ZA200703246B - Method for production of a seamless hot-finished steel tube and device for carrying out said method - Google Patents
Method for production of a seamless hot-finished steel tube and device for carrying out said method Download PDFInfo
- Publication number
- ZA200703246B ZA200703246B ZA200703246A ZA200703246A ZA200703246B ZA 200703246 B ZA200703246 B ZA 200703246B ZA 200703246 A ZA200703246 A ZA 200703246A ZA 200703246 A ZA200703246 A ZA 200703246A ZA 200703246 B ZA200703246 B ZA 200703246B
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- South Africa
- Prior art keywords
- forging
- hollow ingot
- rolling
- shaping
- piercing
- Prior art date
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- 238000000034 method Methods 0.000 title claims description 61
- 238000004519 manufacturing process Methods 0.000 title claims description 15
- 229910000831 Steel Inorganic materials 0.000 title claims description 4
- 239000010959 steel Substances 0.000 title claims description 4
- 238000005242 forging Methods 0.000 claims description 63
- 230000008569 process Effects 0.000 claims description 30
- 238000005096 rolling process Methods 0.000 claims description 25
- 238000007493 shaping process Methods 0.000 claims description 17
- 238000004080 punching Methods 0.000 claims description 9
- 238000010438 heat treatment Methods 0.000 claims description 6
- 230000009467 reduction Effects 0.000 claims description 4
- 238000009499 grossing Methods 0.000 claims description 3
- 230000008859 change Effects 0.000 claims description 2
- 239000003795 chemical substances by application Substances 0.000 claims description 2
- 239000000314 lubricant Substances 0.000 claims description 2
- 230000008901 benefit Effects 0.000 description 3
- 238000004513 sizing Methods 0.000 description 3
- 230000009286 beneficial effect Effects 0.000 description 2
- 238000009749 continuous casting Methods 0.000 description 2
- 230000001066 destructive effect Effects 0.000 description 2
- 239000000463 material Substances 0.000 description 2
- 238000000926 separation method Methods 0.000 description 2
- 244000144725 Amygdalus communis Species 0.000 description 1
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 description 1
- 229910001208 Crucible steel Inorganic materials 0.000 description 1
- 101001126084 Homo sapiens Piwi-like protein 2 Proteins 0.000 description 1
- XEEYBQQBJWHFJM-UHFFFAOYSA-N Iron Chemical compound [Fe] XEEYBQQBJWHFJM-UHFFFAOYSA-N 0.000 description 1
- 229910019142 PO4 Inorganic materials 0.000 description 1
- 102100029365 Piwi-like protein 2 Human genes 0.000 description 1
- GYMWQLRSSDFGEQ-ADRAWKNSSA-N [(3e,8r,9s,10r,13s,14s,17r)-13-ethyl-17-ethynyl-3-hydroxyimino-1,2,6,7,8,9,10,11,12,14,15,16-dodecahydrocyclopenta[a]phenanthren-17-yl] acetate;(8r,9s,13s,14s,17r)-17-ethynyl-13-methyl-7,8,9,11,12,14,15,16-octahydro-6h-cyclopenta[a]phenanthrene-3,17-diol Chemical compound OC1=CC=C2[C@H]3CC[C@](C)([C@](CC4)(O)C#C)[C@@H]4[C@@H]3CCC2=C1.O/N=C/1CC[C@@H]2[C@H]3CC[C@](CC)([C@](CC4)(OC(C)=O)C#C)[C@@H]4[C@@H]3CCC2=C\1 GYMWQLRSSDFGEQ-ADRAWKNSSA-N 0.000 description 1
- 238000005520 cutting process Methods 0.000 description 1
- 238000009826 distribution Methods 0.000 description 1
- 230000000694 effects Effects 0.000 description 1
- 239000010439 graphite Substances 0.000 description 1
- 229910002804 graphite Inorganic materials 0.000 description 1
- 238000003780 insertion Methods 0.000 description 1
- 230000037431 insertion Effects 0.000 description 1
- 238000002372 labelling Methods 0.000 description 1
- 238000003801 milling Methods 0.000 description 1
- 230000004048 modification Effects 0.000 description 1
- 238000012986 modification Methods 0.000 description 1
- 239000010452 phosphate Substances 0.000 description 1
- NBIIXXVUZAFLBC-UHFFFAOYSA-K phosphate Chemical compound [O-]P([O-])([O-])=O NBIIXXVUZAFLBC-UHFFFAOYSA-K 0.000 description 1
- 238000009420 retrofitting Methods 0.000 description 1
- 238000005496 tempering Methods 0.000 description 1
- 230000008646 thermal stress Effects 0.000 description 1
- 230000000007 visual effect Effects 0.000 description 1
- 238000011179 visual inspection Methods 0.000 description 1
Description
METHOD OF MAKING A SEAMLESS HOT-FINISHED STEEL PIPE, AND
DEVICE FOR CARRYING OUT THE METHOD
The invention relates to a method of making a seamless hot-finished steel pipe according to the preamble of claim 1.
