AT155152B - Process for driving away and controlling insects and their larvae. - Google Patents
Process for driving away and controlling insects and their larvae.Info
- Publication number
- AT155152B AT155152B AT155152DA AT155152B AT 155152 B AT155152 B AT 155152B AT 155152D A AT155152D A AT 155152DA AT 155152 B AT155152 B AT 155152B
- Authority
- AT
- Austria
- Prior art keywords
- larvae
- thianthrene
- driving away
- controlling insects
- insects
- Prior art date
Links
- 241000238631 Hexapoda Species 0.000 title claims description 6
- 238000000034 method Methods 0.000 title claims description 3
- GVIJJXMXTUZIOD-UHFFFAOYSA-N thianthrene Chemical compound C1=CC=C2SC3=CC=CC=C3SC2=C1 GVIJJXMXTUZIOD-UHFFFAOYSA-N 0.000 claims description 6
- NINIDFKCEFEMDL-UHFFFAOYSA-N Sulfur Chemical compound [S] NINIDFKCEFEMDL-UHFFFAOYSA-N 0.000 claims description 3
- 239000000203 mixture Substances 0.000 claims description 3
- 238000006467 substitution reaction Methods 0.000 claims description 3
- 229910052717 sulfur Inorganic materials 0.000 claims description 3
- 239000011593 sulfur Substances 0.000 claims description 3
- 150000001875 compounds Chemical class 0.000 description 4
- -1 3-amino-6-methylthianthrene chlorohydrate Chemical compound 0.000 description 3
- 150000005029 thianthrenes Chemical class 0.000 description 3
- 241000607479 Yersinia pestis Species 0.000 description 2
- 238000007598 dipping method Methods 0.000 description 2
- 210000003746 feather Anatomy 0.000 description 2
- NYVGTLXTOJKHJN-UHFFFAOYSA-N thianthrene 5-oxide Chemical compound C1=CC=C2S(=O)C3=CC=CC=C3SC2=C1 NYVGTLXTOJKHJN-UHFFFAOYSA-N 0.000 description 2
- 210000002268 wool Anatomy 0.000 description 2
- UFCGWEZWBLLGPD-UHFFFAOYSA-N 1,2-dimethoxythianthrene Chemical compound COC1=C(C=2SC3=CC=CC=C3SC2C=C1)OC UFCGWEZWBLLGPD-UHFFFAOYSA-N 0.000 description 1
- RUYCABJQOCNLKD-UHFFFAOYSA-N 1,2-dinitrothianthrene Chemical compound [N+](=O)([O-])C1=C(C=2SC3=CC=CC=C3SC=2C=C1)[N+](=O)[O-] RUYCABJQOCNLKD-UHFFFAOYSA-N 0.000 description 1
- VJPMQVSYJQEJQE-UHFFFAOYSA-N 1-chloro-8-nitrothianthrene Chemical compound ClC1=C2SC=3C=C(C=CC=3SC2=CC=C1)[N+](=O)[O-] VJPMQVSYJQEJQE-UHFFFAOYSA-N 0.000 description 1
- RPIJSBMZQLHZLK-UHFFFAOYSA-N 1-methyl-8-nitrothianthrene Chemical compound [N+](=O)([O-])C=1C=CC=2SC3=CC=CC(=C3SC2C1)C RPIJSBMZQLHZLK-UHFFFAOYSA-N 0.000 description 1
- ZSMGYPFNCUHPKU-UHFFFAOYSA-N 2-chlorothianthrene Chemical compound C1=CC=C2SC3=CC(Cl)=CC=C3SC2=C1 ZSMGYPFNCUHPKU-UHFFFAOYSA-N 0.000 description 1
- LHYBYHSFGJENBI-UHFFFAOYSA-N COC1=CC=C2[S+](C)C(C=C(C=C3)[N+]([O-])=O)=C3SC2=C1 Chemical compound COC1=CC=C2[S+](C)C(C=C(C=C3)[N+]([O-])=O)=C3SC2=C1 LHYBYHSFGJENBI-UHFFFAOYSA-N 0.000 description 1
- BWGNESOTFCXPMA-UHFFFAOYSA-N Dihydrogen disulfide Chemical compound SS BWGNESOTFCXPMA-UHFFFAOYSA-N 0.000 description 1
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 description 1
- OFOBLEOULBTSOW-UHFFFAOYSA-N Malonic acid Chemical compound OC(=O)CC(O)=O OFOBLEOULBTSOW-UHFFFAOYSA-N 0.000 description 1
- 241001465754 Metazoa Species 0.000 description 1
- 241000253999 Phasmatodea Species 0.000 description 1
- 239000000654 additive Substances 0.000 description 1
- 230000000996 additive effect Effects 0.000 description 1
- 150000001298 alcohols Chemical class 0.000 description 1
- 230000001680 brushing effect Effects 0.000 description 1
- 239000003795 chemical substances by application Substances 0.000 description 1
- 150000008280 chlorinated hydrocarbons Chemical class 0.000 description 1
- 238000007796 conventional method Methods 0.000 description 1
