ATE55278T1 - Verfahren zur katalytischen epoxidation von olefinen mit wasserstoffperoxid. - Google Patents
Verfahren zur katalytischen epoxidation von olefinen mit wasserstoffperoxid.Info
- Publication number
- ATE55278T1 ATE55278T1 AT86114003T AT86114003T ATE55278T1 AT E55278 T1 ATE55278 T1 AT E55278T1 AT 86114003 T AT86114003 T AT 86114003T AT 86114003 T AT86114003 T AT 86114003T AT E55278 T1 ATE55278 T1 AT E55278T1
- Authority
- AT
- Austria
- Prior art keywords
- alkyl
- gps
- pyridyl
- oxo
- molybdenum
- Prior art date
Links
- 150000001336 alkenes Chemical class 0.000 title abstract 2
- 230000003197 catalytic effect Effects 0.000 title abstract 2
- MHAJPDPJQMAIIY-UHFFFAOYSA-N Hydrogen peroxide Chemical compound OO MHAJPDPJQMAIIY-UHFFFAOYSA-N 0.000 title 2
- 125000000217 alkyl group Chemical group 0.000 abstract 7
- -1 hydroxy, carboxy, cyano, thiocyano Chemical group 0.000 abstract 5
- ZOKXTWBITQBERF-UHFFFAOYSA-N Molybdenum Chemical compound [Mo] ZOKXTWBITQBERF-UHFFFAOYSA-N 0.000 abstract 2
- 125000005236 alkanoylamino group Chemical group 0.000 abstract 2
- 125000003917 carbamoyl group Chemical group [H]N([H])C(*)=O 0.000 abstract 2
- 229910052750 molybdenum Inorganic materials 0.000 abstract 2
- 239000011733 molybdenum Substances 0.000 abstract 2
- 125000004076 pyridyl group Chemical group 0.000 abstract 2
- 125000000954 2-hydroxyethyl group Chemical group [H]C([*])([H])C([H])([H])O[H] 0.000 abstract 1
- 125000003545 alkoxy group Chemical group 0.000 abstract 1
- 125000003282 alkyl amino group Chemical group 0.000 abstract 1
- 125000004448 alkyl carbonyl group Chemical group 0.000 abstract 1
- 150000001450 anions Chemical class 0.000 abstract 1
- 125000004429 atom Chemical group 0.000 abstract 1
- DNZSHSJERXNJGX-UHFFFAOYSA-N chembl3040240 Chemical compound C1=CC(C(=C2C=CC(N2)=C(C=2C=CN=CC=2)C=2C=CC(N=2)=C(C=2C=CN=CC=2)C2=CC=C3N2)C=2C=CN=CC=2)=NC1=C3C1=CC=NC=C1 DNZSHSJERXNJGX-UHFFFAOYSA-N 0.000 abstract 1
- 238000006243 chemical reaction Methods 0.000 abstract 1
- 238000006735 epoxidation reaction Methods 0.000 abstract 1
- 229910052736 halogen Inorganic materials 0.000 abstract 1
- 150000002367 halogens Chemical class 0.000 abstract 1
- 125000004435 hydrogen atom Chemical group [H]* 0.000 abstract 1
- 239000003446 ligand Substances 0.000 abstract 1
- 125000000956 methoxy group Chemical group [H]C([H])([H])O* 0.000 abstract 1
- 125000000449 nitro group Chemical group [O-][N+](*)=O 0.000 abstract 1
- HCIIFBHDBOCSAF-UHFFFAOYSA-N octaethylporphyrin Chemical compound N1C(C=C2C(=C(CC)C(C=C3C(=C(CC)C(=C4)N3)CC)=N2)CC)=C(CC)C(CC)=C1C=C1C(CC)=C(CC)C4=N1 HCIIFBHDBOCSAF-UHFFFAOYSA-N 0.000 abstract 1
- PQQKPALAQIIWST-UHFFFAOYSA-N oxomolybdenum Chemical compound [Mo]=O PQQKPALAQIIWST-UHFFFAOYSA-N 0.000 abstract 1
- 150000002978 peroxides Chemical class 0.000 abstract 1
- 125000001997 phenyl group Chemical group [H]C1=C([H])C([H])=C(*)C([H])=C1[H] 0.000 abstract 1
- 150000004032 porphyrins Chemical class 0.000 abstract 1
- YNHJECZULSZAQK-UHFFFAOYSA-N tetraphenylporphyrin Chemical compound C1=CC(C(=C2C=CC(N2)=C(C=2C=CC=CC=2)C=2C=CC(N=2)=C(C=2C=CC=CC=2)C2=CC=C3N2)C=2C=CC=CC=2)=NC1=C3C1=CC=CC=C1 YNHJECZULSZAQK-UHFFFAOYSA-N 0.000 abstract 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07D—HETEROCYCLIC COMPOUNDS
- C07D303/00—Compounds containing three-membered rings having one oxygen atom as the only ring hetero atom
- C07D303/02—Compounds containing oxirane rings
