AR117524A1 - Ácido r-piridiloxicarboxílico y sal, derivado de éster, método de preparación, composición herbicida y su aplicación - Google Patents
Ácido r-piridiloxicarboxílico y sal, derivado de éster, método de preparación, composición herbicida y su aplicaciónInfo
- Publication number
- AR117524A1 AR117524A1 ARP190103875A ARP190103875A AR117524A1 AR 117524 A1 AR117524 A1 AR 117524A1 AR P190103875 A ARP190103875 A AR P190103875A AR P190103875 A ARP190103875 A AR P190103875A AR 117524 A1 AR117524 A1 AR 117524A1
- Authority
- AR
- Argentina
- Prior art keywords
- alkyl
- halogen
- substituted
- unsubstituted
- salt
- Prior art date
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Classifications
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- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07D—HETEROCYCLIC COMPOUNDS
- C07D213/00—Heterocyclic compounds containing six-membered rings, not condensed with other rings, with one nitrogen atom as the only ring hetero atom and three or more double bonds between ring members or between ring members and non-ring members
- C07D213/02—Heterocyclic compounds containing six-membered rings, not condensed with other rings, with one nitrogen atom as the only ring hetero atom and three or more double bonds between ring members or between ring members and non-ring members having three double bonds between ring members or between ring members and non-ring members
- C07D213/04—Heterocyclic compounds containing six-membered rings, not condensed with other rings, with one nitrogen atom as the only ring hetero atom and three or more double bonds between ring members or between ring members and non-ring members having three double bonds between ring members or between ring members and non-ring members having no bond between the ring nitrogen atom and a non-ring member or having only hydrogen or carbon atoms directly attached to the ring nitrogen atom
- C07D213/60—Heterocyclic compounds containing six-membered rings, not condensed with other rings, with one nitrogen atom as the only ring hetero atom and three or more double bonds between ring members or between ring members and non-ring members having three double bonds between ring members or between ring members and non-ring members having no bond between the ring nitrogen atom and a non-ring member or having only hydrogen or carbon atoms directly attached to the ring nitrogen atom with hetero atoms or with carbon atoms having three bonds to hetero atoms with at the most one bond to halogen, e.g. ester or nitrile radicals, directly attached to ring carbon atoms
- C07D213/72—Nitrogen atoms
- C07D213/73—Unsubstituted amino or imino radicals
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- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
- A01N25/00—Biocides, pest repellants or attractants, or plant growth regulators, characterised by their forms, or by their non-active ingredients or by their methods of application, e.g. seed treatment or sequential application; Substances for reducing the noxious effect of the active ingredients to organisms other than pests
- A01N25/32—Ingredients for reducing the noxious effect of the active substances to organisms other than pests, e.g. toxicity reducing compositions, self-destructing compositions
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- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
- A01N43/00—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds
- A01N43/34—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with one nitrogen atom as the only ring hetero atom
- A01N43/40—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with one nitrogen atom as the only ring hetero atom six-membered rings
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- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
- A01N43/00—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds
- A01N43/48—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with two nitrogen atoms as the only ring hetero atoms
- A01N43/50—1,3-Diazoles; Hydrogenated 1,3-diazoles
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- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
- A01N43/00—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds
- A01N43/48—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with two nitrogen atoms as the only ring hetero atoms
- A01N43/54—1,3-Diazines; Hydrogenated 1,3-diazines
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- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
- A01N43/00—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds
- A01N43/48—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with two nitrogen atoms as the only ring hetero atoms