Following the invention by the brothers Mannesmann to produce a thick-walled hollow tubular ingot from a heated billet, many different proposals have been suggested to stretch this hollow tubular ingot in a same hot-working step at same temperature. Keywords include the continuous rolling process, the rotary- forged process, the piercing mill process, and the Pilger step-by-step rolling process (Stahlrohr-Handbuch [Steel Pipe Handbook], 10. ed; Vulkan-Verlag
Essen, 1986, Ill. Manufacturing Processes).
All mentioned processes have their benefits for different size ranges and materials, whereby combinations are possible as well. The continuous rolling process and the piercing mill process are applicable for the size range of 5 to 18", the Pilger-mill process is applicable for the size range of up to 26". When a thicker wall in the range of > 30 mm is involved, the continuous rolling process and the piercing mill process are less suitable while the Pilger-mill process, although not encountering any problems with the wall thickness, exhibits a production cycle that is slower. A drawback common to all mentioned processes is the more or less long modification times during a change in size.
The three stages piercing - stretching - reduction rolling are a characteristic for the production of seamless pipes from a heated billet (H. Biller, Das Walzen nahtloser Rohre - Probleme der Verfahrensauswahl [Rolling of Seamless
Tubes - Problems of Process Selection], Stahl und Eisen 106 (1986), No. 9, pages 431-437).
For some time, attempts have been made to save a step in order to lower production and assembly costs. These attempts have shown little success to date.
DE 1 908 961 A1 discloses a method of making seamless tubes from hollow bodies produced by continuous casting. In this known process, the cast strand is divided and the respective section is initially stretched with the assistance of an internal tool and rolling by hot forging. Thereafter, the pre-stretched section is rolled to a tube (shell) by a continuous rolling train, and a finished pipe is made thereform through subsequent stretch-reduction. This proposed process should be applied for mass production of pipes of small diameter from hollow bodies made through continuous casting. The proposal is intended to overcome the problem of excessive strain of the skew rolls during initial stretching. lt is an object of the invention to provide a production method for seamless hot-finished steel pipes, which has superior yield and productivity than known methods for the size range of 5” to 30" outer diameter and wall thicknesses >0.1 x outer diameter for the range of 5” to <16” outer diameter or >40 mm wall thickness for the range of 16” to 30” outer diameter, but also for small lot sizes.
Based on the preamble, this object is attained by the characterizing part of claim 1. Advantageous improvements are the subject matter of sub-claims.
According to the teaching of the invention, the previously known second and third shaping steps defined by rolling (stretch-rolling and reduction-rolling) are replaced by one shaping step in the form of a radial forging process, using an internal tool pushed into the hollow ingot and at least two forging jaws of a forging machine for acting on the outer surface area of the hollow ingot, whereby a turning and axial advance of the hollow ingot is clocked in the idle stroke phase of the forging jaws. Depending on the type of control, the turning and axial advance of the hollow ingot may be executed simultaneously or time- staggered.
®
The proposed method has the advantage of allowing an optimal production also of thick-walled tubes while keeping retrofitting times low. Similar to Pilger- milling, the stretching process produces through forging a high elongation also of very thick-walled tubes. As a result, also thick-walled pipes of great pipe length can be produced. A further advantage is the possibility to eliminate the need for the downstream sizing mill, which is otherwise necessary in the majority of applications, because now the thus-produced hot-finished pipe has the finished pipe quality after the stretching process through forging.
