ZA200403378B - In-situ hydroisomerization of a synthesized hydrocarbon liquid in a slurry fischer-tropsch reactor. - Google Patents
In-situ hydroisomerization of a synthesized hydrocarbon liquid in a slurry fischer-tropsch reactor. Download PDFInfo
- Publication number
- ZA200403378B ZA200403378B ZA200403378A ZA200403378A ZA200403378B ZA 200403378 B ZA200403378 B ZA 200403378B ZA 200403378 A ZA200403378 A ZA 200403378A ZA 200403378 A ZA200403378 A ZA 200403378A ZA 200403378 B ZA200403378 B ZA 200403378B
- Authority
- ZA
- South Africa
- Prior art keywords
- slurry
- liquid
- catalyst
- gas
- process according
- Prior art date
Links
- 239000002002 slurry Substances 0.000 title claims description 157
- 229930195733 hydrocarbon Natural products 0.000 title claims description 108
- 150000002430 hydrocarbons Chemical class 0.000 title claims description 108
- 239000007788 liquid Substances 0.000 title claims description 100
- 239000004215 Carbon black (E152) Substances 0.000 title claims description 85
- 238000011065 in-situ storage Methods 0.000 title description 2
- 239000003054 catalyst Substances 0.000 claims description 129
- 239000007789 gas Substances 0.000 claims description 111
- 238000003786 synthesis reaction Methods 0.000 claims description 108
- 230000015572 biosynthetic process Effects 0.000 claims description 94
- 238000000034 method Methods 0.000 claims description 54
- 229910052739 hydrogen Inorganic materials 0.000 claims description 52
- 230000008569 process Effects 0.000 claims description 52
- UFHFLCQGNIYNRP-UHFFFAOYSA-N Hydrogen Chemical compound [H][H] UFHFLCQGNIYNRP-UHFFFAOYSA-N 0.000 claims description 47
- 239000001257 hydrogen Substances 0.000 claims description 44
- 238000006243 chemical reaction Methods 0.000 claims description 30
- 239000007787 solid Substances 0.000 claims description 24
- 239000012530 fluid Substances 0.000 claims description 19
- 230000002829 reductive effect Effects 0.000 claims description 19
- 230000003068 static effect Effects 0.000 claims description 13
- 239000000203 mixture Substances 0.000 claims description 12
- 238000002347 injection Methods 0.000 claims description 10
- 239000007924 injection Substances 0.000 claims description 10
- 238000002156 mixing Methods 0.000 claims description 10
- 239000002245 particle Substances 0.000 claims description 10
- 229910002091 carbon monoxide Inorganic materials 0.000 claims description 9
- 238000011144 upstream manufacturing Methods 0.000 claims description 9
- 229910000510 noble metal Inorganic materials 0.000 claims description 6
- 238000005194 fractionation Methods 0.000 claims description 3
- 230000003197 catalytic effect Effects 0.000 description 18
- 229910052751 metal Inorganic materials 0.000 description 18
- 239000002184 metal Substances 0.000 description 18
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 description 14
- DCAYPVUWAIABOU-UHFFFAOYSA-N hexadecane Chemical compound CCCCCCCCCCCCCCCC DCAYPVUWAIABOU-UHFFFAOYSA-N 0.000 description 12
- 239000000047 product Substances 0.000 description 11
- PNEYBMLMFCGWSK-UHFFFAOYSA-N aluminium oxide Inorganic materials [O-2].[O-2].[O-2].[Al+3].[Al+3] PNEYBMLMFCGWSK-UHFFFAOYSA-N 0.000 description 10
- 229910017052 cobalt Inorganic materials 0.000 description 10
- 239000010941 cobalt Substances 0.000 description 10
