AR106299A1 - PIRIDONA COMPOUNDS AND AGRICULTURAL AND HERTICAL FUNGICIDES CONTAINING THESE COMPOUNDS AS ACTIVE INGREDIENT - Google Patents
PIRIDONA COMPOUNDS AND AGRICULTURAL AND HERTICAL FUNGICIDES CONTAINING THESE COMPOUNDS AS ACTIVE INGREDIENTInfo
- Publication number
- AR106299A1 AR106299A1 ARP160103080A ARP160103080A AR106299A1 AR 106299 A1 AR106299 A1 AR 106299A1 AR P160103080 A ARP160103080 A AR P160103080A AR P160103080 A ARP160103080 A AR P160103080A AR 106299 A1 AR106299 A1 AR 106299A1
- Authority
- AR
- Argentina
- Prior art keywords
- group
- substituent
- optionally substituted
- haloalkyl
- alkyl
- Prior art date
Links
- 150000001875 compounds Chemical class 0.000 title abstract 3
- 239000004480 active ingredient Substances 0.000 title 1
- 239000000417 fungicide Substances 0.000 title 1
- 125000001424 substituent group Chemical group 0.000 abstract 36
- 125000004169 (C1-C6) alkyl group Chemical group 0.000 abstract 12
- 125000000171 (C1-C6) haloalkyl group Chemical group 0.000 abstract 12
- 125000004737 (C1-C6) haloalkoxy group Chemical group 0.000 abstract 11
- 125000006552 (C3-C8) cycloalkyl group Chemical group 0.000 abstract 11
- 125000000000 cycloalkoxy group Chemical group 0.000 abstract 9
- 125000004191 (C1-C6) alkoxy group Chemical group 0.000 abstract 8
- 125000004093 cyano group Chemical group *C#N 0.000 abstract 6
- 125000004435 hydrogen atom Chemical group [H]* 0.000 abstract 6
- 125000002887 hydroxy group Chemical group [H]O* 0.000 abstract 6
- 125000000262 haloalkenyl group Chemical group 0.000 abstract 5
- 125000000232 haloalkynyl group Chemical group 0.000 abstract 5
- 125000005843 halogen group Chemical group 0.000 abstract 4
- -1 homopiperidinyl group Chemical group 0.000 abstract 4
- 125000000882 C2-C6 alkenyl group Chemical group 0.000 abstract 3
- 125000003601 C2-C6 alkynyl group Chemical group 0.000 abstract 3
- 125000004430 oxygen atom Chemical group O* 0.000 abstract 3
- 102220084927 rs778740017 Human genes 0.000 abstract 3
- 125000003342 alkenyl group Chemical group 0.000 abstract 2
- 125000000217 alkyl group Chemical group 0.000 abstract 2
- 125000000304 alkynyl group Chemical group 0.000 abstract 2
- 125000002393 azetidinyl group Chemical group 0.000 abstract 2
- 125000004069 aziridinyl group Chemical group 0.000 abstract 2
- 125000001786 isothiazolyl group Chemical group 0.000 abstract 2
- 125000000449 nitro group Chemical group [O-][N+](*)=O 0.000 abstract 2
- 229910052757 nitrogen Inorganic materials 0.000 abstract 2
- 125000004433 nitrogen atom Chemical group N* 0.000 abstract 2
- 125000001997 phenyl group Chemical group [H]C1=C([H])C([H])=C(*)C([H])=C1[H] 0.000 abstract 2
- 125000003386 piperidinyl group Chemical group 0.000 abstract 2
- 125000003373 pyrazinyl group Chemical group 0.000 abstract 2
- 125000002098 pyridazinyl group Chemical group 0.000 abstract 2
- 125000004076 pyridyl group Chemical group 0.000 abstract 2
- 125000000714 pyrimidinyl group Chemical group 0.000 abstract 2
- 125000000719 pyrrolidinyl group Chemical group 0.000 abstract 2
- 125000005247 tetrazinyl group Chemical group N1=NN=NC(=C1)* 0.000 abstract 2
- 125000001113 thiadiazolyl group Chemical group 0.000 abstract 2
- 125000000335 thiazolyl group Chemical group 0.000 abstract 2
- 125000001544 thienyl group Chemical group 0.000 abstract 2
- 125000004306 triazinyl group Chemical group 0.000 abstract 2
- 125000003545 alkoxy group Chemical group 0.000 abstract 1
- 125000005083 alkoxyalkoxy group Chemical group 0.000 abstract 1
- 125000000753 cycloalkyl group Chemical group 0.000 abstract 1
- 102200127349 rs11547328 Human genes 0.000 abstract 1
- 102200042269 rs864309693 Human genes 0.000 abstract 1
- 150000003839 salts Chemical class 0.000 abstract 1
- 229910052717 sulfur Inorganic materials 0.000 abstract 1
- 125000004434 sulfur atom Chemical group 0.000 abstract 1
Classifications
-
- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
- A01N43/00—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds
- A01N43/34—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with one nitrogen atom as the only ring hetero atom
- A01N43/40—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with one nitrogen atom as the only ring hetero atom six-membered rings
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07F—ACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
- C07F7/00—Compounds containing elements of Groups 4 or 14 of the Periodic System
- C07F7/02—Silicon compounds
- C07F7/08—Compounds having one or more C—Si linkages
- C07F7/0803—Compounds with Si-C or Si-Si linkages
- C07F7/081—Compounds with Si-C or Si-Si linkages comprising at least one atom selected from the elements N, O, halogen, S, Se or Te
- C07F7/0812—Compounds with Si-C or Si-Si linkages comprising at least one atom selected from the elements N, O, halogen, S, Se or Te comprising a heterocyclic ring
-
- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
- A01N25/00—Biocides, pest repellants or attractants, or plant growth regulators, characterised by their forms, or by their non-active ingredients or by their methods of application, e.g. seed treatment or sequential application; Substances for reducing the noxious effect of the active ingredients to organisms other than pests
-
- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
