AR106858A1 - Partículas de sílica funcionalizadas y cargadas con agentes fungicidas, su preparación y su uso como sistemas de liberación dirigida y controlada de fungicidas - Google Patents
Partículas de sílica funcionalizadas y cargadas con agentes fungicidas, su preparación y su uso como sistemas de liberación dirigida y controlada de fungicidasInfo
- Publication number
- AR106858A1 AR106858A1 ARP160103783A ARP160103783A AR106858A1 AR 106858 A1 AR106858 A1 AR 106858A1 AR P160103783 A ARP160103783 A AR P160103783A AR P160103783 A ARP160103783 A AR P160103783A AR 106858 A1 AR106858 A1 AR 106858A1
- Authority
- AR
- Argentina
- Prior art keywords
- phepropylphosphine
- fungicidal agent
- particles
- methyl
- fungicide
- Prior art date
Links
- 239000000417 fungicide Substances 0.000 title abstract 18
- 230000000855 fungicidal effect Effects 0.000 title abstract 5
- 238000002360 preparation method Methods 0.000 title abstract 2
- 239000011856 silicon-based particle Substances 0.000 title 1
- 239000002245 particle Substances 0.000 abstract 14
- -1 procimidone Chemical compound 0.000 abstract 12
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 abstract 9
- 125000001183 hydrocarbyl group Chemical group 0.000 abstract 5
- 239000000243 solution Substances 0.000 abstract 5
- 230000000717 retained effect Effects 0.000 abstract 4
- 235000012055 fruits and vegetables Nutrition 0.000 abstract 3
- 230000003993 interaction Effects 0.000 abstract 3
- 239000003960 organic solvent Substances 0.000 abstract 3
- 150000003839 salts Chemical class 0.000 abstract 3
- YXIWHUQXZSMYRE-UHFFFAOYSA-N 1,3-benzothiazole-2-thiol Chemical compound C1=CC=C2SC(S)=NC2=C1 YXIWHUQXZSMYRE-UHFFFAOYSA-N 0.000 abstract 2
- WPYMKLBDIGXBTP-UHFFFAOYSA-N benzoic acid Chemical compound OC(=O)C1=CC=CC=C1 WPYMKLBDIGXBTP-UHFFFAOYSA-N 0.000 abstract 2
- LLEMOWNGBBNAJR-UHFFFAOYSA-N biphenyl-2-ol Chemical compound OC1=CC=CC=C1C1=CC=CC=C1 LLEMOWNGBBNAJR-UHFFFAOYSA-N 0.000 abstract 2
- 125000004432 carbon atom Chemical group C* 0.000 abstract 2
- XBDQKXXYIPTUBI-UHFFFAOYSA-N dimethylselenoniopropionate Natural products CCC(O)=O XBDQKXXYIPTUBI-UHFFFAOYSA-N 0.000 abstract 2
- DMBHHRLKUKUOEG-UHFFFAOYSA-N diphenylamine Chemical compound C=1C=CC=CC=1NC1=CC=CC=C1 DMBHHRLKUKUOEG-UHFFFAOYSA-N 0.000 abstract 2
- 238000007306 functionalization reaction Methods 0.000 abstract 2
- 125000005842 heteroatom Chemical group 0.000 abstract 2
- RONFGUROBZGJKP-UHFFFAOYSA-N iminoctadine Chemical compound NC(N)=NCCCCCCCCNCCCCCCCCN=C(N)N RONFGUROBZGJKP-UHFFFAOYSA-N 0.000 abstract 2
- 208000015181 infectious disease Diseases 0.000 abstract 2
- ZQEIXNIJLIKNTD-GFCCVEGCSA-N metalaxyl-M Chemical compound COCC(=O)N([C@H](C)C(=O)OC)C1=C(C)C=CC=C1C ZQEIXNIJLIKNTD-GFCCVEGCSA-N 0.000 abstract 2
- 238000000034 method Methods 0.000 abstract 2
- 229910052757 nitrogen Inorganic materials 0.000 abstract 2
- 229910052760 oxygen Inorganic materials 0.000 abstract 2
- 229920006395 saturated elastomer Polymers 0.000 abstract 2
- 239000000377 silicon dioxide Substances 0.000 abstract 2
- 238000005507 spraying Methods 0.000 abstract 2
- UCSJYZPVAKXKNQ-HZYVHMACSA-N streptomycin Chemical compound CN[C@H]1[C@H](O)[C@@H](O)[C@H](CO)O[C@H]1O[C@@H]1[C@](C=O)(O)[C@H](C)O[C@H]1O[C@@H]1[C@@H](NC(N)=N)[C@H](O)[C@@H](NC(N)=N)[C@H](O)[C@H]1O UCSJYZPVAKXKNQ-HZYVHMACSA-N 0.000 abstract 2
- 229910052717 sulfur Inorganic materials 0.000 abstract 2
- 238000005406 washing Methods 0.000 abstract 2
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 abstract 2
- XERJKGMBORTKEO-VZUCSPMQSA-N (1e)-2-(ethylcarbamoylamino)-n-methoxy-2-oxoethanimidoyl cyanide Chemical compound CCNC(=O)NC(=O)C(\C#N)=N\OC XERJKGMBORTKEO-VZUCSPMQSA-N 0.000 abstract 1
- NHOWDZOIZKMVAI-UHFFFAOYSA-N (2-chlorophenyl)(4-chlorophenyl)pyrimidin-5-ylmethanol Chemical compound C=1N=CN=CC=1C(C=1C(=CC=CC=1)Cl)(O)C1=CC=C(Cl)C=C1 NHOWDZOIZKMVAI-UHFFFAOYSA-N 0.000 abstract 1
- SAPGTCDSBGMXCD-UHFFFAOYSA-N (2-chlorophenyl)-(4-fluorophenyl)-pyrimidin-5-ylmethanol Chemical compound C=1N=CN=CC=1C(C=1C(=CC=CC=1)Cl)(O)C1=CC=C(F)C=C1 SAPGTCDSBGMXCD-UHFFFAOYSA-N 0.000 abstract 1
- IXNUTQCZWAHNPN-UHFFFAOYSA-N (2-tert-butyl-4,6-dinitrophenyl) ethyl carbonate Chemical compound CCOC(=O)OC1=C([N+]([O-])=O)C=C([N+]([O-])=O)C=C1C(C)(C)C IXNUTQCZWAHNPN-UHFFFAOYSA-N 0.000 abstract 1
- ZMYFCFLJBGAQRS-IRXDYDNUSA-N (2R,3S)-epoxiconazole Chemical compound C1=CC(F)=CC=C1[C@@]1(CN2N=CN=C2)[C@H](C=2C(=CC=CC=2)Cl)O1 ZMYFCFLJBGAQRS-IRXDYDNUSA-N 0.000 abstract 1
- URDNHJIVMYZFRT-KGLIPLIRSA-N (2r,3r)-1-(2,4-dichlorophenyl)-4,4-dimethyl-2-(1,2,4-triazol-1-yl)pentan-3-ol Chemical compound C([C@H]([C@H](O)C(C)(C)C)N1N=CN=C1)C1=CC=C(Cl)C=C1Cl URDNHJIVMYZFRT-KGLIPLIRSA-N 0.000 abstract 1
