ATE306320T1 - Zinn aktivierter platinum katalysator für die karbonylierung von niedrigen aliphatischen alkoholen - Google Patents

Zinn aktivierter platinum katalysator für die karbonylierung von niedrigen aliphatischen alkoholen

Info

Publication number
ATE306320T1
ATE306320T1 AT02742103T AT02742103T ATE306320T1 AT E306320 T1 ATE306320 T1 AT E306320T1 AT 02742103 T AT02742103 T AT 02742103T AT 02742103 T AT02742103 T AT 02742103T AT E306320 T1 ATE306320 T1 AT E306320T1
Authority
AT
Austria
Prior art keywords
carbonylation
aliphatic alcohols
platinum catalyst
low aliphatic
activated platinum
Prior art date
Application number
AT02742103T
Other languages
German (de)
English (en)
Inventor
Joseph Robert Zoeller
Andy Hugh Singleton
Gerald Charles Tustin
Donald Lee Carver
Original Assignee
Eastman Chem Co
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Eastman Chem Co filed Critical Eastman Chem Co
Application granted granted Critical
Publication of ATE306320T1 publication Critical patent/ATE306320T1/de

Links

Classifications

    • CCHEMISTRY; METALLURGY
    • C07ORGANIC CHEMISTRY
    • C07CACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C51/00Preparation of carboxylic acids or their salts, halides or anhydrides
    • C07C51/10Preparation of carboxylic acids or their salts, halides or anhydrides by reaction with carbon monoxide
    • C07C51/12Preparation of carboxylic acids or their salts, halides or anhydrides by reaction with carbon monoxide on an oxygen-containing group in organic compounds, e.g. alcohols
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J23/00Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B01J23/38Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of noble metals
    • B01J23/54Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of noble metals combined with metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36
    • B01J23/56Platinum group metals
    • B01J23/62Platinum group metals with gallium, indium, thallium, germanium, tin or lead
    • B01J23/622Platinum group metals with gallium, indium, thallium, germanium, tin or lead with germanium, tin or lead
    • B01J23/626Platinum group metals with gallium, indium, thallium, germanium, tin or lead with germanium, tin or lead with tin
    • CCHEMISTRY; METALLURGY
    • C07ORGANIC CHEMISTRY
    • C07CACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C67/00Preparation of carboxylic acid esters
    • C07C67/36Preparation of carboxylic acid esters by reaction with carbon monoxide or formates
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J21/00Catalysts comprising the elements, oxides, or hydroxides of magnesium, boron, aluminium, carbon, silicon, titanium, zirconium, or hafnium
    • B01J21/18Carbon
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J37/00Processes, in general, for preparing catalysts; Processes, in general, for activation of catalysts
    • B01J37/02Impregnation, coating or precipitation
    • B01J37/0201Impregnation
    • B01J37/0205Impregnation in several steps

Landscapes

  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Engineering & Computer Science (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • Materials Engineering (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
  • Catalysts (AREA)
AT02742103T 2001-06-19 2002-06-14 Zinn aktivierter platinum katalysator für die karbonylierung von niedrigen aliphatischen alkoholen ATE306320T1 (de)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
US09/884,775 US6903045B2 (en) 2001-06-19 2001-06-19 Tin promoted platinum catalyst for carbonylation of lower alkyl alcohols
PCT/US2002/018957 WO2002102506A1 (en) 2001-06-19 2002-06-14 Tin promoted platinum catalyst for carbonylation of lower alkyl alcohols

Publications (1)

Publication Number Publication Date
ATE306320T1 true ATE306320T1 (de) 2005-10-15

Family

ID=25385366

Family Applications (1)

Application Number Title Priority Date Filing Date
AT02742103T ATE306320T1 (de) 2001-06-19 2002-06-14 Zinn aktivierter platinum katalysator für die karbonylierung von niedrigen aliphatischen alkoholen

Country Status (7)

Country Link
US (1) US6903045B2 (enExample)
EP (1) EP1397206B1 (enExample)
JP (1) JP4365207B2 (enExample)
CN (1) CN1289189C (enExample)
AT (1) ATE306320T1 (enExample)
DE (1) DE60206623T2 (enExample)
WO (1) WO2002102506A1 (enExample)