- A01N47/00—Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds containing a carbon atom not being member of a ring and having no bond to a carbon or hydrogen atom, e.g. derivatives of carbonic acid
- A01N47/02—Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds containing a carbon atom not being member of a ring and having no bond to a carbon or hydrogen atom, e.g. derivatives of carbonic acid the carbon atom having no bond to a nitrogen atom
-
- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
- A01N47/00—Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds containing a carbon atom not being member of a ring and having no bond to a carbon or hydrogen atom, e.g. derivatives of carbonic acid
- A01N47/40—Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds containing a carbon atom not being member of a ring and having no bond to a carbon or hydrogen atom, e.g. derivatives of carbonic acid the carbon atom having a double or triple bond to nitrogen, e.g. cyanates, cyanamides
-
- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
- A01N55/00—Biocides, pest repellants or attractants, or plant growth regulators, containing organic compounds containing elements other than carbon, hydrogen, halogen, oxygen, nitrogen and sulfur
-
- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01P—BIOCIDAL, PEST REPELLANT, PEST ATTRACTANT OR PLANT GROWTH REGULATORY ACTIVITY OF CHEMICAL COMPOUNDS OR PREPARATIONS
- A01P3/00—Fungicides
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07D—HETEROCYCLIC COMPOUNDS
- C07D211/00—Heterocyclic compounds containing hydrogenated pyridine rings, not condensed with other rings
- C07D211/04—Heterocyclic compounds containing hydrogenated pyridine rings, not condensed with other rings with only hydrogen or carbon atoms directly attached to the ring nitrogen atom
- C07D211/80—Heterocyclic compounds containing hydrogenated pyridine rings, not condensed with other rings with only hydrogen or carbon atoms directly attached to the ring nitrogen atom having two double bonds between ring members or between ring members and non-ring members
- C07D211/84—Heterocyclic compounds containing hydrogenated pyridine rings, not condensed with other rings with only hydrogen or carbon atoms directly attached to the ring nitrogen atom having two double bonds between ring members or between ring members and non-ring members with hetero atoms or with carbon atoms having three bonds to hetero atoms, with at the most one bond to halogen directly attached to ring carbon atoms
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07D—HETEROCYCLIC COMPOUNDS
- C07D211/00—Heterocyclic compounds containing hydrogenated pyridine rings, not condensed with other rings
- C07D211/04—Heterocyclic compounds containing hydrogenated pyridine rings, not condensed with other rings with only hydrogen or carbon atoms directly attached to the ring nitrogen atom
- C07D211/80—Heterocyclic compounds containing hydrogenated pyridine rings, not condensed with other rings with only hydrogen or carbon atoms directly attached to the ring nitrogen atom having two double bonds between ring members or between ring members and non-ring members
- C07D211/84—Heterocyclic compounds containing hydrogenated pyridine rings, not condensed with other rings with only hydrogen or carbon atoms directly attached to the ring nitrogen atom having two double bonds between ring members or between ring members and non-ring members with hetero atoms or with carbon atoms having three bonds to hetero atoms, with at the most one bond to halogen directly attached to ring carbon atoms
- C07D211/86—Oxygen atoms
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07D—HETEROCYCLIC COMPOUNDS
- C07D213/00—Heterocyclic compounds containing six-membered rings, not condensed with other rings, with one nitrogen atom as the only ring hetero atom and three or more double bonds between ring members or between ring members and non-ring members
- C07D213/02—Heterocyclic compounds containing six-membered rings, not condensed with other rings, with one nitrogen atom as the only ring hetero atom and three or more double bonds between ring members or between ring members and non-ring members having three double bonds between ring members or between ring members and non-ring members
- C07D213/04—Heterocyclic compounds containing six-membered rings, not condensed with other rings, with one nitrogen atom as the only ring hetero atom and three or more double bonds between ring members or between ring members and non-ring members having three double bonds between ring members or between ring members and non-ring members having no bond between the ring nitrogen atom and a non-ring member or having only hydrogen or carbon atoms directly attached to the ring nitrogen atom
- C07D213/60—Heterocyclic compounds containing six-membered rings, not condensed with other rings, with one nitrogen atom as the only ring hetero atom and three or more double bonds between ring members or between ring members and non-ring members having three double bonds between ring members or between ring members and non-ring members having no bond between the ring nitrogen atom and a non-ring member or having only hydrogen or carbon atoms directly attached to the ring nitrogen atom with hetero atoms or with carbon atoms having three bonds to hetero atoms with at the most one bond to halogen, e.g. ester or nitrile radicals, directly attached to ring carbon atoms