- PPDBOQMNKNNODG-NTEUORMPSA-N (5E)-5-(4-chlorobenzylidene)-2,2-dimethyl-1-(1,2,4-triazol-1-ylmethyl)cyclopentanol Chemical compound C1=NC=NN1CC1(O)C(C)(C)CC\C1=C/C1=CC=C(Cl)C=C1 PPDBOQMNKNNODG-NTEUORMPSA-N 0.000 abstract 1
- CKPCAYZTYMHQEX-NBVRZTHBSA-N (e)-1-(2,4-dichlorophenyl)-n-methoxy-2-pyridin-3-ylethanimine Chemical compound C=1C=C(Cl)C=C(Cl)C=1C(=N/OC)/CC1=CC=CN=C1 CKPCAYZTYMHQEX-NBVRZTHBSA-N 0.000 abstract 1
- GVTLFGJNTIRUEG-ZHACJKMWSA-N (e)-n-(3-methoxyphenyl)-3-phenylprop-2-enamide Chemical compound COC1=CC=CC(NC(=O)\C=C\C=2C=CC=CC=2)=C1 GVTLFGJNTIRUEG-ZHACJKMWSA-N 0.000 abstract 1
- TUBQDCKAWGHZPF-UHFFFAOYSA-N 1,3-benzothiazol-2-ylsulfanylmethyl thiocyanate Chemical compound C1=CC=C2SC(SCSC#N)=NC2=C1 TUBQDCKAWGHZPF-UHFFFAOYSA-N 0.000 abstract 1
- JWUCHKBSVLQQCO-UHFFFAOYSA-N 1-(2-fluorophenyl)-1-(4-fluorophenyl)-2-(1H-1,2,4-triazol-1-yl)ethanol Chemical compound C=1C=C(F)C=CC=1C(C=1C(=CC=CC=1)F)(O)CN1C=NC=N1 JWUCHKBSVLQQCO-UHFFFAOYSA-N 0.000 abstract 1
- WURBVZBTWMNKQT-UHFFFAOYSA-N 1-(4-chlorophenoxy)-3,3-dimethyl-1-(1,2,4-triazol-1-yl)butan-2-one Chemical compound C1=NC=NN1C(C(=O)C(C)(C)C)OC1=CC=C(Cl)C=C1 WURBVZBTWMNKQT-UHFFFAOYSA-N 0.000 abstract 1
- PXMNMQRDXWABCY-UHFFFAOYSA-N 1-(4-chlorophenyl)-4,4-dimethyl-3-(1H-1,2,4-triazol-1-ylmethyl)pentan-3-ol Chemical compound C1=NC=NN1CC(O)(C(C)(C)C)CCC1=CC=C(Cl)C=C1 PXMNMQRDXWABCY-UHFFFAOYSA-N 0.000 abstract 1
- HZTCLDNADGMACV-UHFFFAOYSA-N 1-(8-hydroxyquinolin-5-yl)ethanone Chemical compound C1=CC=C2C(C(=O)C)=CC=C(O)C2=N1 HZTCLDNADGMACV-UHFFFAOYSA-N 0.000 abstract 1
- VGPIBGGRCVEHQZ-UHFFFAOYSA-N 1-(biphenyl-4-yloxy)-3,3-dimethyl-1-(1,2,4-triazol-1-yl)butan-2-ol Chemical compound C1=NC=NN1C(C(O)C(C)(C)C)OC(C=C1)=CC=C1C1=CC=CC=C1 VGPIBGGRCVEHQZ-UHFFFAOYSA-N 0.000 abstract 1
- LQDARGUHUSPFNL-UHFFFAOYSA-N 1-[2-(2,4-dichlorophenyl)-3-(1,1,2,2-tetrafluoroethoxy)propyl]1,2,4-triazole Chemical compound C=1C=C(Cl)C=C(Cl)C=1C(COC(F)(F)C(F)F)CN1C=NC=N1 LQDARGUHUSPFNL-UHFFFAOYSA-N 0.000 abstract 1
- WKBPZYKAUNRMKP-UHFFFAOYSA-N 1-[2-(2,4-dichlorophenyl)pentyl]1,2,4-triazole Chemical compound C=1C=C(Cl)C=C(Cl)C=1C(CCC)CN1C=NC=N1 WKBPZYKAUNRMKP-UHFFFAOYSA-N 0.000 abstract 1
- PZBPKYOVPCNPJY-UHFFFAOYSA-N 1-[2-(allyloxy)-2-(2,4-dichlorophenyl)ethyl]imidazole Chemical compound ClC1=CC(Cl)=CC=C1C(OCC=C)CN1C=NC=C1 PZBPKYOVPCNPJY-UHFFFAOYSA-N 0.000 abstract 1
- DELJNDWGTWHHFA-UHFFFAOYSA-N 1-azaniumylpropyl(hydroxy)phosphinate Chemical compound CCC(N)P(O)(O)=O DELJNDWGTWHHFA-UHFFFAOYSA-N 0.000 abstract 1
- FPJNQQRSBJPGHM-UHFFFAOYSA-N 1-chloro-2-nitropropane Chemical compound ClCC(C)[N+]([O-])=O FPJNQQRSBJPGHM-UHFFFAOYSA-N 0.000 abstract 1
- YIKWKLYQRFRGPM-UHFFFAOYSA-N 1-dodecylguanidine acetate Chemical compound CC(O)=O.CCCCCCCCCCCCN=C(N)N YIKWKLYQRFRGPM-UHFFFAOYSA-N 0.000 abstract 1
- PFFIDZXUXFLSSR-UHFFFAOYSA-N 1-methyl-N-[2-(4-methylpentan-2-yl)-3-thienyl]-3-(trifluoromethyl)pyrazole-4-carboxamide Chemical compound S1C=CC(NC(=O)C=2C(=NN(C)C=2)C(F)(F)F)=C1C(C)CC(C)C PFFIDZXUXFLSSR-UHFFFAOYSA-N 0.000 abstract 1
- SVPKNMBRVBMTLB-UHFFFAOYSA-N 2,3-dichloronaphthalene-1,4-dione Chemical compound C1=CC=C2C(=O)C(Cl)=C(Cl)C(=O)C2=C1 SVPKNMBRVBMTLB-UHFFFAOYSA-N 0.000 abstract 1
- NIOPZPCMRQGZCE-WEVVVXLNSA-N 2,4-dinitro-6-(octan-2-yl)phenyl (E)-but-2-enoate Chemical compound CCCCCCC(C)C1=CC([N+]([O-])=O)=CC([N+]([O-])=O)=C1OC(=O)\C=C\C NIOPZPCMRQGZCE-WEVVVXLNSA-N 0.000 abstract 1
- STMIIPIFODONDC-UHFFFAOYSA-N 2-(2,4-dichlorophenyl)-1-(1H-1,2,4-triazol-1-yl)hexan-2-ol Chemical compound C=1C=C(Cl)C=C(Cl)C=1C(O)(CCCC)CN1C=NC=N1 STMIIPIFODONDC-UHFFFAOYSA-N 0.000 abstract 1
- HZJKXKUJVSEEFU-UHFFFAOYSA-N 2-(4-chlorophenyl)-2-(1H-1,2,4-triazol-1-ylmethyl)hexanenitrile Chemical compound C=1C=C(Cl)C=CC=1C(CCCC)(C#N)CN1C=NC=N1 HZJKXKUJVSEEFU-UHFFFAOYSA-N 0.000 abstract 1
- UFNOUKDBUJZYDE-UHFFFAOYSA-N 2-(4-chlorophenyl)-3-cyclopropyl-1-(1H-1,2,4-triazol-1-yl)butan-2-ol Chemical compound C1=NC=NN1CC(O)(C=1C=CC(Cl)=CC=1)C(C)C1CC1 UFNOUKDBUJZYDE-UHFFFAOYSA-N 0.000 abstract 1
- KWLVWJPJKJMCSH-UHFFFAOYSA-N 2-(4-chlorophenyl)-N-{2-[3-methoxy-4-(prop-2-yn-1-yloxy)phenyl]ethyl}-2-(prop-2-yn-1-yloxy)acetamide Chemical compound C1=C(OCC#C)C(OC)=CC(CCNC(=O)C(OCC#C)C=2C=CC(Cl)=CC=2)=C1 KWLVWJPJKJMCSH-UHFFFAOYSA-N 0.000 abstract 1
- YABFPHSQTSFWQB-UHFFFAOYSA-N 2-(4-fluorophenyl)-1-(1,2,4-triazol-1-yl)-3-(trimethylsilyl)propan-2-ol Chemical compound C=1C=C(F)C=CC=1C(O)(C[Si](C)(C)C)CN1C=NC=N1 YABFPHSQTSFWQB-UHFFFAOYSA-N 0.000 abstract 1
