ATE378344T1 - Rutheniumkomplexe von phosphinaminophosphinliganden - Google Patents
Rutheniumkomplexe von phosphinaminophosphinligandenInfo
- Publication number
- ATE378344T1 ATE378344T1 AT05759576T AT05759576T ATE378344T1 AT E378344 T1 ATE378344 T1 AT E378344T1 AT 05759576 T AT05759576 T AT 05759576T AT 05759576 T AT05759576 T AT 05759576T AT E378344 T1 ATE378344 T1 AT E378344T1
- Authority
- AT
- Austria
- Prior art keywords
- asymmetric
- ruthenium complexes
- hydroxycarbonyl
- ligands
- phosphinaminophospine
- Prior art date
Links
- 239000003446 ligand Substances 0.000 title abstract 2
- KJTLSVCANCCWHF-UHFFFAOYSA-N Ruthenium Chemical class [Ru] KJTLSVCANCCWHF-UHFFFAOYSA-N 0.000 title 1
- 150000003303 ruthenium Chemical class 0.000 abstract 3
- 238000009876 asymmetric hydrogenation reaction Methods 0.000 abstract 2
- 238000000034 method Methods 0.000 abstract 2
- 150000000180 1,2-diols Chemical class 0.000 abstract 1
- -1 1,3-diol compounds Chemical class 0.000 abstract 1
- MNKCOIOOGRJIGH-UHFFFAOYSA-N P.NP Chemical compound P.NP MNKCOIOOGRJIGH-UHFFFAOYSA-N 0.000 abstract 1
- 238000007792 addition Methods 0.000 abstract 1
- 150000001336 alkenes Chemical class 0.000 abstract 1
- 238000006717 asymmetric allylation reaction Methods 0.000 abstract 1
- 238000006243 chemical reaction Methods 0.000 abstract 1
- 238000006197 hydroboration reaction Methods 0.000 abstract 1
- 238000005984 hydrogenation reaction Methods 0.000 abstract 1
- 238000006459 hydrosilylation reaction Methods 0.000 abstract 1
- ORTFAQDWJHRMNX-UHFFFAOYSA-N hydroxidooxidocarbon(.) Chemical group O[C]=O ORTFAQDWJHRMNX-UHFFFAOYSA-N 0.000 abstract 1
- 238000006317 isomerization reaction Methods 0.000 abstract 1
- JRZJOMJEPLMPRA-UHFFFAOYSA-N olefin Natural products CCCCCCCC=C JRZJOMJEPLMPRA-UHFFFAOYSA-N 0.000 abstract 1
- 125000002524 organometallic group Chemical group 0.000 abstract 1
- 238000002360 preparation method Methods 0.000 abstract 1
- 230000009467 reduction Effects 0.000 abstract 1
- 239000000758 substrate Substances 0.000 abstract 1
Classifications
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
- B01J31/16—Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes
- B01J31/24—Phosphines, i.e. phosphorus bonded to only carbon atoms, or to both carbon and hydrogen atoms, including e.g. sp2-hybridised phosphorus compounds such as phosphabenzene, phosphole or anionic phospholide ligands
- B01J31/2495—Ligands comprising a phosphine-P atom and one or more further complexing phosphorus atoms covered by groups B01J31/1845 - B01J31/1885, e.g. phosphine/phosphinate or phospholyl/phosphonate ligands
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
- B01J31/16—Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes
- B01J31/22—Organic complexes
- B01J31/2282—Unsaturated compounds used as ligands
- B01J31/2295—Cyclic compounds, e.g. cyclopentadienyls
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07B—GENERAL METHODS OF ORGANIC CHEMISTRY; APPARATUS THEREFOR
- C07B53/00—Asymmetric syntheses
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C29/00—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring
- C07C29/132—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring by reduction of an oxygen containing functional group
- C07C29/136—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring by reduction of an oxygen containing functional group of >C=O containing groups, e.g. —COOH
- C07C29/143—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring by reduction of an oxygen containing functional group of >C=O containing groups, e.g. —COOH of ketones
- C07C29/145—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring by reduction of an oxygen containing functional group of >C=O containing groups, e.g. —COOH of ketones with hydrogen or hydrogen-containing gases
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C67/00—Preparation of carboxylic acid esters
- C07C67/30—Preparation of carboxylic acid esters by modifying the acid moiety of the ester, such modification not being an introduction of an ester group
