AR099378A1 - PROCEDURE FOR PREPARATION OF A CONFORMED ADSORBENT MATERIAL THAT INCLUDES A CONFORMATION STAGE IN THE PRESENCE OF A MINERAL BINDER, AND PROCEDURE FOR EXTRACTION OF LITHIUM FROM SALIN SOLUTIONS USING SUCH MATERIAL - Google Patents

PROCEDURE FOR PREPARATION OF A CONFORMED ADSORBENT MATERIAL THAT INCLUDES A CONFORMATION STAGE IN THE PRESENCE OF A MINERAL BINDER, AND PROCEDURE FOR EXTRACTION OF LITHIUM FROM SALIN SOLUTIONS USING SUCH MATERIAL

Info

Publication number
AR099378A1
AR099378A1 ARP140104892A ARP140104892A AR099378A1 AR 099378 A1 AR099378 A1 AR 099378A1 AR P140104892 A ARP140104892 A AR P140104892A AR P140104892 A ARP140104892 A AR P140104892A AR 099378 A1 AR099378 A1 AR 099378A1
Authority
AR
Argentina
Prior art keywords
procedure
lithium
stage
conformed
salin
Prior art date
Application number
ARP140104892A
Other languages
Spanish (es)
Inventor
Boualleg Malika
Charles Joseph Ren Soulairol Romain
Andr Pierre Burdet Fabien
Original Assignee
Eramet
Ifp Energies Now
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Eramet, Ifp Energies Now filed Critical Eramet
Publication of AR099378A1 publication Critical patent/AR099378A1/en

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01D—COMPOUNDS OF ALKALI METALS, i.e. LITHIUM, SODIUM, POTASSIUM, RUBIDIUM, CAESIUM, OR FRANCIUM
    • C01D15/00—Lithium compounds
    • C01D15/04—Halides
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J20/00—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof
    • B01J20/02—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof comprising inorganic material
    • B01J20/04—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof comprising inorganic material comprising compounds of alkali metals, alkaline earth metals or magnesium
    • B01J20/046—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof comprising inorganic material comprising compounds of alkali metals, alkaline earth metals or magnesium containing halogens, e.g. halides
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J20/00—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof
    • B01J20/02—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof comprising inorganic material
    • B01J20/06—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof comprising inorganic material comprising oxides or hydroxides of metals not provided for in group B01J20/04
    • B01J20/08—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof comprising inorganic material comprising oxides or hydroxides of metals not provided for in group B01J20/04 comprising aluminium oxide or hydroxide; comprising bauxite
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J20/00—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof
    • B01J20/30—Processes for preparing, regenerating, or reactivating
    • B01J20/3007—Moulding, shaping or extruding
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J20/00—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof
    • B01J20/30—Processes for preparing, regenerating, or reactivating
    • B01J20/3078—Thermal treatment, e.g. calcining or pyrolizing
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J20/00—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof
    • B01J20/30—Processes for preparing, regenerating, or reactivating
    • B01J20/3085—Chemical treatments not covered by groups B01J20/3007 - B01J20/3078
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01F—COMPOUNDS OF THE METALS BERYLLIUM, MAGNESIUM, ALUMINIUM, CALCIUM, STRONTIUM, BARIUM, RADIUM, THORIUM, OR OF THE RARE-EARTH METALS
    • C01F7/00—Compounds of aluminium
    • C01F7/02—Aluminium oxide; Aluminium hydroxide; Aluminates
    • C01F7/04—Preparation of alkali metal aluminates; Aluminium oxide or hydroxide therefrom
    • C01F7/043—Lithium aluminates
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2220/00—Aspects relating to sorbent materials
    • B01J2220/50—Aspects relating to the use of sorbent or filter aid materials
    • B01J2220/58—Use in a single column
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01P—INDEXING SCHEME RELATING TO STRUCTURAL AND PHYSICAL ASPECTS OF SOLID INORGANIC COMPOUNDS
    • C01P2002/00—Crystal-structural characteristics
    • C01P2002/70—Crystal-structural characteristics defined by measured X-ray, neutron or electron diffraction data
    • C01P2002/72—Crystal-structural characteristics defined by measured X-ray, neutron or electron diffraction data by d-values or two theta-values, e.g. as X-ray diagram
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01P—INDEXING SCHEME RELATING TO STRUCTURAL AND PHYSICAL ASPECTS OF SOLID INORGANIC COMPOUNDS
    • C01P2006/00—Physical properties of inorganic compounds
    • C01P2006/12—Surface area

