AU2003294764A1 - Organometallic transition metal compound, biscyclopentadienyl ligand system, catalyst system and process for preparing polyolefins - Google Patents

Organometallic transition metal compound, biscyclopentadienyl ligand system, catalyst system and process for preparing polyolefins

Info

Publication number
AU2003294764A1
AU2003294764A1 AU2003294764A AU2003294764A AU2003294764A1 AU 2003294764 A1 AU2003294764 A1 AU 2003294764A1 AU 2003294764 A AU2003294764 A AU 2003294764A AU 2003294764 A AU2003294764 A AU 2003294764A AU 2003294764 A1 AU2003294764 A1 AU 2003294764A1
Authority
AU
Australia
Prior art keywords
transition metal
metal compound
preparing polyolefins
organometallic transition
catalyst system
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Abandoned
Application number
AU2003294764A
Other languages
English (en)
Inventor
Yoshikuni Okumura
Jorg Schottek
Jorg Schulte
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Basell Polyolefine GmbH
Original Assignee
Basell Polyolefine GmbH
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Priority claimed from DE10257332A external-priority patent/DE10257332A1/de
Application filed by Basell Polyolefine GmbH filed Critical Basell Polyolefine GmbH
Publication of AU2003294764A1 publication Critical patent/AU2003294764A1/en
Abandoned legal-status Critical Current

Links

Classifications

    • CCHEMISTRY; METALLURGY
    • C07ORGANIC CHEMISTRY
    • C07FACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
    • C07F17/00Metallocenes
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J31/00Catalysts comprising hydrides, coordination complexes or organic compounds
    • B01J31/16Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes
    • B01J31/22Organic complexes
    • B01J31/2282Unsaturated compounds used as ligands
    • B01J31/2295Cyclic compounds, e.g. cyclopentadienyls
    • CCHEMISTRY; METALLURGY
    • C07ORGANIC CHEMISTRY
    • C07CACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C13/00Cyclic hydrocarbons containing rings other than, or in addition to, six-membered aromatic rings
    • C07C13/28Polycyclic hydrocarbons or acyclic hydrocarbon derivatives thereof
    • C07C13/32Polycyclic hydrocarbons or acyclic hydrocarbon derivatives thereof with condensed rings
    • C07C13/45Polycyclic hydrocarbons or acyclic hydrocarbon derivatives thereof with condensed rings with a bicyclo ring system containing nine carbon atoms
    • C07C13/465Indenes; Completely or partially hydrogenated indenes
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08FMACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F110/00Homopolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
    • C08F110/04Monomers containing three or four carbon atoms
    • C08F110/06Propene
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2531/00Additional information regarding catalytic systems classified in B01J31/00
    • B01J2531/40Complexes comprising metals of Group IV (IVA or IVB) as the central metal
    • B01J2531/48Zirconium
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08FMACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F4/00Polymerisation catalysts
    • C08F4/42Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
    • C08F4/44Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
    • C08F4/60Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
    • C08F4/62Refractory metals or compounds thereof
    • C08F4/64Titanium, zirconium, hafnium or compounds thereof
    • C08F4/659Component covered by group C08F4/64 containing a transition metal-carbon bond
    • C08F4/65912Component covered by group C08F4/64 containing a transition metal-carbon bond in combination with an organoaluminium compound
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08FMACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F4/00Polymerisation catalysts
    • C08F4/42Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
    • C08F4/44Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
    • C08F4/60Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
    • C08F4/62Refractory metals or compounds thereof
    • C08F4/64Titanium, zirconium, hafnium or compounds thereof
    • C08F4/659Component covered by group C08F4/64 containing a transition metal-carbon bond
    • C08F4/65916Component covered by group C08F4/64 containing a transition metal-carbon bond supported on a carrier, e.g. silica, MgCl2, polymer
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10TECHNICAL SUBJECTS COVERED BY FORMER USPC
    • Y10STECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10S526/00Synthetic resins or natural rubbers -- part of the class 520 series
    • Y10S526/941Synthetic resins or natural rubbers -- part of the class 520 series having the transition metal bonded directly to carbon
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10TECHNICAL SUBJECTS COVERED BY FORMER USPC
    • Y10STECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10S526/00Synthetic resins or natural rubbers -- part of the class 520 series
    • Y10S526/943Polymerization with metallocene catalysts