- OGBSAJWRIPNIER-UHFFFAOYSA-N 2-chloro-6-(furan-2-ylmethoxy)-4-(trichloromethyl)pyridine Chemical compound ClC1=CC(C(Cl)(Cl)Cl)=CC(OCC=2OC=CC=2)=N1 OGBSAJWRIPNIER-UHFFFAOYSA-N 0.000 abstract 1
- OWDLFBLNMPCXSD-UHFFFAOYSA-N 2-chloro-N-(2,6-dimethylphenyl)-N-(2-oxotetrahydrofuran-3-yl)acetamide Chemical compound CC1=CC=CC(C)=C1N(C(=O)CCl)C1C(=O)OCC1 OWDLFBLNMPCXSD-UHFFFAOYSA-N 0.000 abstract 1
- NCVGSSQICKMAIA-UHFFFAOYSA-N 2-heptadecyl-4,5-dihydro-1h-imidazole Chemical compound CCCCCCCCCCCCCCCCCC1=NCCN1 NCVGSSQICKMAIA-UHFFFAOYSA-N 0.000 abstract 1
- 125000003903 2-propenyl group Chemical group [H]C([*])([H])C([H])=C([H])[H] 0.000 abstract 1
- PDPWCKVFIFAQIQ-UHFFFAOYSA-N 2-{2-[(2,5-dimethylphenoxy)methyl]phenyl}-2-methoxy-N-methylacetamide Chemical compound CNC(=O)C(OC)C1=CC=CC=C1COC1=CC(C)=CC=C1C PDPWCKVFIFAQIQ-UHFFFAOYSA-N 0.000 abstract 1
- OVFHHJZHXHZIHT-UHFFFAOYSA-N 3-(2,4-dichlorophenyl)-2-(1,2,4-triazol-1-yl)quinazolin-4-one Chemical compound ClC1=CC(Cl)=CC=C1N1C(=O)C2=CC=CC=C2N=C1N1N=CN=C1 OVFHHJZHXHZIHT-UHFFFAOYSA-N 0.000 abstract 1
- FSCWZHGZWWDELK-UHFFFAOYSA-N 3-(3,5-dichlorophenyl)-5-ethenyl-5-methyl-2,4-oxazolidinedione Chemical compound O=C1C(C)(C=C)OC(=O)N1C1=CC(Cl)=CC(Cl)=C1 FSCWZHGZWWDELK-UHFFFAOYSA-N 0.000 abstract 1
- XTDZGXBTXBEZDN-UHFFFAOYSA-N 3-(difluoromethyl)-N-(9-isopropyl-1,2,3,4-tetrahydro-1,4-methanonaphthalen-5-yl)-1-methylpyrazole-4-carboxamide Chemical compound CC(C)C1C2CCC1C1=C2C=CC=C1NC(=O)C1=CN(C)N=C1C(F)F XTDZGXBTXBEZDN-UHFFFAOYSA-N 0.000 abstract 1
- LCOWUMNPNWEMAZ-UHFFFAOYSA-N 3-[benzyl(methyl)amino]-2-cyanoprop-2-enoic acid Chemical compound N#CC(C(O)=O)=CN(C)CC1=CC=CC=C1 LCOWUMNPNWEMAZ-UHFFFAOYSA-N 0.000 abstract 1
- WYVVKGNFXHOCQV-UHFFFAOYSA-N 3-iodoprop-2-yn-1-yl butylcarbamate Chemical compound CCCCNC(=O)OCC#CI WYVVKGNFXHOCQV-UHFFFAOYSA-N 0.000 abstract 1
- RQDJADAKIFFEKQ-UHFFFAOYSA-N 4-(4-chlorophenyl)-2-phenyl-2-(1,2,4-triazol-1-ylmethyl)butanenitrile Chemical compound C1=CC(Cl)=CC=C1CCC(C=1C=CC=CC=1)(C#N)CN1N=CN=C1 RQDJADAKIFFEKQ-UHFFFAOYSA-N 0.000 abstract 1
- NEKULYKCZPJMMJ-UHFFFAOYSA-N 5-chloro-N-{1-[4-(difluoromethoxy)phenyl]propyl}-6-methylpyrimidin-4-amine Chemical compound C=1C=C(OC(F)F)C=CC=1C(CC)NC1=NC=NC(C)=C1Cl NEKULYKCZPJMMJ-UHFFFAOYSA-N 0.000 abstract 1
- GOFJDXZZHFNFLV-UHFFFAOYSA-N 5-fluoro-1,3-dimethyl-N-[2-(4-methylpentan-2-yl)phenyl]pyrazole-4-carboxamide Chemical compound CC(C)CC(C)C1=CC=CC=C1NC(=O)C1=C(F)N(C)N=C1C GOFJDXZZHFNFLV-UHFFFAOYSA-N 0.000 abstract 1
- PCCSBWNGDMYFCW-UHFFFAOYSA-N 5-methyl-5-(4-phenoxyphenyl)-3-(phenylamino)-1,3-oxazolidine-2,4-dione Chemical compound O=C1C(C)(C=2C=CC(OC=3C=CC=CC=3)=CC=2)OC(=O)N1NC1=CC=CC=C1 PCCSBWNGDMYFCW-UHFFFAOYSA-N 0.000 abstract 1
- 239000005725 8-Hydroxyquinoline Substances 0.000 abstract 1
- 239000005964 Acibenzolar-S-methyl Substances 0.000 abstract 1
- 239000005726 Ametoctradin Substances 0.000 abstract 1
- 239000005727 Amisulbrom Substances 0.000 abstract 1
- 239000005730 Azoxystrobin Substances 0.000 abstract 1
- 239000005734 Benalaxyl Substances 0.000 abstract 1
- 239000005735 Benalaxyl-M Substances 0.000 abstract 1
- 239000005711 Benzoic acid Substances 0.000 abstract 1
- 239000005738 Bixafen Substances 0.000 abstract 1
- 239000005740 Boscalid Substances 0.000 abstract 1
- 239000005741 Bromuconazole Substances 0.000 abstract 1
- 239000005742 Bupirimate Substances 0.000 abstract 1
- ZZVVDIVWGXTDRQ-BSYVCWPDSA-N Buthiobate Chemical compound C=1C=CN=CC=1\N=C(/SCCCC)SCC1=CC=C(C(C)(C)C)C=C1 ZZVVDIVWGXTDRQ-BSYVCWPDSA-N 0.000 abstract 1
- TWFZGCMQGLPBSX-UHFFFAOYSA-N Carbendazim Natural products C1=CC=C2NC(NC(=O)OC)=NC2=C1 TWFZGCMQGLPBSX-UHFFFAOYSA-N 0.000 abstract 1
- 239000004215 Carbon black (E152) Substances 0.000 abstract 1
- 239000005746 Carboxin Substances 0.000 abstract 1
- 239000005747 Chlorothalonil Substances 0.000 abstract 1
- 239000005756 Cymoxanil Substances 0.000 abstract 1
- 239000005757 Cyproconazole Substances 0.000 abstract 1
- 239000005758 Cyprodinil Substances 0.000 abstract 1
- KRZUZYJEQBXUIN-UHFFFAOYSA-N Cyprofuram Chemical compound ClC1=CC=CC(N(C2C(OCC2)=O)C(=O)C2CC2)=C1 KRZUZYJEQBXUIN-UHFFFAOYSA-N 0.000 abstract 1
- 239000005644 Dazomet Substances 0.000 abstract 1
- 239000005759 Diethofencarb Substances 0.000 abstract 1
- 239000005760 Difenoconazole Substances 0.000 abstract 1
- 239000005762 Dimoxystrobin Substances 0.000 abstract 1
- MTBZIGHNGSTDJV-UHFFFAOYSA-N Ditalimfos Chemical compound C1=CC=C2C(=O)N(P(=S)(OCC)OCC)C(=O)C2=C1 MTBZIGHNGSTDJV-UHFFFAOYSA-N 0.000 abstract 1
- 239000005764 Dithianon Substances 0.000 abstract 1
- 239000005766 Dodine Substances 0.000 abstract 1
- OOTHTARUZHONSW-LCYFTJDESA-N Drazoxolon Chemical compound CC1=NOC(=O)\C1=N/NC1=CC=CC=C1Cl OOTHTARUZHONSW-LCYFTJDESA-N 0.000 abstract 1
