022-11-08 Saudi Arabian Oil Company Hydrogen production with membrane reformer
US11583824B2 (en) 2020-06-18 2023-02-21 Saudi Arabian Oil Company Hydrogen production with membrane reformer
US11999619B2 (en) 2020-06-18 2024-06-04 Saudi Arabian Oil Company Hydrogen production with membrane reactor
US12220666B2 (en) 2021-01-12 2025-02-11 Saudi Arabian Oil Company Ultrathin membrane fabrication
US11718575B2 (en) 2021-08-12 2023-08-08 Saudi Arabian Oil Company Methanol production via dry reforming and methanol synthesis in a vessel
US11787759B2 (en) 2021-08-12 2023-10-17 Saudi Arabian Oil Company Dimethyl ether production via dry reforming and dimethyl ether synthesis in a vessel
US12258272B2 (en) 2021-08-12 2025-03-25 Saudi Arabian Oil Company Dry reforming of methane using a nickel-based bi-metallic catalyst
US11578016B1 (en) 2021-08-12 2023-02-14 Saudi Arabian Oil Company Olefin production via dry reforming and olefin synthesis in a vessel
US11617981B1 (en) 2022-01-03 2023-04-04 Saudi Arabian Oil Company Method for capturing CO2 with assisted vapor compression
DE102022103269A1 (de) 2022-02-11 2023-08-17 Karlsruher Institut für Technologie Katalytischer membranreaktor
CN115463523B (zh) * 2022-11-02 2023-03-24 中国华能集团清洁能源技术研究院有限公司 吸收塔和碳捕集系统
IT202300017721A1 (it) * 2023-08-29 2025-03-01 Milano Politecnico Reattore a flusso radiale riscaldato elettricamente in modo diretto per processi catalitici endotermici

Citations (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US5217506A (en) * 1990-08-10 1993-06-08 Bend Research, Inc. Hydrogen-permeable composite metal membrane and uses thereof
US5393325A (en) * 1990-08-10 1995-02-28 Bend Research, Inc. Composite hydrogen separation metal membrane
US5498278A (en) * 1990-08-10 1996-03-12 Bend Research, Inc. Composite hydrogen separation element and module
WO1999030806A1 (en) * 1997-12-15 1999-06-24 Worcester Polytechnic Institute Hydrogen gas-extraction module
WO2002066144A2 (fr) * 2001-02-19 2002-08-29 Compagnie D'etude Des Techniques De L'hydrogene (Ceth) Structures composites de membranes selectivement permeables a l'hydrogene et processeurs de gaz combustibles en faisant usage
WO2004098751A1 (en) * 2003-05-02 2004-11-18 Worcester Polytechnic Institute Composite gas separation modules having high tamman temperature intermediate layers

Family Cites Families (10)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US5139541A (en) * 1990-08-10 1992-08-18 Bend Research, Inc. Hydrogen-permeable composite metal membrane
JPH04346824A (ja) * 1991-05-21 1992-12-02 Mitsubishi Heavy Ind Ltd 水素分離膜
JPH0585702A (ja) * 1991-09-30 1993-04-06 Mitsubishi Heavy Ind Ltd 水素分離膜の製造方法
JP3117276B2 (ja) * 1992-04-09 2000-12-11 三菱重工業株式会社 水素分離膜
JP3621785B2 (ja) * 1996-07-12 2005-02-16 トヨタ自動車株式会社 水素分離構造体
JP2001286742A (ja) * 2000-04-10 2001-10-16 Mitsubishi Heavy Ind Ltd 水素分離膜
JP2002219341A (ja) * 2001-01-30 2002-08-06 Kobe Steel Ltd 水素選択透過膜支持用基材および水素選択透過部材
DE10135390A1 (de) * 2001-07-25 2003-02-20 Fraunhofer Ges Forschung Metallische Lösungs-Diffusions-Membran sowie Verfahren zur Herstellung
AU2003268522A1 (en) * 2002-09-05 2004-03-29 Miglin, Maria, Therese Apparatus and process for production of high purity hydrogen
US7175694B2 (en) * 2003-03-21 2007-02-13 Worcester Polytechnic Institute Composite gas separation modules having intermediate porous metal layers