- C07D213/62—Oxygen or sulfur atoms
- C07D213/63—One oxygen atom
- C07D213/64—One oxygen atom attached in position 2 or 6
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07D—HETEROCYCLIC COMPOUNDS
- C07D213/00—Heterocyclic compounds containing six-membered rings, not condensed with other rings, with one nitrogen atom as the only ring hetero atom and three or more double bonds between ring members or between ring members and non-ring members
- C07D213/02—Heterocyclic compounds containing six-membered rings, not condensed with other rings, with one nitrogen atom as the only ring hetero atom and three or more double bonds between ring members or between ring members and non-ring members having three double bonds between ring members or between ring members and non-ring members
- C07D213/04—Heterocyclic compounds containing six-membered rings, not condensed with other rings, with one nitrogen atom as the only ring hetero atom and three or more double bonds between ring members or between ring members and non-ring members having three double bonds between ring members or between ring members and non-ring members having no bond between the ring nitrogen atom and a non-ring member or having only hydrogen or carbon atoms directly attached to the ring nitrogen atom
- C07D213/60—Heterocyclic compounds containing six-membered rings, not condensed with other rings, with one nitrogen atom as the only ring hetero atom and three or more double bonds between ring members or between ring members and non-ring members having three double bonds between ring members or between ring members and non-ring members having no bond between the ring nitrogen atom and a non-ring member or having only hydrogen or carbon atoms directly attached to the ring nitrogen atom with hetero atoms or with carbon atoms having three bonds to hetero atoms with at the most one bond to halogen, e.g. ester or nitrile radicals, directly attached to ring carbon atoms
- C07D213/62—Oxygen or sulfur atoms
- C07D213/63—One oxygen atom
- C07D213/64—One oxygen atom attached in position 2 or 6
- C07D213/643—2-Phenoxypyridines; Derivatives thereof
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07D—HETEROCYCLIC COMPOUNDS
- C07D213/00—Heterocyclic compounds containing six-membered rings, not condensed with other rings, with one nitrogen atom as the only ring hetero atom and three or more double bonds between ring members or between ring members and non-ring members
- C07D213/02—Heterocyclic compounds containing six-membered rings, not condensed with other rings, with one nitrogen atom as the only ring hetero atom and three or more double bonds between ring members or between ring members and non-ring members having three double bonds between ring members or between ring members and non-ring members
- C07D213/04—Heterocyclic compounds containing six-membered rings, not condensed with other rings, with one nitrogen atom as the only ring hetero atom and three or more double bonds between ring members or between ring members and non-ring members having three double bonds between ring members or between ring members and non-ring members having no bond between the ring nitrogen atom and a non-ring member or having only hydrogen or carbon atoms directly attached to the ring nitrogen atom
- C07D213/60—Heterocyclic compounds containing six-membered rings, not condensed with other rings, with one nitrogen atom as the only ring hetero atom and three or more double bonds between ring members or between ring members and non-ring members having three double bonds between ring members or between ring members and non-ring members having no bond between the ring nitrogen atom and a non-ring member or having only hydrogen or carbon atoms directly attached to the ring nitrogen atom with hetero atoms or with carbon atoms having three bonds to hetero atoms with at the most one bond to halogen, e.g. ester or nitrile radicals, directly attached to ring carbon atoms
- C07D213/62—Oxygen or sulfur atoms
- C07D213/70—Sulfur atoms
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07D—HETEROCYCLIC COMPOUNDS
- C07D401/00—Heterocyclic compounds containing two or more hetero rings, having nitrogen atoms as the only ring hetero atoms, at least one ring being a six-membered ring with only one nitrogen atom
- C07D401/02—Heterocyclic compounds containing two or more hetero rings, having nitrogen atoms as the only ring hetero atoms, at least one ring being a six-membered ring with only one nitrogen atom containing two hetero rings
- C07D401/04—Heterocyclic compounds containing two or more hetero rings, having nitrogen atoms as the only ring hetero atoms, at least one ring being a six-membered ring with only one nitrogen atom containing two hetero rings directly linked by a ring-member-to-ring-member bond
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07D—HETEROCYCLIC COMPOUNDS
- C07D405/00—Heterocyclic compounds containing both one or more hetero rings having oxygen atoms as the only ring hetero atoms, and one or more rings having nitrogen as the only ring hetero atom