Families Citing this family (55)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US20060068986A1 (en) * 2004-09-27 2006-03-30 Dimascio Felice Catalyst elements and methods of making and using
US20060110311A1 (en) * 2004-11-03 2006-05-25 Dimascio Felice Catalyst composite and methods of making and using
US20060292059A1 (en) * 2005-06-22 2006-12-28 Dimascio Felice Catalyst element and use thereof
US8546622B2 (en) 2008-07-31 2013-10-01 Celanese International Corporation Process for making ethanol from acetic acid using acidic catalysts
US8304586B2 (en) * 2010-02-02 2012-11-06 Celanese International Corporation Process for purifying ethanol
US8501652B2 (en) 2008-07-31 2013-08-06 Celanese International Corporation Catalysts for making ethanol from acetic acid
US8680317B2 (en) * 2008-07-31 2014-03-25 Celanese International Corporation Processes for making ethyl acetate from acetic acid
US8309773B2 (en) 2010-02-02 2012-11-13 Calanese International Corporation Process for recovering ethanol
US8338650B2 (en) 2008-07-31 2012-12-25 Celanese International Corporation Palladium catalysts for making ethanol from acetic acid
US20100197486A1 (en) * 2008-07-31 2010-08-05 Celanese International Corporation Catalysts for making ethyl acetate from acetic acid
US8637714B2 (en) 2008-07-31 2014-01-28 Celanese International Corporation Process for producing ethanol over catalysts containing platinum and palladium
US8471075B2 (en) 2008-07-31 2013-06-25 Celanese International Corporation Processes for making ethanol from acetic acid
US8309772B2 (en) 2008-07-31 2012-11-13 Celanese International Corporation Tunable catalyst gas phase hydrogenation of carboxylic acids
US8450535B2 (en) 2009-07-20 2013-05-28 Celanese International Corporation Ethanol production from acetic acid utilizing a cobalt catalyst
US8680321B2 (en) * 2009-10-26 2014-03-25 Celanese International Corporation Processes for making ethanol from acetic acid using bimetallic catalysts
US8710277B2 (en) * 2009-10-26 2014-04-29 Celanese International Corporation Process for making diethyl ether from acetic acid
US8211821B2 (en) * 2010-02-01 2012-07-03 Celanese International Corporation Processes for making tin-containing catalysts
WO2011097246A1 (en) 2010-02-02 2011-08-11 Celanese International Corporation Preparation and use of a catalyst for producing ethanol comprising a crystalline support modifier
US8668750B2 (en) 2010-02-02 2014-03-11 Celanese International Corporation Denatured fuel ethanol compositions for blending with gasoline or diesel fuel for use as motor fuels
US8314272B2 (en) 2010-02-02 2012-11-20 Celanese International Corporation Process for recovering ethanol with vapor separation
US8728179B2 (en) 2010-02-02 2014-05-20 Celanese International Corporation Ethanol compositions
US8541633B2 (en) * 2010-02-02 2013-09-24 Celanese International Corporation Processes for producing anhydrous ethanol compositions
US8460405B2 (en) 2010-02-02 2013-06-11 Celanese International Corporation Ethanol compositions
US8932372B2 (en) 2010-02-02 2015-01-13 Celanese International Corporation Integrated process for producing alcohols from a mixed acid feed
US8858659B2 (en) 2010-02-02 2014-10-14 Celanese International Corporation Processes for producing denatured ethanol
US8575403B2 (en) 2010-05-07 2013-11-05 Celanese International Corporation Hydrolysis of ethyl acetate in ethanol separation process
US8680343B2 (en) 2010-02-02 2014-03-25 Celanese International Corporation Process for purifying ethanol
US8344186B2 (en) 2010-02-02 2013-01-01 Celanese International Corporation Processes for producing ethanol from acetaldehyde
