ATE119889T1 - S-triazinderivate mit benzalmalonaten als substituenten, verfahren zu ihrer herstellung, diese enthaltende kosmetische zubereitungen mit filternder wirkung und ihre verwendung als schutzmittel für haut und haar. - Google Patents
S-triazinderivate mit benzalmalonaten als substituenten, verfahren zu ihrer herstellung, diese enthaltende kosmetische zubereitungen mit filternder wirkung und ihre verwendung als schutzmittel für haut und haar.Info
- Publication number
- ATE119889T1 ATE119889T1 AT92400932T AT92400932T ATE119889T1 AT E119889 T1 ATE119889 T1 AT E119889T1 AT 92400932 T AT92400932 T AT 92400932T AT 92400932 T AT92400932 T AT 92400932T AT E119889 T1 ATE119889 T1 AT E119889T1
- Authority
- AT
- Austria
- Prior art keywords
- skin
- hair
- benzalmalonates
- substituents
- production
- Prior art date
Links
- JIHQDMXYYFUGFV-UHFFFAOYSA-N 1,3,5-triazine Chemical class C1=NC=NC=N1 JIHQDMXYYFUGFV-UHFFFAOYSA-N 0.000 title 1
- 239000002537 cosmetic Substances 0.000 title 1
- 230000000694 effects Effects 0.000 title 1
- 238000001914 filtration Methods 0.000 title 1
- 238000004519 manufacturing process Methods 0.000 title 1
- 238000000034 method Methods 0.000 title 1
- 238000002360 preparation method Methods 0.000 title 1
- 239000003223 protective agent Substances 0.000 title 1
- 125000003837 (C1-C20) alkyl group Chemical group 0.000 abstract 2
- 150000001875 compounds Chemical class 0.000 abstract 2
- 125000004191 (C1-C6) alkoxy group Chemical group 0.000 abstract 1
- 125000003860 C1-C20 alkoxy group Chemical group 0.000 abstract 1
- 125000004663 dialkyl amino group Chemical group 0.000 abstract 1
- 229910052736 halogen Inorganic materials 0.000 abstract 1
- 125000005843 halogen group Chemical group 0.000 abstract 1
- 230000005855 radiation Effects 0.000 abstract 1
Classifications
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K8/00—Cosmetics or similar toiletry preparations
- A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
- A61K8/30—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds
- A61K8/49—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds containing heterocyclic compounds
- A61K8/494—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds containing heterocyclic compounds with more than one nitrogen as the only hetero atom
- A61K8/4966—Triazines or their condensed derivatives
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61Q—SPECIFIC USE OF COSMETICS OR SIMILAR TOILETRY PREPARATIONS
- A61Q17/00—Barrier preparations; Preparations brought into direct contact with the skin for affording protection against external influences, e.g. sunlight, X-rays or other harmful rays, corrosive materials, bacteria or insect stings
- A61Q17/04—Topical preparations for affording protection against sunlight or other radiation; Topical sun tanning preparations
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07D—HETEROCYCLIC COMPOUNDS
- C07D251/00—Heterocyclic compounds containing 1,3,5-triazine rings
- C07D251/02—Heterocyclic compounds containing 1,3,5-triazine rings not condensed with other rings
- C07D251/12—Heterocyclic compounds containing 1,3,5-triazine rings not condensed with other rings having three double bonds between ring members or between ring members and non-ring members
