AR098941A1 - PROCEDURE FOR PREPARATION OF AN ADSORBENT MATERIAL, CONFORMED BY PRECIPITATION OF ALUMINUM SULFATE, AND OF SODIUM ALUMINATE, AND PROCEDURE OF EXTRACTION OF LITHIUM USING SUCH MATERIAL - Google Patents

PROCEDURE FOR PREPARATION OF AN ADSORBENT MATERIAL, CONFORMED BY PRECIPITATION OF ALUMINUM SULFATE, AND OF SODIUM ALUMINATE, AND PROCEDURE OF EXTRACTION OF LITHIUM USING SUCH MATERIAL

Info

Publication number
AR098941A1
AR098941A1 ARP140104888A ARP140104888A AR098941A1 AR 098941 A1 AR098941 A1 AR 098941A1 AR P140104888 A ARP140104888 A AR P140104888A AR P140104888 A ARP140104888 A AR P140104888A AR 098941 A1 AR098941 A1 AR 098941A1
Authority
AR
Argentina
Prior art keywords
procedure
lithium
stage
aluminum sulfate
sodium aluminate
Prior art date
Application number
ARP140104888A
Other languages
Spanish (es)
Inventor
Boualleg Malika
Lafon Olivier
Andr Pierre Burdet Fabien
Charles Joseph Ren Soulairol Romain
Original Assignee
Eramet
Ifp Energies Now
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Eramet, Ifp Energies Now filed Critical Eramet
Publication of AR098941A1 publication Critical patent/AR098941A1/en

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01D—COMPOUNDS OF ALKALI METALS, i.e. LITHIUM, SODIUM, POTASSIUM, RUBIDIUM, CAESIUM, OR FRANCIUM
    • C01D15/00—Lithium compounds
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J20/00—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof
    • B01J20/02—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof comprising inorganic material
    • B01J20/04—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof comprising inorganic material comprising compounds of alkali metals, alkaline earth metals or magnesium
    • B01J20/045—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof comprising inorganic material comprising compounds of alkali metals, alkaline earth metals or magnesium containing sulfur, e.g. sulfates, thiosulfates, gypsum
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J20/00—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof
    • B01J20/02—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof comprising inorganic material
    • B01J20/06—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof comprising inorganic material comprising oxides or hydroxides of metals not provided for in group B01J20/04
    • B01J20/08—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof comprising inorganic material comprising oxides or hydroxides of metals not provided for in group B01J20/04 comprising aluminium oxide or hydroxide; comprising bauxite
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J20/00—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof
    • B01J20/30—Processes for preparing, regenerating, or reactivating
    • B01J20/3007—Moulding, shaping or extruding
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J20/00—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof
    • B01J20/30—Processes for preparing, regenerating, or reactivating
    • B01J20/3042—Use of binding agents; addition of materials ameliorating the mechanical properties of the produced sorbent
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J20/00—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof
    • B01J20/30—Processes for preparing, regenerating, or reactivating
    • B01J20/3078—Thermal treatment, e.g. calcining or pyrolizing
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01D—COMPOUNDS OF ALKALI METALS, i.e. LITHIUM, SODIUM, POTASSIUM, RUBIDIUM, CAESIUM, OR FRANCIUM
    • C01D15/00—Lithium compounds
    • C01D15/02—Oxides; Hydroxides
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01D—COMPOUNDS OF ALKALI METALS, i.e. LITHIUM, SODIUM, POTASSIUM, RUBIDIUM, CAESIUM, OR FRANCIUM
    • C01D15/00—Lithium compounds
    • C01D15/06—Sulfates; Sulfites
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01F—COMPOUNDS OF THE METALS BERYLLIUM, MAGNESIUM, ALUMINIUM, CALCIUM, STRONTIUM, BARIUM, RADIUM, THORIUM, OR OF THE RARE-EARTH METALS
    • C01F7/00—Compounds of aluminium
    • C01F7/02—Aluminium oxide; Aluminium hydroxide; Aluminates
    • C01F7/04—Preparation of alkali metal aluminates; Aluminium oxide or hydroxide therefrom
    • C01F7/043—Lithium aluminates
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2220/00—Aspects relating to sorbent materials
    • B01J2220/50—Aspects relating to the use of sorbent or filter aid materials
    • B01J2220/58—Use in a single column
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01P—INDEXING SCHEME RELATING TO STRUCTURAL AND PHYSICAL ASPECTS OF SOLID INORGANIC COMPOUNDS
    • C01P2002/00—Crystal-structural characteristics
    • C01P2002/70—Crystal-structural characteristics defined by measured X-ray, neutron or electron diffraction data
    • C01P2002/72—Crystal-structural characteristics defined by measured X-ray, neutron or electron diffraction data by d-values or two theta-values, e.g. as X-ray diagram
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01P—INDEXING SCHEME RELATING TO STRUCTURAL AND PHYSICAL ASPECTS OF SOLID INORGANIC COMPOUNDS
    • C01P2006/00—Physical properties of inorganic compounds
    • C01P2006/12—Surface area

Landscapes

  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Inorganic Chemistry (AREA)
  • Analytical Chemistry (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Physics & Mathematics (AREA)
  • Thermal Sciences (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Geology (AREA)
  • Solid-Sorbent Or Filter-Aiding Compositions (AREA)