- 239000005767 Epoxiconazole Substances 0.000 abstract 1
- 239000005772 Famoxadone Substances 0.000 abstract 1
- 239000005774 Fenamidone Substances 0.000 abstract 1
- IWDQPCIQCXRBQP-UHFFFAOYSA-M Fenaminosulf Chemical compound [Na+].CN(C)C1=CC=C(N=NS([O-])(=O)=O)C=C1 IWDQPCIQCXRBQP-UHFFFAOYSA-M 0.000 abstract 1
- 239000005775 Fenbuconazole Substances 0.000 abstract 1
- 239000005776 Fenhexamid Substances 0.000 abstract 1
- 239000005779 Fenpyrazamine Substances 0.000 abstract 1
- 239000005780 Fluazinam Substances 0.000 abstract 1
- 239000005781 Fludioxonil Substances 0.000 abstract 1
- 239000005782 Fluopicolide Substances 0.000 abstract 1
- 239000005783 Fluopyram Substances 0.000 abstract 1
- 239000005784 Fluoxastrobin Substances 0.000 abstract 1
- 239000005785 Fluquinconazole Substances 0.000 abstract 1
- 239000005786 Flutolanil Substances 0.000 abstract 1
- 239000005787 Flutriafol Substances 0.000 abstract 1
- 239000005788 Fluxapyroxad Substances 0.000 abstract 1
- 239000005791 Fuberidazole Substances 0.000 abstract 1
- 241000233866 Fungi Species 0.000 abstract 1
- ULCWZQJLFZEXCS-KGLIPLIRSA-N Furconazole-cis Chemical compound O1[C@@H](OCC(F)(F)F)CC[C@@]1(C=1C(=CC(Cl)=CC=1)Cl)CN1N=CN=C1 ULCWZQJLFZEXCS-KGLIPLIRSA-N 0.000 abstract 1
- CEAZRRDELHUEMR-URQXQFDESA-N Gentamicin Chemical compound O1[C@H](C(C)NC)CC[C@@H](N)[C@H]1O[C@H]1[C@H](O)[C@@H](O[C@@H]2[C@@H]([C@@H](NC)[C@@](C)(O)CO2)O)[C@H](N)C[C@@H]1N CEAZRRDELHUEMR-URQXQFDESA-N 0.000 abstract 1
- 229930182566 Gentamicin Natural products 0.000 abstract 1
- YDNLKBDXQCHOTH-UHFFFAOYSA-N Halacrinate Chemical compound C1=CC=C2C(Cl)=CC(Br)=C(OC(=O)C=C)C2=N1 YDNLKBDXQCHOTH-UHFFFAOYSA-N 0.000 abstract 1
- 239000005795 Imazalil Substances 0.000 abstract 1
- 239000005796 Ipconazole Substances 0.000 abstract 1
- 239000005867 Iprodione Substances 0.000 abstract 1
- 239000005797 Iprovalicarb Substances 0.000 abstract 1
- 239000005799 Isopyrazam Substances 0.000 abstract 1
- 239000005800 Kresoxim-methyl Substances 0.000 abstract 1
- NWUWYYSKZYIQAE-ZBFHGGJFSA-N L-(R)-iprovalicarb Chemical compound CC(C)OC(=O)N[C@@H](C(C)C)C(=O)N[C@H](C)C1=CC=C(C)C=C1 NWUWYYSKZYIQAE-ZBFHGGJFSA-N 0.000 abstract 1
- 239000005574 MCPA Substances 0.000 abstract 1
- 239000005802 Mancozeb Substances 0.000 abstract 1
- 239000005803 Mandestrobin Substances 0.000 abstract 1
- 239000005804 Mandipropamid Substances 0.000 abstract 1
- 239000005805 Mepanipyrim Substances 0.000 abstract 1
- 239000005806 Meptyldinocap Substances 0.000 abstract 1
- 239000005807 Metalaxyl Substances 0.000 abstract 1
- 239000005808 Metalaxyl-M Substances 0.000 abstract 1
- 239000002169 Metam Substances 0.000 abstract 1
- 239000005868 Metconazole Substances 0.000 abstract 1
- 239000005809 Metiram Substances 0.000 abstract 1
- 239000005810 Metrafenone Substances 0.000 abstract 1
- 239000005811 Myclobutanil Substances 0.000 abstract 1
- XFOXDUJCOHBXRC-UHFFFAOYSA-N N-Ethyl-N-methyl-4-(trifluoromethyl)-2-(3,4-dimethoxyphenyl)benzamide Chemical compound CCN(C)C(=O)C1=CC=C(C(F)(F)F)C=C1C1=CC=C(OC)C(OC)=C1 XFOXDUJCOHBXRC-UHFFFAOYSA-N 0.000 abstract 1
- KYGZCKSPAKDVKC-UHFFFAOYSA-N Oxolinic acid Chemical compound C1=C2N(CC)C=C(C(O)=O)C(=O)C2=CC2=C1OCO2 KYGZCKSPAKDVKC-UHFFFAOYSA-N 0.000 abstract 1
- 239000004100 Oxytetracycline Substances 0.000 abstract 1
- 239000005813 Penconazole Substances 0.000 abstract 1
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- IBSNKSODLGJUMQ-SDNWHVSQSA-N picoxystrobin Chemical compound CO\C=C(\C(=O)OC)C1=CC=CC=C1COC1=CC=CC(C(F)(F)F)=N1 IBSNKSODLGJUMQ-SDNWHVSQSA-N 0.000 abstract 1
- JPFWJDMDPLEUBD-ITJAGOAWSA-N polyoxorim Polymers O[C@@H]1[C@H](O)[C@@H]([C@H](NC(=O)[C@H]([C@H](O)[C@@H](O)COC(N)=O)N)C(O)=O)O[C@H]1N1C(=O)NC(=O)C(C(O)=O)=C1 JPFWJDMDPLEUBD-ITJAGOAWSA-N 0.000 abstract 1
- 229920002635 polyurethane Polymers 0.000 abstract 1
- WHHIPMZEDGBUCC-UHFFFAOYSA-N probenazole Chemical compound C1=CC=C2C(OCC=C)=NS(=O)(=O)C2=C1 WHHIPMZEDGBUCC-UHFFFAOYSA-N 0.000 abstract 1
- TVLSRXXIMLFWEO-UHFFFAOYSA-N prochloraz Chemical compound C1=CN=CN1C(=O)N(CCC)CCOC1=C(Cl)C=C(Cl)C=C1Cl TVLSRXXIMLFWEO-UHFFFAOYSA-N 0.000 abstract 1
- WZZLDXDUQPOXNW-UHFFFAOYSA-N propamocarb Chemical compound CCCOC(=O)NCCCN(C)C WZZLDXDUQPOXNW-UHFFFAOYSA-N 0.000 abstract 1
- STJLVHWMYQXCPB-UHFFFAOYSA-N propiconazole Chemical compound O1C(CCC)COC1(C=1C(=CC(Cl)=CC=1)Cl)CN1N=CN=C1 STJLVHWMYQXCPB-UHFFFAOYSA-N 0.000 abstract 1
- KKMLIVYBGSAJPM-UHFFFAOYSA-L propineb Chemical compound [Zn+2].[S-]C(=S)NC(C)CNC([S-])=S KKMLIVYBGSAJPM-UHFFFAOYSA-L 0.000 abstract 1
- 235000019260 propionic acid Nutrition 0.000 abstract 1