- C07D251/26—Heterocyclic compounds containing 1,3,5-triazine rings not condensed with other rings having three double bonds between ring members or between ring members and non-ring members with only hetero atoms directly attached to ring carbon atoms
- C07D251/40—Nitrogen atoms
- C07D251/48—Two nitrogen atoms
- C07D251/52—Two nitrogen atoms with an oxygen or sulfur atom attached to the third ring carbon atom
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07D—HETEROCYCLIC COMPOUNDS
- C07D251/00—Heterocyclic compounds containing 1,3,5-triazine rings
- C07D251/02—Heterocyclic compounds containing 1,3,5-triazine rings not condensed with other rings
- C07D251/12—Heterocyclic compounds containing 1,3,5-triazine rings not condensed with other rings having three double bonds between ring members or between ring members and non-ring members
- C07D251/26—Heterocyclic compounds containing 1,3,5-triazine rings not condensed with other rings having three double bonds between ring members or between ring members and non-ring members with only hetero atoms directly attached to ring carbon atoms
- C07D251/40—Nitrogen atoms
- C07D251/54—Three nitrogen atoms
- C07D251/70—Other substituted melamines
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
- Y10S—TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10S424/00—Drug, bio-affecting and body treating compositions
- Y10S424/01—Aerosol hair preparation
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
- Y10S—TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10S424/00—Drug, bio-affecting and body treating compositions
- Y10S424/05—Stick
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Health & Medical Sciences (AREA)
- Life Sciences & Earth Sciences (AREA)
- Animal Behavior & Ethology (AREA)
- General Health & Medical Sciences (AREA)
- Public Health (AREA)
- Veterinary Medicine (AREA)
- Birds (AREA)
- Epidemiology (AREA)
- Dermatology (AREA)
- Cosmetics (AREA)
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| FR9104122A FR2674850B1 (fr) | 1991-04-04 | 1991-04-04 | Derives s-triaziniques portant des substituants benzalmalonates, compositions cosmetiques filtrantes les contenant et leur utilisation pour proteger la peau et les cheveux du rayonnement ultraviolet. |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| ATE119889T1 true ATE119889T1 (de) | 1995-04-15 |
Family
ID=9411485
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| AT92400932T ATE119889T1 (de) | 1991-04-04 | 1992-04-03 | S-triazinderivate mit benzalmalonaten als substituenten, verfahren zu ihrer herstellung, diese enthaltende kosmetische zubereitungen mit filternder wirkung und ihre verwendung als schutzmittel für haut und haar. |
Country Status (8)
| Country | Link |
|---|---|
| US (1) | US5236698A (de) |
| EP (1) | EP0507691B1 (de) |
| JP (1) | JP3083904B2 (de) |
| AT (1) | ATE119889T1 (de) |
| CA (1) | CA2064930A1 (de) |
| DE (1) | DE69201667T2 (de) |
| ES (1) | ES2069388T3 (de) |
| FR (1) | FR2674850B1 (de) |
Families Citing this family (69)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| FR2744721B1 (fr) * | 1996-02-12 | 1999-06-18 | Oreal | Nouveaux derives insolubles de s-triazine, leur procede de preparation, compositions les contenant et leurs utilisations |
