ATE417875T1 - Mehrschrittverfahren zur herstellung von heterophasigen propylencopolymeren - Google Patents

Mehrschrittverfahren zur herstellung von heterophasigen propylencopolymeren

Info

Publication number
ATE417875T1
ATE417875T1 AT04763927T AT04763927T ATE417875T1 AT E417875 T1 ATE417875 T1 AT E417875T1 AT 04763927 T AT04763927 T AT 04763927T AT 04763927 T AT04763927 T AT 04763927T AT E417875 T1 ATE417875 T1 AT E417875T1
Authority
AT
Austria
Prior art keywords
sub
sup
polymer obtained
weight
optionally
Prior art date
Application number
AT04763927T
Other languages
German (de)
English (en)
Inventor
Anteo Pelliconi
Maria Tonti
Luigi Resconi
Original Assignee
Basell Polyolefine Gmbh
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Basell Polyolefine Gmbh filed Critical Basell Polyolefine Gmbh
Application granted granted Critical
Publication of ATE417875T1 publication Critical patent/ATE417875T1/de

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F297/00—Macromolecular compounds obtained by successively polymerising different monomer systems using a catalyst of the ionic or coordination type without deactivating the intermediate polymer
    • C08F297/06—Macromolecular compounds obtained by successively polymerising different monomer systems using a catalyst of the ionic or coordination type without deactivating the intermediate polymer using a catalyst of the coordination type
    • C08F297/08—Macromolecular compounds obtained by successively polymerising different monomer systems using a catalyst of the ionic or coordination type without deactivating the intermediate polymer using a catalyst of the coordination type polymerising mono-olefins
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F210/00—Copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
    • C08F210/04—Monomers containing three or four carbon atoms
    • C08F210/06—Propene
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F10/00—Homopolymers and copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F2/00—Processes of polymerisation
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F297/00—Macromolecular compounds obtained by successively polymerising different monomer systems using a catalyst of the ionic or coordination type without deactivating the intermediate polymer
    • C08F297/06—Macromolecular compounds obtained by successively polymerising different monomer systems using a catalyst of the ionic or coordination type without deactivating the intermediate polymer using a catalyst of the coordination type
    • C08F297/08—Macromolecular compounds obtained by successively polymerising different monomer systems using a catalyst of the ionic or coordination type without deactivating the intermediate polymer using a catalyst of the coordination type polymerising mono-olefins
    • C08F297/083—Macromolecular compounds obtained by successively polymerising different monomer systems using a catalyst of the ionic or coordination type without deactivating the intermediate polymer using a catalyst of the coordination type polymerising mono-olefins the monomers being ethylene or propylene
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F4/00—Polymerisation catalysts
    • C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
    • C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
    • C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
    • C08F4/62—Refractory metals or compounds thereof
    • C08F4/64—Titanium, zirconium, hafnium or compounds thereof
    • C08F4/643—Component covered by group C08F4/64 with a metal or compound covered by group C08F4/44 other than an organo-aluminium compound
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L23/00—Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers
    • C08L23/02—Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers not modified by chemical after-treatment
    • C08L23/10—Homopolymers or copolymers of propene
    • C08L23/14—Copolymers of propene
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F4/00—Polymerisation catalysts
    • C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
    • C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
    • C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
    • C08F4/62—Refractory metals or compounds thereof
    • C08F4/64—Titanium, zirconium, hafnium or compounds thereof
    • C08F4/659—Component covered by group C08F4/64 containing a transition metal-carbon bond
    • C08F4/65912—Component covered by group C08F4/64 containing a transition metal-carbon bond in combination with an organoaluminium compound
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F4/00—Polymerisation catalysts
    • C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
    • C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
    • C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
    • C08F4/62—Refractory metals or compounds thereof
    • C08F4/64—Titanium, zirconium, hafnium or compounds thereof
    • C08F4/659—Component covered by group C08F4/64 containing a transition metal-carbon bond
    • C08F4/65916—Component covered by group C08F4/64 containing a transition metal-carbon bond supported on a carrier, e.g. silica, MgCl2, polymer
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L2207/00—Properties characterising the ingredient of the composition
    • C08L2207/02—Heterophasic composition
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L23/00—Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers
    • C08L23/02—Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers not modified by chemical after-treatment
    • C08L23/04—Homopolymers or copolymers of ethene
    • C08L23/08—Copolymers of ethene
    • C08L23/0807—Copolymers of ethene with unsaturated hydrocarbons only containing four or more carbon atoms
    • C08L23/0815—Copolymers of ethene with unsaturated hydrocarbons only containing four or more carbon atoms with aliphatic 1-olefins containing one carbon-to-carbon double bond
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L2308/00—Chemical blending or stepwise polymerisation process with the same catalyst