Landscapes

  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Analytical Chemistry (AREA)
  • Inorganic Chemistry (AREA)
  • Materials Engineering (AREA)
  • Engineering & Computer Science (AREA)
  • Physics & Mathematics (AREA)
  • Thermal Sciences (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Geology (AREA)
  • Solid-Sorbent Or Filter-Aiding Compositions (AREA)
  • Nitrogen And Oxygen Or Sulfur-Condensed Heterocyclic Ring Systems (AREA)

Abstract

Se describe un procedimiento de preparación de un material sólido cristalizado de fórmula LiCl.2Al(OH)₃,nH₂O con n que está comprendido entre 0,01 y 10, que comprende a) una etapa de mezcla, en medio acuoso, de al menos una fuente de alúmina y de, al menos, una fuente de litio, para obtener una suspensión, b) una etapa de filtración de la suspensión obtenida en la etapa a) para obtener una pasta, c) una etapa de secado de la pasta obtenida como resultado de la etapa b), a una temperatura comprendida entre 20 y 80ºC durante un lapso comprendido entre 1 h y 12 h, d) una etapa de conformado por amasado-extrusión de dicha pasta secada, en presencia de, al menos, un precursor sólido de alúmina y de, al menos, un ácido en solución en proporciones tales que la relación molar ácido/Al está comprendida entre 0,01 y 1,2, para obtener extruidos, y e) el secado de los extruidos obtenidos como resultado de la etapa d) a una temperatura comprendida entre 20 y 200ºC durante un lapso comprendido entre 1 y 20 horas, para obtener el material sólido cristalizado de fórmula LiCl.2Al(OH)₃,nH₂O en forma de extruidos. La presente se refiere también a un procedimiento de extracción de litio a partir de soluciones salinas que utilizan el material así preparado .También se refiere a un material sólido cristalizado de fórmula LiCl.2Al(OH)₃,nH₂O con n que está comprendido entre 0,01 y 10, conformado. La solicitud se refiere también a un dispositivo que emplea el procedimiento de extracción de litio.A process for preparing a crystallized solid material of the formula LiCl.2Al (OH) ₃, nH₂O with n is comprised between 0.01 and 10, comprising a) a mixing step, in aqueous medium, of at least a source of alumina and at least one source of lithium, to obtain a suspension, b) a filtration stage of the suspension obtained in stage a) to obtain a paste, c) a stage of drying the obtained paste as a result of step b), at a temperature between 20 and 80 ° C for a period between 1 h and 12 h, d) a stage of kneading-extrusion of said dried paste, in the presence of at least one precursor alumina solid and at least one acid in solution in proportions such that the acid / Al molar ratio is between 0.01 and 1.2, to obtain extrudates, and e) drying of the extrudates obtained as a result of the step d) at a temperature between 20 and 200 ° C for one l from 1 to 20 hours, to obtain the crystallized solid material of the formula LiCl.2Al (OH) ₃, nH₂O in the form of extrudates. This also refers to a process of extracting lithium from saline solutions using the material so prepared. It also refers to a crystallized solid material of formula LiCl. 2 Al (OH) ₃, nH₂O with n which is between 0 , 01 and 10, conformed. The application also refers to a device that uses the lithium extraction procedure.