- FLVBXVXXXMLMOX-UHFFFAOYSA-N proquinazid Chemical compound C1=C(I)C=C2C(=O)N(CCC)C(OCCC)=NC2=C1 FLVBXVXXXMLMOX-UHFFFAOYSA-N 0.000 abstract 1
- HZRSNVGNWUDEFX-UHFFFAOYSA-N pyraclostrobin Chemical compound COC(=O)N(OC)C1=CC=CC=C1COC1=NN(C=2C=CC(Cl)=CC=2)C=C1 HZRSNVGNWUDEFX-UHFFFAOYSA-N 0.000 abstract 1
- ZLIBICFPKPWGIZ-UHFFFAOYSA-N pyrimethanil Chemical compound CC1=CC(C)=NC(NC=2C=CC=CC=2)=N1 ZLIBICFPKPWGIZ-UHFFFAOYSA-N 0.000 abstract 1
- 229960003811 pyrithione disulfide Drugs 0.000 abstract 1
- IUVKMZGDUIUOCP-BTNSXGMBSA-N quinbolone Chemical compound O([C@H]1CC[C@H]2[C@H]3[C@@H]([C@]4(C=CC(=O)C=C4CC3)C)CC[C@@]21C)C1=CCCC1 IUVKMZGDUIUOCP-BTNSXGMBSA-N 0.000 abstract 1
- MCJGNVYPOGVAJF-UHFFFAOYSA-N quinolin-8-ol Chemical compound C1=CN=C2C(O)=CC=CC2=C1 MCJGNVYPOGVAJF-UHFFFAOYSA-N 0.000 abstract 1
- FBQQHUGEACOBDN-UHFFFAOYSA-N quinomethionate Chemical compound N1=C2SC(=O)SC2=NC2=CC(C)=CC=C21 FBQQHUGEACOBDN-UHFFFAOYSA-N 0.000 abstract 1
- BHRZNVHARXXAHW-UHFFFAOYSA-N sec-butylamine Chemical compound CCC(C)N BHRZNVHARXXAHW-UHFFFAOYSA-N 0.000 abstract 1
- 235000019259 sodium dehydroacetate Nutrition 0.000 abstract 1
- 229940079839 sodium dehydroacetate Drugs 0.000 abstract 1
- DSOWAKKSGYUMTF-GZOLSCHFSA-M sodium;(1e)-1-(6-methyl-2,4-dioxopyran-3-ylidene)ethanolate Chemical compound [Na+].C\C([O-])=C1/C(=O)OC(C)=CC1=O DSOWAKKSGYUMTF-GZOLSCHFSA-M 0.000 abstract 1
- 235000010199 sorbic acid Nutrition 0.000 abstract 1
- 239000004334 sorbic acid Substances 0.000 abstract 1
- 229940075582 sorbic acid Drugs 0.000 abstract 1
- 229960005322 streptomycin Drugs 0.000 abstract 1
- IWVCMVBTMGNXQD-UHFFFAOYSA-N terramycin dehydrate Natural products C1=CC=C2C(O)(C)C3C(O)C4C(N(C)C)C(O)=C(C(N)=O)C(=O)C4(O)C(O)=C3C(=O)C2=C1O IWVCMVBTMGNXQD-UHFFFAOYSA-N 0.000 abstract 1
- 239000004308 thiabendazole Substances 0.000 abstract 1
- 235000010296 thiabendazole Nutrition 0.000 abstract 1
- WJCNZQLZVWNLKY-UHFFFAOYSA-N thiabendazole Chemical compound S1C=NC(C=2NC3=CC=CC=C3N=2)=C1 WJCNZQLZVWNLKY-UHFFFAOYSA-N 0.000 abstract 1
- 229960004546 thiabendazole Drugs 0.000 abstract 1
- WOSNCVAPUOFXEH-UHFFFAOYSA-N thifluzamide Chemical compound S1C(C)=NC(C(F)(F)F)=C1C(=O)NC1=C(Br)C=C(OC(F)(F)F)C=C1Br WOSNCVAPUOFXEH-UHFFFAOYSA-N 0.000 abstract 1
- YFNCATAIYKQPOO-UHFFFAOYSA-N thiophanate Chemical compound CCOC(=O)NC(=S)NC1=CC=CC=C1NC(=S)NC(=O)OCC YFNCATAIYKQPOO-UHFFFAOYSA-N 0.000 abstract 1
- QGHREAKMXXNCOA-UHFFFAOYSA-N thiophanate-methyl Chemical compound COC(=O)NC(=S)NC1=CC=CC=C1NC(=S)NC(=O)OC QGHREAKMXXNCOA-UHFFFAOYSA-N 0.000 abstract 1
- OBZIQQJJIKNWNO-UHFFFAOYSA-N tolclofos-methyl Chemical compound COP(=S)(OC)OC1=C(Cl)C=C(C)C=C1Cl OBZIQQJJIKNWNO-UHFFFAOYSA-N 0.000 abstract 1
- HYVWIQDYBVKITD-UHFFFAOYSA-N tolylfluanid Chemical compound CN(C)S(=O)(=O)N(SC(F)(Cl)Cl)C1=CC=C(C)C=C1 HYVWIQDYBVKITD-UHFFFAOYSA-N 0.000 abstract 1
- BAZVSMNPJJMILC-UHFFFAOYSA-N triadimenol Chemical compound C1=NC=NN1C(C(O)C(C)(C)C)OC1=CC=C(Cl)C=C1 BAZVSMNPJJMILC-UHFFFAOYSA-N 0.000 abstract 1
- IQGKIPDJXCAMSM-UHFFFAOYSA-N triazoxide Chemical compound N=1C2=CC=C(Cl)C=C2[N+]([O-])=NC=1N1C=CN=C1 IQGKIPDJXCAMSM-UHFFFAOYSA-N 0.000 abstract 1
- ONCZDRURRATYFI-TVJDWZFNSA-N trifloxystrobin Chemical compound CO\N=C(\C(=O)OC)C1=CC=CC=C1CO\N=C(/C)C1=CC=CC(C(F)(F)F)=C1 ONCZDRURRATYFI-TVJDWZFNSA-N 0.000 abstract 1
- HSMVPDGQOIQYSR-KGENOOAVSA-N triflumizole Chemical compound C1=CN=CN1C(/COCCC)=N/C1=CC=C(Cl)C=C1C(F)(F)F HSMVPDGQOIQYSR-KGENOOAVSA-N 0.000 abstract 1
- RROQIUMZODEXOR-UHFFFAOYSA-N triforine Chemical compound O=CNC(C(Cl)(Cl)Cl)N1CCN(C(NC=O)C(Cl)(Cl)Cl)CC1 RROQIUMZODEXOR-UHFFFAOYSA-N 0.000 abstract 1
- JARYYMUOCXVXNK-IMTORBKUSA-N validamycin Chemical compound N([C@H]1C[C@@H]([C@H]([C@H](O)[C@H]1O)O[C@H]1[C@@H]([C@@H](O)[C@H](O)[C@@H](CO)O1)O)CO)[C@H]1C=C(CO)[C@H](O)[C@H](O)[C@H]1O JARYYMUOCXVXNK-IMTORBKUSA-N 0.000 abstract 1
- DBXFMOWZRXXBRN-LWKPJOBUSA-N valifenalate Chemical compound CC(C)OC(=O)N[C@@H](C(C)C)C(=O)NC(CC(=O)OC)C1=CC=C(Cl)C=C1 DBXFMOWZRXXBRN-LWKPJOBUSA-N 0.000 abstract 1
- 239000003643 water by type Substances 0.000 abstract 1
Classifications
-
- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
- A01N25/00—Biocides, pest repellants or attractants, or plant growth regulators, characterised by their forms, or by their non-active ingredients or by their methods of application, e.g. seed treatment or sequential application; Substances for reducing the noxious effect of the active ingredients to organisms other than pests
