ATE90951T1 - Haarrissbildungsbestaendige, lineare, polymodale blockcopolymere mit endbloecken von kontinuierlich sich aendernder zusammensetzung. - Google Patents

Haarrissbildungsbestaendige, lineare, polymodale blockcopolymere mit endbloecken von kontinuierlich sich aendernder zusammensetzung.

Info

Publication number
ATE90951T1
ATE90951T1 AT87104253T AT87104253T ATE90951T1 AT E90951 T1 ATE90951 T1 AT E90951T1 AT 87104253 T AT87104253 T AT 87104253T AT 87104253 T AT87104253 T AT 87104253T AT E90951 T1 ATE90951 T1 AT E90951T1
Authority
AT
Austria
Prior art keywords
stage
monomer
conjugated diene
polymerization
monovinylaromatic
Prior art date
Application number
AT87104253T
Other languages
English (en)
Inventor
Alonzo Gene Kitchen
Frank John Szalla
Original Assignee
Phillips Petroleum Co
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Phillips Petroleum Co filed Critical Phillips Petroleum Co
Application granted granted Critical
Publication of ATE90951T1 publication Critical patent/ATE90951T1/de

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F293/00—Macromolecular compounds obtained by polymerisation on to a macromolecule having groups capable of inducing the formation of new polymer chains bound exclusively at one or both ends of the starting macromolecule
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F297/00—Macromolecular compounds obtained by successively polymerising different monomer systems using a catalyst of the ionic or coordination type without deactivating the intermediate polymer
    • C08F297/02—Macromolecular compounds obtained by successively polymerising different monomer systems using a catalyst of the ionic or coordination type without deactivating the intermediate polymer using a catalyst of the anionic type
    • C08F297/04—Macromolecular compounds obtained by successively polymerising different monomer systems using a catalyst of the ionic or coordination type without deactivating the intermediate polymer using a catalyst of the anionic type polymerising vinyl aromatic monomers and conjugated dienes

Landscapes

  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Health & Medical Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Inorganic Chemistry (AREA)
  • Graft Or Block Polymers (AREA)
  • Compositions Of Macromolecular Compounds (AREA)
  • Macromolecular Compounds Obtained By Forming Nitrogen-Containing Linkages In General (AREA)
  • Polymerization Catalysts (AREA)
  • Agricultural Chemicals And Associated Chemicals (AREA)
  • Cosmetics (AREA)
AT87104253T 1986-03-24 1987-03-23 Haarrissbildungsbestaendige, lineare, polymodale blockcopolymere mit endbloecken von kontinuierlich sich aendernder zusammensetzung. ATE90951T1 (de)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
US06/843,443 US4704434A (en) 1986-03-24 1986-03-24 Craze-resistant polymodal linear block copolymers with terminal tapered blocks
EP87104253A EP0242614B1 (de) 1986-03-24 1987-03-23 Haarrissbildungsbeständige, lineare, polymodale Blockcopolymere mit Endblöcken von kontinuierlich sich ändernder Zusammensetzung

Publications (1)

Publication Number Publication Date
ATE90951T1 true ATE90951T1 (de) 1993-07-15

Family

ID=25289993

Family Applications (1)

Application Number Title Priority Date Filing Date
AT87104253T ATE90951T1 (de) 1986-03-24 1987-03-23 Haarrissbildungsbestaendige, lineare, polymodale blockcopolymere mit endbloecken von kontinuierlich sich aendernder zusammensetzung.