US8747492B2 (en) 2010-02-02 2014-06-10 Celanese International Corporation Ethanol/fuel blends for use as motor fuels
US8222466B2 (en) 2010-02-02 2012-07-17 Celanese International Corporation Process for producing a water stream from ethanol production
US8754267B2 (en) 2010-05-07 2014-06-17 Celanese International Corporation Process for separating acetaldehyde from ethanol-containing mixtures
US8664454B2 (en) 2010-07-09 2014-03-04 Celanese International Corporation Process for production of ethanol using a mixed feed using copper containing catalyst
US8710279B2 (en) 2010-07-09 2014-04-29 Celanese International Corporation Hydrogenolysis of ethyl acetate in alcohol separation processes
US8704008B2 (en) 2010-07-09 2014-04-22 Celanese International Corporation Process for producing ethanol using a stacked bed reactor
US9272970B2 (en) 2010-07-09 2016-03-01 Celanese International Corporation Hydrogenolysis of ethyl acetate in alcohol separation processes
US8350098B2 (en) 2011-04-04 2013-01-08 Celanese International Corporation Ethanol production from acetic acid utilizing a molybdenum carbide catalyst
US8592635B2 (en) 2011-04-26 2013-11-26 Celanese International Corporation Integrated ethanol production by extracting halides from acetic acid
US8754268B2 (en) 2011-04-26 2014-06-17 Celanese International Corporation Process for removing water from alcohol mixtures
US9073816B2 (en) 2011-04-26 2015-07-07 Celanese International Corporation Reducing ethyl acetate concentration in recycle streams for ethanol production processes
TW201302684A (zh) 2011-04-26 2013-01-16 Celanese Int Corp 由醋酸進料及再循環醋酸乙酯進料生產乙醇之製程
US8895786B2 (en) 2011-08-03 2014-11-25 Celanese International Corporation Processes for increasing alcohol production
US8536382B2 (en) 2011-10-06 2013-09-17 Celanese International Corporation Processes for hydrogenating alkanoic acids using catalyst comprising tungsten
US8658843B2 (en) 2011-10-06 2014-02-25 Celanese International Corporation Hydrogenation catalysts prepared from polyoxometalate precursors and process for using same to produce ethanol while minimizing diethyl ether formation
US8703868B2 (en) 2011-11-28 2014-04-22 Celanese International Corporation Integrated process for producing polyvinyl alcohol or a copolymer thereof and ethanol
US9233899B2 (en) 2011-12-22 2016-01-12 Celanese International Corporation Hydrogenation catalysts having an amorphous support
US9000234B2 (en) 2011-12-22 2015-04-07 Celanese International Corporation Calcination of modified support to prepare hydrogenation catalysts
US9024086B2 (en) 2012-01-06 2015-05-05 Celanese International Corporation Hydrogenation catalysts with acidic sites
US8981164B2 (en) 2012-01-06 2015-03-17 Celanese International Corporation Cobalt and tin hydrogenation catalysts
US8865609B2 (en) 2012-01-06 2014-10-21 Celanese International Corporation Hydrogenation catalysts
US8729311B2 (en) 2012-02-10 2014-05-20 Celanese International Corporaton Catalysts for converting acetic acid to acetone
US9050585B2 (en) 2012-02-10 2015-06-09 Celanese International Corporation Chemisorption of ethyl acetate during hydrogenation of acetic acid to ethanol
US8802903B2 (en) 2012-03-13 2014-08-12 Celanese International Corporation Stacked bed reactor with diluents for producing ethanol
US8772553B2 (en) 2012-10-26 2014-07-08 Celanese International Corporation Hydrogenation reaction conditions for producing ethanol
FR3039082B1 (fr) * 2015-07-24 2017-07-21 Ifp Energies Now Catalyseur multi-metallique dope par du phosphore et un lanthanide
CN115605559A (zh) * 2019-12-30 2023-01-13 巴西石油公司(Br) 用于联合应用结垢去除剂和结垢抑制剂的方法