- C07C67/31—Preparation of carboxylic acid esters by modifying the acid moiety of the ester, such modification not being an introduction of an ester group by introduction of functional groups containing oxygen only in singly bound form
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07F—ACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
- C07F15/00—Compounds containing elements of Groups 8, 9, 10 or 18 of the Periodic Table
- C07F15/0006—Compounds containing elements of Groups 8, 9, 10 or 18 of the Periodic Table compounds of the platinum group
- C07F15/0046—Ruthenium compounds
- C07F15/0053—Ruthenium compounds without a metal-carbon linkage
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J2231/00—Catalytic reactions performed with catalysts classified in B01J31/00
- B01J2231/60—Reduction reactions, e.g. hydrogenation
- B01J2231/64—Reductions in general of organic substrates, e.g. hydride reductions or hydrogenations
- B01J2231/641—Hydrogenation of organic substrates, i.e. H2 or H-transfer hydrogenations, e.g. Fischer-Tropsch processes
- B01J2231/643—Hydrogenation of organic substrates, i.e. H2 or H-transfer hydrogenations, e.g. Fischer-Tropsch processes of R2C=O or R2C=NR (R= C, H)
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J2531/00—Additional information regarding catalytic systems classified in B01J31/00
- B01J2531/02—Compositional aspects of complexes used, e.g. polynuclearity
- B01J2531/0202—Polynuclearity
- B01J2531/0205—Bi- or polynuclear complexes, i.e. comprising two or more metal coordination centres, without metal-metal bonds, e.g. Cp(Lx)Zr-imidazole-Zr(Lx)Cp
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J2531/00—Additional information regarding catalytic systems classified in B01J31/00
- B01J2531/80—Complexes comprising metals of Group VIII as the central metal
- B01J2531/82—Metals of the platinum group
- B01J2531/821—Ruthenium
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J2531/00—Additional information regarding catalytic systems classified in B01J31/00
- B01J2531/80—Complexes comprising metals of Group VIII as the central metal
- B01J2531/82—Metals of the platinum group
- B01J2531/825—Osmium
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J2531/00—Additional information regarding catalytic systems classified in B01J31/00
- B01J2531/80—Complexes comprising metals of Group VIII as the central metal
- B01J2531/84—Metals of the iron group
- B01J2531/842—Iron
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
- B01J31/16—Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes
- B01J31/18—Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes containing nitrogen, phosphorus, arsenic or antimony as complexing atoms, e.g. in pyridine ligands, or in resonance therewith, e.g. in isocyanide ligands C=N-R or as complexed central atoms
- B01J31/1845—Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes containing nitrogen, phosphorus, arsenic or antimony as complexing atoms, e.g. in pyridine ligands, or in resonance therewith, e.g. in isocyanide ligands C=N-R or as complexed central atoms the ligands containing phosphorus
- B01J31/1875—Phosphinites (R2P(OR), their isomeric phosphine oxides (R3P=O) and RO-substitution derivatives thereof)
- B01J31/188—Amide derivatives thereof
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
- B01J31/16—Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes
- B01J31/24—Phosphines, i.e. phosphorus bonded to only carbon atoms, or to both carbon and hydrogen atoms, including e.g. sp2-hybridised phosphorus compounds such as phosphabenzene, phosphole or anionic phospholide ligands
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
- B01J31/16—Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes
- B01J31/24—Phosphines, i.e. phosphorus bonded to only carbon atoms, or to both carbon and hydrogen atoms, including e.g. sp2-hybridised phosphorus compounds such as phosphabenzene, phosphole or anionic phospholide ligands
- B01J31/2404—Cyclic ligands, including e.g. non-condensed polycyclic ligands, the phosphine-P atom being a ring member or a substituent on the ring
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07B—GENERAL METHODS OF ORGANIC CHEMISTRY; APPARATUS THEREFOR