Landscapes

  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Health & Medical Sciences (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Inorganic Chemistry (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Transition And Organic Metals Composition Catalysts For Addition Polymerization (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
AU2003294764A 2002-12-06 2003-12-02 Organometallic transition metal compound, biscyclopentadienyl ligand system, catalyst system and process for preparing polyolefins Abandoned AU2003294764A1 (en)

Applications Claiming Priority (5)

Application Number Priority Date Filing Date Title
DE10257332A DE10257332A1 (de) 2002-12-06 2002-12-06 Organoübergangsmetallverbindung, Biscyclopentadienylligandsystem, Katalysatorsystem und Verfahren zur Herstellung von Polyolefinen
DE10257332.8 2002-12-06
US44459503P 2003-02-03 2003-02-03
US60/444,595 2003-02-03
PCT/EP2003/013553 WO2004052945A1 (en) 2002-12-06 2003-12-02 Organometallic transition metal compound, biscyclopentadienyl ligand system, catalyst system and process for preparing polyolefins

Publications (1)

Publication Number Publication Date
AU2003294764A1 true AU2003294764A1 (en) 2004-06-30

Family

ID=32509743

Family Applications (1)

Application Number Title Priority Date Filing Date
AU2003294764A Abandoned AU2003294764A1 (en) 2002-12-06 2003-12-02 Organometallic transition metal compound, biscyclopentadienyl ligand system, catalyst system and process for preparing polyolefins

Country Status (5)

Country Link
US (1) US7405261B2 (enExample)
EP (1) EP1567560B1 (enExample)
JP (1) JP2006512410A (enExample)
AU (1) AU2003294764A1 (enExample)
WO (1) WO2004052945A1 (enExample)

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* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US7638915B2 (en) * 2006-08-31 2009-12-29 Smartin Technologies Llc Modular magneto-mechanical device
EP2532687A3 (en) 2011-06-10 2013-04-10 Borealis AG Bridged Metallocene Catalysts
WO2014096171A1 (en) 2012-12-21 2014-06-26 Borealis Ag Catalyst
EP2746301B1 (en) 2012-12-21 2018-05-30 Borealis AG Catalyst
EP2746289B1 (en) 2012-12-21 2017-09-27 Borealis AG Catalysts
JP2016531978A (ja) 2013-07-17 2016-10-13 エクソンモービル ケミカル パテンツ インコーポレイテッド 置換メタロセン触媒
WO2015009472A1 (en) 2013-07-17 2015-01-22 Exxonmobil Chemcal Patents Inc. Metallocenes and catalyst compositions derived therefrom
EP3022233B1 (en) 2013-07-17 2019-05-01 ExxonMobil Chemical Patents Inc. Cyclopropyl substituted metallocene catalysts
EP3022236B1 (en) 2013-07-17 2017-11-15 ExxonMobil Chemical Patents Inc. Process using substituted metallocene catalysts and products therefrom
US9938364B2 (en) 2013-07-17 2018-04-10 Exxonmobil Chemical Patents Inc. Substituted metallocene catalysts
EP3022235B1 (en) 2013-07-17 2020-04-08 ExxonMobil Chemical Patents Inc. Metallocenes and catalyst compositions derived therefrom
GB201420215D0 (en) * 2014-11-13 2014-12-31 Scg Chemicals Co Ltd Catalysts
US10759886B2 (en) 2015-06-05 2020-09-01 Exxonmobil Chemical Patents Inc. Single reactor production of polymers in gas or slurry phase
WO2016196331A1 (en) 2015-06-05 2016-12-08 Exxonmobil Chemical Patents Inc. Supported metallocene catalyst systems for polymerization
US10294316B2 (en) 2015-06-05 2019-05-21 Exxonmobil Chemical Patents Inc. Silica supports with high aluminoxane loading capability
US10329360B2 (en) 2015-06-05 2019-06-25 Exxonmobil Chemical Patents Inc. Catalyst system comprising supported alumoxane and unsupported alumoxane particles
EP3303422B1 (en) 2015-06-05 2021-03-17 ExxonMobil Chemical Patents Inc. Production of heterophasic polymers in gas or slurry phase
US10280235B2 (en) 2015-06-05 2019-05-07 Exxonmobil Chemical Patents Inc. Catalyst system containing high surface area supports and sequential polymerization to produce heterophasic polymers
US9809664B2 (en) 2015-06-05 2017-11-07 Exxonmobil Chemical Patents Inc. Bimodal propylene polymers and sequential polymerization
US10280233B2 (en) 2015-06-05 2019-05-07 Exxonmobil Chemical Patents Inc. Catalyst systems and methods of making and using the same
US9988410B2 (en) 2015-07-15 2018-06-05 Exxonmobil Chemical Patents Inc. Substituted bis indenyl metallocene catalyst compounds comprising-Si—Si-bridge
CN106565871B (zh) * 2015-10-13 2019-07-30 中国石油化工股份有限公司 烯烃聚合用催化剂组分及其制备方法和聚乙烯的制备方法
US11059918B2 (en) 2016-05-27 2021-07-13 Exxonmobil Chemical Patents Inc. Metallocene catalyst compositions and polymerization process therewith
US11130827B2 (en) 2017-11-14 2021-09-28 Exxonmobil Chemical Patents Inc. Polyethylene compositions and articles made therefrom
WO2019099250A1 (en) 2017-11-14 2019-05-23 Exxonmobil Chemical Patents Inc. (di)silicon bridged metallocenes that produce polyethylene broad molecular weight distribution and molecular weight
US11214631B2 (en) 2017-11-14 2022-01-04 Exxonmobil Chemical Patents Inc. (Di)silicon bridged metallocenes that produce polyethylene with broad molecular weight distribution and high molecular weight
US11472828B2 (en) 2019-10-11 2022-10-18 Exxonmobil Chemical Patents Inc. Indacene based metallocene catalysts useful in the production of propylene polymers