| ES2235222T3 (es) * | 1996-09-17 | 2005-07-01 | Ciba Specialty Chemicals Holding Inc. | Uso de absorbentes uv liposomogenicos para proteger el cabello. |
| FR2755692B1 (fr) | 1996-11-08 | 1998-12-04 | Oreal | Nouveaux filtres solaires, compositions cosmetiques photoprotectrices les contenant et utilisations |
| FR2757055B1 (fr) * | 1996-12-17 | 1999-02-05 | Oreal | Compositions comprenant un derive de dibenzoylmethane, un derive de 1,2,3-triazine et un benzalmalonate de dialkyle et utilisations |
| FR2760464B1 (fr) * | 1997-03-07 | 2005-07-01 | Oreal | Procede pour ameliorer la photostabilite d'un derive de dibenzoylmethane par un silane, benzalmalonate, procede de preparation de silanes benzalmalonates |
| AU8306398A (en) | 1997-10-09 | 1999-04-29 | Sumitomo Chemical Company, Limited | Method for controlling acarina |
| CN1675995B (zh) | 1997-10-10 | 2013-09-04 | 纯生物科学公司 | 消毒剂及其制造方法 |
| SG75939A1 (en) * | 1998-04-09 | 2000-10-24 | Ciba Sc Holding Ag | Diresorcinyl-alkoxy-and-aryloxy-s-triazines |
| DE19817296A1 (de) * | 1998-04-18 | 2000-01-20 | Beiersdorf Ag | Kosmetische oder dermatologische Zubereitungen mit einem Gehalt an unsymmetrisch substituierten Triazinderivaten, welche wasserfeste Lichtschutzzubereitungen in Form von O/W-Emulsionen darstellen |
| DE19831107A1 (de) * | 1998-07-11 | 2000-01-13 | Beiersdorf Ag | Kosmetische und dermatologische Lichtschutzformulierungen mit einem Gehalt an Triazinderivaten und Alkancarbonsäuren bzw. deren Salzen |
| FR2783711B1 (fr) * | 1998-09-25 | 2000-11-10 | Oreal | Compositions cosmetiques photoprotectrices et utilisations |
| US7261905B2 (en) * | 1999-04-07 | 2007-08-28 | Pure Bioscience | Disinfectant and method of making |
| US6890953B2 (en) * | 2000-04-06 | 2005-05-10 | Innovative Medical Services | Process for treating water |
| DE10124332A1 (de) * | 2001-05-18 | 2002-11-21 | Basf Ag | Kosmetische oder pharmazeutische Zubereitungen, die Enaminotriazine als Lichtschutzmittel enthalten und neue Enaminotriazine |
| FR2826264B1 (fr) | 2001-06-26 | 2005-03-04 | Oreal | Solubilisation de derives 1,3,5 triazine par des esters n-acyles d'acide amine |
| US20040044073A1 (en) * | 2002-08-31 | 2004-03-04 | Innovative Medical Services | Composition and process for treating acne |
| US7534421B2 (en) | 2003-03-03 | 2009-05-19 | L'oreal | s-Triazine compounds bearing at least one para-aminobenzalmalonic salt substituent and photoprotective cosmetic compositions comprised thereof |
| FR2852009B1 (fr) * | 2003-03-03 | 2007-06-08 | Oreal | Nouveaux derives amine, amides, sulfonamides et carbamates des sels de l'acide benzamalonique et compositions cosmetiques photoprotectrices contenant ces derives |
| US7008935B2 (en) | 2003-03-03 | 2006-03-07 | L'oreal | Amine, amide, sulphonamide and carbamate derivatives of benzalmalonic salts and photoprotective cosmetic compositions comprised thereof |
| FR2852010B1 (fr) * | 2003-03-03 | 2005-04-15 | Nouveaux derives de s-triazine possedant au moins un sel d'acide para-amino benzalmalonique greffe et compositions cosmetiques photoprotectrices contenant ces derives | |
| FR2854157B1 (fr) | 2003-04-22 | 2006-07-14 | Oreal | Derives de s-triazine possedant 3 groupements para-aminobenzalmalonates particuliers; compositions cosmetiques photoprotectrices contenant ces derives; utilisations desdits derives de s-triazine |
