AT109083B - Process for the production of hot cathodes from hafnium. - Google Patents
Process for the production of hot cathodes from hafnium.Info
- Publication number
- AT109083B AT109083B AT109083DA AT109083B AT 109083 B AT109083 B AT 109083B AT 109083D A AT109083D A AT 109083DA AT 109083 B AT109083 B AT 109083B
- Authority
- AT
- Austria
- Prior art keywords
- hafnium
- production
- hot cathodes
- hot
- cathodes
- Prior art date
Links
- 229910052735 hafnium Inorganic materials 0.000 title description 8
- VBJZVLUMGGDVMO-UHFFFAOYSA-N hafnium atom Chemical compound [Hf] VBJZVLUMGGDVMO-UHFFFAOYSA-N 0.000 title description 8
- 238000000034 method Methods 0.000 title description 3
- 238000004519 manufacturing process Methods 0.000 title description 2
- 229910052783 alkali metal Inorganic materials 0.000 description 5
- 150000001340 alkali metals Chemical class 0.000 description 5
- 239000003638 chemical reducing agent Substances 0.000 description 4
- 238000000576 coating method Methods 0.000 description 3
- 229910052751 metal Inorganic materials 0.000 description 3
- 239000002184 metal Substances 0.000 description 3
- 239000011248 coating agent Substances 0.000 description 2
- 229910045601 alloy Inorganic materials 0.000 description 1
- 239000000956 alloy Substances 0.000 description 1
- 230000015572 biosynthetic process Effects 0.000 description 1
- 150000001875 compounds Chemical class 0.000 description 1
- 150000002363 hafnium compounds Chemical class 0.000 description 1
- 238000010438 heat treatment Methods 0.000 description 1
- 238000002844 melting Methods 0.000 description 1
- 150000002739 metals Chemical class 0.000 description 1
Landscapes
- Manufacture And Refinement Of Metals (AREA)
Description
<Desc/Clms Page number 1>
EMI1.1
Es ist bereits vorgeschlagen worden, Glühkathoden aus Hafnium oder Hafniumlegierungen herzustellen. Auch ist vorgesehlagen worden. @berzüge aus Metallen mit spezifisch hoher Elektronenemission durch Reduktion einer Verbindung des betreffenden Metalles herzustellen.
Gemäss der Erfindung erhält man besonders wirksame Glühkathoden aus Hafnium, wenn man auf
EMI1.2
mit Hilfe eines Alkalimetalles herstellt. Man kann beispielsweise von Oxyd des Hafniums ausgehen und das Oxyd durch Alkalimetalle reduzieren. Ein besonderer Vorteil des Verfahrens gemäss der Erfindung besteht darin, dass das Reduktionsmittel schon bei verhältnismässig niedrigen Temperaturen verdampft und deshalb leicht von der Glühkathode entfernt werden kann. so dass es die Elektronenemission des Hafniums nicht beeinträchtigt. Es hat sich nämlich gezeigt. dass die Emissionsfähigkeit der Glühkathode von der Art ihrer Reduktion abhängt.
Es ist nicht gleichgültig, ob man zur Reduktion Alkalimetalle oder
EMI1.3
Reduktionsmittels die Emissionsfähigkeit herabgesetzt, was wahrscheinlich auf Karbidbildung zurückzuführen ist. Bei der Verwendung von Alkalimetallen als Reduktionsmittel dagegen geht einerseits die Reduktion rasch vor sich und anderseits kann man durch eine verhältnismässig geringe Erhitzung der Kathode erreichen, dass das Reduktionsmittel verdampft.
PATENT-ANSPRL'CHH: 1. Verfahren zur Herstellung von Glühkathoden aus Hafnium, bei dem ein Glühfaden aus hochschmelzendem Metall mit einem Überzug aus Hafnium versehen wird, dadurch gekennzeichnet, dass ein. eine Hafniumverbindung enthaltender Überzug des Glühfadens durch ein Alkalimetall reduziert wird
**WARNUNG** Ende DESC Feld kannt Anfang CLMS uberlappen**.
<Desc / Clms Page number 1>
EMI1.1
It has already been proposed to produce hot cathodes from hafnium or hafnium alloys. It has also been proposed. @ Produce coatings from metals with a specifically high electron emission by reducing a compound of the metal in question.
According to the invention, particularly effective hot cathodes made of hafnium are obtained when one is on
EMI1.2
with the help of an alkali metal. One can, for example, start from the oxide of hafnium and reduce the oxide with alkali metals. A particular advantage of the method according to the invention is that the reducing agent evaporates even at relatively low temperatures and can therefore be easily removed from the hot cathode. so that it does not affect the electron emission of the hafnium. Because it has been shown. that the emissivity of the hot cathode depends on how it is reduced.
It does not matter whether one goes for reduction or alkali metals
EMI1.3
Reducing agent reduced the emissivity, which is probably due to carbide formation. When using alkali metals as reducing agents, on the one hand, the reduction proceeds quickly and, on the other hand, a relatively low heating of the cathode can cause the reducing agent to evaporate.
PATENT-ANSPRL'CHH: 1. A method for the production of hot cathodes made of hafnium, in which a filament made of high-melting metal is provided with a coating of hafnium, characterized in that a. a coating of the filament containing a hafnium compound is reduced by an alkali metal
** WARNING ** End of DESC field may overlap beginning of CLMS **.
Claims (1)
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| DE109083X | 1924-12-17 |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| AT109083B true AT109083B (en) | 1928-03-10 |
Family
ID=5651594
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| AT109083D AT109083B (en) | 1924-12-17 | 1925-10-14 | Process for the production of hot cathodes from hafnium. |
Country Status (1)
| Country | Link |
|---|---|
| AT (1) | AT109083B (en) |
-
1925
- 1925-10-14 AT AT109083D patent/AT109083B/en active
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