The proposed forging process is especially effective and of beneficial quality, when using, instead of two, a total of four forging jaws which act in one plane upon the outer surface area of the hollow ingot in synchronism. It may be advantageous for a better distribution, in particular of the thermal stress, to move the internal tool during forging in a same direction or in opposition to the axial advance.
At great stretch rate (>4) and slight wall thickness (<30 mm), it may be required to apply a separating agent and lubricant, e.g. on phosphate or graphite basis, prior to forging. This prevents the forged hollow ingot from caking together with the internal tool.
The first shaping step may selectively be a hole punching or piercing by means of skew rolls. Following hole punching, the bottom is severed or pierced.
Separation may be realized by flame cutting or hot sawing. The hollow ingot produced by hole punching or piercing by means of skew rolls may be forged directly or pre-stretched by a subsequent skew rolling, before receiving the final pipe size through forging.
In this procedure, separation or piercing of the bottom may be omitted after hole punching. A two-high rolling mili or three-high rolling mill is used for skew rolling. Descaling of the outer and/or inner surface is beneficial depending on the preliminary process.
®
After the normal finishing steps, such as sizing, visual nspectinlidbdind, Bc? 2 4 8 the forged finished pipe is either ready for immediate delivery or undergoes, as previously, a heat treatment and/or a non-destructive test. Heat treatment may involve normalizing or tempering. Leveling may be required depending on the demand for straightness. Depending on the delivery demands, it may also be necessary to grind the outer surface or treat it by another suitable material-removing process to eliminate slight unevenness caused by the forging process.
The starting billet being used is either a section of a continuously cast bar, preferably a round cast bar or cast billet (ingot). Depending of the applied piercing process. materials that are difficult to shape, it may be required to pre- shape the cast through rolling or forging. Heating of the initial billet is carried out in a known manner in a rotary hearth furnace or a rocker bar type furnace.
When large weights are involved, the use of other heat furnaces, such as, e.g., pit furnaces, is also conceivable.
The device for carrying out the method is characterized by a radial forging machine having a forging stand and at least two forging jaws which are replaceably arranged in the forging stand. The rotary movement as well as the axial advance of the hollow ingot is realized by a manipulator on the entry side as well as on the exit side. To minimize the possible need for leveling, it has proven advantageous to arrange a guide between manipulator and forging stand at least one the exit side. This should ensure that the forged finished pipe leaving the forging stand is substantially held truly axial.
In principle, the forging process is possible with straight forging jaws; however, the surface quality is significantly improved when each forging jaw includes on the side facing the workpiece a narrowing entry portion which terminates in a smoothing part, when viewed in length section. Viewed in cross section, the entry zone is curved concavely, with the radius being always greater in the respective cross section plane than the actual radius of the engaged hollow ingot. The greater curvature in the cross section plane results in a clamping effect. It is however not necessary to provide a separate set of forging jaws for each entry diameter of the hollow ingot; Rather, one set is able to cover a range of different entry diameters.
The inner diameter as well as the inner contour as viewed along the length of the forged finished pipe is essentially determined primarily by the type of internal tool, preferably in the form of a cylindrical mandrel.
The use of a slightly conical mandrel increases the clearance between the forged finished pipe and the internal tool so that the withdrawal of the finished pipe from the internal tool is facilitated. The conicity should, however, be only slight because otherwise the wall thickness, as viewed over the length, would inadmissibly alter.
The use of a stepped mandrel could be useful for the production of axles with thickened ends. Depending on the type of gradation, it may also be possible to make several axles from a hollow ingot. Singling could subsequently be carried out.
A further field of application would be the production of threaded pipes in the form of an integral connection. There would also be the option to directly forge the socket in so-called socket pipes instead separately.
The method according to the invention will be described in greater detail with reference to two schematic illustrations.
It is shown in
Figure 1 the method according to the invention with a piercing unit (skew roll),
Figure 2 the method according to the invention with a piercing unit (skew roll) and subsequent pre-stretching unit (elongator),
: WQO 2006/045301 PCT/DE2005/001944
Figure 3 a longitudinal section of an engaged hollow ingot,
Figure 4 a section in the direction A-A in Figure 3.
Figure 1 shows a schematic illustration of the method according to the invention with only one piercing unit as first shaping step. By way of example. a billet 1, sized to length from a cast steel bar is placed in a rotary hearth furnace 2 and heated to a shaping temperature of, e.g., 1250 °C. After heating and exiting the rotary hearth furnace 2, the heated billet is fed via a roller table 3 to a piercing unit.