| US7435438B1 (en) | 2003-05-16 | 2008-10-14 | Pure Bioscience | Disinfectant and method of use |
| US20050008588A1 (en) * | 2003-06-05 | 2005-01-13 | L'oreal | Aminoarylvinyl-s-triazine compounds and uses thereof |
| FR2855755B1 (fr) * | 2003-06-05 | 2007-09-07 | Oreal | Utilisation d'au moins un filtre de la lumiere bleue pour preserve le capital de carotenoides endogenes de la peau; nouveaux filtres de la lumiere bleue; compositions cosmetiques |
| US20050012594A1 (en) * | 2003-07-17 | 2005-01-20 | Youngtack Shim | Key assemblies and methods |
| CA2536955A1 (en) * | 2003-08-28 | 2005-03-10 | Pure Bioscience | Silver dihydrogen citrate compositions comprising a second antimicrobial agent |
| US8221728B2 (en) | 2004-02-24 | 2012-07-17 | L'oreal | Silanic para-aminobenzalmalonate-substituted s-triazine compounds and photoprotective compositions comprised thereof |
| FR2866648B1 (fr) | 2004-02-24 | 2006-03-31 | Oreal | Derives de s-triazine possedant au moins 2 groupements para aminobenzalmalonates silaniques; compositions cosmetiques photoprotectrices contenant ces derives; utilisations desdits derives de s-triazine |
| ES2633640T3 (es) | 2004-03-22 | 2017-09-22 | L'oreal | Composición cosmética que comprende un elastómero de silicona poliglicerolado |
| US8323624B2 (en) | 2004-09-02 | 2012-12-04 | L'oreal | S-triazine sunscreens bearing hindered para-aminobenzalmalonate/para-aminobenzalmalonamide and aminobenzoate/aminobenzamide substituents |
| ES2365619T3 (es) * | 2004-09-02 | 2011-10-07 | L'oreal | Compuestos de s-triazina que poseen dos substituyentes seleccionados entre grupos para-aminobenzalmalonato y para-aminobenzalmalonamida voluminosos y un substituyente aminobenzoato, composiciones y utilizaciones. |
| US20060051430A1 (en) * | 2004-09-07 | 2006-03-09 | Arata Andrew B | Silver dihydrogen citrate compositions |
| FR2879447B1 (fr) | 2004-12-17 | 2007-01-26 | Oreal | Procede cosmetique de soin de la peau et kit associe |
| FR2879456B1 (fr) | 2004-12-20 | 2007-05-04 | Oreal | Composition solaire comprenant au moins un filtre uv lipophile et au moins une hydroxyalkyluree |
| FR2883168B1 (fr) | 2005-03-18 | 2008-01-11 | Oreal | Compositions cosmetiques de soin, renforcement et/ou reparation des substrats keratiniques comprenant des polypeptides kap |
| US8216554B2 (en) | 2005-04-20 | 2012-07-10 | L'oreal | Stable transfer-resistant self-tanning gel containing a water-soluble or water-dispersible gelling agent |
| FR2885797B1 (fr) * | 2005-05-17 | 2007-07-27 | Oreal | Particules d'huile gelifiee comportant au moins un filtre solaire hydrophobe |
| FR2888113B1 (fr) * | 2005-07-08 | 2007-09-07 | Oreal | Composition photoprotectrice contenant un derive amide, sulfonamide ou carbamate d'un ester de l'acide benzalmalonique; nouveaux composes ; procedes de preparation utilisations. |
| US20070196294A1 (en) * | 2006-02-03 | 2007-08-23 | L'oreal | Photostable sunscreen compositions comprising dibenzoylmethane compound UV-A filters and s-triazine compounds |
| FR2896988B1 (fr) * | 2006-02-03 | 2008-03-14 | Oreal | Compositions contenant un filtre uv-b du type ester de l'acide cinnamique et un derive de s-triazine ; procede de photostabilisation d'un filtre uv-b du type ester de l'acide cinnamique |