- 239000006071 cream Substances 0.000 description 1
- 150000002019 disulfides Chemical class 0.000 description 1
- 238000001035 drying Methods 0.000 description 1
- 239000003925 fat Substances 0.000 description 1
- 210000004209 hair Anatomy 0.000 description 1
- 229930195733 hydrocarbon Natural products 0.000 description 1
- 150000002430 hydrocarbons Chemical class 0.000 description 1
- 150000002576 ketones Chemical class 0.000 description 1
- 239000003921 oil Substances 0.000 description 1
- 239000003960 organic solvent Substances 0.000 description 1
- 239000000843 powder Substances 0.000 description 1
- 238000005507 spraying Methods 0.000 description 1
- 239000000126 substance Substances 0.000 description 1
- OLAQGXHWYVZUNZ-UHFFFAOYSA-N thianthrene-1-sulfonic acid Chemical compound S1C2=CC=CC=C2SC2=C1C=CC=C2S(=O)(=O)O OLAQGXHWYVZUNZ-UHFFFAOYSA-N 0.000 description 1
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 1
Landscapes
- Agricultural Chemicals And Associated Chemicals (AREA)
Description
<Desc/Clms Page number 1>
Verfahren zum Vertreiben und Bekämpfen von Insekten und deren Larven.
Es wurde gefunden, dass man neue, wertvolle Mittel zum Vertreiben und Bekämpfen von
Insekten und deren Larven erhält, wenn man in üblicher Anwendungsweise Thianthren, dessen
Derivate oder Substitntionsprod) 1kte, deren zyklisch gebundener Schwefel nicht in der Oniumform vorliegt, in Lösungen oder Mischungen verwendet.
Verbindungen solcher Art sind in grosser Zahl bekannt. lis folgenden seien einige derselben aufgezählt, ohne dadurch den Umfang der vorliegenden
Erfindung beschränken zu wollen :
Thianthren, 2. 6-Dimethylthianthren, 1.3. 5. 7-Tetramethylthianthren, 2-Chlorthianthren, 2. 7-Di- chlorthianthren, 2. 7-Dichlor-3. 6-dimethylthianthren, 4. 5-Dichlor-1. 8-dimethylthianthren, Dimethoxythianthren (C. 1922, 1., 818), 2.3. 6. 7-Tetramethoxythianthren, Dinitrothianthren BI (3) 15 ;
423, 3-Nitro-6-methylthianthren, 3-Nitro-8-methoxy-5-methylthianthren, 6-Chlor-3-nitrothianthren, 5. 8-Di- chlor-3-nitrothianthren, 3-amino-6-methylthianthren-ehlorhydrat, Thianthlendicarbonsäure (C. 1922,
1., 818), Thianthrensulfonsäure (C. 1927, 1., 360), Naphthianthien usw., feiner die S-Oxyde obiger
Verbindungen, wie beispielsweise : Thianthren-S-oxyd, Thianthren-S-dioxyd, Thianthren-mono-oder - disulfon, 2. 6-Dimethylthianthren-S-oxyde, 2.3. 6. 7-Tetramethoxythianthren-S-oxyde usw., oder die Disulfide, die sich von den Thianthrenverbindungen ableiten, beispielsweise 3.7-Dimethoxy-
2. 6-dioxythianthren-disulfid usw. Die meisten dieser Verbindungen sind im Schrifttum beschrieben ; sofern sie unbekannt sind, lassen sie sich nach üblichen Methoden herstellen.
Die genannten Thianthrene eignen sich beispielsweise hervorrager. d zum Schützen von Wolle,
Haaren, Pelzwerk, Federn u. dgl. vor Mottenfrass. Bereits in sehr geringen Konzentrationen verleihen sie der behandelten Ware zuverlässigen Schutz. Für die Verwendung kommen hauptsächlich Lösungen in Wasser oder billigen organischen Lösungsmitteln, wie Kohlenwasserstoffen, Chlorkohlenwasser- stoffen, Alkoholen, Ketonen usw. oder deren Gemischen in Frage. Die zu schützenden Stoffe können durch Bestreichen, Bespritzen oder Eintauchen imprägniert werden. Ausserdem können die Thianthrene in Ölen, Fetten und Cremen emulgiert oder als Zusatz zu Pulvern oder überhaupt in allen für die Zwecke der Schädlings-, insbesondere Insektenbekämpfung üblichen Anwendungsformen verwendet werden.
Ebenso kommen sie in Kombination mit andern, für gleiche Zwecke schon bekannten Bekämpfungs- und Vertreibungsmitteln in Betracht.