Country Status (13)

Country Link
US (1) US4704434A (de)
EP (1) EP0242614B1 (de)
JP (1) JPS62232419A (de)
KR (1) KR930002902B1 (de)
CN (1) CN87100183A (de)
AT (1) ATE90951T1 (de)
CA (1) CA1257029A (de)
DE (1) DE3786295T2 (de)
ES (1) ES2041250T3 (de)
HK (1) HK83794A (de)
IN (1) IN168085B (de)
MX (1) MX166468B (de)
ZA (1) ZA871595B (de)

Families Citing this family (49)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
LU86698A1 (fr) * 1986-12-04 1988-07-14 Labofina Sa Procede pour fabriquer des copolymeres blocs transparents
US4956408A (en) * 1988-06-13 1990-09-11 Phillips Petroleum Company Complex acrylates as stabilizer for conjugated diene/monovinyl aromatic copolymers
CA2028410C (en) * 1990-01-02 1996-09-17 William J. Trepka Tapered block styrene/butadiene copolymers
US5319033A (en) * 1990-01-02 1994-06-07 Phillips Petroleum Company Tapered block monovinyl aromatic/conjugated diene copolymer
US5227419A (en) * 1990-12-20 1993-07-13 Phillips Petroleum Company Tapered block styrene/butadiene copolymers
US5223579A (en) * 1991-01-28 1993-06-29 Shell Oil Company Solid viscosity index improvers which provide excellant low temperature viscosity
US5256736A (en) * 1991-05-08 1993-10-26 Phillips Petroleum Company Tapered block copolymers of conjugated dienes and monovinylarenes
US5272207A (en) * 1992-01-31 1993-12-21 Bridgestone Corporation Process for continuously producing cyclicly tapered SBR-type copolymers
US5290875A (en) * 1992-11-30 1994-03-01 Phillips Petroleum Company Conjugated diene/monovinylarene block copolymers with multiple tapered blocks
US5296547A (en) * 1993-01-28 1994-03-22 Minnesota Mining And Manufacturing Company Block copolymer having mixed molecular weight endblocks
US5405903A (en) * 1993-03-30 1995-04-11 Shell Oil Company Process for the preparation of a block copolymer blend
CA2117708C (en) * 1993-09-30 2002-10-22 William J. Trepka Block copolymers of monovinylarenes and conjugated dienes and preparation thereof
US5436298A (en) * 1993-09-30 1995-07-25 Phillips Petroleum Company Block copolymers of monovinylarenes and conjugated dienes and preparation thereof
CA2134026C (en) * 1993-11-15 1998-06-09 William J. Trepka Tapered block copolymers of monovinylarenes and conjugated dienes
TW283152B (de) * 1993-11-18 1996-08-11 Shell Internat Res Schappej Bv
US5399628A (en) * 1993-12-02 1995-03-21 Phillips Petroleum Company Block copolymers of monovinylarenes and conjugated dienes containing two interior tapered blocks
FR2714384B1 (fr) * 1993-12-29 1996-02-02 Atochem Elf Sa Copolymère bloc étoile d'un monomère vinylaromatique et d'un diène conjugué, son procédé d'obtention, et les compositions comprenant ledit copolymère et du polystyrène cristal.
US6835778B2 (en) * 1995-08-29 2004-12-28 Chevron Phillips Chemical Company Lp Conjugated diene/monovinylarene block copolymers blends
US6096828A (en) 1995-08-29 2000-08-01 Phillips Petroleum Company Conjugated diene/monovinylarene block copolymers, methods for preparing same, and polymer blends
US5649874A (en) * 1996-08-05 1997-07-22 Marble Vision Inc. Transparent ball with insert, and process of manufacture thereof
US6630531B1 (en) * 2000-02-02 2003-10-07 3M Innovative Properties Company Adhesive for bonding to low surface energy surfaces
US20030211308A1 (en) * 2001-02-02 2003-11-13 Khandpur Ashish K Adhesive for bonding to low surface energy surfaces
KR100425243B1 (ko) * 2001-11-14 2004-03-30 주식회사 엘지화학 선형의 블록 공중합체의 제조방법