In this exemplified embodiment, the piercing unit is designed as skew rolling mill 4 with two skew rolls 5, 5', and includes an internal tool, comprised of a piercing mandrel 6 and a holding rod 7. As piercing by means of skew rolls is generally known, a more detailed discussion is omitted.
Piercing the billet 1 produces a hollow ingot 8 which is fed via a transverse transport 9 to the forging machine 10. The subsequent stretching process by way of radial forging combines in accordance with the invention the otherwise typical second and third shaping steps, in lieu of the otherwise typical rolls, be it a continuous rolling process, piercing process, or Pilger step-by-step rolling process with subsequent reduction rolls.
After insertion of the internal tool 11, preferably in the form of a cylindrical mandrel, the hollow ingot 8 is transported by a manipulator 13 on the entry side longitudinally through the forging stand 14 and turned at the same time. This rotation and the axial advance of the hollow ingot 8 is clocked in the idle stroke phase of the forging jaws either simultaneously or time-staggered.
On the exit side, a second manipulator 12 receives later the finished pipe 16 in order to allow conclusion of the forging process. The forging unit is shown here only schematically and includes unillustrated forging jaws which embrace the
® hollow ingot 8 and act upon the outer surface area in rast d 9.7 Ld 2 4 6 hollow ingot 8 through reduction of the outer diameter as well as of the wall thickness.
After the stretching process through forging, the hot-finished pipe 16 is transported to the finishing line according to arrow 15 to make it ready for shipment. Finishing includes typically a sizing to length, visual inspection, labeling, and depending on demand a preceding heat treatment and/or a non- destructive test. For space-saving reasons, the hot-finished pipe 16 is shown shorter as it would be according to the elongation.
By way of example, the operating sequence shown in Figure 1 produces, after piercing from a billet 1 with a round dimension of 406 mm and a length of 2.8 m, a hollow ingot 8 with a dimension 390 outer diameter x 123 mm wall thickness with a length of 3.5 m. After forging, the hot-finished pipe 16 has an outer diameter of 203 mm with a wall thickness of 50 mm and a length of 15 meters.
Figure 2 shows a variation of the method of Figure 1, whereby same reference numerals have been selected for same parts. The first shaping step up to the production of a hollow ingot 8 is identical with the shaping step described with reference to Figure 1. Disposed prior to the stretching process through forging, the second shaping step, is a pre-stretching unit, a so-called elongator 17. The elongator is also configured in this exemplified embodiment as a skew rolling mill with two skew rolls 18, 18’ and an internal tool comprised of a plug 19 which is connected to a holding rod 20.
The hollow ingot 8 exiting the piercing unit is fed via a transverse transport 9 to the entry side of the elongator 7. Skew rolling per-stretches the hollow ingot 8 and a hollow ingot 8' with reduced wall thickness is produced. The diameter of the hollow ingot 8' may be the same, smaller, or greater after initial stretching.
Subsequently, the hollow ingot 8’ is fed via a transverse transport 9' to the forging machine 10, already described with reference to Figure 1. As the following steps are identical, a repetition thereof is omitted.
By way of example, the operating sequence shown in Figure 2 produces, after piercing from a billet 1 with a round dimension of 500 mm and a length of 4 m, a hollow ingot 8 with a dimension 500 mm outer diameter x 180 mm wall thickness with a length of 4.3 m.
After passing through the elongator, a hollow ingot 8' is produced with the dimensions of 480 mm outer diameter x 120 mm wall thickness and a length of 58 m.
After the stretching process through forging, the hot-finished pipe 16 has an outer diameter of 339.7 mm with a wall thickness of 75 mm and a length of 12.6 m.
Figure 3 shows a longitudinal section of an engaged hollow ingot 8 which is to be forged and which enters the forging machine from the left and exits the forging machine on the right in the form of a hot-finished pipe 16. In this exemplified embodiment, four forging jaws 21, 21", 217, 21” acting on the outer surface in the forging zone cooperate with a cylindrical mandrel 22 on the inside. The mandrel 22 is held in place by a holding rod 23; it may, however, as an alternative, also move axially back and forth during the forging process.
