AR037030A1 - Sintesis de hidrocarburos en suspension con hidroisomerizacion de liquidos en el reactor de sintesis - Google Patents

Sintesis de hidrocarburos en suspension con hidroisomerizacion de liquidos en el reactor de sintesis

Info

Publication number
AR037030A1
AR037030A1 ARP020104059A ARP020104059A AR037030A1 AR 037030 A1 AR037030 A1 AR 037030A1 AR P020104059 A ARP020104059 A AR P020104059A AR P020104059 A ARP020104059 A AR P020104059A AR 037030 A1 AR037030 A1 AR 037030A1
Authority
AR
Argentina
Prior art keywords
suspension
synthesis
reactor
hydroisomerization
hydrocarbons
Prior art date
Application number
ARP020104059A
Other languages
English (en)
Original Assignee
Exxonmobil Res & Eng Co
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Exxonmobil Res & Eng Co filed Critical Exxonmobil Res & Eng Co
Publication of AR037030A1 publication Critical patent/AR037030A1/es

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
    • C10G2/00—Production of liquid hydrocarbon mixtures of undefined composition from oxides of carbon
    • C10G2/30—Production of liquid hydrocarbon mixtures of undefined composition from oxides of carbon from carbon monoxide with hydrogen
    • C10G2/32—Production of liquid hydrocarbon mixtures of undefined composition from oxides of carbon from carbon monoxide with hydrogen with the use of catalysts
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J19/00—Chemical, physical or physico-chemical processes in general; Their relevant apparatus
    • B01J19/24—Stationary reactors without moving elements inside
    • B01J19/248—Reactors comprising multiple separated flow channels
    • B01J19/2485—Monolithic reactors
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J8/00—Chemical or physical processes in general, conducted in the presence of fluids and solid particles; Apparatus for such processes
    • B01J8/005—Separating solid material from the gas/liquid stream
    • B01J8/006—Separating solid material from the gas/liquid stream by filtration
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J8/00—Chemical or physical processes in general, conducted in the presence of fluids and solid particles; Apparatus for such processes
    • B01J8/18—Chemical or physical processes in general, conducted in the presence of fluids and solid particles; Apparatus for such processes with fluidised particles
    • B01J8/20—Chemical or physical processes in general, conducted in the presence of fluids and solid particles; Apparatus for such processes with fluidised particles with liquid as a fluidising medium
    • B01J8/22—Chemical or physical processes in general, conducted in the presence of fluids and solid particles; Apparatus for such processes with fluidised particles with liquid as a fluidising medium gas being introduced into the liquid
    • B01J8/224—Chemical or physical processes in general, conducted in the presence of fluids and solid particles; Apparatus for such processes with fluidised particles with liquid as a fluidising medium gas being introduced into the liquid the particles being subject to a circulatory movement
    • B01J8/226—Chemical or physical processes in general, conducted in the presence of fluids and solid particles; Apparatus for such processes with fluidised particles with liquid as a fluidising medium gas being introduced into the liquid the particles being subject to a circulatory movement internally, i.e. the particles rotate within the vessel
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
    • C10G2/00—Production of liquid hydrocarbon mixtures of undefined composition from oxides of carbon
    • C10G2/30—Production of liquid hydrocarbon mixtures of undefined composition from oxides of carbon from carbon monoxide with hydrogen
    • C10G2/32—Production of liquid hydrocarbon mixtures of undefined composition from oxides of carbon from carbon monoxide with hydrogen with the use of catalysts
    • C10G2/34—Apparatus, reactors
    • C10G2/342—Apparatus, reactors with moving solid catalysts
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
    • C10G45/00—Refining of hydrocarbon oils using hydrogen or hydrogen-generating compounds
    • C10G45/58—Refining of hydrocarbon oils using hydrogen or hydrogen-generating compounds to change the structural skeleton of some of the hydrocarbon content without cracking the other hydrocarbons present, e.g. lowering pour point; Selective hydrocracking of normal paraffins
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2208/00—Processes carried out in the presence of solid particles; Reactors therefor
    • B01J2208/00796—Details of the reactor or of the particulate material
    • B01J2208/00823—Mixing elements
    • B01J2208/00831—Stationary elements
    • B01J2208/0084—Stationary elements inside the bed, e.g. baffles
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2208/00—Processes carried out in the presence of solid particles; Reactors therefor
    • B01J2208/02—Processes carried out in the presence of solid particles; Reactors therefor with stationary particles
    • B01J2208/023—Details
    • B01J2208/024—Particulate material
    • B01J2208/025—Two or more types of catalyst
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
    • Y10S—TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10S208/00—Mineral oils: processes and products
    • Y10S208/95—Processing of "fischer-tropsch" crude