KR100466941B1 (ko) * 2001-12-12 2005-01-24 금호석유화학 주식회사 투명한 블록공중합체 수지의 제조방법
KR100452812B1 (ko) 2002-05-15 2004-10-14 금호석유화학 주식회사 2조성 선형 블락 공중합체，제조방법 및 용도
KR100452813B1 (ko) * 2002-05-15 2004-10-14 금호석유화학 주식회사 2조성 선형 블락 공중합체， 그 제조방법 및 용도
US20040115381A1 (en) * 2002-12-12 2004-06-17 Chevron Phillips Chemical Company, Lp Method for manufacturing articles with materials containing tapered polymers
US20050090587A1 (en) * 2003-10-28 2005-04-28 Dunn John E. Ultraviolet light stability of monovinylarene-conjugated diene copolymer compositions
US7037980B2 (en) * 2003-11-10 2006-05-02 Chevron Phillips Chemical Company, Lp Monovinylarene/conjugated diene copolymers having lower glass transition temperatures
US20050166551A1 (en) * 2004-02-02 2005-08-04 Keane J. A. Multilayer high clarity shrink film comprising monovinylarene-conjugated diene copolymer
US7717893B2 (en) 2004-06-04 2010-05-18 The Procter & Gamble Company Absorbent articles comprising a slow recovery elastomer
US7905872B2 (en) * 2004-06-04 2011-03-15 The Procter & Gamble Company Absorbent articles comprising a slow recovery stretch laminate
US8419701B2 (en) 2005-01-10 2013-04-16 The Procter & Gamble Company Absorbent articles with stretch zones comprising slow recovery elastic materials
MX2007008590A (es) 2005-01-26 2007-08-14 Procter & Gamble Panal desechable tipo calzon que tiene una cintura elastica de recuperacion lenta con fuerza baja.
US20070269670A1 (en) * 2006-05-17 2007-11-22 Ronald Wilmer Multilayered structures and their use as optical storage media
US8415429B2 (en) 2006-12-11 2013-04-09 Chervron Phillips Chemical Company LP Styrene butadiene block copolymers for film applications
US8323257B2 (en) 2007-11-21 2012-12-04 The Procter & Gamble Company Absorbent articles comprising a slow recovery stretch laminate and method for making the same
US9017305B2 (en) 2010-11-12 2015-04-28 The Procter Gamble Company Elastomeric compositions that resist force loss and disintegration
US9441090B1 (en) 2015-03-12 2016-09-13 Chevron Phillips Chemical Company Lp Methods for controlling hardness of styrene-butadiene block copolymers
US9598524B1 (en) 2015-09-18 2017-03-21 Chevron Phillips Chemical Company Lp Styrene-butadiene block copolymers with a terminal butadiene block for tubing applications
US9540475B2 (en) 2015-03-12 2017-01-10 Chevron Phillips Chemical Company Lp Styrene-butadiene block copolymers for tubing applications
US9738781B2 (en) 2015-09-03 2017-08-22 Ineos Styrolution Group Gmbh Blends of styrene-butadiene block copolymer with styrenic thermoplastic elastomers for tubing applications
US9828455B2 (en) 2016-02-24 2017-11-28 Ineos Styrolution Group Gmbh Styrene-butadiene block copolymers with an internal butadiene block for tubing applications
US10023676B2 (en) 2016-02-24 2018-07-17 Ineos Styrolution Group Gmbh Styrene-butadiene block copolymers with an internal butadiene block for tubing applications
CN106397696B (zh) * 2016-08-31 2019-03-22 广东众和化塑有限公司 一种同时具备高透、高抗曲折性和高发泡效率的sbs弹性体及其制备方法
WO2018194028A1 (ja) * 2017-04-18 2018-10-25 株式会社ブリヂストン 多元共重合体の製造方法、多元共重合体、ゴム組成物およびタイヤ
KR20200123140A (ko) 2018-02-16 2020-10-28 이네오스 스티롤루션 그룹 게엠베하 높은 내열성 abs 성형 조성물
WO2019201784A1 (en) 2018-04-16 2019-10-24 Ineos Styrolution Group Gmbh Ultra-high flow acrylonitrile butadiene styrene copolymer compositions
CN112334533B (zh) 2018-04-16 2024-02-06 英力士苯领集团股份公司 超高流量苯乙烯丙烯腈共聚物组合物