The curved arrow 24 as well as the axial arrow 25 are intended to emphasize that the hollow ingot 8’ is rotated and axially advanced during the idle stroke of the forging jaws 21-21".
In length section, each forging jaw 21-21" has a predominantly conically designed entry portion 26 which terminates in a smoothing part 27. The entry part 26 may also be curved slightly convex.
As shown in cross section (Figure 4), all forging jaws 21-21" have a concave curvature. Normally, the curvature is an arc having a radius which is greater than the actual radius of the part to be forged.
The movement arrows 28, depicted in Figures 3 and 4 should indicate the radial stroke of the respective forging jaw 21-21".
Ry
List of Reference Signs
No. Designation ; 1 | Billet 2 | Rotary hearth furnace 3,3 Roller table 4 pe 55 Skew roll i
LB | Piercing mandrel
Holding rod 8 | Hollowingot 99 | Transverse transport 12 Manipulator, exit side 13 Manipulator, entry side : 14 Forging stand 171 Elongatr 18,18 1 "Skewrol 1 —"71"Pwg 000
Holding rod 21.21,21%,21" | Forgingjaw 22 1 Mandel 24 1 "Cuvedamow 26 1 Entypotion 27 1" Smoothingpat 28 1 Movementamow
Claims (26)
1. Method of making a seamless hot-finished steel pipe, in which originating from a billet heated to a shaping temperature, a first shaping produces through a piercing step a thick-walled hollow ingot which is subsequently elongated in a second shaping step at same temperature through rolling accompanied by a change in diameter and wall thickness to form a tube (shell), and from which a finished pipe is produced in a third shaping step through reduction rolling, characterized in that the second and third shaping steps defined by rolling are replaced by one shaping step in the form of a radial forging process, using an internal tool inserted in the hollow ingot and at least two forging jaws of a forging machine which act on the outer surface area of the hoilow ingot, wherein the hollow ingot is turned and axially advanced in a clocked manner in the idle stroke phase of the forging jaws.
2. Method according to claim 1, characterized in that the rotation and the axial advance of the hollow ingot are carried out simultaneously or time-staggered.
3. Method according to claim 1 and 2, characterized in that four forging jaws are used which act in a plane in synchronism upon the outer surface area of the hollow ingot.
4. Method according to the claims 1-3, characterized in that the internal tool is stationary during forging.
5. Method according to the claims 1-3, characterized in that the internal tool is moved in a same direction as the axial advance during forging.
6. Method according to the claims 1-3, characterized in that the internal tool is moved in opposite direction to the axial advance during forging.
7. Method according to the claims 1-6, characterized in that a separating agent and lubricant is applied upon the inner side of the hollow ingot before the start of the radial forging process.
8. Method according to the claims 1-7, characterized in that the first shaping step is a hole punching.
9. Method according to claim 8, characterized in that the bottom is pierced following the hole punching.
10. Method according to claim 8, characterized in that the bottom is severed following the hole punching.
11. Method according to the claims 8-10, characterized in that the hollow ingot is descaled on the inside and outside following the hole punching and removal of the bottom.
12. Method according to claim 8, characterized in
WQ 2006/045301 PCT/DE2005/001944 ~ "t 2007/0346 that the hole punching is followed by initial stretching by means of skew h rolls.
13. Method according to claim 12, characterized in that the hollow ingot is descaled after skew rolling.
14. Method according to the claims 1-7, characterized in that the first shaping step is a piercing by means of skew rolls.
15. Method according to claim 14, characterized in that the piercing is followed by initial stretching by means of skew rolls.
16. Method according to the claims 14 and 15, characterized in that the produced hollow ingot is descaled on the inside.
17. Method according to the claims 1-16, characterized in that the finished pipe undergoes a heat treatment.
18. Method according to the claims 1-17, characterized in that the finished pipe is straightened.
19. Method according to the claims 1-18, characterized in that the outer surface of the finished pipe is treated by a material- removing process.
PCT/DE2005/001944
20. Method according to claim 19, characterized in that the treatment is grinding.
21. Device for carrying out the method according to claim 1 with a radial forging machine, comprised of a forging stand and at least two forging jaws which are replaceably arranged in the forging stand, and a manipulator as well as a mandrel projecting into the forging stand and being axially movable, characterized in that a manipulator (12, 13) is disposed on the entry side as well as on the exit side, and at least the exit side has a guide, that viewed in length section, each forging jaw (21-21) has on the side facing the workpiece a narrowing entry portion (26) which terminates in a flat smoothing part (27), and viewed in cross section, the forging jaw (21-21) is curved concavely, with the radius in the respective cross section plane being always greater than the actual radius of the engaged hollow ingot (8, 8).
