AR000285A1 - Proceso para preparar complejos de coordinación detitanio y de zirconio que tienen un solo grupo II-ligado deslocalizado o ciclico y complejos de coordinación preparados con dicho proceso - Google Patents

Proceso para preparar complejos de coordinación detitanio y de zirconio que tienen un solo grupo II-ligado deslocalizado o ciclico y complejos de coordinación preparados con dicho proceso

Info

Publication number
AR000285A1
AR000285A1 AR33450895A AR33450895A AR000285A1 AR 000285 A1 AR000285 A1 AR 000285A1 AR 33450895 A AR33450895 A AR 33450895A AR 33450895 A AR33450895 A AR 33450895A AR 000285 A1 AR000285 A1 AR 000285A1
Authority
AR
Argentina
Prior art keywords
coordination complexes
zirconium
delocalized
detitanium
cyclic
Prior art date
Application number
AR33450895A
Other languages
English (en)
Original Assignee
Dow Chemical Co
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Dow Chemical Co filed Critical Dow Chemical Co
Publication of AR000285A1 publication Critical patent/AR000285A1/es

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07F—ACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
    • C07F17/00—Metallocenes

Landscapes

  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
  • Catalysts (AREA)
  • Transition And Organic Metals Composition Catalysts For Addition Polymerization (AREA)

Abstract

Se trata de la preparación de complejos de coordinación de titanio y de zirconio, que poseen un solo ligando cíclico deslocalizado, O-ligado en el queel metal de dicho complejo tiene número de oxidación formal + 2, haciendo reaccionar con excelente rendimiento y pureza, haluros de titanio o de zirconiocuyo estado de oxidación, está expresado por el número de oxidación +3 ó +4 con un reactivo de n-alquilo de Grignard. Se proponen también los complejos decoordinación obtenidos, de aplicación como catalizadores en la polimerización de alfa-olefinas.
AR33450895A 1994-12-07 1995-12-05 Proceso para preparar complejos de coordinación detitanio y de zirconio que tienen un solo grupo II-ligado deslocalizado o ciclico y complejos de coordinación preparados con dicho proceso AR000285A1 (es)

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
US08/350,924 US5512693A (en) 1994-12-07 1994-12-07 Preparation of titanium (II) or zirconium (II) complexes

Publications (1)

Publication Number Publication Date
AR000285A1 true AR000285A1 (es) 1997-06-18

Family

ID=23378782

Family Applications (1)

Application Number Title Priority Date Filing Date
AR33450895A AR000285A1 (es) 1994-12-07 1995-12-05 Proceso para preparar complejos de coordinación detitanio y de zirconio que tienen un solo grupo II-ligado deslocalizado o ciclico y complejos de coordinación preparados con dicho proceso

Country Status (18)

Country Link
US (1) US5512693A (es)
EP (1) EP0796267B1 (es)
JP (1) JPH10510262A (es)
AR (1) AR000285A1 (es)
AT (1) ATE174032T1 (es)
AU (1) AU699689B2 (es)
BR (1) BR9510081A (es)
CA (1) CA2204605C (es)
CO (1) CO4440493A1 (es)
DE (1) DE69506443T2 (es)
DK (1) DK0796267T3 (es)
ES (1) ES2126956T3 (es)
FI (1) FI972432A0 (es)
MY (1) MY112742A (es)
NO (1) NO307183B1 (es)
TW (1) TW357159B (es)
WO (1) WO1996017857A1 (es)
ZA (1) ZA9510188B (es)

Families Citing this family (20)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US6265338B1 (en) * 1989-09-13 2001-07-24 Exxon Chemical Patents, Inc. Monocyclopentadienyl titanium metal compounds for ethylene-α-olefin copolymer production catalysts
NZ268270A (en) * 1993-06-24 1997-10-24 Dow Chemical Co Titanium (ii)- or zirconium (ii)- containing complexes and addition polymerisation catalysts therefrom (m is ti or zr)
ES2116776T3 (es) * 1994-10-31 1998-07-16 Dsm Nv Composicion catalitica y procedimiento para la polimerizacion de una olefina.
DE19522013A1 (de) * 1995-06-21 1997-01-02 Hoechst Ag Übergangsmetallverbindung
US5679814A (en) * 1995-12-11 1997-10-21 Albemarle Corporation Purification of metallocenes
US5679816A (en) * 1996-01-03 1997-10-21 The Dow Chemical Company Preparation of biscyclopentadienyl diene complexes
US6313239B1 (en) * 1996-03-05 2001-11-06 Bayer Corporation Olefin polymerization with group 4 metal-containing organosilicon dendrimers
WO1997032918A2 (en) * 1996-03-05 1997-09-12 Massachusetts Institute Of Technology Group 4 metal-containing organosilicon dendrimers and method for synthesizing organosilicon dendrimers
US5710299A (en) * 1996-06-27 1998-01-20 Albemarle Corporation Production of bridged metallocene complexes and intermediates therefor
US5760262A (en) * 1996-09-17 1998-06-02 Albemarle Corporation Enhanced production of bridged hafnocenes
US5936108A (en) * 1996-10-17 1999-08-10 Albemarle Corporation Metallocene synthesis
CN100488988C (zh) 1997-12-23 2009-05-20 陶氏环球技术公司 在烯烃溶液聚合反应工艺中用于增加聚合物含量的处理设计
EP1062219B1 (en) * 1998-03-11 2002-08-28 The Dow Chemical Company Integrated process for preparation of diene complexes
AU6402099A (en) * 1998-10-29 2000-05-22 Dow Chemical Company, The Preparation of titanium(ii) or zirconium(ii) complexes
US6015916A (en) * 1999-02-02 2000-01-18 Boulder Scientific Company Constrained geometry metallocene catalyst complexes
JP2003501436A (ja) * 1999-06-04 2003-01-14 バセル テクノロジー カンパニー ビー．ブイ． チタン錯体の製造法
US6809209B2 (en) 2000-04-07 2004-10-26 Exxonmobil Chemical Patents Inc. Nitrogen-containing group-13 anionic compounds for olefin polymerization
US6455719B1 (en) * 2001-01-17 2002-09-24 Boulder Scientific Company Constrained geometry ligands and complexes derived therefrom
US8784996B2 (en) 2009-11-24 2014-07-22 Dow Global Technologies Llc Extrusion coating composition
US8679639B2 (en) 2009-11-24 2014-03-25 Dow Global Technologies Llc Extrusion coating composition