Landscapes

  • Chemical & Material Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • Organic Chemistry (AREA)
  • Engineering & Computer Science (AREA)
  • General Chemical & Material Sciences (AREA)
  • Crystallography & Structural Chemistry (AREA)
  • Combustion & Propulsion (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
  • Catalysts (AREA)
  • Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)
  • Physical Or Chemical Processes And Apparatus (AREA)
  • Devices And Processes Conducted In The Presence Of Fluids And Solid Particles (AREA)

Abstract

Un procedimiento de Fischer-Tropsch de síntesis de hidrocarburos en suspensión para sintetizar hidrocarburos líquidos a partir de gas de síntesis en un reactor de síntesis también hidroisomeriza el líquido de hidrocarburos sintetizado, que comprende el líquido de suspensión, en uno o más reactores elevadores inmersos en la masa en suspensión en el reactor de síntesis. Un catalizador monolítico es preferentemente utilizado para la hidroisomerización, y la circulación de suspensión hacia arriba a través de los reactores elevadores desde la masa en suspensión circundante es lograda por lo menos en parte por la acción elevadora del gas de tratamiento de hidroisomerización. Preferentemente, partículas de catalizador son también removidas antes que la suspensión contacte el catalizador. La hidroisomerización se produce mientras el reactor de síntesis está produciendo hidrocarburos, sin interferir con la reacción de síntesis. Un conducto descendente reductor de burbujas de gas puede ser utilizado para producir y alimentar la suspensión reducida en burbujas de gas al reactor elevador, proporcionándose de este modo una carga hidrostática que asiste en la circulación de suspensión hacia arriba a través y hacia afuera del reactor elevador.
ARP020104059A 2001-11-06 2002-10-25 Sintesis de hidrocarburos en suspension con hidroisomerizacion de liquidos en el reactor de sintesis AR037030A1 (es)

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
US09/992,141 US6717024B2 (en) 2001-11-06 2001-11-06 Slurry hydrocarbon synthesis with liquid hydroisomerization in the synthesis reactor

Publications (1)

Publication Number Publication Date
AR037030A1 true AR037030A1 (es) 2004-10-20

Family

ID=25537955

Family Applications (1)

Application Number Title Priority Date Filing Date
ARP020104059A AR037030A1 (es) 2001-11-06 2002-10-25 Sintesis de hidrocarburos en suspension con hidroisomerizacion de liquidos en el reactor de sintesis

Country Status (15)

Country Link
US (1) US6717024B2 (es)
EP (1) EP1444179B1 (es)
JP (1) JP4309762B2 (es)
CN (1) CN1318542C (es)
AR (1) AR037030A1 (es)
AT (1) ATE388928T1 (es)
AU (1) AU2002327750B2 (es)
CA (1) CA2465970A1 (es)
DE (1) DE60225585T2 (es)
DK (1) DK1444179T3 (es)
ES (1) ES2301671T3 (es)
SA (1) SA02230396B1 (es)
TW (1) TW568948B (es)
WO (1) WO2003040067A2 (es)
ZA (1) ZA200403383B (es)