| FR2896987B1 (fr) * | 2006-02-03 | 2008-03-14 | Oreal | Composition contenant un filtre uv-b du type ester de l'acide cinnamique, un filtre uv-a du type dibenzoylmethane et un derive de s-triazine ; procede de photostabilisation |
| US20070218022A1 (en) * | 2006-02-03 | 2007-09-20 | L'oreal, Paris, France | Photostable sunscreen compositions comprising cinnamic acid ester UV-B filters, dibenzoylmethane UV-A filters and s-triazine compounds |
| FR2896989B1 (fr) * | 2006-02-03 | 2008-03-14 | Oreal | Compositions contenant un filtre uv-a du type derive de dibenzoylmethane et un derive de s-triazine ; procede de photostabilisation |
| FR2909552B1 (fr) | 2006-12-12 | 2009-11-20 | Oreal | Utilisation cosmetique de l'acide anisique pour favoriser la desquamation |
| EP2100585A1 (de) | 2008-03-11 | 2009-09-16 | L'Oréal | Kosmetische Zusammensetzung, die eine Ascorbinsäure- oder eine Salicylsäureverbindung enthält |
| FR2939042B1 (fr) | 2008-11-28 | 2010-11-26 | Oreal | PROCEDE DE DEPIGMENTATION DES MATIERES KERATINIQUES A l'AIDE DE COMPOSES DITHIOLANNES. |
| FR2939310B1 (fr) | 2008-12-08 | 2012-04-20 | Oreal | Compositions cosmetiques comprenant un derive ester de 2-pyrrolidinone 4-carboxy et un filtre lipophile triazine ; utilisation dudit derive comme solvant d'un filtre lipophile triazine |
| FR2949330B1 (fr) | 2009-08-28 | 2012-08-10 | Oreal | Composition cosmetique comprenant un derive diphenyl-methane hydroxyle |
| DE102009044891A1 (de) | 2009-12-14 | 2011-06-16 | Gabriele Dr. Blume | Trägersystem zum Einschließen lipophiler Wirkstoffe und Öle in hoher Konzentration |
| US8585782B2 (en) | 2010-09-14 | 2013-11-19 | Basf Se | Use of specific bis(biphenyl)triazine derivatives and mixtures thereof as UV absorbers |
| WO2012052499A1 (en) | 2010-10-22 | 2012-04-26 | Basf Se | Use of silane and siloxane bis(biphenyl)triazine derivatives as uv absorbers |
| FR2968661B1 (fr) | 2010-12-14 | 2016-01-01 | Oreal | Procede de depigmentation des matieres keratiniques a l'aide de composes thiopyridinones |
| FR2969149B1 (fr) | 2010-12-16 | 2012-12-28 | Oreal | Procede de depigmentation des matieres keratiniques a l' aide de composes derives de resorcinol |
| EP2744335B1 (de) | 2011-08-16 | 2018-10-10 | Basf Se | Zusammensetzung enthaltend wirkstoff, öl und ionische flüssigkeit |
| FR2991985B1 (fr) | 2012-06-19 | 2019-11-08 | L'oreal | Procede de depigmentation des matieres keratiniques a l'aide de nouveaux composes derives de resorcinol |
| FR2991986B1 (fr) | 2012-06-19 | 2015-02-27 | Oreal | Nouveaux derives de resorcinol et leurs applications cosmetiques |
| FR2991984B1 (fr) | 2012-06-19 | 2014-07-11 | Oreal | Nouveaux derives de resorcinol et leur application cosmetique |
| EP2743337B1 (de) | 2012-12-14 | 2016-10-12 | Cognis IP Management GmbH | Oberflächenaktive polyglycerinderivate |
| FR3045604B1 (fr) | 2015-12-18 | 2018-01-26 | L'oreal | Procede de depigmentation des matieres keratiniques a l'aide de composes thiopyridinones |
| FR3061008B1 (fr) * | 2016-12-22 | 2020-05-01 | L'oreal | Composition cosmetique comprenant une ou plusieurs huile(s) polaire(s), un monoalcool aliphatique en c2-c6 et un polyol, et comprenant moins de 5% en poids d’eau |