22. Device according to claim 21, characterized in that the guide is arranged between manipulator (12) and forging stand (14).
23. Device according to one of the claims 21-22, characterized in that the mandrel (22) is cylindrical.
24. Device according to one of the claims 21-22, characterized in that the mandrel is conical.
25. Device according to one of the claims 21-22, characterized in that the mandrel is stepped. AMENDED SHEET
PCT/DE2005/001944
26. Device according to one of the claims 21-25, characterized in that also the entry side includes a guide. AMENDED SHEET
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| DE102004052406 | 2004-10-25 |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| ZA200703246B true ZA200703246B (en) | 2008-06-25 |
Family
ID=38880881
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| ZA200703246A ZA200703246B (en) | 2004-10-25 | 2007-04-19 | Method for production of a seamless hot-finished steel tube and device for carrying out said method |
Country Status (3)
| Country | Link |
|---|---|
| CN (1) | CN100518989C (en) |
| UA (1) | UA90116C2 (en) |
| ZA (1) | ZA200703246B (en) |
Families Citing this family (7)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN102501000B (en) * | 2011-09-28 | 2014-04-02 | 南阳市红阳锻造有限公司 | Precision forming process for rim supporting shafts of engineering machinery and heavy-duty trucks |
| CN102761045A (en) * | 2012-07-19 | 2012-10-31 | 镇江步云电子有限公司 | Insertion core manufacturing process for radiofrequency coaxial connector |
| CN113118353B (en) * | 2021-04-21 | 2022-03-18 | 西安交通大学 | Surface-strengthened inner-step shaft inner hole precision forming process |
| CN113525012A (en) * | 2021-07-20 | 2021-10-22 | 安徽大昌科技股份有限公司 | Eccentric flaring torsion beam longitudinal arm structure |
| CN114713667A (en) * | 2022-03-18 | 2022-07-08 | 温州英特不锈钢有限公司 | Nonrust steel pipe forming device |
| CN114769352A (en) * | 2022-03-21 | 2022-07-22 | 温州英特不锈钢有限公司 | Stainless steel pipe forming method |
| CN117816882B (en) * | 2024-03-06 | 2024-05-03 | 江苏圣贤锻造有限责任公司 | Petrochemical pressure vessel tube plate forging equipment and process |
Family Cites Families (7)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| AT346156B (en) * | 1977-04-01 | 1978-10-25 | Gfm Fertigungstechnik | FORGING MACHINE FOR FORGING LARGE PIPES OVER A LONG THORN |
| CN1003005B (en) * | 1985-04-01 | 1989-01-04 | 国营青岛钢厂 | Manufacture of fin-tube |
| RU2000160C1 (en) * | 1992-06-04 | 1993-09-07 | Московский институт стали и сплавов | Blanks with elongated axis radial reduction method |
| CA2192970A1 (en) * | 1994-06-16 | 1995-12-21 | Heinz Josef Kron | Method of producing a seamless hot-finished tube |
| WO1996012574A1 (en) * | 1994-10-20 | 1996-05-02 | Sumitomo Metal Industries, Ltd. | Method of manufacturing seamless steel pipes and manufacturing equipment therefor |
| CN2530742Y (en) * | 2002-02-07 | 2003-01-15 | 赵金发 | Tube mill mandrel |
| CN1207114C (en) * | 2002-09-21 | 2005-06-22 | 王旭午 | Technology for rolling seamless steel pipe |
-
2005
- 2005-10-25 CN CNB200580041393XA patent/CN100518989C/en not_active Expired - Fee Related
- 2005-10-25 UA UAA200705651A patent/UA90116C2/en unknown
-
2007
- 2007-04-19 ZA ZA200703246A patent/ZA200703246B/en unknown
Also Published As
| Publication number | Publication date |
|---|---|
| CN100518989C (en) | 2009-07-29 |
| UA90116C2 (en) | 2010-04-12 |
| CN101068636A (en) | 2007-11-07 |
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