Family Cites Families (33)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US3717670A (en) 1968-08-02 1973-02-20 Monsanto Co Production of carboxylic acids and esters
US3772380A (en) 1970-03-12 1973-11-13 Monsanto Co Production of carboxylic acids and esters
US3689533A (en) 1971-03-15 1972-09-05 Monsanto Co Production of carboxylic acids and esters
US3996293A (en) * 1972-05-08 1976-12-07 Texaco Inc. Selective hydroformylation process
US3987089A (en) 1974-10-21 1976-10-19 Rohm And Haas Company Preparation of β-alkoxy esters from olefins
US4075259A (en) * 1975-11-20 1978-02-21 Uop Inc. Saturated hydrocarbon isomerization utilizing a catalyst of platinum group metal, cobalt, tin and halogen on a carrier
JPS54119407A (en) * 1978-03-09 1979-09-17 Agency Of Ind Science & Technol Preparation of aldehydes
JPS56166139A (en) * 1980-05-28 1981-12-21 Toa Nenryo Kogyo Kk Preparation of aldehyde
US4417077A (en) 1980-10-01 1983-11-22 University Of Illinois Foundation Heterogeneous anionic transition metal catalysts
US4433166A (en) 1980-12-29 1984-02-21 Monsanto Company Process for stabilizing carbonylation catalyst in soluble form
US4424380A (en) * 1981-12-07 1984-01-03 Sun Tech, Inc. Hydroformylation catalyst and process of using it
US4612387A (en) 1982-01-04 1986-09-16 Air Products And Chemicals, Inc. Production of carboxylic acids and esters
FR2539647B1 (fr) * 1983-01-24 1985-06-07 Inst Francais Du Petrole Procede de preparation de catalyseurs bimetalliques ou plurimetalliques supportes a base d'un ou plusieurs metaux du groupe viii et d'au moins un metal du groupe iv catalyseurs obtenus et leurs utilisations
DE3463257D1 (en) 1983-03-25 1987-05-27 Texaco Development Corp A process for producing carboxylic acids by carbonylation of alkanols over a carbon catalyst
DE3323654A1 (de) 1983-07-01 1985-01-03 Basf Ag, 6700 Ludwigshafen Verfahren zur herstellung von essigsaeure und methylacetat
US4542119A (en) * 1984-04-11 1985-09-17 Sun Tech, Inc. Hydroformylation catalyst and process
US4524142A (en) * 1984-04-11 1985-06-18 Sun Tech, Inc. Platinum (O) complex-based hydroformylation catalyst
US4528278A (en) * 1984-04-11 1985-07-09 Sun Tech, Inc. Catalyst for hydroformylation of olefins
US4542120A (en) * 1984-04-11 1985-09-17 Sun Tech, Inc. Hydroformylation catalyst and process
FR2566420B1 (fr) * 1984-06-25 1987-07-24 Prod Catalyse Ste Fse Catalyseur d'hydrocraquage et son procede de preparation
EP0203286B1 (de) 1985-03-27 1988-09-14 Hoechst Aktiengesellschaft Trägerkatalysator und Verfahren zur Herstellung von Monocarbonsäureanhydriden
DE3643894A1 (de) 1986-12-22 1988-06-23 Degussa Rhodium-haltige organopolysiloxan-ammoniumverbindungen, verfahren zu ihrer herstellung und verwendung
US5185462A (en) 1987-01-08 1993-02-09 Bp Chemicals Limited Production of carboxylic acids and esters thereof
GB8807284D0 (en) 1988-03-26 1988-04-27 Bp Chem Int Ltd Chemical process
US5218140A (en) 1988-08-02 1993-06-08 Union Carbide Chemicals & Plastics Technology Corporation Carbonylation reaction and catalyst therefor
US5237097A (en) 1990-02-09 1993-08-17 Quantum Chemical Corporation Catalytic carbonylation process
DE4020941A1 (de) 1990-06-30 1992-01-02 Bayer Ag Verfahren zur herstellung von dialkylcarbonaten
US5488143A (en) 1992-06-30 1996-01-30 Korea Institute Of Science And Technology Processes for the carbonylation of methanol to form acetic acid, methyl acetate and acetic anhydride
GB9517184D0 (en) 1995-08-22 1995-10-25 Bp Chem Int Ltd Process
US6160163A (en) * 1999-02-16 2000-12-12 Eastman Chemical Company Method for the vapor-phase carbonylation of lower aliphatic alcohols using a supported platinum catalyst and halide promoter
US6235673B1 (en) 2000-04-05 2001-05-22 Eastman Chemical Company Carbonylation catalyst supported on a carbonized polysulfonated divinylbenzene-styrene copolymer
EP1225177A1 (en) * 2001-01-19 2002-07-24 Atofina Vlissingen B.V. Process for the production of monoalkyltin trihalides
US6613938B2 (en) * 2001-06-19 2003-09-02 Eastman Chemical Company Method for carbonylation of lower aliphatic alcohols using tin promoted platinum catalyst

Also Published As

Publication number Publication date
WO2002102506A1 (en) 2002-12-27
JP4365207B2 (ja) 2009-11-18
US20030032552A1 (en) 2003-02-13
CN1289189C (zh) 2006-12-13
EP1397206B1 (en) 2005-10-12
CN1503694A (zh) 2004-06-09
DE60206623D1 (de) 2006-02-23
EP1397206A1 (en) 2004-03-17
JP2004529769A (ja) 2004-09-30
US6903045B2 (en) 2005-06-07
DE60206623T2 (de) 2006-04-27

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