| FR3061009B1 (fr) * | 2016-12-22 | 2020-09-25 | Oreal | Composition cosmetique comprenant une ou plusieurs huile(s) polaire(s), un monoalcool aliphatique en c2-c6 et un polyol, au moins un actif hydrophile, et comprenant moins de 7% en poids d’eau |
| FR3117825B1 (fr) | 2020-12-18 | 2026-02-20 | Oreal | Composition cosmétique ou dermatologique comprenant une mérocyanine, un filtre UV triazine, et un polysaccharide modifié par des chaînes hydrophobes |
| FR3117789B1 (fr) | 2020-12-22 | 2025-11-07 | Oreal | Composition cosmétique comprenant au moins une argile, au moins un corps gras cristallisable et au moins un filtre UV liposoluble |
| FR3141345B1 (fr) | 2022-10-28 | 2025-08-22 | Oreal | Emulsion comprenant une dispersion polymérique spécifique et un filtre UV |
| CN120112266A (zh) | 2022-10-28 | 2025-06-06 | 帝斯曼知识产权资产管理有限公司 | 包括人乳寡糖的防晒组合物 |
| US20250325472A1 (en) | 2022-10-28 | 2025-10-23 | Dsm Ip Assets B.V. | Novel compositions |
| EP4608364A1 (de) | 2022-10-28 | 2025-09-03 | DSM IP Assets B.V. | Sonnenschutzzusammensetzungen mit einem menschlichen milcholigosaccharid |
| WO2025132323A1 (en) | 2023-12-21 | 2025-06-26 | Dsm-Firmenich Ag | Compositions comprising a sunscreen active agent |
| WO2026002420A1 (fr) | 2024-06-28 | 2026-01-02 | Kokuma | Utilisation cosmétique de composés dérivés de l'acide oléanolique |
Family Cites Families (7)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| NL223154A (de) * | 1956-12-14 | |||
| CH401074A (de) * | 1960-03-04 | 1965-10-31 | Ciba Geigy | Verfahren zur Herstellung neuer Bistriazinylaminostilbendisulfonsäuren |
| NL276475A (de) * | 1961-03-28 | |||
| NL130993C (de) * | 1963-02-07 | |||
| CH433296A (de) * | 1963-02-18 | 1967-04-15 | Ciba Geigy | Verwendung neuer Hydroxyaryl-1,3,5-triazine als Ultraviolettschutzmittel für nicht-textile organische Materialien |
| CH469053A (de) * | 1963-07-26 | 1969-02-28 | Ciba Geigy | Verwendung von neuen Hydroxyphenyl-1,3,5-triazinen als Schutzmittel gegen Ultraviolettstrahlung für nichttextile organische Materialien |
| DE3206398A1 (de) * | 1982-02-23 | 1983-09-01 | Basf Ag, 6700 Ludwigshafen | S-triazinderivate und ihre verwendung als lichtschutzmittel |
-
1991
- 1991-04-04 FR FR9104122A patent/FR2674850B1/fr not_active Expired - Fee Related
-
1992
- 1992-04-02 CA CA002064930A patent/CA2064930A1/fr not_active Abandoned
- 1992-04-03 JP JP04081871A patent/JP3083904B2/ja not_active Expired - Fee Related
- 1992-04-03 AT AT92400932T patent/ATE119889T1/de not_active IP Right Cessation
- 1992-04-03 ES ES92400932T patent/ES2069388T3/es not_active Expired - Lifetime
- 1992-04-03 DE DE69201667T patent/DE69201667T2/de not_active Expired - Fee Related
- 1992-04-03 EP EP92400932A patent/EP0507691B1/de not_active Expired - Lifetime
-
1993
- 1993-04-02 US US07/862,378 patent/US5236698A/en not_active Expired - Lifetime
Also Published As
| Publication number | Publication date |
|---|---|
| DE69201667D1 (de) | 1995-04-20 |
| FR2674850B1 (fr) | 1993-07-02 |
| FR2674850A1 (fr) | 1992-10-09 |
| JPH05230040A (ja) | 1993-09-07 |
| JP3083904B2 (ja) | 2000-09-04 |
| EP0507691B1 (de) | 1995-03-15 |
| ES2069388T3 (es) | 1995-05-01 |
| EP0507691A1 (de) | 1992-10-07 |
| DE69201667T2 (de) | 1995-07-20 |
| US5236698A (en) | 1993-08-17 |
| CA2064930A1 (fr) | 1992-10-05 |
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