- A01N25/08—Biocides, pest repellants or attractants, or plant growth regulators, characterised by their forms, or by their non-active ingredients or by their methods of application, e.g. seed treatment or sequential application; Substances for reducing the noxious effect of the active ingredients to organisms other than pests containing solids as carriers or diluents
- A01N25/10—Macromolecular compounds
-
- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
- A01N25/00—Biocides, pest repellants or attractants, or plant growth regulators, characterised by their forms, or by their non-active ingredients or by their methods of application, e.g. seed treatment or sequential application; Substances for reducing the noxious effect of the active ingredients to organisms other than pests
- A01N25/26—Biocides, pest repellants or attractants, or plant growth regulators, characterised by their forms, or by their non-active ingredients or by their methods of application, e.g. seed treatment or sequential application; Substances for reducing the noxious effect of the active ingredients to organisms other than pests in coated particulate form
- A01N25/28—Microcapsules or nanocapsules
-
- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
- A01N43/00—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds
- A01N43/48—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with two nitrogen atoms as the only ring hetero atoms
- A01N43/50—1,3-Diazoles; Hydrogenated 1,3-diazoles
-
- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
- A01N43/00—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds
- A01N43/64—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with three nitrogen atoms as the only ring hetero atoms
- A01N43/647—Triazoles; Hydrogenated triazoles
- A01N43/653—1,2,4-Triazoles; Hydrogenated 1,2,4-triazoles
-
- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
- A01N43/00—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds
- A01N43/72—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with nitrogen atoms and oxygen or sulfur atoms as ring hetero atoms
- A01N43/74—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with nitrogen atoms and oxygen or sulfur atoms as ring hetero atoms five-membered rings with one nitrogen atom and either one oxygen atom or one sulfur atom in positions 1,3
- A01N43/78—1,3-Thiazoles; Hydrogenated 1,3-thiazoles
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07F—ACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
- C07F7/00—Compounds containing elements of Groups 4 or 14 of the Periodic Table
- C07F7/02—Silicon compounds
- C07F7/08—Compounds having one or more C—Si linkages
- C07F7/0834—Compounds having one or more O-Si linkage
- C07F7/0838—Compounds with one or more Si-O-Si sequences
- C07F7/0872—Preparation and treatment thereof
- C07F7/0874—Reactions involving a bond of the Si-O-Si linkage
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07F—ACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
- C07F7/00—Compounds containing elements of Groups 4 or 14 of the Periodic Table
- C07F7/02—Silicon compounds
- C07F7/08—Compounds having one or more C—Si linkages
- C07F7/0834—Compounds having one or more O-Si linkage
- C07F7/0838—Compounds with one or more Si-O-Si sequences
- C07F7/0872—Preparation and treatment thereof
- C07F7/0876—Reactions involving the formation of bonds to a Si atom of a Si-O-Si sequence other than a bond of the Si-O-Si linkage
- C07F7/0878—Si-C bond
Landscapes
- Life Sciences & Earth Sciences (AREA)
- General Health & Medical Sciences (AREA)
- Health & Medical Sciences (AREA)
- Dentistry (AREA)
- Pest Control & Pesticides (AREA)
- Plant Pathology (AREA)
- Engineering & Computer Science (AREA)
- Agronomy & Crop Science (AREA)
- Wood Science & Technology (AREA)
- Zoology (AREA)
- Environmental Sciences (AREA)
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Toxicology (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Agricultural Chemicals And Associated Chemicals (AREA)
Abstract
Reivindicación 1: Una partícula de sílica porosa parcialmente funcionalizada con restos de cadenas largas hidrocarbonadas caracterizada porque está cargada con un agente fungicida retenido por interacciones no covalentes con las cadenas largas hidrocarbonadas. Reivindicación 2: Una partícula de acuerdo con la reivindicación 1 donde el tamaño de la partícula se encuentra en el rango de 0.02 - 500 mm. Reivindicación 3: Una partícula de acuerdo con cualquiera de las reivindicaciones anteriores donde la sílica es microporosa, mesoporosa o macroporosa. Reivindicación 4: Una partícula de acuerdo con cualquiera de las reivindicaciones anteriores que comprende un patrón de funcionalización de acuerdo con las estructuras de superficie de