Family Cites Families (35)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US953011A (en) * 1907-05-28 1910-03-22 Oneida Steel Pulley Company Sheet-metal pulley.
US967004A (en) * 1907-06-17 1910-08-09 Hatchik Ehikian Knee-cushion.
US3507934A (en) * 1965-12-20 1970-04-21 Shell Oil Co Block copolymer compositions having improved processability
US3639517A (en) * 1969-09-22 1972-02-01 Phillips Petroleum Co Resinous branched block copolymers
US4054616A (en) * 1973-09-29 1977-10-18 Sumitomo Chemical Company, Limited Process for producing transparent block copolymer resins
US4089913A (en) * 1974-01-10 1978-05-16 Sumitomo Chemical Company, Limited Process for producing transparent block copolymer resin
JPS5232774B2 (de) * 1974-02-02 1977-08-24
US4122134A (en) * 1974-02-13 1978-10-24 Sumitomo Chemical Company, Limited Method for producing transparent block copolymer resin
US3937760A (en) * 1974-04-29 1976-02-10 The Firestone Tire & Rubber Company Process for producing multiblock copolymer and products produced thereby
US4208356A (en) * 1974-09-17 1980-06-17 Asahi Kasei Kogyo Kabushiki Kaisha Process for producing mixture of block copolymers
US3987006A (en) * 1975-08-14 1976-10-19 Phillips Petroleum Company Carbon dioxide and excess water treatment of polymer stabilized with phosphite and glycine
UST953011I4 (en) 1975-11-07 1976-12-07 The Firestone Tire & Rubber Company Transparent impact polystyrene plastics of multiple block copolymers
DE2550226C2 (de) * 1975-11-08 1984-12-13 Basf Ag, 6700 Ludwigshafen Verzweigte Blockcopolymerisate und Verfahren zu ihrer Herstellung
US4167545A (en) * 1975-11-08 1979-09-11 Basf Aktiengesellschaft Branched block copolymers and their manufacture
US4080407A (en) * 1975-11-10 1978-03-21 Phillips Petroleum Company Resinous linear copolymers having blocks with a heterogeneity index of 2.3 to 4.5
UST967004I4 (en) 1975-11-28 1978-02-07 The Firestone Tire & Rubber Company Transparent impact polystyrene plastics of di-block copolymers
US4120915A (en) * 1976-07-12 1978-10-17 Phillips Petroleum Company Styrene-diene1 -diene2 block terpolymer with improved thermal stability
US4107124A (en) * 1977-01-26 1978-08-15 Shell Oil Company Block copolymer compositions
US4163764A (en) * 1977-06-23 1979-08-07 Phillips Petroleum Company Coupled block copolymers with improved tack for adhesives
US4163765A (en) * 1977-11-28 1979-08-07 Phillips Petroleum Company Polymeric compositions
US4152370A (en) * 1978-02-09 1979-05-01 Phillips Petroleum Company Preparation, composition, and use of block polymers
US4248983A (en) * 1979-02-05 1981-02-03 Arco Polymers, Inc. Clear impact resistant thermoplastic star-block copolymers
US4180530A (en) * 1979-02-05 1979-12-25 Arco Polymers, Inc. Clear impact resistant thermoplastic star-block copolymers
US4248981A (en) * 1979-04-30 1981-02-03 Arco Polymers, Inc. Clear impact resistant thermoplastic star-block copolymers
US4248982A (en) * 1979-04-30 1981-02-03 Arco Polymers, Inc. Clear impact resistant thermoplastic star-block copolymers
US4248980A (en) * 1979-04-30 1981-02-03 Arco Polymers, Inc. Clear impact resistant thermoplastic star-block copolymers
US4248984A (en) * 1979-05-11 1981-02-03 Arco Polymers, Inc. Clear impact resistant thermoplastic star-block copolymers
US4221884A (en) * 1979-05-14 1980-09-09 Arco Polymers, Inc. Clear impact resistant thermoplastic star-block copolymers
DE2940861A1 (de) * 1979-10-09 1981-04-23 Basf Ag, 6700 Ludwigshafen Verfahren zur herstellung von mischungen linearer dreiblockcopolymerisate sowie formteile aus diesen
US4346198A (en) * 1980-07-14 1982-08-24 Atlantic Richfield Company Clear impact resistant thermoplastic star-block copolymers
DE3032832A1 (de) * 1980-08-30 1982-04-22 Basf Ag, 6700 Ludwigshafen Verfahren zur herstellung von verzweigten blockcopolymerisaten, verwendung derselben und formteile aus diesen
US4346193A (en) * 1981-05-04 1982-08-24 Atlantic Richfield Company Continuous process for making star-block copolymers
US4403074A (en) * 1982-01-13 1983-09-06 Phillips Petroleum Company Clear haze-free impact-resistant resinous polymers
US4405754A (en) * 1982-01-13 1983-09-20 Phillips Petroleum Company Haze-free, clear, impact-resistant resinous polymers
US4584346A (en) * 1984-02-29 1986-04-22 Phillips Petroleum Company Craze-resistant transparent resinous polymodal block copolymers