- C07D405/02—Heterocyclic compounds containing both one or more hetero rings having oxygen atoms as the only ring hetero atoms, and one or more rings having nitrogen as the only ring hetero atom containing two hetero rings
- C07D405/12—Heterocyclic compounds containing both one or more hetero rings having oxygen atoms as the only ring hetero atoms, and one or more rings having nitrogen as the only ring hetero atom containing two hetero rings linked by a chain containing hetero atoms as chain links
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07F—ACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
- C07F7/00—Compounds containing elements of Groups 4 or 14 of the Periodic System
- C07F7/02—Silicon compounds
- C07F7/08—Compounds having one or more C—Si linkages
- C07F7/12—Organo silicon halides
Abstract
Reivindicación 1: Un compuesto representado por la fórmula (1) o una de sus sales, [caracterizado porque R¹ representa un grupo hidroxi, un grupo ciano, un grupo alquilo C₁₋₆ opcionalmente sustituido con el sustituyente A, un grupo haloalquilo C₁₋₆, un grupo cicloalquilo C₃₋₈ opcionalmente sustituido con el sustituyente A, un grupo alquenilo C₂₋₆ opcionalmente sustituido con el sustituyente A, un grupo haloalquenilo C₂₋₆, un grupo alquinilo C₂₋₆ opcionalmente sustituido con el sustituyente A, un grupo haloalquinilo C₂₋₆, un grupo alcoxi C₁₋₆ opcionalmente sustituido con el sustituyente A, un grupo haloalcoxi C₁₋₆,un grupo cicloalcoxi C₃₋₈ opcionalmente sustituido con el sustituyente A, grupo alquenil C₂₋₆-oxi opcionalmente sustituido con el sustituyente A, un grupo haloalquenil C₂₋₆-oxi, un grupo alquinil C₃₋₆-oxi opcionalmente sustituido con el sustituyente A, un grupo haloalquinil C₃₋₆-oxi, o un R¹⁰R¹¹N- (en donde R¹⁰ y R¹¹ representan cada uno, de modo independiente, un átomo de hidrógeno o un grupo alquilo C₁₋₆); R² representa un átomo de halógeno, un grupo hidroxi, un grupo ciano, un grupo nitro, un grupo alquilo C₁₋₆ opcionalmente sustituido con el sustituyente B, un grupo haloalquilo C₁₋₆, un grupo cicloalquilo C₃₋₈ opcionalmente sustituido con el sustituyente B, un grupo alquenilo C₂₋₆ opcionalmente sustituido con el sustituyente B, un grupo haloalquenilo C₂₋₆, un grupo alquinilo C₂₋₆ opcionalmente sustituido con el sustituyente B, un grupo haloalquinilo C₂₋₆, un grupo alcoxi C₁₋₆ opcionalmente sustituido con el sustituyente B, un grupo haloalcoxi C₁₋₆, un grupo cicloalcoxi C₃₋₈ opcionalmente sustituido con el sustituyente B, un grupo alquenil C₂₋₆-oxi opcionalmente sustituido con el sustituyente B, un grupo haloalquenil C₂₋₆-oxi, un grupo alquinil C₃₋₆-oxi opcionalmente sustituido con el sustituyente B, un grupo haloalquinil C₃₋₆-oxi, un R²⁰C(=O)- (en donde R²⁰ representa un grupo alquilo C₁₋₆, un grupo haloalquilo C₁₋₆, un grupo cicloalquilo C₃₋₈, un grupo alcoxi C₁₋₆, un grupo haloalcoxi C₁₋₆, un grupo cicloalcoxi C₃₋₈ o un R²¹R²²N- (en donde R²¹ y R²² representan cada uno, de modo independiente, un átomo de hidrógeno, un grupo alquilo C₁₋₆ opcionalmente sustituido con el sustituyente B¹, un grupo haloalquilo C₁₋₆ o un grupo cicloalquilo C₃₋₈ o R²¹ y R²² en combinación con el átomo de nitrógeno al que están unidos forman un grupo aziridinilo, un grupo azetidinilo, un grupo pirrolidinilo, un grupo piperidinilo, un grupo homopiperidinilo o un grupo azocanilo)), un R²⁰C(=O)O- (en donde R²⁰ es como se definió con anterioridad en la presente), un grupo de anillo de 3 a 6 miembros con contenido de 1 a 2 átomos de oxígeno, un R²³-L²- (en donde R²³ representa un grupo alquilo C₁₋₆ o un grupo haloalquilo C₁₋₆ y L² es S, SO o SO₂), un R²¹R²²N- (en donde R²¹ y R²² son como se definieron con anterioridad en la presente), o un R²⁴C(=O)N(R²⁵)- (en donde R²⁴ representa un átomo de hidrógeno, un grupo alquilo C₁₋₆, un grupo haloalquilo C₁₋₆, un grupo cicloalquilo C₃₋₈, un grupo alcoxi C₁₋₆, un grupo haloalcoxi C₁₋₆, un grupo cicloalcoxi C₃₋₈ o un R²¹R²²N- (en donde R²¹ y R²² son como se definieron con anterioridad en la presente) y R²⁵ representa un átomo de hidrógeno, un grupo alquilo C₁₋₆ opcionalmente sustituido con el sustituyente B¹, un grupo haloalquilo C₁₋₆ o un grupo cicloalquilo C₃₋₈); R³ representa un átomo de hidrógeno, un átomo de halógeno, un grupo nitro, un grupo alquilo C₁₋₆ opcionalmente sustituido con el sustituyente C, un grupo haloalquilo C₁₋₆, un grupo cicloalquilo C₃₋₈ opcionalmente sustituido con el sustituyente C, un grupo alcoxi C₁₋₆ opcionalmente sustituido con el sustituyente C, un grupo haloalcoxi C₁₋₆, un grupo alquenilo C₂₋₆ opcionalmente sustituido con el sustituyente C, un grupo haloalquenilo C₂₋₆ un grupo alquinilo C₂₋₆ opcionalmente sustituido con el sustituyente C, un grupo haloalquinilo C₂₋₆, un R³⁰-L³- (en donde R³⁰ tiene la misma definición que R²³ y L³ tiene la misma definición que L²), un R³¹R³²N- (en donde R³¹ y R³² tienen la misma definición que R²¹ y R²²), o un R³³C(=O)- (en donde R³³ representa un grupo alquilo C₁₋₆ un grupo haloalquilo C₁₋₆ o un grupo cicloalquilo C₃₋₈); n representa un número entero de 0 a 5 (siempre que cuando n es 2 o más, los dos o más R² representen sustituyentes independientes); X representa un átomo de oxígeno o un átomo de azufre; Y representa un grupo fenilo, un grupo piridilo, un grupo piridazinilo, un grupo pirimidinilo, un grupo pirazinilo, un grupo triazinilo, un grupo tetrazinilo, un grupo tienilo, un grupo