- A01N43/56—1,2-Diazoles; Hydrogenated 1,2-diazoles
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- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
- A01N43/00—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds
- A01N43/72—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with nitrogen atoms and oxygen or sulfur atoms as ring hetero atoms
- A01N43/74—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with nitrogen atoms and oxygen or sulfur atoms as ring hetero atoms five-membered rings with one nitrogen atom and either one oxygen atom or one sulfur atom in positions 1,3
- A01N43/78—1,3-Thiazoles; Hydrogenated 1,3-thiazoles
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- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
- A01N47/00—Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds containing a carbon atom not being member of a ring and having no bond to a carbon or hydrogen atom, e.g. derivatives of carbonic acid
- A01N47/02—Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds containing a carbon atom not being member of a ring and having no bond to a carbon or hydrogen atom, e.g. derivatives of carbonic acid the carbon atom having no bond to a nitrogen atom
- A01N47/06—Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds containing a carbon atom not being member of a ring and having no bond to a carbon or hydrogen atom, e.g. derivatives of carbonic acid the carbon atom having no bond to a nitrogen atom containing —O—CO—O— groups; Thio analogues thereof
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- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
- A01N47/00—Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds containing a carbon atom not being member of a ring and having no bond to a carbon or hydrogen atom, e.g. derivatives of carbonic acid
- A01N47/08—Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds containing a carbon atom not being member of a ring and having no bond to a carbon or hydrogen atom, e.g. derivatives of carbonic acid the carbon atom having one or more single bonds to nitrogen atoms
- A01N47/10—Carbamic acid derivatives, i.e. containing the group —O—CO—N<; Thio analogues thereof
- A01N47/12—Carbamic acid derivatives, i.e. containing the group —O—CO—N<; Thio analogues thereof containing a —O—CO—N< group, or a thio analogue thereof, neither directly attached to a ring nor the nitrogen atom being a member of a heterocyclic ring
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- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01P—BIOCIDAL, PEST REPELLANT, PEST ATTRACTANT OR PLANT GROWTH REGULATORY ACTIVITY OF CHEMICAL COMPOUNDS OR PREPARATIONS
- A01P13/00—Herbicides; Algicides
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- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07D—HETEROCYCLIC COMPOUNDS
- C07D213/00—Heterocyclic compounds containing six-membered rings, not condensed with other rings, with one nitrogen atom as the only ring hetero atom and three or more double bonds between ring members or between ring members and non-ring members
- C07D213/02—Heterocyclic compounds containing six-membered rings, not condensed with other rings, with one nitrogen atom as the only ring hetero atom and three or more double bonds between ring members or between ring members and non-ring members having three double bonds between ring members or between ring members and non-ring members
- C07D213/04—Heterocyclic compounds containing six-membered rings, not condensed with other rings, with one nitrogen atom as the only ring hetero atom and three or more double bonds between ring members or between ring members and non-ring members having three double bonds between ring members or between ring members and non-ring members having no bond between the ring nitrogen atom and a non-ring member or having only hydrogen or carbon atoms directly attached to the ring nitrogen atom
- C07D213/60—Heterocyclic compounds containing six-membered rings, not condensed with other rings, with one nitrogen atom as the only ring hetero atom and three or more double bonds between ring members or between ring members and non-ring members having three double bonds between ring members or between ring members and non-ring members having no bond between the ring nitrogen atom and a non-ring member or having only hydrogen or carbon atoms directly attached to the ring nitrogen atom with hetero atoms or with carbon atoms having three bonds to hetero atoms with at the most one bond to halogen, e.g. ester or nitrile radicals, directly attached to ring carbon atoms
- C07D213/72—Nitrogen atoms
- C07D213/74—Amino or imino radicals substituted by hydrocarbon or substituted hydrocarbon radicals