Patent Citations (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US5217506A (en) * 1990-08-10 1993-06-08 Bend Research, Inc. Hydrogen-permeable composite metal membrane and uses thereof
US5393325A (en) * 1990-08-10 1995-02-28 Bend Research, Inc. Composite hydrogen separation metal membrane
US5498278A (en) * 1990-08-10 1996-03-12 Bend Research, Inc. Composite hydrogen separation element and module
WO1999030806A1 (en) * 1997-12-15 1999-06-24 Worcester Polytechnic Institute Hydrogen gas-extraction module
WO2002066144A2 (fr) * 2001-02-19 2002-08-29 Compagnie D'etude Des Techniques De L'hydrogene (Ceth) Structures composites de membranes selectivement permeables a l'hydrogene et processeurs de gaz combustibles en faisant usage
WO2004098751A1 (en) * 2003-05-02 2004-11-18 Worcester Polytechnic Institute Composite gas separation modules having high tamman temperature intermediate layers

Non-Patent Citations (2)

* Cited by examiner, † Cited by third party
Title
EDLUND D J et al: 'The relationship between inter-metallic diffusion and flux decline in composite-metal membranes: implications for achieving long membrane lifetime', JOURNAL OF MEMBRANE SCIENCE, ELSEVIER SCINENTIFIC PUBLICATIONS COMPANY. *
SHU J et al: 'Structurally stable composite Pd-Ag alloy membranes: Introduction of a diffusion barrier'. THIN SOLID FILMS, ELSEVIER-SEQUIOA S.A LAUSANNE, CH, vol. 286, no. 1, 30 September 1996, pages 72- 79, XP004049419, ISSN: 00040-6090 *

Also Published As

Publication number Publication date
NO20071530L (no) 2007-04-20
AU2005286952A1 (en) 2006-03-30
WO2006034100A1 (en) 2006-03-30
TW200619136A (en) 2006-06-16
CA2580585A1 (en) 2006-03-30
JP2008513338A (ja) 2008-05-01
EP1789171A1 (en) 2007-05-30

Similar Documents

Publication Publication Date Title
AU2005286952B2 (en) Membrane steam reformer
AU2005287034B2 (en) Membrane enhanced reactor
AU2005286955B2 (en) Reactor and process for steam reforming
CN107073427B (zh) 用于重整天然气的壳管式反应器和使用其制备合成气或氢气的方法
JP4279548B2 (ja) 合成ガスを製造するための混合伝導膜
US8518151B2 (en) Porous hollow fiber supported dense membrane for hydrogen production, separation, or purification
US7018446B2 (en) Metal gas separation membrane
JP5366556B2 (ja) 酸化反応器および酸化方法
EP1663512B1 (en) Method for providing thin hydrogen separation membranes
AU2001295502A1 (en) Mixed conducting membranes for syngas production
Li et al. Development of palladium-alloy membranes for hydrogen separation and purification
US20140251131A1 (en) Palladium-alloyed membranes and methods of making and using the same
KR102344813B1 (ko) 프리리포머(pre-reformer) 및 분리막 리포머를 이용한 수소 생산 장치 및 공정
RU2305587C2 (ru) Композитная кислородпроводящая мембрана
KR102482676B1 (ko) 원통형 또는 튜브형 지지체 상에 분말 입자들이 순차적으로 적층되어 결정화된 적층막의 제조방법
Tanaka et al. Recent Developments on Supported Pd Membranes for Hydrogen Separation and Membrane Reactors
TWI473760B (zh) 膜管複合體及利用該複合體之高純度氫氣產生裝置
Iaquaniello et al. Palladium-based selective membranes for hydrogen production
She Composite palladium membranes: synthesis, separation and reaction

Legal Events

Date Code Title Description
FGA Letters patent sealed or granted (standard patent)
MK14 Patent ceased section 143(a) (annual fees not paid) or expired