Also Published As

Publication number Publication date
IN168085B (de) 1991-02-02
MX166468B (es) 1993-01-12
ZA871595B (en) 1987-08-26
ES2041250T3 (es) 1993-11-16
CA1257029A (en) 1989-07-04
DE3786295T2 (de) 1993-09-30
JPS62232419A (ja) 1987-10-12
EP0242614A3 (en) 1989-06-14
CN87100183A (zh) 1988-07-27
HK83794A (en) 1994-08-26
US4704434A (en) 1987-11-03
KR930002902B1 (ko) 1993-04-15
EP0242614A2 (de) 1987-10-28
EP0242614B1 (de) 1993-06-23
JPH0545605B2 (de) 1993-07-09
KR870008923A (ko) 1987-10-22
DE3786295D1 (de) 1993-07-29

Similar Documents

Publication Publication Date Title
ATE90951T1 (de) Haarrissbildungsbestaendige, lineare, polymodale blockcopolymere mit endbloecken von kontinuierlich sich aendernder zusammensetzung.
ES2059318T3 (es) Copolimeros de bloques lineales polimodales, resistentes al agrietamiento, con bloques resinosos terminales.
TW197451B (de)
DE3587313D1 (de) Lichtrisswiderstaendiges transparentes harz.
ATE88197T1 (de) Verfahren zur herstellung von durchsichtigen blockkopolymeren.
DE69020324D1 (de) Verfahren zur Herstellung von Blockcopolymeren.
DE69211767D1 (de) Blockcopolymerisate von Monovinylaren und konjugierten Dien mit Endblöcken von kontinuierlich sich ändernder Zusammensetzung
ATE328921T1 (de) Verfahren zur herstellung blockcopolymerisate von monovinylarenen und konjugierten dienen mit endblöcken von kontinuierlich sich ändernder zusammensetzung, so erhaltene blockcopolymerisate,zusammensetzungen und artikeln
EP0528038A4 (en) Composite composition excellent in transparency and production thereof
JPS5628234A (en) Molding resin composition
ATE241655T1 (de) Blockcopolymere von monovinylarenen und konjugierten dienen und verfahren zu deren herstellung
ES2029153A6 (es) Procedimiento para la preparacion de copolimeros lineales de bloques alternados.
ATE138401T1 (de) Makromere von polyvinylidenfluorid mit acrylatendgruppen und ihre thermoplastischen elastomercopolymere
EP0297706A3 (de) Schlagfeste Acrylfolie
Morton Research on anionic triblock copolymers
JPS57109812A (en) Methyl methacrylate copolymer and its production
DE3673711D1 (de) Modifierte zusammensetzung von thermoplastischen polymeren durch ein massenverfahren hergestellt.
JPS5778452A (en) Thermoplastic resin composition
JPS64111A (en) Surface modification of polymeric material

Legal Events

Date Code Title Description
UEP Publication of translation of european patent specification
REN Ceased due to non-payment of the annual fee