Family Cites Families (15)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US5055438A (en) * 1989-09-13 1991-10-08 Exxon Chemical Patents, Inc. Olefin polymerization catalysts
US5198401A (en) * 1987-01-30 1993-03-30 Exxon Chemical Patents Inc. Ionic metallocene catalyst compositions
PL276385A1 (en) * 1987-01-30 1989-07-24 Exxon Chemical Patents Inc Method for polymerization of olefines,diolefins and acetylene unsaturated compounds
US5153157A (en) * 1987-01-30 1992-10-06 Exxon Chemical Patents Inc. Catalyst system of enhanced productivity
US5096867A (en) * 1990-06-04 1992-03-17 Exxon Chemical Patents Inc. Monocyclopentadienyl transition metal olefin polymerization catalysts
NZ235032A (en) * 1989-08-31 1993-04-28 Dow Chemical Co Constrained geometry complexes of titanium, zirconium or hafnium comprising a substituted cyclopentadiene ligand; use as olefin polymerisation catalyst component
US5057475A (en) * 1989-09-13 1991-10-15 Exxon Chemical Patents Inc. Mono-Cp heteroatom containing group IVB transition metal complexes with MAO: supported catalyst for olefin polymerization
US5064802A (en) * 1989-09-14 1991-11-12 The Dow Chemical Company Metal complex compounds
JP2545006B2 (ja) * 1990-07-03 1996-10-16 ザ ダウ ケミカル カンパニー 付加重合触媒
US5721185A (en) * 1991-06-24 1998-02-24 The Dow Chemical Company Homogeneous olefin polymerization catalyst by abstraction with lewis acids
ES2108766T3 (es) * 1991-10-15 1998-01-01 Dow Chemical Co Preparacion de complejos de coordinacion de metal.
US5374696A (en) * 1992-03-26 1994-12-20 The Dow Chemical Company Addition polymerization process using stabilized reduced metal catalysts
US5350723A (en) * 1992-05-15 1994-09-27 The Dow Chemical Company Process for preparation of monocyclopentadienyl metal complex compounds and method of use
US5372682A (en) * 1993-06-24 1994-12-13 The Dow Chemical Company Electrochemical preparation of addition polymerization catalysts
NZ268270A (en) * 1993-06-24 1997-10-24 Dow Chemical Co Titanium (ii)- or zirconium (ii)- containing complexes and addition polymerisation catalysts therefrom (m is ti or zr)

Also Published As

Publication number Publication date
AU699689B2 (en) 1998-12-10
DK0796267T3 (da) 1999-08-16
ATE174032T1 (de) 1998-12-15
FI972432A (fi) 1997-06-06
EP0796267A1 (en) 1997-09-24
CA2204605C (en) 2007-12-18
AU4199096A (en) 1996-06-26
NO972621L (no) 1997-06-06
CO4440493A1 (es) 1997-05-07
DE69506443T2 (de) 1999-07-22
MY112742A (en) 2001-08-30
EP0796267B1 (en) 1998-12-02
TW357159B (en) 1999-05-01
MX9704116A (es) 1997-09-30
ZA9510188B (en) 1997-05-30
WO1996017857A1 (en) 1996-06-13
BR9510081A (pt) 1998-07-14
CA2204605A1 (en) 1996-06-13
DE69506443D1 (de) 1999-01-14
FI972432A0 (fi) 1997-06-06
NO307183B1 (no) 2000-02-21
NO972621D0 (no) 1997-06-06
US5512693A (en) 1996-04-30
JPH10510262A (ja) 1998-10-06
ES2126956T3 (es) 1999-04-01

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