fórmula (1), (2) y (3), donde R¹ y R² son cadenas hidrocarbonadas de 1 a 5 átomos de carbono, lineales o ramificadas, saturadas o insaturadas y que pueden comprender entre 0 y 3 heteroátomos que se seleccionan del grupo que consiste en S, O y N; R³ es una cadena hidrocarbonada de 8 a 20 átomos de carbono, lineal o ramificada, saturada o insaturada y que puede comprender entre 0 y 10 heteroátomos que se seleccionan del grupo que consiste en S, O y N; y F representa el agente fungicida retenido. Reivindicación 10: Una partícula de acuerdo con cualquiera de las reivindicaciones anteriores donde el agente fungicida se selecciona del grupo que consiste en o-fenilfenol, benomilo, carbendacima, fuberidazol, tiabendazol, tiofanato, metil tiofanato, clozolinato, iprodiona, procimidona, vinclozolina, imazalil, oxiconazol, pefurazoato, procloraz, triflumizol, triforina, pirifenox, fenarimol, nuarimol, azaconazol, bitertanol, bromuconazol, ciproconazol, difenoconazol, diniconazol, epoxiconazol, fenbuconazol, fluquinconazol, flusilazol, flutriafol, hexaconazol, imibenconazol, ipconazol, metconazol, miclobutanil, penconazol, propiconazol, protioconazol, simeconazol, tebuconazol, tetraconazol, triadimefon, triadimenol, triticonazol, benalaxil, furalaxil, metalaxil, mefenoxam, oxadixil, ofurace, aldimorf, dodemorf, fenpropimorf, tridemorf, fenpropidina, piperalina, spiroxamina, edifenfos, iprobenfos, pirazofos, isoprotiolano, benodanilo, boscalid, carboxin, fenfuram, flutolanil, furametpir, mepronil, oxycarboxina, pentiopirad, tifluzamida, bupirimato, dimetirimol, etirimol, ciprodinil, mepanipirim, pirimetanil, dietofencarb, azoxistrobin, enestrobin, picoxistrobin, piraclostrobin, kresoxim-metil, trifloxistrobin, dimoxistrobin, metominostrobin, orysastrobin, famoxadona, fluoxastrobin, fenamidona, fenpiclonil, fludioxonil, quinoxifenbifenilo, cloroneb, dicloran, quintozeno, tecnazeno, tolclofos-metil, etridiazol, ftalida, piroquilon, triciclazol, carpropamida, diclocimet, fenoxanil, fenhexamid, piributicarb, naftifina, terbinafina, polioxina, pencicurona, ciazofamid, zoxamida, blasticidinaS, kasugamicina, streptomicina, validamicina, cimoxanilo, iodocarb, propamocarb, protiocarb, binapacril, dinocap, ferimzona, fluazinam, fentin acetato, fentin cloruro, fentin hidróxido, ácido oxolínico, himexazol, octilinona, fosetil-Al, ácido fosforoso y sus sales, tecloftalam, triazoxido, flusulfamida, diclomezina, siltiofam, diflumetorim, dimetomorf, flumorf, bentiavalicarb, iprovalicarb, mandipropamid, oxitetraciclina, metasulfocarb, acibenzolar-S-metil, probenazol, tiadinil, etaboxam, ciflufenamid, proquinazid, metrafenona, fluopicolida, ferbam, mancozeb, maneb, metiram, propineb, tiram, zineb, ziram, captan, captafol, folpet, clorotalonil, diclofluanid, tolilfluanid, dodina, guazatina, iminoctadina, anilazina, ditianon, ampropilfos, benzamacrilo, betoxazina, butiobato, ácido clorosulfámico, cicloprato, ciprofuram, diclona, diclobutrazol, dinoterbon, difenilamina, dipiritiona, ditalimfos, drazoxolon, etaconazol, fenaminosulf, flumetover, fluoroimida, cis-furconazol, furmeciclox, furofanato, gentamicina, gliodin, halacrinato, hexaclorofeno, korax, dimetilditiocarbamato, ácido 2-metil-4-clorofenoxiacético, mercaptobenzotiazol, metalaxil-M, metfuroxam, metsulfovax, milneb, miclozolina, nitrotal-isopropilo, oxicarboxina, oxitioquinox, fosdifen, ácido ftalámico, policarbamato, polioxorim, piracarbolid, piridinitril, piroxifur, quinacetol, quinconazol, sec-butilamina, dehidroacetato sódico, (2-benzotiazoliltio)metil tiocianato, tetrayodoetileno, ticiofen, triclamida, zarilamida, valifenalato, sedaxano, apiriofenona, penflufen, oxatiapiprolina, metam, meptildinocap, mandestrobin, lyserfenvalpir, isopirazam, osofetamida, fluxapiroxad, flutianil, fluopiram, fenpirazamina, dazomet, bixafen, benzovindiflupir, benalaxyl-M, amisulbrom, ametoctradin, 8-hidroxiquinolina, 2,5-diclorobenzoato de metilo, cloropicrin; ácido sórbico y sus sales, ácido benzoico y sus sales, ácido propiónico y sus sales, o combinaciones de los mismos. Reivindicación 12: Un procedimiento para la preparación de las partículas de sílica porosa de acuerdo con la reivindicación 1 que comprende las etapas de: a) funcionalización de la partículas de sílica con cadenas largas hidrocarbonadas, b) carga de la partículas funcionalizadas en la etapa a) con el agente fungicida que comprende llevar a cabo uno cualquiera de los siguientes pasos: b1) suspender las partículas funcionalizadas en la etapa a) en una solución acuosa concentrada del agente fungicida en su forma iónica y variar el pH de