tiazolilo, un grupo isotiazolilo o un grupo tiadiazolilo, el grupo fenilo está sustituido con el sustituyente D en una posición orto y además está sustituido con 0 a 4 sustituyentes independientes D¹ de modo apropiado, el grupo piridilo, el grupo pirazinilo, el grupo pirimidinilo, el grupo piridazinilo, el grupo triazinilo o el grupo tetrazinilo está sustituido con el sustituyente D en una posición orto y además está sustituido con 0 a 3 sustituyentes independientes D¹ de modo apropiado, el grupo tienilo, el grupo tiazolilo, el grupo isotiazolilo o el grupo tiadiazolilo está sustituido con el sustituyente D en una posición orto y además está sustituido con 0 a 2 sustituyentes independientes D¹ de modo apropiado; el enlace con una línea de puntos indica un enlace doble o un enlace simple, el sustituyente A es al menos uno seleccionado del grupo que consiste en: un grupo hidroxi, un grupo ciano, un grupo cicloalquilo C₃₋₈, un grupo alcoxi C₁₋₆, un grupo haloalcoxi C₁₋₆, un grupo cicloalcoxi C₃₋₈, un R¹²R¹³N- (en donde R¹² y R¹³ representan cada uno, de modo independiente, un átomo de hidrógeno, un grupo alquilo C₁₋₆, un grupo haloalquilo C₁₋₆ o un grupo cicloalquilo C₃₋₈ o R¹² y R¹³ en combinación con el átomo de nitrógeno al que están unidos forman un grupo aziridinilo, un grupo azetidinilo, un grupo pirrolidinilo, un grupo piperidinilo, un grupo homopiperidinilo o un grupo azocanilo) y un R¹⁴-L¹- (en donde R¹⁴ representa un grupo alquilo C₁₋₆ o un grupo haloalquilo C₁₋₆ y L¹ representa S, SO o SO₂); el sustituyente B es al menos uno seleccionado del grupo que consiste en: un grupo hidroxi, un grupo ciano, un grupo cicloalquilo C₃₋₈, un grupo alcoxi C₁₋₆, un grupo haloalcoxi C₁₋₆, un grupo cicloalcoxi C₃₋₈, un grupo alcoxialcoxi C₂₋₆, un R²¹R²²N- (en donde R²¹ y R²² son como se definieron con anterioridad en la presente), un R²³-L²- (en donde R²³ y L² son como se definieron con anterioridad en la presente), un R²⁶R²⁷R²⁸Si- (en donde R²⁶, R²⁷ y R²⁸ representan cada uno, de modo independiente, un grupo alquilo C₁₋₆), un R²⁶R²⁷R²⁸Si-(CH₂)ₛ-O- (en donde s representa un número entero de 1 a 3 y R²⁶, R²⁷ y R²⁸ son como se definieron con anterioridad en la presente), un R²⁰C(=O)- (en donde R²⁰ es como se definió con anterioridad en la presente) y un grupo de anillo de 3 a 6 miembros con contenido de 1 a 2 átomos de oxígeno; el sustituyente B¹ es al menos uno seleccionado del grupo que consiste en: un grupo ciano, un grupo alcoxi C₁₋₆ un grupo haloalcoxi C₁₋₆ y un grupo cicloalcoxi C₃₋₈; el sustituyente C es al menos uno seleccionado del grupo que consiste en: un grupo hidroxi, un grupo ciano, un grupo cicloalquilo C₃₋₈, un grupo alcoxi C₁₋₆, un grupo haloalcoxi C₁₋₆, un grupo cicloalcoxi C₃₋₈, un R³¹R³²N- (en donde R³¹ y R³² tienen la misma definición que R²¹ y R²²) y un R³⁰-L³- (en donde R³⁰ tiene la misma definición que R¹⁴ y L³ tiene la misma definición que L¹); el sustituyente D es al menos uno seleccionado del grupo que consiste en: un átomo de halógeno, un grupo alquilo C₁₋₆, un grupo haloalquilo C₁₋₆, un grupo alcoxi C₁₋₆ y un grupo haloalcoxi C₁₋₆; y el sustituyente D¹ es al menos uno seleccionado del grupo que consiste en: un grupo hidroxi, un átomo de halógeno, un grupo alquilo C₁₋₆, un grupo haloalquilo C₁₋₆, un grupo cicloalquilo C₃₋₈, un grupo alcoxi C₁₋₆, un grupo haloalcoxi C₁₋₆ y un grupo cicloalcoxi C₃₋₈.]Claim 1: A compound represented by the formula (1) or a salt thereof, [characterized in that R¹ represents a hydroxy group, a cyano group, a C₁₋₆ alkyl group optionally substituted with substituent A, a C₁₋₆ haloalkyl group , a C₃₋₈ cycloalkyl group optionally substituted with substituent A, a C₂₋₆ alkenyl group optionally substituted with substituent A, a C₂₋₆ haloalkenyl group, a C₂₋₆ alkynyl group optionally substituted with substituent A, a haloalkynyl group C₂₋₆, a C₁₋₆ alkoxy group optionally substituted with substituent A, a C₁₋₆ haloalkoxy group, a C₃₋₈ cycloalkoxy group optionally substituted with substituent A, C₂₋₆-oxy alkenyl group optionally substituted with substituent A , a C₂₋₆-oxy haloalkenyl group, a C₃₋₆-oxy alkynyl group optionally substituted with substituent A, a C₃₋₆-oxy haloalkynyl group, or an R ⁰R¹¹N- (where R¹⁰ and R¹¹ in each represent, independently, a hydrogen atom or an alkyl C₁₋₆); R² represents a halogen atom, a hydroxy group, a cyano group, a nitro group, a C₁₋₆ alkyl group optionally substituted with the substituent B, a C₁₋₆ haloalkyl group, a C₃₋₈ cycloalkyl group optionally substituted with the substituent B, a C₂₋₆ alkenyl group optionally substituted with substituent B, a C₂₋₆ haloalkenyl group, a C₂₋₆ alkynyl group optionally substituted with substituent B, a C₂₋₆ haloalkynyl group, an optionally substituted C₁₋₆ alkoxy group with substituent B, a C₁₋₆ haloalkoxy group, a C₃₋₈ cycloalkoxy group optionally substituted with substituent B, a C₂₋₆-oxy alkenyl group optionally substituted with substituent B, a C₂₋₆-oxy haloalkenyl group, a C₃₋₆-oxy alkynyl group optionally substituted with substituent B, a C₃₋₆-oxy haloalkynyl group, a R²⁰C (= O) - (where R²⁰ represents a C₁₋ alkyl group , a C₁₋₆ haloalkyl group, a C₃₋₈ cycloalkyl group, a C₁₋₆ alkoxy group, a C₁₋₆ haloalkoxy group, a C₃₋₈ cycloalkoxy group or an R²¹R²²N- (where R²¹ and R²² each represent, of independently, a