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- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07D—HETEROCYCLIC COMPOUNDS
- C07D213/00—Heterocyclic compounds containing six-membered rings, not condensed with other rings, with one nitrogen atom as the only ring hetero atom and three or more double bonds between ring members or between ring members and non-ring members
- C07D213/02—Heterocyclic compounds containing six-membered rings, not condensed with other rings, with one nitrogen atom as the only ring hetero atom and three or more double bonds between ring members or between ring members and non-ring members having three double bonds between ring members or between ring members and non-ring members
- C07D213/04—Heterocyclic compounds containing six-membered rings, not condensed with other rings, with one nitrogen atom as the only ring hetero atom and three or more double bonds between ring members or between ring members and non-ring members having three double bonds between ring members or between ring members and non-ring members having no bond between the ring nitrogen atom and a non-ring member or having only hydrogen or carbon atoms directly attached to the ring nitrogen atom
- C07D213/60—Heterocyclic compounds containing six-membered rings, not condensed with other rings, with one nitrogen atom as the only ring hetero atom and three or more double bonds between ring members or between ring members and non-ring members having three double bonds between ring members or between ring members and non-ring members having no bond between the ring nitrogen atom and a non-ring member or having only hydrogen or carbon atoms directly attached to the ring nitrogen atom with hetero atoms or with carbon atoms having three bonds to hetero atoms with at the most one bond to halogen, e.g. ester or nitrile radicals, directly attached to ring carbon atoms
- C07D213/72—Nitrogen atoms
- C07D213/75—Amino or imino radicals, acylated by carboxylic or carbonic acids, or by sulfur or nitrogen analogues thereof, e.g. carbamates
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- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07D—HETEROCYCLIC COMPOUNDS
- C07D401/00—Heterocyclic compounds containing two or more hetero rings, having nitrogen atoms as the only ring hetero atoms, at least one ring being a six-membered ring with only one nitrogen atom
- C07D401/02—Heterocyclic compounds containing two or more hetero rings, having nitrogen atoms as the only ring hetero atoms, at least one ring being a six-membered ring with only one nitrogen atom containing two hetero rings
- C07D401/12—Heterocyclic compounds containing two or more hetero rings, having nitrogen atoms as the only ring hetero atoms, at least one ring being a six-membered ring with only one nitrogen atom containing two hetero rings linked by a chain containing hetero atoms as chain links
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- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07D—HETEROCYCLIC COMPOUNDS
- C07D405/00—Heterocyclic compounds containing both one or more hetero rings having oxygen atoms as the only ring hetero atoms, and one or more rings having nitrogen as the only ring hetero atom
- C07D405/02—Heterocyclic compounds containing both one or more hetero rings having oxygen atoms as the only ring hetero atoms, and one or more rings having nitrogen as the only ring hetero atom containing two hetero rings
- C07D405/12—Heterocyclic compounds containing both one or more hetero rings having oxygen atoms as the only ring hetero atoms, and one or more rings having nitrogen as the only ring hetero atom containing two hetero rings linked by a chain containing hetero atoms as chain links
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- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07D—HETEROCYCLIC COMPOUNDS
- C07D409/00—Heterocyclic compounds containing two or more hetero rings, at least one ring having sulfur atoms as the only ring hetero atoms
- C07D409/02—Heterocyclic compounds containing two or more hetero rings, at least one ring having sulfur atoms as the only ring hetero atoms containing two hetero rings
- C07D409/12—Heterocyclic compounds containing two or more hetero rings, at least one ring having sulfur atoms as the only ring hetero atoms containing two hetero rings linked by a chain containing hetero atoms as chain links
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- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07D—HETEROCYCLIC COMPOUNDS
- C07D417/00—Heterocyclic compounds containing two or more hetero rings, at least one ring having nitrogen and sulfur atoms as the only ring hetero atoms, not provided for by group C07D415/00