la solución hasta llevar al agente fungicida a su forma no iónica quedando dicho agente retenido por interacciones no covalentes en el interior de la partículas; o b2) suspender las partículas funcionalizadas en la etapa a) en una disolución del agente fungicida en su forma no iónica con un disolvente orgánico miscible en agua y posteriormente añadir agua para disminuir la solubilidad del agente fungicida en el disolvente orgánico y forzar la carga de las partículas de sílica al ser más favorable la interacción del agente fungicida con las cadenas largas hidrocarbonadas de las partículas de sílica que su presencia en la disolución; o b3) suspender las partículas funcionalizadas en la etapa a) en una disolución del agente fungicida en su forma no iónica con un disolvente orgánico de bajo punto de ebullición que posteriormente se evapora a presión reducida, quedando retenido el agente fungicida en el interior de las partículas de sílica. Reivindicación 17: Un sistema de liberación controlada y dirigida de fungicidas sobre lugares de infección de tejidos vegetales que comprende partículas de acuerdo con cualquiera de las reivindicaciones 1 a 11 suspendidas en una solución tamponada a un pH en el que el agente fungicida se mantenga en su forma no iónica. Reivindicación 21: Uso de las partículas de acuerdo con cualquiera de las reivindicaciones 1 a 11 o del sistema de acuerdo con cualquiera de las reivindicaciones 17 a 20 para un tratamiento fungicida dirigido a los lugares de infección de tejidos vegetales Reivindicación 23: Método para evitar el podrido causado por hongos en productos hortofrutícolas sin generar residuos de fungicida libre en aguas de tratamiento y de lavado y reduciendo el residuo de fungicida en fruto a nivel de trazas que comprende: a) tratar el producto hortofrutícola mediante duchado, nebulizado, pulverizado, fumigado o inmersión en un sistema de liberación controlada y dirigida de fungicidas de acuerdo con cualquiera de las reivindicaciones 17 - 20, b) eliminar el exceso de partículas de la superficie de los productos hortofrutícolas mediante cepillado, aire a presión, lavado con agua o con una solución acuosa o cualquier combinación de los anteriores.
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| PCT/ES2015/070907 WO2017103292A1 (es) | 2015-12-15 | 2015-12-15 | Partículas de sílica funcionalizadas y cargadas con agentes fungicidas, su preparación y su uso como sistemas de liberación dirigida y controlada de fungicidas |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| AR106858A1 true AR106858A1 (es) | 2018-02-28 |
Family
ID=55310834
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| ARP160103783A AR106858A1 (es) | 2015-12-15 | 2016-12-12 | Partículas de sílica funcionalizadas y cargadas con agentes fungicidas, su preparación y su uso como sistemas de liberación dirigida y controlada de fungicidas |
Country Status (6)
| Country | Link |
|---|---|
| US (1) | US10736316B2 (es) |
| EP (1) | EP3403503A1 (es) |
| AR (1) | AR106858A1 (es) |
| UY (1) | UY37023A (es) |
| WO (1) | WO2017103292A1 (es) |
| ZA (1) | ZA201803982B (es) |
Families Citing this family (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CZ308794B6 (cs) * | 2016-11-25 | 2021-05-26 | Česká zemědělská univerzita v Praze | Mezoporézní materiál na bázi oxidu křemičitého pro řízené uvolňování aktivních látek a jeho použití |
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| CA2554236C (en) * | 2004-02-04 | 2012-09-11 | Janssen Pharmaceutica N.V. | Synergistic antifungal didecyl dimethyl ammonium chloride compositions |
| WO2011054046A1 (en) | 2009-11-06 | 2011-05-12 | The University Of Queensland And The State Of Queensland Acting Through Its Department Of Primary Industries And Fisheries | Controlled release particles and method for preparation thereof |
| WO2011081787A2 (en) | 2009-12-15 | 2011-07-07 | Fmc Corporation | Sustained-release silica microcapsules |
| EP2552196B1 (en) * | 2010-03-30 | 2018-05-09 | University Of Central Florida Research Foundation, Inc. | Multifunctional silica-based compositions and gels, methods of making them, and methods of using them |
| US20120074603A1 (en) | 2010-06-25 | 2012-03-29 | Traynor Daniel H | Delivery of Herbicidal Actives From Highly Charged Microcapsules |
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| US10736316B2 (en) | 2020-08-11 |
| UY37023A (es) | 2017-01-31 |
| US20180368396A1 (en) | 2018-12-27 |
| EP3403503A1 (en) | 2018-11-21 |
| WO2017103292A1 (es) | 2017-06-22 |
| ZA201803982B (en) | 2019-04-24 |
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