AR098943A1 - MATERIAL AND PROCEDURE FOR PREPARING AN ADSORBENT MATERIAL IN THE FORM OF EXTRUDED IN THE PRESENCE OF AN ORGANIC BINDER, AND PROCEDURE FOR EXTRACTION OF LITHIUM FROM SALIN SOLUTIONS USING SUCH MATERIAL - Google Patents

MATERIAL AND PROCEDURE FOR PREPARING AN ADSORBENT MATERIAL IN THE FORM OF EXTRUDED IN THE PRESENCE OF AN ORGANIC BINDER, AND PROCEDURE FOR EXTRACTION OF LITHIUM FROM SALIN SOLUTIONS USING SUCH MATERIAL

Info

Publication number
AR098943A1
AR098943A1 ARP140104890A ARP140104890A AR098943A1 AR 098943 A1 AR098943 A1 AR 098943A1 AR P140104890 A ARP140104890 A AR P140104890A AR P140104890 A ARP140104890 A AR P140104890A AR 098943 A1 AR098943 A1 AR 098943A1
Authority
AR
Argentina
Prior art keywords
procedure
lithium
stage
preparing
organic binder
Prior art date
Application number
ARP140104890A
Other languages
Spanish (es)
Inventor
Andr Pierre Burdet Fabien
Charles Joseph Ren Soulairol Romain
Boualleg Malika
Lafon Olivier
Original Assignee
Eramet
Ifp Energies Now
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Eramet, Ifp Energies Now filed Critical Eramet
Publication of AR098943A1 publication Critical patent/AR098943A1/en

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01D—COMPOUNDS OF ALKALI METALS, i.e. LITHIUM, SODIUM, POTASSIUM, RUBIDIUM, CAESIUM, OR FRANCIUM
    • C01D15/00—Lithium compounds
    • C01D15/04—Halides
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J20/00—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof
    • B01J20/02—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof comprising inorganic material
    • B01J20/04—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof comprising inorganic material comprising compounds of alkali metals, alkaline earth metals or magnesium
    • B01J20/046—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof comprising inorganic material comprising compounds of alkali metals, alkaline earth metals or magnesium containing halogens, e.g. halides
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J20/00—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof
    • B01J20/02—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof comprising inorganic material
    • B01J20/06—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof comprising inorganic material comprising oxides or hydroxides of metals not provided for in group B01J20/04
    • B01J20/08—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof comprising inorganic material comprising oxides or hydroxides of metals not provided for in group B01J20/04 comprising aluminium oxide or hydroxide; comprising bauxite
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J20/00—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof
    • B01J20/30—Processes for preparing, regenerating, or reactivating
    • B01J20/3007—Moulding, shaping or extruding
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J20/00—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof
    • B01J20/30—Processes for preparing, regenerating, or reactivating
    • B01J20/3042—Use of binding agents; addition of materials ameliorating the mechanical properties of the produced sorbent
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J20/00—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof
    • B01J20/30—Processes for preparing, regenerating, or reactivating
    • B01J20/3078—Thermal treatment, e.g. calcining or pyrolizing
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J20/00—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof
    • B01J20/30—Processes for preparing, regenerating, or reactivating
    • B01J20/3085—Chemical treatments not covered by groups B01J20/3007 - B01J20/3078
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01F—COMPOUNDS OF THE METALS BERYLLIUM, MAGNESIUM, ALUMINIUM, CALCIUM, STRONTIUM, BARIUM, RADIUM, THORIUM, OR OF THE RARE-EARTH METALS
    • C01F7/00—Compounds of aluminium
    • C01F7/02—Aluminium oxide; Aluminium hydroxide; Aluminates
    • C01F7/04—Preparation of alkali metal aluminates; Aluminium oxide or hydroxide therefrom
    • C01F7/043—Lithium aluminates
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2220/00—Aspects relating to sorbent materials
    • B01J2220/50—Aspects relating to the use of sorbent or filter aid materials
    • B01J2220/58—Use in a single column
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01P—INDEXING SCHEME RELATING TO STRUCTURAL AND PHYSICAL ASPECTS OF SOLID INORGANIC COMPOUNDS
    • C01P2002/00—Crystal-structural characteristics
    • C01P2002/70—Crystal-structural characteristics defined by measured X-ray, neutron or electron diffraction data
    • C01P2002/72—Crystal-structural characteristics defined by measured X-ray, neutron or electron diffraction data by d-values or two theta-values, e.g. as X-ray diagram
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01P—INDEXING SCHEME RELATING TO STRUCTURAL AND PHYSICAL ASPECTS OF SOLID INORGANIC COMPOUNDS
    • C01P2006/00—Physical properties of inorganic compounds
    • C01P2006/12—Surface area

Landscapes

  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Analytical Chemistry (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Inorganic Chemistry (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Geology (AREA)
  • Physics & Mathematics (AREA)
  • Thermal Sciences (AREA)
  • Solid-Sorbent Or Filter-Aiding Compositions (AREA)
  • Inorganic Compounds Of Heavy Metals (AREA)
  • Glass Compositions (AREA)