- C07B2200/00—Indexing scheme relating to specific properties of organic compounds
- C07B2200/07—Optical isomers
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07B—GENERAL METHODS OF ORGANIC CHEMISTRY; APPARATUS THEREFOR
- C07B2200/00—Indexing scheme relating to specific properties of organic compounds
- C07B2200/09—Geometrical isomers
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Inorganic Chemistry (AREA)
- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
- Catalysts (AREA)
- Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| US10/876,392 US6939981B1 (en) | 2004-06-25 | 2004-06-25 | Ruthenium complexes of phosphine-aminophosphine ligands |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| ATE378344T1 true ATE378344T1 (de) | 2007-11-15 |
Family
ID=34887859
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| AT05759576T ATE378344T1 (de) | 2004-06-25 | 2005-06-16 | Rutheniumkomplexe von phosphinaminophosphinliganden |
Country Status (6)
| Country | Link |
|---|---|
| US (1) | US6939981B1 (cg-RX-API-DMAC10.html) |
| EP (1) | EP1758913B1 (cg-RX-API-DMAC10.html) |
| JP (1) | JP2008504260A (cg-RX-API-DMAC10.html) |
| AT (1) | ATE378344T1 (cg-RX-API-DMAC10.html) |
| DE (1) | DE602005003363T2 (cg-RX-API-DMAC10.html) |
| WO (1) | WO2006012027A1 (cg-RX-API-DMAC10.html) |
Families Citing this family (17)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| DE10211250A1 (de) * | 2002-03-13 | 2003-10-23 | Degussa | Ferrocenylliganden und ihre Verwendung in der Katalyse |
| DE10219490A1 (de) * | 2002-04-30 | 2003-11-13 | Degussa | Ferrocenylliganden und ein Verfahren zur Herstellung solcher Liganden |
| US6906213B1 (en) * | 2004-06-25 | 2005-06-14 | Eastman Chemical Company | Preparation of aminophosphines |
| US6906212B1 (en) * | 2004-06-25 | 2005-06-14 | Eastman Chemical Company | Phosphine-phosphoramidite compounds |
| DE102006017594A1 (de) * | 2006-04-13 | 2007-10-18 | Wacker Chemie Ag | Neuartige Ru-Komplexe, deren Herstellung und Verwendung |
| US7615671B2 (en) | 2007-11-30 | 2009-11-10 | Eastman Chemical Company | Hydrogenation process for the preparation of 1,2-diols |
| GB0823554D0 (en) * | 2008-12-24 | 2009-01-28 | Novartis Ag | Process for the preparation of optically active compounds using transfer hydrogenation |
| EP2386536A1 (en) * | 2010-05-11 | 2011-11-16 | Lonza Ltd. | A process for the hydrogenation of ketoesters |
| WO2014034956A1 (ja) * | 2012-09-03 | 2014-03-06 | 住友化学株式会社 | ４－（メチルチオ）ブタン－１，２－ジオールの製造方法 |
| US9255059B2 (en) | 2013-08-02 | 2016-02-09 | Eastman Chemical Company | Method for producing an alkyl 3-hydroxybutyrate |
| US9163202B2 (en) | 2013-08-02 | 2015-10-20 | Eastman Chemical Company | Aqueous cleaning compositions including an alkyl 3-hydroxybutyrate |
| US9388114B2 (en) | 2013-08-02 | 2016-07-12 | Eastman Chemical Company | Compositions including an alkyl 3-hydroxybutyrate |
| US9249378B2 (en) | 2013-08-02 | 2016-02-02 | Eastman Chemical Company | Aqueous cleaning compositions having enhanced properties |
| GB201320869D0 (en) * | 2013-11-26 | 2014-01-08 | Johnson Matthey Plc | Process |
| DE102016110830B4 (de) | 2015-06-14 | 2022-01-13 | Zema - Zentrum Für Mechatronik Und Automatisierungstechnik Gemeinnützige Gmbh | Vorrichtung zur Befestigung einer Adaptionsplatte an einer Radnabe eines Fahrzeugs und Verfahren zum Betrieb einer Adaptionsplatte an einer Radnabe eines Fahrzeugs |
| JPWO2019240009A1 (ja) * | 2018-06-12 | 2021-06-24 | Jnc株式会社 | １，３−ブチレングリコールの製造方法 |
| CN114345414B (zh) * | 2021-12-31 | 2023-03-07 | 厦门大学 | 一种有机金属催化剂及使用其制备3-羟基丙酸酯的方法 |
Family Cites Families (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| ATE223925T1 (de) * | 1996-04-25 | 2002-09-15 | Hoechst Ag | 2,2'-disubstituierte 1,1'-diphosphino-ferrocene und 1',2-disubstituierte 1-phosphino-ferrocene, verfahren zu ihrer herstellung, ihre verwendung sowie sie enthaltende übergangsmetallkomplexe |
| DE19918420A1 (de) | 1999-04-23 | 2000-10-26 | Aventis Res & Tech Gmbh & Co | Bidentate Organophosphorliganden und ihre Verwendung |
| JP5185485B2 (ja) * | 2000-07-03 | 2013-04-17 | ソルヴィーアス アクチェンゲゼルシャフト | フェロセニルジホスフィンおよびその使用 |