Abstract

Se describe un procedimiento de preparación de un material sólido cristalizado de fórmula Li₂SO₄.4AI(OH)₃,nH₂O con n que está comprendido entre 0,01 y 10, donde dicho procedimiento comprende al menos las etapas siguientes: a) una etapa de precipitación, en medio acuoso, de sulfato de aluminio y de aluminato de sodio y de, al menos, una fuente de litio, para obtener una suspensión, b) una etapa de filtración de la suspensión obtenida en la etapa a) para obtener una pasta, y a dicha etapa de filtración sigue, al menos. una etapa de lavado de Ia pasta obtenida, c) una etapa de secado de la pasta obtenida como resultado de la etapa b), d) una etapa de conformado por extrusión de dicha pasta secada para obtener extruídos. y e) el secado de los extruídos obtenidos a una temperatura comprendida entre 20 y 200ºC durante un lapso comprendido entre 1 hora y 20 horas, para obtener dicho material sólido cristalizado en forma de extruídos. La presente se refiere también a un procedimiento de extracción de litio a partir de soluciones salinas que utilizan el material así obtenido. La presente se refiere a un material sólido cristalizado de fórmula Li₂SO₄.4AI(OH)₃,nH₂O con n que está comprendido entre 0,01 y 10, conformado. La presente se refiere también a un dispositivo que emplea el procedimiento de extracción de litio.A process for preparing a crystallized solid material of the formula Li₂SO₄.4AI (OH) ₃, nH₂O is described with n which is between 0.01 and 10, wherein said process comprises at least the following steps: a) a precipitation step , in aqueous medium, of aluminum sulfate and sodium aluminate and of at least one source of lithium, to obtain a suspension, b) a filtration stage of the suspension obtained in stage a) to obtain a paste, and said filtration stage continues at least. a stage of washing the pulp obtained, c) a stage of drying the pulp obtained as a result of step b), d) a step of forming by extrusion of said dried pulp to obtain extrudates. and e) drying the extrudates obtained at a temperature between 20 and 200 ° C for a period between 1 hour and 20 hours, to obtain said crystallized solid material in the form of extrudates. This also refers to a process of extracting lithium from saline solutions using the material thus obtained. This refers to a crystallized solid material of the formula Li₂SO₄.4AI (OH) ₃, nH₂O with n which is comprised between 0.01 and 10, formed. This also refers to a device that uses the lithium extraction procedure.

ARP140104888A 2013-12-23 2014-12-23 PROCEDURE FOR PREPARATION OF AN ADSORBENT MATERIAL, CONFORMED BY PRECIPITATION OF ALUMINUM SULFATE, AND OF SODIUM ALUMINATE, AND PROCEDURE OF EXTRACTION OF LITHIUM USING SUCH MATERIAL AR098941A1 (en)

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
FR1363460A FR3015459A1 (en) 2013-12-23 2013-12-23 PROCESS FOR PREPARING ADSORBENT MATERIAL, SHAPED BY PRECIPITATION OF ALUMINUM SULFATE AND SODIUM ALUMINATE, AND LITHIUM EXTRACTION METHOD USING THE SAME

Publications (1)

Publication Number Publication Date
AR098941A1 true AR098941A1 (en) 2016-06-22

Family

ID=50290057

Family Applications (1)

Application Number Title Priority Date Filing Date
ARP140104888A AR098941A1 (en) 2013-12-23 2014-12-23 PROCEDURE FOR PREPARATION OF AN ADSORBENT MATERIAL, CONFORMED BY PRECIPITATION OF ALUMINUM SULFATE, AND OF SODIUM ALUMINATE, AND PROCEDURE OF EXTRACTION OF LITHIUM USING SUCH MATERIAL

Country Status (3)

Country Link
AR (1) AR098941A1 (en)
FR (1) FR3015459A1 (en)
WO (1) WO2015097201A1 (en)

Families Citing this family (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
WO2020219625A1 (en) 2019-04-25 2020-10-29 Saint-Gobain Ceramics & Plastics, Inc. Adsorbent particles and methods of forming thereof
CN112808226B (en) * 2020-12-18 2022-11-15 湖南邦普循环科技有限公司 Aluminum-based lithium ion sieve and preparation method and application thereof
CN117000199B (en) * 2023-09-04 2024-04-12 四川泛宇锂能新材料科技有限公司 High sulfate radical resistant double-doped aluminum-based lithium adsorbent and preparation method thereof

Family Cites Families (9)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US2964381A (en) * 1957-01-29 1960-12-13 Dow Chemical Co Recovery of lithium
US4348297A (en) * 1979-11-19 1982-09-07 The Dow Chemical Company Crystalline lithium aluminates
EP0103034A1 (en) * 1982-09-09 1984-03-21 The Dow Chemical Company Crystalline lithium aluminates and a process for the preparation thereof
WO1994019280A1 (en) * 1993-02-16 1994-09-01 Nauchno-Proizvodstvennoe Aktsionernoe Obschestvo 'ekostar' Process for obtaining lithium chloride from solutions and a device for carrying out the same
US5599516A (en) 1993-05-24 1997-02-04 Fmc Corporation Recovery of lithium values from brines
CN1243112A (en) 1999-08-23 2000-02-02 李凤杰 Multielement synergistic nitrogen fertilizer additive and preparation process thereof
RU2234367C1 (en) 2002-12-15 2004-08-20 Закрытое акционерное общество "Экостар-Наутех" Method of production of a sorbent for extraction of lithium from saline solutions
EP2200941A4 (en) * 2007-09-17 2013-12-25 Areva Fed Services Llc A process for removal of aluminum oxides from aqueous media
CN101829538B (en) * 2010-05-19 2013-06-26 浙江海虹控股集团有限公司 Preparation method of high-performance lithium adsorbent

Also Published As

Publication number Publication date
WO2015097201A1 (en) 2015-07-02
FR3015459A1 (en) 2015-06-26

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