Landscapes

  • Chemical & Material Sciences (AREA)
  • Health & Medical Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Organic Chemistry (AREA)
  • Inorganic Chemistry (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Transition And Organic Metals Composition Catalysts For Addition Polymerization (AREA)
  • Graft Or Block Polymers (AREA)
AT04763927T 2003-09-11 2004-08-06 Mehrschrittverfahren zur herstellung von heterophasigen propylencopolymeren ATE417875T1 (de)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
EP03077866 2003-09-11
US50503703P 2003-09-22 2003-09-22

Publications (1)

Publication Number Publication Date
ATE417875T1 true ATE417875T1 (de) 2009-01-15

Family

ID=34276741

Family Applications (1)

Application Number Title Priority Date Filing Date
AT04763927T ATE417875T1 (de) 2003-09-11 2004-08-06 Mehrschrittverfahren zur herstellung von heterophasigen propylencopolymeren

Country Status (9)

Country Link
US (1) US20060287436A1 (enExample)
EP (1) EP1664140B1 (enExample)
JP (1) JP2007505176A (enExample)
KR (1) KR20060135607A (enExample)
CN (1) CN1878806A (enExample)
AT (1) ATE417875T1 (enExample)
BR (1) BRPI0413958A (enExample)
DE (1) DE602004018516D1 (enExample)
WO (1) WO2005023892A1 (enExample)

Families Citing this family (11)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
ATE445651T1 (de) * 2002-09-06 2009-10-15 Basell Polyolefine Gmbh Verfahren zur copolymerisation von ethylen
US7906599B2 (en) 2006-04-19 2011-03-15 Japan Polypropylene Corporation Transition metal compound, catalyst for olefin polymerization containing the same, and method for producing propylene/ethylene-α-olefin block copolymer by using the catalyst
JP5201944B2 (ja) * 2007-10-24 2013-06-05 日本ポリプロ株式会社 熱可塑性樹脂重合粒子
JP5201943B2 (ja) * 2007-10-24 2013-06-05 日本ポリプロ株式会社 熱可塑性樹脂重合粒子
CN101693211B (zh) * 2009-10-22 2013-04-10 北京颖泰嘉和生物科技有限公司 过渡金属催化剂以及采用该催化剂制备甲基吡啶的方法
CN101693210B (zh) * 2009-10-22 2011-11-30 北京颖新泰康国际贸易有限公司 一种制备甲基吡啶的方法
CN105051075B (zh) 2013-03-14 2018-03-30 格雷斯公司 丙烯/丁烯互聚物制备系统和方法
CN106674721B (zh) * 2015-11-06 2019-08-20 中国石油化工股份有限公司 一种高熔体强度抗冲聚丙烯发泡珠粒及其制备方法
CN106674719B (zh) * 2015-11-06 2020-04-07 中国石油化工股份有限公司 一种聚丙烯吹塑膜及其制备方法
CN106674720B (zh) * 2015-11-06 2019-12-24 中国石油化工股份有限公司 一种高熔体强度抗冲聚丙烯发泡珠粒及其制备方法
EP4735486A1 (en) * 2023-06-30 2026-05-06 Borealis GmbH Process