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Publication number Priority date Publication date Assignee Title
US7488601B2 (en) 2003-06-20 2009-02-10 Roche Diagnostic Operations, Inc. System and method for determining an abused sensor during analyte measurement
US7452457B2 (en) 2003-06-20 2008-11-18 Roche Diagnostics Operations, Inc. System and method for analyte measurement using dose sufficiency electrodes
US8148164B2 (en) 2003-06-20 2012-04-03 Roche Diagnostics Operations, Inc. System and method for determining the concentration of an analyte in a sample fluid
MY140160A (en) 2004-01-28 2009-11-30 Shell Int Research Heat exchanger for carrying out an exothermic reaction
MY169458A (en) * 2004-03-08 2019-04-11 Shell Int Research Filter system with filter means retractable into a housing
EP1720647B1 (en) * 2004-03-08 2017-04-19 Shell Internationale Research Maatschappij B.V. Reactor with a gas distributor
KR101160371B1 (ko) * 2004-04-26 2012-06-26 메르크 파텐트 게엠베하 에이에스-인다센 유도체
CN101798086B (zh) 2009-01-20 2013-07-24 三菱综合材料株式会社 三氯硅烷制造装置以及三氯硅烷制造方法
US8519011B2 (en) * 2010-10-28 2013-08-27 Chevron U.S.A. Inc. Process of synthesis gas conversion to liquid hydrocarbon mixtures using alternating layers of synthesis gas conversion catalyst, hydrocracking and hydroisomerization catalyst
US10661232B2 (en) * 2014-11-12 2020-05-26 Eni S.P.A. Reaction device with air-lift type internal circulation
CN112844042B (zh) * 2021-01-29 2023-04-25 中冶华天工程技术有限公司 防止粘性粉尘堵塞脱硝催化剂的方法及系统

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US4523047A (en) * 1982-12-01 1985-06-11 Mobil Oil Corporation Process for syngas conversions to liquid hydrocarbon products utilizing ZSM-45 zeolite
US4423265A (en) * 1982-12-01 1983-12-27 Mobil Oil Corporation Process for snygas conversions to liquid hydrocarbon products
US4471145A (en) * 1982-12-01 1984-09-11 Mobil Oil Corporation Process for syngas conversions to liquid hydrocarbon products utilizing zeolite Beta
US4832819A (en) * 1987-12-18 1989-05-23 Exxon Research And Engineering Company Process for the hydroisomerization and hydrocracking of Fisher-Tropsch waxes to produce a syncrude and upgraded hydrocarbon products
FR2676749B1 (fr) * 1991-05-21 1993-08-20 Inst Francais Du Petrole Procede d'hydroisomerisation de paraffines issues du procede fischer-tropsch a l'aide de catalyseurs a base de zeolithe h-y.
US5382748A (en) * 1992-12-18 1995-01-17 Exxon Research & Engineering Co. Hydrocarbon synthesis reactor employing vertical downcomer with gas disengaging means
US5659108A (en) * 1995-07-07 1997-08-19 The Dow Chemical Company Process for the complete saturation of halogenated hydrocarbon streams containing unsaturated compounds
US5821270A (en) * 1997-05-02 1998-10-13 Exxon Research And Engineering Company Slurry hydrocarbon synthesis process with multistage catalyst rejuvenation
US5811469A (en) * 1997-05-06 1998-09-22 Exxon Research And Engineering Company Slurry hydrocarbon synthesis with downcomer fed product filtration (LAW552)
US5811468A (en) * 1997-05-06 1998-09-22 Exxon Research And Engineering Company Combination gas disengaging downcomer-rejuvenation tube for in-situ slurry catalyst rejuvenation (LAW541)
US5866621A (en) * 1997-05-06 1999-02-02 Exxon Research And Engineering Company Gas and solids reducing slurry downcomer
IT1301801B1 (it) * 1998-06-25 2000-07-07 Agip Petroli Procedimento per la preparazione di idrocarburi da gas di sintesi
JP3648430B2 (ja) * 2000-04-04 2005-05-18 トヨタ自動車株式会社 合成ガスからの低級イソパラフィンの合成方法

Also Published As

Publication number Publication date
JP4309762B2 (ja) 2009-08-05
EP1444179B1 (en) 2008-03-12
DK1444179T3 (da) 2008-06-16
US20030087970A1 (en) 2003-05-08
ES2301671T3 (es) 2008-07-01
WO2003040067A2 (en) 2003-05-15
ATE388928T1 (de) 2008-03-15
SA02230396B1 (ar) 2007-07-31
CN1318542C (zh) 2007-05-30
ZA200403383B (en) 2005-02-22
EP1444179A2 (en) 2004-08-11
JP2005508376A (ja) 2005-03-31
CN1578821A (zh) 2005-02-09
WO2003040067A3 (en) 2003-12-04
CA2465970A1 (en) 2003-05-15
US6717024B2 (en) 2004-04-06
AU2002327750B2 (en) 2007-06-14
TW568948B (en) 2004-01-01
DE60225585T2 (de) 2009-04-23
DE60225585D1 (de) 2008-04-24

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