Family Cites Families (15)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
DE69033368T3 (de) 1990-01-02 2008-07-03 Exxon Chemical Patents, Inc. Ionische Metallocenkatalysatoren auf Träger für Olefinpolymerisation
TW294669B (enExample) * 1992-06-27 1997-01-01 Hoechst Ag
DE69431222T2 (de) 1993-06-07 2003-04-17 Mitsui Chemicals, Inc. Übergangsmetallverbindung, und diese enthaltender Polymerisationkatalysator
CA2193882C (en) 1994-06-24 2005-07-26 Anthony Nicholas Speca Polymerization catalyst systems, their production and use
CN1076282C (zh) * 1995-03-02 2001-12-19 三井化学株式会社 聚丙烯复合膜
DE19517851A1 (de) * 1995-05-16 1996-11-21 Hoechst Ag Organometallverbindung
DE19757563A1 (de) * 1997-03-07 1999-07-08 Targor Gmbh Geträgertes Katalysatorsystem, Verfahren zur Herstellung und seine Verwendung zur Polymerisation von Olefinen
AU7332398A (en) * 1997-03-07 1998-09-29 Targor Gmbh Method for producing olefin polymers with a higher melting point
US6492539B1 (en) * 1997-03-07 2002-12-10 Basell Polypropylen Gmbh Preparation of preparing substituted indanones
DE19733017A1 (de) 1997-07-31 1999-02-04 Hoechst Ag Chemische Verbindung
DE19804970A1 (de) * 1998-02-07 1999-08-12 Aventis Res & Tech Gmbh & Co Katalysatorsystem
DE19833170A1 (de) 1998-07-23 2000-01-27 Targor Gmbh Verfahren zur Herstellung eines metallhaltigen Trägerkatalysators oder einer Trägerkatalysatorkomponente durch Tränkung einer Trägersubstanz
BR9906934B1 (pt) 1998-11-25 2010-08-24 composto, catalisador, processo para preparar uma poliolefina, e, uso de um catalisador.
ATE293632T1 (de) * 2000-08-29 2005-05-15 Basell Polyolefine Gmbh Verfahren zur herstellung von alkylverbrückten ligandsystemen und übergangsmetallverbindungen
WO2004037756A1 (en) 2002-10-22 2004-05-06 Basell Polyolefine Gmbh Preparation of substituted indenes

Also Published As

Publication number Publication date
JP2006512410A (ja) 2006-04-13
US20060122345A1 (en) 2006-06-08
EP1567560B1 (en) 2011-01-19
US7405261B2 (en) 2008-07-29
WO2004052945A1 (en) 2004-06-24
EP1567560A1 (en) 2005-08-31

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MK6 Application lapsed section 142(2)(f)/reg. 8.3(3) - pct applic. not entering national phase