- C07D303/04—Compounds containing oxirane rings containing only hydrogen and carbon atoms in addition to the ring oxygen atoms
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
- B01J31/16—Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes
- B01J31/18—Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes containing nitrogen, phosphorus, arsenic or antimony as complexing atoms, e.g. in pyridine ligands, or in resonance therewith, e.g. in isocyanide ligands C=N-R or as complexed central atoms
- B01J31/1805—Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes containing nitrogen, phosphorus, arsenic or antimony as complexing atoms, e.g. in pyridine ligands, or in resonance therewith, e.g. in isocyanide ligands C=N-R or as complexed central atoms the ligands containing nitrogen
- B01J31/181—Cyclic ligands, including e.g. non-condensed polycyclic ligands, comprising at least one complexing nitrogen atom as ring member, e.g. pyridine
- B01J31/1815—Cyclic ligands, including e.g. non-condensed polycyclic ligands, comprising at least one complexing nitrogen atom as ring member, e.g. pyridine with more than one complexing nitrogen atom, e.g. bipyridyl, 2-aminopyridine
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07D—HETEROCYCLIC COMPOUNDS
- C07D301/00—Preparation of oxiranes
- C07D301/02—Synthesis of the oxirane ring
- C07D301/03—Synthesis of the oxirane ring by oxidation of unsaturated compounds, or of mixtures of unsaturated and saturated compounds
- C07D301/12—Synthesis of the oxirane ring by oxidation of unsaturated compounds, or of mixtures of unsaturated and saturated compounds with hydrogen peroxide or inorganic peroxides or peracids
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J2231/00—Catalytic reactions performed with catalysts classified in B01J31/00
- B01J2231/70—Oxidation reactions, e.g. epoxidation, (di)hydroxylation, dehydrogenation and analogues
- B01J2231/72—Epoxidation
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J2531/00—Additional information regarding catalytic systems classified in B01J31/00
- B01J2531/02—Compositional aspects of complexes used, e.g. polynuclearity
- B01J2531/0238—Complexes comprising multidentate ligands, i.e. more than 2 ionic or coordinative bonds from the central metal to the ligand, the latter having at least two donor atoms, e.g. N, O, S, P
- B01J2531/0241—Rigid ligands, e.g. extended sp2-carbon frameworks or geminal di- or trisubstitution
- B01J2531/025—Ligands with a porphyrin ring system or analogues thereof, e.g. phthalocyanines, corroles
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J2531/00—Additional information regarding catalytic systems classified in B01J31/00
- B01J2531/60—Complexes comprising metals of Group VI (VIA or VIB) as the central metal
- B01J2531/64—Molybdenum
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Inorganic Chemistry (AREA)
- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)
- Epoxy Compounds (AREA)
- Catalysts (AREA)
Applications Claiming Priority (2)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| DE19853539268 DE3539268A1 (de) | 1985-11-06 | 1985-11-06 | Verfahren zur katalytischen epoxidation von olefinen mit wasserstoffperoxid |
| EP86114003A EP0222167B1 (en) | 1985-11-06 | 1986-10-09 | Process for the catalytic epoxidation of olefines with hydrogen peroxide |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| ATE55278T1 true ATE55278T1 (de) | 1990-08-15 |