ARP140104892A 2013-12-23 2014-12-23 PROCEDURE FOR PREPARATION OF A CONFORMED ADSORBENT MATERIAL THAT INCLUDES A CONFORMATION STAGE IN THE PRESENCE OF A MINERAL BINDER, AND PROCEDURE FOR EXTRACTION OF LITHIUM FROM SALIN SOLUTIONS USING SUCH MATERIAL AR099378A1 (en)

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
FR1363497A FR3015458A1 (en) 2013-12-23 2013-12-23 PROCESS FOR THE PREPARATION OF A SHAPED ADSORBENT MATERIAL COMPRISING A SHAPING STEP IN THE PRESENCE OF A MINERAL BINDER AND METHOD OF EXTRACTING LITHIUM FROM SALINE SOLUTIONS USING THE MATERIAL

Publications (1)

Publication Number Publication Date
AR099378A1 true AR099378A1 (en) 2016-07-20

Family

ID=50483058

Family Applications (1)

Application Number Title Priority Date Filing Date
ARP140104892A AR099378A1 (en) 2013-12-23 2014-12-23 PROCEDURE FOR PREPARATION OF A CONFORMED ADSORBENT MATERIAL THAT INCLUDES A CONFORMATION STAGE IN THE PRESENCE OF A MINERAL BINDER, AND PROCEDURE FOR EXTRACTION OF LITHIUM FROM SALIN SOLUTIONS USING SUCH MATERIAL

Country Status (3)

Country Link
AR (1) AR099378A1 (en)
FR (1) FR3015458A1 (en)
WO (1) WO2015097205A1 (en)

Families Citing this family (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
FR3044002B1 (en) * 2015-11-24 2017-12-29 Eramet PROCESS FOR THE PREPARATION OF AN ADSORBENT MATERIAL BASED ON THE BASIC MIXING OF A DRIED DRY POWDER OR OVEN OR BY ATOMIZATION AND METHOD OF EXTRACTING LITHIUM
FR3044001B1 (en) * 2015-11-24 2017-12-29 Eramet PROCESS FOR PREPARING AN ADSORBENT MATERIAL COMPRISING A BASIC MIXING STEP AND METHOD OF EXTRACTING LITHIUM FROM SALINE SOLUTIONS USING THE SAME
FR3051787B1 (en) * 2016-05-25 2022-07-08 Eramet METHOD FOR PREPARING AN ADSORBENT MATERIAL AND METHOD FOR EXTRACTION OF LITHIUM USING SAID MATERIAL
FR3053264B1 (en) * 2016-06-30 2022-07-29 Eramet METHOD FOR PREPARING AN ADSORBENT MATERIAL AND METHOD FOR EXTRACTING LITHIUM FROM SALINE SOLUTIONS USING SAID MATERIAL

Family Cites Families (7)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
WO1994019280A1 (en) * 1993-02-16 1994-09-01 Nauchno-Proizvodstvennoe Aktsionernoe Obschestvo 'ekostar' Process for obtaining lithium chloride from solutions and a device for carrying out the same
US5599516A (en) 1993-05-24 1997-02-04 Fmc Corporation Recovery of lithium values from brines
CN1243112A (en) 1999-08-23 2000-02-02 李凤杰 Multielement synergistic nitrogen fertilizer additive and preparation process thereof
WO2003041857A1 (en) * 2001-10-25 2003-05-22 Eurosina Technology Consulting & Project Development Gmbh Method for producing granulated sorbents and installation for carrying out the method
RU2234367C1 (en) * 2002-12-15 2004-08-20 Закрытое акционерное общество "Экостар-Наутех" Method of production of a sorbent for extraction of lithium from saline solutions
JP5700338B2 (en) * 2009-11-10 2015-04-15 公益財団法人北九州産業学術推進機構 Lithium adsorbent production method, lithium concentration method, and lithium concentration apparatus
CN101829538B (en) * 2010-05-19 2013-06-26 浙江海虹控股集团有限公司 Preparation method of high-performance lithium adsorbent

Also Published As

Publication number Publication date
WO2015097205A1 (en) 2015-07-02
FR3015458A1 (en) 2015-06-26

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