- C07D417/02—Heterocyclic compounds containing two or more hetero rings, at least one ring having nitrogen and sulfur atoms as the only ring hetero atoms, not provided for by group C07D415/00 containing two hetero rings
- C07D417/12—Heterocyclic compounds containing two or more hetero rings, at least one ring having nitrogen and sulfur atoms as the only ring hetero atoms, not provided for by group C07D415/00 containing two hetero rings linked by a chain containing hetero atoms as chain links
Landscapes
- Chemical & Material Sciences (AREA)
- Life Sciences & Earth Sciences (AREA)
- Organic Chemistry (AREA)
- Pest Control & Pesticides (AREA)
- Engineering & Computer Science (AREA)
- Plant Pathology (AREA)
- Wood Science & Technology (AREA)
- Zoology (AREA)
- Environmental Sciences (AREA)
- General Health & Medical Sciences (AREA)
- Health & Medical Sciences (AREA)
- Dentistry (AREA)
- Agronomy & Crop Science (AREA)
- General Chemical & Material Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Toxicology (AREA)
- Agricultural Chemicals And Associated Chemicals (AREA)
- Plural Heterocyclic Compounds (AREA)
- Pyridine Compounds (AREA)
- Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
- Catching Or Destruction (AREA)
- Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)
Abstract
Reivindicación 1: Un ácido R-piridiloxicarboxílico representado por la fórmula (1) y la sal, su derivado de éster, en donde A y B, representan cada uno independientemente halógeno; o alquilo o cicloalquilo con o sin halógeno; C representa hidrógeno, halógeno, alquilo o haloalquilo; Q representa halógeno, ciano, cianoalquilo, hidroxialquilo, amino, nitro, formilo; alquilo, alquenilo, alquinilo, cicloalquilo, alcoxi, alquiltio, alquilcarbonilo, alcoxi-carbonilo, alquilaminoalquilo o alcoxialquilo con o sin halógeno; o arilo, heteroarilo, arilalquilo, heteroarilalquilo sustituido o no sustituido; Y representa nitro o NR¹R²; en donde R¹ representa H; alquilo, alquenilo o alquinilo opcionalmente sustituido con 1 - 2 R¹¹; -COR¹², nitro, OR¹³, SO₂R¹⁴, NR¹⁵R¹⁶, N=CR¹⁷R¹⁸, alquilcarbamoilo, dialquilcarbamoilo, trialquilsililo o dialquilfosfono; R² representa H; alquilo opcionalmente sustituido con 1 - 2 R¹¹; o -COR¹²; o NR¹R² representa N=CR²¹NR²²R²³, N=CR²⁴OR²⁵; o un anillo saturado o insaturado de 5 ó 6 miembros con o sin átomo de oxígeno, átomo de azufre u otro átomo de nitrógeno, que está sin sustituir o sustituido por 1 - 2 grupos seleccionados independientemente del grupo que consiste en halógeno, alquilo, alcoxi, haloalcoxi, alquiltio, haloalquiltio, amino, alquilamino, dialquilamino, alcoxicarbonilo; en donde R¹¹ representa independientemente halógeno, hidroxi, alcoxi, haloalcoxi, alquiltio, haloalquiltio, amino, alquilamino, dialquilamino, alcoxicarbonilo; o arilo, heteroarilo no sustituido o sustituido; R¹² representa H, alquilo, haloalquilo, alcoxi, fenilo, fenoxi o benciloxi; R¹³ representa H, alquilo, haloalquilo, fenilo, bencilo o CHR³¹C(O)OR³²; R³¹ representa H, alquilo o alcoxi; R³² representa H, alquilo o bencilo; R¹⁴ representa alquilo o haloalquilo; R¹⁵ representa H, alquilo, formilo, alquilacilo, haloalquilacilo, alcoxicarbonilo, fenilcarbonilo, fenoxicarbonilo o benciloxicarbonilo; R¹⁶ representa H o alquilo; R¹⁷ representa H, alquilo; o fenilo que está sin sustituir o sustituido con 1 - 3 grupos seleccionados del grupo que consiste en halógeno, alquilo, alcoxi; R¹⁸ representa H o alquilo; o N=CR¹⁷R¹⁸ representa un resto de fórmula (3) ó (4); R²¹, R²⁴ representan cada uno independientemente H o alquilo; R²², R²³ representan cada uno independientemente H o alquilo; o NR²²R²³ representa un anillo saturado o insaturado de 5 ó 6 miembros con o sin átomo de oxígeno, átomo de azufre u otro átomo de nitrógeno; R²⁵ representa alquilo; la sal es sal metálica, sal de amina, sal de sulfonio o sal de fosfonio; el éster es de fórmula (2), en donde X representa O ó S; M representa alquilo, alquenilo, alquinilo, cicloalquilo, cicloalquilalquilo, -alquilo-Z, un resto seleccionado del grupo de fórmulas (5) con o sin halógeno; o heterociclilo, arilo, heteroarilo no sustituido o sustituido; Z representa un compuesto del grupo de fórmulas (6), ciano, nitro, o heterociclilo, arilo, heteroarilo no sustituido o sustituido; R³ representa cada uno independientemente alquilo, alquenilo, alquinilo, cicloalquilo, cicloalquilalquilo o heterociclilo, arilo, heteroarilo, heterocicloalquilo, arilalquilo, heteroarilalquilo no sustituido o sustituido; R⁴, R⁵, R⁶ representan cada uno independientemente hidrógeno, alquilo, alquenilo, alquinilo, cicloalquilo, cicloalquilalquilo, alcoxicarbonilo o heterociclilo, arilo, heteroarilo, heterociclilalquilo, arilalquilo, heteroarilalquilo no sustituido o sustituido.