hydrogen atom, a C₁₋₆ alkyl group optionally substituted with the substituent B¹, a C₁₋₆ haloalkyl group or a C₃₋₈ or R²¹ and R²² cycloalkyl group in combination with the nitrogen atom to which they are attached form an aziridinyl group, an azetidinyl group, a pyrrolidinyl group, a piperidinyl group, a homopiperidinyl group or an azocanyl group)), an R²⁰C (= O) O- (where R²⁰ is as defined hereinbefore), a 3 to 6 member ring group containing 1 to 2 oxygen atoms, a R²³-L²- (where R²³ represents a C₁₋₆ alkyl group or a C₁₋₆ haloalkyl group and L² is S, SO or SO₂) , an R²¹R²²N- (where R²¹ and R²² are as defined were previously initiated herein), or an R²⁴C (= O) N (R²⁵) - (where R²⁴ represents a hydrogen atom, a C₁₋₆ alkyl group, a C₁₋₆ haloalkyl group, a C₃₋₈ cycloalkyl group , a C₁₋₆ alkoxy group, a C₁₋₆ haloalkoxy group, a C₃₋₈ cycloalkoxy group or an R²¹R²²N- (where R²¹ and R²² are as defined hereinbefore) and R²⁵ represents a hydrogen atom, a C₁₋₆ alkyl group optionally substituted with the substituent B¹, a C₁₋₆ haloalkyl group or a C₃₋₈ cycloalkyl group); R³ represents a hydrogen atom, a halogen atom, a nitro group, a C₁₋₆ alkyl group optionally substituted with the C substituent, a C₁₋₆ haloalkyl group, a C₃₋₈ cycloalkyl group optionally substituted with the C substituent, a C₁₋₆ alkoxy group optionally substituted with substituent C, a C₁₋₆ haloalkoxy group, a C₂₋₆ alkenyl group optionally substituted with substituent C, a C₂₋₆ haloalkenyl group, a C₂₋₆ alkynyl group optionally substituted with substituent C , a haloalkynyl group C₂₋₆, a R³⁰-L³- (where R³⁰ has the same definition as R²³ and L³ has the same definition as L²), a R³¹R³²N- (where R³¹ and R³² have the same definition as R²¹ and R²² ), or an R³³C (= O) - (where R³³ represents a C₁₋₆ alkyl group, a C₁₋₆ haloalkyl group or a C₃₋₈ cycloalkyl group); n represents an integer from 0 to 5 (provided that when n is 2 or more, the two or more R² represent independent substituents); X represents an oxygen atom or a sulfur atom; And it represents a phenyl group, a pyridyl group, a pyridazinyl group, a pyrimidinyl group, a pyrazinyl group, a triazinyl group, a tetrazinyl group, a thienyl group, a thiazolyl group, an isothiazolyl group or a thiadiazolyl group, the phenyl group is substituted with the substituent D in an ortho position and in addition it is substituted with 0 to 4 independent substituents D¹ appropriately, the pyridyl group, the pyrazinyl group, the pyrimidinyl group, the pyridazinyl group, the triazinyl group or the tetrazinyl group is substituted with substituent D in an ortho position and in addition is substituted with 0 to 3 independent substituents D¹ appropriately, the thienyl group, the thiazolyl group, the isothiazolyl group or the thiadiazolyl group is substituted with the substituent D in an ortho position and is substituted with 0 to 2 independent substituents D¹ appropriately; the link with a dotted line indicates a double bond or a single bond, the substituent A is at least one selected from the group consisting of: a hydroxy group, a cyano group, a C₃₋₈ cycloalkyl group, a C₁₋ alkoxy group ₆, a C₁₋₆ haloalkoxy group, a C₃₋₈ cycloalkoxy group, a R¹²R¹³N- (where R¹² and R¹³ each independently represent a hydrogen atom, a C₁₋₆ alkyl group, a C₁₋ haloalkyl group ₆ or a C₃₋₈ or R¹² and R¹³ cycloalkyl group in combination with the nitrogen atom to which they are attached form an aziridinyl group, an azetidinyl group, a pyrrolidinyl group, a piperidinyl group, a homopiperidinyl group or an azocanyl group) and a R¹⁴-L¹- (where R¹⁴ represents a C₁₋₆ alkyl group or a C₁₋₆ haloalkyl group and L¹ represents S, SO or SO₂); the substituent B is at least one selected from the group consisting of: a hydroxy group, a cyano group, a C₃₋₈ cycloalkyl group, a C₁₋₆ alkoxy group, a C₁₋₆ haloalkoxy group, a C₃₋₈ cycloalkoxy group, an alkoxyalkoxy group C₂₋₆, an R²¹R²²N- (where R²¹ and R²² are as defined hereinbefore), an R²³-L²- (where R²³ and L² are as defined hereinbefore), a R²⁶R²⁷R²⁸Si- (where R²⁶, R²⁷ and R²⁸ each independently represent a C alquilo alkyl group), a R²⁶R²⁷R²⁸Si- (CH₂) ₛ-O- (where s represents an integer from 1 to 3 and R²⁶ , R²⁷ and R²⁸ are as defined hereinbefore), an R²⁰C (= O) - (where R²⁰ is as defined hereinbefore) and a 3 to 6 member ring group containing 1 at 2 oxygen atoms; the substituent B¹ is at least one selected from the group consisting of: a cyano group, a C alco alkoxy group, a C₁₋₆ haloalkoxy group and a C₃₋₈ cycloalkoxy group; the substituent C is at least one selected from the group consisting of: a hydroxy group, a cyano group, a C₃₋₈ cycloalkyl group, a C₁₋₆ alkoxy group, a C₁₋₆ haloalkoxy group, a C₃₋₈ cycloalkoxy group, a R³¹R³²N- (where R³¹ and R³² have the same definition as R²¹ and R²²) and a R³⁰-L³- (where R³⁰ has the same definition as R¹⁴ and L³ has the same definition as L¹); the substituent D is at least one selected from the group consisting of: a halogen atom, a C₁₋₆ alkyl group, a C₁₋₆ haloalkyl group, a C₁₋₆ alkoxy group and a C₁₋₆ haloalkoxy group; and the substituent D¹ is at least one selected from the group consisting of: a hydroxy group, a halogen atom, a C₁₋₆ alkyl group, a C₁₋₆ haloalkyl group, a C₃₋₈ cycloalkyl group, a C₁₋ alkoxy group ₆, a C₁₋₆ haloalkoxy group and a C₃₋₈ cycloalkoxy group.]