Family
ID=6285239
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| AT86114003T ATE55278T1 (de) | 1985-11-06 | 1986-10-09 | Verfahren zur katalytischen epoxidation von olefinen mit wasserstoffperoxid. |
Country Status (4)
| Country | Link |
|---|---|
| EP (1) | EP0222167B1 (forum.php) |
| JP (1) | JPS62114980A (forum.php) |
| AT (1) | ATE55278T1 (forum.php) |
| DE (1) | DE3539268A1 (forum.php) |
Families Citing this family (11)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| DE3860625D1 (de) * | 1987-03-25 | 1990-10-25 | Degussa | Verfahren zur katalytischen epoxidation von olefinen mit wasserstoffperoxid. |
| DE3731690C1 (de) * | 1987-09-21 | 1989-01-19 | Degussa | Verfahren zur katalytischen Epoxidation von Olefinen mit Wasserstoffperoxid |
| DE3731689A1 (de) * | 1987-09-21 | 1989-03-30 | Degussa | Rhenium-oxo-porphyrin-komplexe |
| ES2113374T3 (es) * | 1990-03-21 | 1998-05-01 | Res Corp Technologies Inc | Catalizadores quirales y reacciones de epoxidacion catalizadas por los mismos. |
| FR2676738B1 (fr) * | 1991-05-22 | 1995-05-05 | Ir2M | Nouveau derive organique de metal de transition a structure porphyrinique, composition therapeutique le contenant, en particulier a activite hypoglycemiante. |
| GR1001349B (el) * | 1992-08-18 | 1993-10-29 | Athanasios Koutsolelos | Μέ?οδος ανακύκλωσης-μετατροπής πολυμερικών ουσιών (πλαστικών) στα αντίστοιχα εποξείδια & πολυαι?έρες τους με καταλυτική δράση πορφυρινών,παρουσία δοτών οξυγόνου & μετατροπή των πολυεποξειδίων σε πολυαλκοόλες & πολυαι?έρες. |
| GB9309458D0 (en) * | 1993-05-07 | 1993-06-23 | Bp Chem Int Ltd | Process |
| US5563263A (en) * | 1994-09-14 | 1996-10-08 | Hoechst Celanese Corporation | D4 -symmetric porphyrin-based catalysts, processes for preparing same, and processes for using same |
| DE19542933A1 (de) * | 1995-11-17 | 1997-05-22 | Buna Sow Leuna Olefinverb Gmbh | Glycidester-ester, Verfahren zu ihrer Herstellung und ihre Verwendung |
| JP5196463B2 (ja) * | 2006-03-09 | 2013-05-15 | 国立大学法人九州大学 | モリブデンポルフィセン錯体及び酸化触媒 |
| CN119192101A (zh) * | 2024-11-29 | 2024-12-27 | 山东华安新材料有限公司 | 一种环氧环己烷的制备方法 |
Family Cites Families (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US3156709A (en) * | 1962-03-06 | 1964-11-10 | Du Pont | Oxidation process |
| DE2049008C3 (de) * | 1970-10-06 | 1980-04-03 | Bundesrepublik Deutschland Vertreten Durch Den Bundesminister Der Verteidigung, 5300 Bonn | Katalysatoren für die Elektroreduktion von Sauerstoff im sauren Elektrolyten |
| US4459427A (en) * | 1981-10-31 | 1984-07-10 | The British Petroleum Company P.L.C. | Process for the conversion of an alkane to a mixture of an alcohol and a ketone |
| EP0118801B1 (en) * | 1983-03-09 | 1987-07-22 | Sumitomo Chemical Company, Limited | A catalyst for isomerization reaction |
-
1985
- 1985-11-06 DE DE19853539268 patent/DE3539268A1/de active Granted
-
1986
- 1986-10-09 AT AT86114003T patent/ATE55278T1/de active
- 1986-10-09 EP EP86114003A patent/EP0222167B1/de not_active Expired - Lifetime
- 1986-11-06 JP JP61262907A patent/JPS62114980A/ja active Pending
Also Published As
| Publication number | Publication date |
|---|---|
| EP0222167A2 (de) | 1987-05-20 |
| EP0222167A3 (de) | 1988-05-18 |
| JPS62114980A (ja) | 1987-05-26 |
| EP0222167B1 (en) | 1990-08-08 |
| DE3539268A1 (de) | 1987-05-07 |
| DE3539268C2 (forum.php) | 1988-05-26 |
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