Family Cites Families (12)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
DE59104869D1 (de) * 1990-11-12 1995-04-13 Hoechst Ag 2-Substituierte Bisindenylmetallocene, Verfahren zu ihrer Herstellung und ihre Verwendung als Katalysatoren bei der Olefinpolymerisation.
US5830821A (en) * 1991-11-30 1998-11-03 Targor Gmbh Process for olefin preparation using metallocenes having benzo-fused indenyl derivatives as ligands
TW294669B (enExample) * 1992-06-27 1997-01-01 Hoechst Ag
DE69518094T2 (de) * 1994-04-11 2001-03-22 Mitsui Chemicals, Inc. Verfahren zur Herstellung von einer Propylen-Polymer-Zusammensetzung und Propylen-Polymer-Zusammensetzung
KR100388331B1 (ko) * 1994-04-11 2003-10-11 미쓰이 가가쿠 가부시키가이샤 프로필렌중합체조성물의제조방법및프로필렌중합체조성물
US6444833B1 (en) * 1999-12-15 2002-09-03 Basell Technology Company Bv Metallocene compounds, process for their preparation and their use in catalytic systems for the polymerization of olefins
CN1590422A (zh) * 1999-12-23 2005-03-09 巴塞尔聚烯烃有限公司 过渡金属化合物，配体体系，催化剂体系及其在烯烃的聚合反应和共聚反应中的用途
DE19962910A1 (de) * 1999-12-23 2001-07-05 Targor Gmbh Chemische Verbindung, Verfahren zu deren Herstellung und deren Verwendung in Katalysatorsystemen zur Herstellung von Polyolefinen
DE19962814A1 (de) * 1999-12-23 2001-06-28 Targor Gmbh Neues Katalysatorsystem und dessen Verwendung
US6492465B1 (en) * 2000-02-08 2002-12-10 Exxonmobil Chemical Patents, Inc. Propylene impact copolymers
JP4171880B2 (ja) * 2001-08-06 2008-10-29 チッソ株式会社 メタロセン化合物、それを含む触媒を用いたオレフィン重合体の製造方法、および、該製造方法により製造されたオレフィン重合体
US7019157B2 (en) * 2001-08-06 2006-03-28 Chisso Corporation Metallocene compounds, production process for olefin polymers using catalysts containing them and olefin polymers produced by the production process

Also Published As

Publication number Publication date
EP1664140A1 (en) 2006-06-07
BRPI0413958A (pt) 2006-10-31
WO2005023892A1 (en) 2005-03-17
JP2007505176A (ja) 2007-03-08
DE602004018516D1 (de) 2009-01-29
CN1878806A (zh) 2006-12-13
EP1664140B1 (en) 2008-12-17
US20060287436A1 (en) 2006-12-21
KR20060135607A (ko) 2006-12-29

Similar Documents

Publication Publication Date Title
EP3050904B1 (en) A preparation method of a supported metallocene catalyst
EP0529908B2 (en) Catalyst useful for the polymerization of olefin
US6420580B1 (en) Catalyst compositions and method of polymerization therewith
EP3040124B1 (en) Method for producing hybrid-supported metallocene catalyst
US7214745B2 (en) Process for producing polymer
EP0526955A1 (en) Copolymers of ethylene and 1,3-butadiene
RU2007139099A (ru) Способ полимеризации олефинов
US6787616B2 (en) Catalyst for olefin polymerization and process for polymerizing olefin by means thereof
KR930002361A (ko) 플루오레닐 함유 메탈로센 제조 방법
WO2017039995A1 (en) Aluminum alkyls with pendant olefins for polyolefin reactions
KR910007971A (ko) 신디오택틱 중합체의 제조방법 및 이에 사용되는 촉매
RU96108407A (ru) Катализаторы и процессы полимеризации олефинов
ATE305945T1 (de) Niederwertige frühübergangsmetallkatalysatoren für die polymerisation von olefinen enthaltend eine cyclopentadienylgruppe
JPWO1995018158A1 (ja) オレフィン系重合体の製造方法及びエチレン系重合体
DE602004018516D1 (de) Mehrschrittverfahren zur herstellung von heterophasigen propylencopolymeren
KR101618460B1 (ko) 올레핀 중합용 담지 촉매 및 이를 이용하여 제조된 올레핀 중합체의 제조방법
JP2007505176A5 (enExample)
DE60211013D1 (de) Zweistufen-polymerisationsverfahren
KR20180102142A (ko) 올레핀-방향족 비닐 화합물계 공중합체의 제조 방법 및 크로스 공중합체의 제조 방법
Panin et al. Triisobutylaluminum as cocatalyst for zirconocenes. I. Sterically opened zirconocene/triisobutylaluminum/perfluorophenylborate as highly effective ternary catalytic system for synthesis of low molecular weight polyethylenes
JPWO2001068719A1 (ja) 重合用遷移金属触媒成分、それを用いた重合体の製造方法
EP0985689A1 (en) Aromatic vinyl compound-ethylene copolymer and method for producing the same
KR960041203A (ko) 지글라-나타 촉매의 제조 방법
JP6485903B2 (ja) 芳香族ビニル化合物系重合体の製造用重合触媒及び芳香族ビニル化合物系重合体の製造方法
RU2008118887A (ru) Гибридные каталитические системы, нанесенные на галогенид магния

Legal Events

Date Code Title Description
RER Ceased as to paragraph 5 lit. 3 law introducing patent treaties