Beispiel l : Man lost 20 Teile Thianthren oder eine andere der oben aufgezählten Verbindungen, beispielsweise 2. 6-Dimethylthianthren, 2. 7-Dichlor-3. 6-dimethylthianthren, oder Thianthren-S-oxyd u. a. in 980 Teilen Alkohol, behandelt Pelze, Federn oder Wolle durch Tauchen, zentrifugieit undtroeknet.
Die so behandelte Ware ist mottenecht ; es genügen schon verdünntere Lösungen, um einen befriedi- genden Schutz zu erzielen.
Beispiel 2 : Bespritzt man tierische Schädlinge aus der Klasse der Insekten, beispielsweise
Stabheuschrecken, mit Lösungen, die Thianthren oder dessen Derivate oder Substitutionsprodukte, deren cyklisch gebundener Schwefel nicht in der Oniumform vorliegt, enthalten, so werden diese in ziemlich kurzer Zeit getötet.
**WARNUNG** Ende DESC Feld kannt Anfang CLMS uberlappen**.
<Desc / Clms Page number 1>
Process for driving away and controlling insects and their larvae.
It has been found that one can find new, valuable means of dispelling and fighting
Insects and their larvae are obtained if one uses thianthrene in the usual manner, its
Derivatives or substitution products, the cyclically bound sulfur of which is not in the onium form, used in solutions or mixtures.
Compounds of this type are known in large numbers. Some of them are enumerated below, without thereby reducing the scope of the present
Wanting to restrict the invention:
Thianthrene, 2. 6-dimethylthianthrene, 1.3. 5. 7-tetramethylthianthrene, 2-chlorothianthrene, 2. 7-dichlorothianthrene, 2. 7-dichloro-3. 6-dimethylthianthrene, 4. 5-dichloro-1. 8-dimethylthianthrene, dimethoxythianthrene (C. 1922, 1., 818), 2.3. 6. 7-tetramethoxythianthrene, dinitrothianthrene BI (3) 15;
423, 3-nitro-6-methylthianthrene, 3-nitro-8-methoxy-5-methylthianthrene, 6-chloro-3-nitrothianthrene, 5. 8-dichloro-3-nitrothianthrene, 3-amino-6-methylthianthrene chlorohydrate, thianthlene dicarboxylic acid (C. 1922,
1., 818), thianthrene sulfonic acid (C. 1927, 1., 360), naphthianthias, etc., finer the S-oxides above
Compounds such as: thianthrene S-oxide, thianthrene-S-dioxide, thianthrene mono- or disulfone, 2. 6-dimethylthianthrene-S-oxides, 2.3. 6. 7-tetramethoxythianthrene-S-oxides, etc., or the disulfides which are derived from the thianthrene compounds, for example 3.7-dimethoxy-
2. 6-dioxythianthrene disulfide, etc. Most of these compounds are described in literature; if they are unknown, they can be produced using conventional methods.
The thianthrenes mentioned are, for example, more suitable. d to protect wool,
Hair, fur, feathers, etc. like before moth damage. Even in very low concentrations, they give the treated goods reliable protection. Solutions in water or cheap organic solvents, such as hydrocarbons, chlorinated hydrocarbons, alcohols, ketones, etc., or mixtures thereof, are mainly suitable for use. The substances to be protected can be impregnated by brushing, spraying or dipping. In addition, the thianthrenes can be emulsified in oils, fats and creams or used as an additive to powders or in all of the application forms customary for the purpose of controlling pests, in particular insects.
They can also be used in combination with other control and repellant agents that are already known for the same purposes.
Example 1: 20 parts of thianthrene or another of the compounds listed above, for example 2. 6-dimethylthianthrene, 2. 7-dichloro-3, are dissolved. 6-dimethylthianthrene, or thianthrene-S-oxide u. a. in 980 parts of alcohol, treated fur, feathers or wool by dipping, centrifuging and drying.
The goods treated in this way are moth-proof; even more dilute solutions are sufficient to achieve satisfactory protection.
Example 2: If animal pests from the class of insects are sprayed, for example
Stick insects, with solutions that contain thianthrene or its derivatives or substitution products, the cyclically bound sulfur of which is not in the onium form, these are killed in a fairly short time.
** WARNING ** End of DESC field may overlap beginning of CLMS **.
Claims (1)
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CH155152X | 1936-05-09 |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| AT155152B true AT155152B (en) | 1938-12-10 |
Family
ID=4409693
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| AT155152D AT155152B (en) | 1936-05-09 | 1937-04-30 | Process for driving away and controlling insects and their larvae. |
Country Status (1)
| Country | Link |
|---|---|
| AT (1) | AT155152B (en) |
-
1937
- 1937-04-30 AT AT155152D patent/AT155152B/en active
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