Applications Claiming Priority (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
JP2015201578 | 2015-10-09 |
Publications (1)
Publication Number | Publication Date |
---|---|
AR106299A1 true AR106299A1 (en) | 2018-01-03 |
Family
ID=58487878
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
ARP160103080A AR106299A1 (en) | 2015-10-09 | 2016-10-07 | PIRIDONA COMPOUNDS AND AGRICULTURAL AND HERTICAL FUNGICIDES CONTAINING THESE COMPOUNDS AS ACTIVE INGREDIENT |
Country Status (9)
Country | Link |
---|---|
US (1) | US10299477B2 (en) |
EP (1) | EP3360860B1 (en) |
JP (1) | JP6869891B2 (en) |
AR (1) | AR106299A1 (en) |
DK (1) | DK3360860T3 (en) |
ES (1) | ES2916833T3 (en) |
PL (1) | PL3360860T3 (en) |
TW (1) | TWI701238B (en) |
WO (1) | WO2017061525A1 (en) |
Families Citing this family (21)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
JP7256509B2 (en) * | 2016-08-22 | 2023-04-12 | エルゴン ファーマシューティカルズ エルエルシー | Compositions and methods of treatment using BCAT1 inhibitors |
EP3575286B1 (en) * | 2017-01-26 | 2022-05-11 | Mitsui Chemicals Agro, Inc. | Pyridone compound and bactericide for agricultural and horticultural use, which uses said compound as active ingredient |
WO2018190349A1 (en) * | 2017-04-10 | 2018-10-18 | 三井化学アグロ株式会社 | Pyridone compound, and agricultural and horticultural fungicide having this as active component |
JP7071962B2 (en) * | 2017-04-10 | 2022-05-19 | 三井化学アグロ株式会社 | Pest control compositions and pest control methods containing pyridone compounds and pest control agents |
WO2018190325A1 (en) * | 2017-04-10 | 2018-10-18 | 三井化学アグロ株式会社 | Wood preservative containing pyridone compound as active component, and use method thereof |
WO2018190321A1 (en) * | 2017-04-10 | 2018-10-18 | 三井化学アグロ株式会社 | Parasitic pest control agent having pyridone compound as active component, and use method thereof |
WO2018190324A1 (en) * | 2017-04-10 | 2018-10-18 | 三井化学アグロ株式会社 | Antifungal agent containing pyridone compound as active component, and use method thereof |
JP7168556B2 (en) * | 2017-04-10 | 2022-11-09 | 三井化学アグロ株式会社 | Pyridone compound and agricultural and horticultural fungicide containing it as an active ingredient |
JP2020121925A (en) * | 2017-04-10 | 2020-08-13 | 三井化学アグロ株式会社 | Pest control composition containing pyridone compound and quinoline-based compound and pest control method, as well as novel quinoline compound |
RU2765748C2 (en) * | 2017-04-11 | 2022-02-02 | Мицуи Кемикалз Агро, Инк. | Pyridones and agricultural and garden fungicides containing them as active ingredients |
JP7110190B2 (en) * | 2017-06-07 | 2022-08-01 | 三井化学アグロ株式会社 | Nitrogen-containing heterocyclic compound and agricultural and horticultural fungicide containing it as an active ingredient |
JP7153645B2 (en) * | 2017-06-08 | 2022-10-14 | 三井化学アグロ株式会社 | Pyridone compound and agricultural and horticultural fungicide containing it as an active ingredient |
US11117863B2 (en) | 2017-06-08 | 2021-09-14 | Mitsui Chemicals Agro, Inc. | Pyridone compounds and agricultural and horticultural fungicides containing the same as active ingredients |
WO2019059161A1 (en) * | 2017-09-20 | 2019-03-28 | 三井化学アグロ株式会社 | Pyridone compound and agricultural and horticultural germicide having same as active ingredient |
CN107721834B (en) * | 2017-10-23 | 2021-02-12 | 青岛润农化工有限公司 | Preparation method of 1- (4-chlorphenyl) -2-cyclopropyl-1-acetone |
JP7328222B2 (en) | 2018-07-24 | 2023-08-16 | 三井化学クロップ&ライフソリューション株式会社 | Pyridone compound and agricultural and horticultural fungicide containing it as an active ingredient |
EP3828177B1 (en) | 2018-07-25 | 2023-11-29 | Mitsui Chemicals Crop & Life Solutions, Inc. | Pyridone compound and agricultural and horticultural fungicide having this as active component |
WO2020075704A1 (en) * | 2018-10-09 | 2020-04-16 | 三井化学アグロ株式会社 | Pyridone compound, and agricultural and horticultural fungicide containing same as active ingredient |
JP7397800B2 (en) | 2018-10-09 | 2023-12-13 | 三井化学クロップ&ライフソリューション株式会社 | Pyridone compounds and agricultural and horticultural fungicides containing them as active ingredients |
CN109735649A (en) * | 2019-01-25 | 2019-05-10 | 河南农业大学 | Corn Zm-APX gene molecule marker, preparation method and the application in the prevention and treatment of curved spore leaf spot |