Applications Claiming Priority (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
CN201811613197 | 2018-12-27 |
Publications (1)
Publication Number | Publication Date |
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AR117524A1 true AR117524A1 (es) | 2021-08-11 |
Family
ID=71127504
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
ARP190103875A AR117524A1 (es) | 2018-12-27 | 2019-12-27 | Ácido r-piridiloxicarboxílico y sal, derivado de éster, método de preparación, composición herbicida y su aplicación |
Country Status (17)
Country | Link |
---|---|
US (1) | US20220098153A1 (es) |
EP (1) | EP3904341A4 (es) |
JP (2) | JP2022515285A (es) |
CN (1) | CN111377856B (es) |
AR (1) | AR117524A1 (es) |
AU (1) | AU2019415587A1 (es) |
BR (1) | BR112021012447A2 (es) |
CA (1) | CA3122138A1 (es) |
CL (1) | CL2021001689A1 (es) |
CO (1) | CO2021008276A2 (es) |
MA (1) | MA53683A1 (es) |
MX (1) | MX2021007798A (es) |
PE (1) | PE20211476A1 (es) |
PH (1) | PH12021551518A1 (es) |
TN (1) | TN2021000132A1 (es) |
WO (1) | WO2020135235A1 (es) |
ZA (1) | ZA202104064B (es) |
Families Citing this family (1)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
BR112022001311A2 (pt) * | 2019-07-27 | 2022-03-22 | Qingdao Kingagroot Chemical Compound Co Ltd | Composição herbicida compreendendo ácido r-piridiloxicarboxílico e derivados e uma aplicação da mesma |
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CN102718700B (zh) * | 2012-07-10 | 2016-03-23 | 南开大学 | 3,5,6-三氯-2-吡啶氧乙酸衍生物制备及应用研究 |
CN104803987B (zh) * | 2014-01-28 | 2017-05-17 | 沈阳中化农药化工研发有限公司 | 一种含肟的羧酸酯类化合物及其用途 |
CN106187872B (zh) * | 2016-07-21 | 2018-12-04 | 四川福思达生物技术开发有限责任公司 | 一种氟草烟的制备方法 |
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- 2019-12-20 CN CN201911321469.4A patent/CN111377856B/zh active Active
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CA3122138A1 (en) | 2020-07-02 |
PH12021551518A1 (en) | 2022-02-28 |
CO2021008276A2 (es) | 2021-07-19 |
BR112021012447A2 (pt) | 2021-09-08 |
ZA202104064B (en) | 2022-09-28 |
CN111377856B (zh) | 2021-08-27 |
AU2019415587A1 (en) | 2021-07-01 |
PE20211476A1 (es) | 2021-08-05 |
CL2021001689A1 (es) | 2021-12-17 |
TN2021000132A1 (en) | 2023-01-05 |
JP2023139056A (ja) | 2023-10-03 |
WO2020135235A1 (zh) | 2020-07-02 |
JP2022515285A (ja) | 2022-02-17 |
CN111377856A (zh) | 2020-07-07 |
MX2021007798A (es) | 2021-10-13 |
US20220098153A1 (en) | 2022-03-31 |
MA53683A1 (fr) | 2022-02-28 |
EP3904341A4 (en) | 2022-08-10 |
EP3904341A1 (en) | 2021-11-03 |
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