Abstract

Se describe un procedimiento de preparación de un material sólido cristalizado de fórmula LiCl.2AI(OH)₃,nH₂O con n que está comprendido entre 0,01 y 10, donde dicho procedimiento comprende al menos las etapas siguientes: a) una etapa de mezcla, en medio acuoso, de al menos una fuente de alúmina y de, al menos, una fuente de litio, para obtener una suspensión, b) una etapa de filtración de la suspensión obtenida en la etapa a) para obtener una pasta, c) una etapa de secado de la pasta obtenida como resultado de la etapa b), a una temperatura comprendida entre 20 y 80ºC durante un lapso comprendido entre 1 h y 12 h, d) una etapa de conformado por amasado-extrusión de dicha pasta secada, en presencia de, al menos, un aglutinante orgánico, y sin adición de ácido ni de base a la pasta secada introducida en dicha etapa d), para obtener extruídos, y e) el secado de los extruídos obtenidos como resultado de la etapa d) a una temperatura comprendida entre 20 y 200ºC durante un lapso comprendido entre 1 hora y 20 horas, para obtener el material sólido cristalizado de fórmula LiCl.2AI(OH)₃,nH₂O en forma de extruídos. La presente se refiere también a un procedimiento de extracción de litio a partir de soluciones salinas que utilizan el material así obtenido. La presente se refiere a un material sólido cristalizado de fórmula LiCl.2Al(OH)₃,nH₂O con n que está comprendido entre 0,01 y 10, conformado. La presente se refiere también a un dispositivo que emplea el procedimiento de extracción de litio.A process for preparing a crystallized solid material of the formula LiCl.2AI (OH) ₃, nH₂O with n is comprised between 0.01 and 10, wherein said process comprises at least the following steps: a) a mixing step , in aqueous medium, of at least one source of alumina and of at least one source of lithium, to obtain a suspension, b) a filtration stage of the suspension obtained in stage a) to obtain a paste, c) a stage of drying the paste obtained as a result of stage b), at a temperature between 20 and 80 ° C for a period of between 1 h and 12 h, d) a stage of forming by kneading-extrusion of said dried paste, in presence of at least one organic binder, and without addition of acid or base to the dried paste introduced in said step d), to obtain extrudates, and e) drying of the extrudates obtained as a result of step d) to a temperature between 20 and 200 ° C for a period between 1 hour and 20 hours, to obtain the crystallized solid material of the formula LiCl.2AI (OH) ₃, nH₂O in the form of extrudates. This also refers to a process of extracting lithium from saline solutions using the material thus obtained. This refers to a crystallized solid material of the formula LiCl.2Al (OH) ₃, nH₂O with n which is comprised between 0.01 and 10, formed. This also refers to a device that uses the lithium extraction procedure.

ARP140104890A 2013-12-23 2014-12-23 MATERIAL AND PROCEDURE FOR PREPARING AN ADSORBENT MATERIAL IN THE FORM OF EXTRUDED IN THE PRESENCE OF AN ORGANIC BINDER, AND PROCEDURE FOR EXTRACTION OF LITHIUM FROM SALIN SOLUTIONS USING SUCH MATERIAL AR098943A1 (en)

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
FR1363490A FR3015457A1 (en) 2013-12-23 2013-12-23 MATERIAL AND PROCESS FOR PREPARING ADSORBENT MATERIAL IN THE FORM OF EXTRUDES IN THE PRESENCE OF AN ORGANIC BINDER AND PROCESS FOR EXTRACTING LITHIUM FROM SALINE SOLUTIONS USING SAID MATERIAL

Publications (1)

Publication Number Publication Date
AR098943A1 true AR098943A1 (en) 2016-06-22

Family

ID=50483054

Family Applications (1)

Application Number Title Priority Date Filing Date
ARP140104890A AR098943A1 (en) 2013-12-23 2014-12-23 MATERIAL AND PROCEDURE FOR PREPARING AN ADSORBENT MATERIAL IN THE FORM OF EXTRUDED IN THE PRESENCE OF AN ORGANIC BINDER, AND PROCEDURE FOR EXTRACTION OF LITHIUM FROM SALIN SOLUTIONS USING SUCH MATERIAL

Country Status (3)

Country Link
AR (1) AR098943A1 (en)
FR (1) FR3015457A1 (en)
WO (1) WO2015097204A1 (en)

Families Citing this family (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN118272670A (en) * 2022-12-30 2024-07-02 西安蓝晓科技新材料股份有限公司 Preparation method and application of adsorption unit for lithium recovery

Family Cites Families (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
WO1994019280A1 (en) * 1993-02-16 1994-09-01 Nauchno-Proizvodstvennoe Aktsionernoe Obschestvo 'ekostar' Process for obtaining lithium chloride from solutions and a device for carrying out the same
CN1302844C (en) * 2001-10-25 2007-03-07 华欧技术咨询及企划发展有限公司 Method for producing granulated sorbents and installation for carrying out the method
RU2234367C1 (en) * 2002-12-15 2004-08-20 Закрытое акционерное общество "Экостар-Наутех" Method of production of a sorbent for extraction of lithium from saline solutions
EP2200941A4 (en) * 2007-09-17 2013-12-25 Areva Fed Services Llc A process for removal of aluminum oxides from aqueous media
CN101829538B (en) * 2010-05-19 2013-06-26 浙江海虹控股集团有限公司 Preparation method of high-performance lithium adsorbent

Also Published As

Publication number Publication date
FR3015457A1 (en) 2015-06-26
WO2015097204A1 (en) 2015-07-02

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