| US6590115B2 (en) | 2000-09-29 | 2003-07-08 | Eastman Chemical Company | Phosphino-aminophosphines |
-
2004
- 2004-06-25 US US10/876,392 patent/US6939981B1/en not_active Expired - Fee Related
-
2005
- 2005-06-16 JP JP2007518127A patent/JP2008504260A/ja not_active Withdrawn
- 2005-06-16 EP EP05759576A patent/EP1758913B1/en not_active Expired - Lifetime
- 2005-06-16 DE DE602005003363T patent/DE602005003363T2/de not_active Expired - Lifetime
- 2005-06-16 AT AT05759576T patent/ATE378344T1/de not_active IP Right Cessation
- 2005-06-16 WO PCT/US2005/021248 patent/WO2006012027A1/en not_active Ceased
Also Published As
| Publication number | Publication date |
|---|---|
| WO2006012027A1 (en) | 2006-02-02 |
| EP1758913A1 (en) | 2007-03-07 |
| EP1758913B1 (en) | 2007-11-14 |
| DE602005003363T2 (de) | 2008-03-13 |
| JP2008504260A (ja) | 2008-02-14 |
| DE602005003363D1 (de) | 2007-12-27 |
| US6939981B1 (en) | 2005-09-06 |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| DE602005003363D1 (de) | Rutheniumkomplexe von phosphinaminophosphinliganden | |
| Bartoszewicz et al. | Enantioselective synthesis of alcohols and amines by iridium‐catalyzed hydrogenation, transfer hydrogenation, and related processes | |
| Xie et al. | Recent advances in the development of chiral metal catalysts for the asymmetric hydrogenation of ketones | |
| Feng et al. | Metal-free asymmetric hydrogenation and hydrosilylation catalyzed by frustrated Lewis pairs | |
| Kim et al. | Access to enantioenriched benzylic 1, 1-silylboronate esters by palladium-catalyzed enantiotopic-group selective Suzuki–Miyaura coupling of (diborylmethyl) silanes with aryl iodides | |
| Sortais et al. | Cycloruthenated primary and secondary amines as efficient catalyst precursors for asymmetric transfer hydrogenation | |
| Wang et al. | Hydrogenation of imino bonds with half-sandwich metal catalysts | |
| Mantilli et al. | Platinum metals in the catalytic asymmetric isomerization of allylic alcohols | |
| Alonso et al. | 2-Azanorbornyl alcohols: Very efficient ligands for ruthenium-catalyzed asymmetric transfer hydrogenation of aromatic ketones | |
| Nomura et al. | Allylic imidate rearrangements catalyzed by planar chiral palladacycles | |
| Wang et al. | Transition-metal-catalyzed asymmetric allylation of carbonyl compounds with unsaturated hydrocarbons | |
| Behera et al. | A concise review on recent advances in catalytic asymmetric hydrogenation | |
| ATE259819T1 (de) | Durch übergangsmetallkomplexe mit zyklischen chiralen liganden katalysierte asymmetrische synthese | |
| Ritleng et al. | Ruthenacycles and iridacycles as transfer hydrogenation catalysts | |
| Yang et al. | Asymmetric borane reduction of prochiral ketones using imidazolium-tagged sulfonamide catalyst | |
| Huo et al. | An iron variant of the Noyori hydrogenation catalyst for the asymmetric transfer hydrogenation of ketones | |
| Park et al. | Asymmetric hydrosilylation of cyclohexa-1, 3-diene with trichlorosilane by palladium catalysts coordinated with chiral phosphoramidite ligands | |
| Mwansa et al. | Catalysis, kinetics and mechanisms of organo-iridium enantioselective hydrogenation-reduction | |
| ATE359986T1 (de) | Verfahren zur katalytischen hydrierung von kohlenstoff-heteroatom-doppelbindungen | |
| Lennon et al. | The application of asymmetric hydrogenation for the manufacture of pharmaceutical intermediates: The need for catalyst diversity | |
| ATE491678T1 (de) | Phosphin-phosphoramiditverbindungen | |
| Cho et al. | A practical method for synthesis of terminal 1, 2-diols in high enantiomeric excess via oxazaborolidine-catalyzed asymmetric reduction | |
| Wang et al. | 1, 1′-Binaphthyl ligands with bulky 3, 3′-tertiaryalkyl substituents for the asymmetric alkyne addition to aromatic aldehydes | |
| RU2005138144A (ru) | Замещенные ферроценилдифосфины в качестве лигандов для гомогенных катализаторов гидрирования | |
| ATE496880T1 (de) | Prozess zur hydrierung von nicht-aktivierten iminen unter verwendung von ruthenium-komplexen als katalysatoren |
Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| RER | Ceased as to paragraph 5 lit. 3 law introducing patent treaties |