TW202321229A (en) | 2021-08-18 | 2023-06-01 | 美商富曼西公司 | Fungicidal substituted heterocycles |
Family Cites Families (6)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
EP0308020A3 (en) | 1987-09-18 | 1990-12-05 | Merck & Co. Inc. | 5-(aryl and heteroaryl)-6-(aryl and heteroaryl)-1,2-dihydro-2-oxo 3-pyridinecarboxylic acids and derivatives thereof |
JPH02121970A (en) * | 1988-10-28 | 1990-05-09 | Sumitomo Chem Co Ltd | Acrylic acid derivative, its production, its use and its intermediate |
GB9711753D0 (en) | 1997-06-06 | 1997-08-06 | Merck Sharp & Dohme | Therapeutic agents |
EP1492784A4 (en) * | 2002-03-28 | 2006-03-29 | Merck & Co Inc | Substituted 2,3-diphenyl pyridines |
PE20090142A1 (en) * | 2007-04-11 | 2009-02-19 | Merck & Co Inc | DERIVATIVES OF FURO [2,3-B] PYRIDINE SUBSTITUTED AS MODULATORS OF THE CANABINOID-1 RECEPTOR |
WO2010093595A1 (en) * | 2009-02-10 | 2010-08-19 | E. I. Du Pont De Nemours And Company | Fungicidal 2-pyridones |
-
2016
- 2016-10-06 EP EP16853679.5A patent/EP3360860B1/en active Active
- 2016-10-06 JP JP2017544213A patent/JP6869891B2/en active Active
- 2016-10-06 PL PL16853679.5T patent/PL3360860T3/en unknown
- 2016-10-06 WO PCT/JP2016/079723 patent/WO2017061525A1/en active Application Filing
- 2016-10-06 ES ES16853679T patent/ES2916833T3/en active Active
- 2016-10-06 US US15/765,809 patent/US10299477B2/en active Active
- 2016-10-06 DK DK16853679.5T patent/DK3360860T3/en active
- 2016-10-07 TW TW105132468A patent/TWI701238B/en active
- 2016-10-07 AR ARP160103080A patent/AR106299A1/en active IP Right Grant
Also Published As
Publication number | Publication date |
---|---|
EP3360860A4 (en) | 2019-06-05 |
US10299477B2 (en) | 2019-05-28 |
WO2017061525A1 (en) | 2017-04-13 |
DK3360860T3 (en) | 2022-06-20 |
JP6869891B2 (en) | 2021-05-12 |
TWI701238B (en) | 2020-08-11 |
TW201718494A (en) | 2017-06-01 |
EP3360860B1 (en) | 2022-05-18 |
ES2916833T3 (en) | 2022-07-06 |
US20180279614A1 (en) | 2018-10-04 |
PL3360860T3 (en) | 2022-09-26 |
EP3360860A1 (en) | 2018-08-15 |
JPWO2017061525A1 (en) | 2018-08-16 |
Similar Documents
Publication | Publication Date | Title |
---|---|---|
AR106299A1 (en) | PIRIDONA COMPOUNDS AND AGRICULTURAL AND HERTICAL FUNGICIDES CONTAINING THESE COMPOUNDS AS ACTIVE INGREDIENT | |
AR113905A1 (en) | HERBICIDE PHENYLETERS | |
AR097633A1 (en) | PESTICIDES OF BICYCLIC AZOL REPLACED WITH HETEROCICLES | |
AR111776A1 (en) | HETEROARILOS INHIBITORS OF THE RUT MUTANT PROTEINS OF G12C | |
AR126406A2 (en) | TETRAZOLINONE COMPOUNDS AND THEIR USE | |
AR088989A1 (en) | BICYCLE DERIVATIVES OF DIHYDROISOQUINOLIN-1-ONA | |
AR101495A1 (en) | CONDENSED COMPOUNDS OF 11 AGRICULTURAL / Horticultural MEMBERS AND FUNGICIDES CONTAINING THEM | |
AR103546A1 (en) | BIPIRIDINE COMPOUNDS AND THEIR USE TO CONTROL HARMFUL ARTHROPODS | |
AR094684A1 (en) | MODIFIED C-19 TRITERPENOIDS, WITH INHIBITING ACTIVITY OF HIV MATURATION | |
AR088872A1 (en) | URACILO DERIVATIVES AS INHIBITORS OF THE AXL AND C-MET KINASE | |
AR110053A2 (en) | MODULATION OF CHEMIOSENSORY AND LIGAND RECEIVERS RELATED TO THEMSELVES | |
AR098475A1 (en) | PESTICIDE COMPOUNDS AND USES | |
AR086829A1 (en) | FUSIONED HETEROCICLICAL COMPOUNDS AS IONIC CHANNEL MODULATORS | |
AR099831A1 (en) | INHIBITORS OF AZAQUINAZOLINE PROTEIN KINASA C ATÍPICA | |
AR110227A2 (en) | PIRAZOL DERIVATIVES WITH ACTION ON FGF | |
AR098492A1 (en) | PURINA DERIVATIVES | |
AR094629A1 (en) | HERBICIDE AZINAS | |
AR109304A1 (en) | OXADIAZOL COMPOUND AND ITS USE | |
AR091261A1 (en) | DERIVATIVES OF 1-PHENYL-2-PYRIDINYL ALKYL ALCOHOLS AS INHIBITORS OF PHOSPHODIESTERASE | |
AR097998A1 (en) | PESTICIDED COMPOUNDS | |
AR107588A1 (en) | IMIDAZOLIL-CARBOXAMIDES REPLACED AS PESTICIDES | |
AR117185A1 (en) | N- (1,3,4-OXADIAZOL-2-IL) ARYLCARBOXAMIDES OR THEIR SALTS, PREPARATION METHODS, HERBICIDE COMPOSITIONS AND USES OF THEM | |
BR112014018875A8 (en) | ARYLOXYACETAMIDE COMPOUND OR SALT THEREOF, PESTICIDE, ACACICIDE OR INSECTICIDE, AND ECTOPARASITES CONTROL AGENT | |
AR110283A1 (en) | CYCLIC DINUCLEOTIDE | |
AR116754A1 (en) | PHENYLPYRAZOLE COMPOUND AND METHOD TO CONTROL PHYTO DISEASES |
Legal Events
Date | Code | Title | Description |
---|---|---|---|
FG | Grant, registration |