- GUTLYIVDDKVIGB-UHFFFAOYSA-N cobalt atom Chemical compound [Co] GUTLYIVDDKVIGB-UHFFFAOYSA-N 0.000 description 10
- 239000000377 silicon dioxide Substances 0.000 description 8
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Chemical compound O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 7
- XEEYBQQBJWHFJM-UHFFFAOYSA-N Iron Chemical compound [Fe] XEEYBQQBJWHFJM-UHFFFAOYSA-N 0.000 description 5
- 239000000919 ceramic Substances 0.000 description 5
- 230000000694 effects Effects 0.000 description 5
- 239000006260 foam Substances 0.000 description 5
- 239000000463 material Substances 0.000 description 5
- 239000010457 zeolite Substances 0.000 description 5
- GWEVSGVZZGPLCZ-UHFFFAOYSA-N Titan oxide Chemical compound O=[Ti]=O GWEVSGVZZGPLCZ-UHFFFAOYSA-N 0.000 description 4
- 230000002378 acidificating effect Effects 0.000 description 4
- 238000009835 boiling Methods 0.000 description 4
- 239000000446 fuel Substances 0.000 description 4
- 229910052742 iron Inorganic materials 0.000 description 4
- VNWKTOKETHGBQD-UHFFFAOYSA-N methane Chemical compound C VNWKTOKETHGBQD-UHFFFAOYSA-N 0.000 description 4
- 229910052750 molybdenum Inorganic materials 0.000 description 4
- 239000003921 oil Substances 0.000 description 4
- 238000012545 processing Methods 0.000 description 4
- 238000013517 stratification Methods 0.000 description 4
- QTBSBXVTEAMEQO-UHFFFAOYSA-N Acetic acid Chemical compound CC(O)=O QTBSBXVTEAMEQO-UHFFFAOYSA-N 0.000 description 3
- ZOKXTWBITQBERF-UHFFFAOYSA-N Molybdenum Chemical compound [Mo] ZOKXTWBITQBERF-UHFFFAOYSA-N 0.000 description 3
- 239000002253 acid Substances 0.000 description 3
- 230000002411 adverse Effects 0.000 description 3
- 238000004517 catalytic hydrocracking Methods 0.000 description 3
- 238000005336 cracking Methods 0.000 description 3
- 238000001914 filtration Methods 0.000 description 3
- 238000005984 hydrogenation reaction Methods 0.000 description 3
- 238000006317 isomerization reaction Methods 0.000 description 3
- 239000011733 molybdenum Substances 0.000 description 3
- 229910052759 nickel Inorganic materials 0.000 description 3
- 229910052707 ruthenium Inorganic materials 0.000 description 3
- XKRFYHLGVUSROY-UHFFFAOYSA-N Argon Chemical compound [Ar] XKRFYHLGVUSROY-UHFFFAOYSA-N 0.000 description 2
- IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 description 2
- RYGMFSIKBFXOCR-UHFFFAOYSA-N Copper Chemical compound [Cu] RYGMFSIKBFXOCR-UHFFFAOYSA-N 0.000 description 2
- 229910021536 Zeolite Inorganic materials 0.000 description 2
- MCMNRKCIXSYSNV-UHFFFAOYSA-N Zirconium dioxide Chemical compound O=[Zr]=O MCMNRKCIXSYSNV-UHFFFAOYSA-N 0.000 description 2
- 230000009471 action Effects 0.000 description 2
- 238000001354 calcination Methods 0.000 description 2
- 229910052802 copper Inorganic materials 0.000 description 2
- 239000010949 copper Substances 0.000 description 2
- 238000006356 dehydrogenation reaction Methods 0.000 description 2
- 238000000280 densification Methods 0.000 description 2
- HNPSIPDUKPIQMN-UHFFFAOYSA-N dioxosilane;oxo(oxoalumanyloxy)alumane Chemical compound O=[Si]=O.O=[Al]O[Al]=O HNPSIPDUKPIQMN-UHFFFAOYSA-N 0.000 description 2
- 238000007327 hydrogenolysis reaction Methods 0.000 description 2
- 239000010687 lubricating oil Substances 0.000 description 2
- 229910044991 metal oxide Inorganic materials 0.000 description 2
- 150000004706 metal oxides Chemical class 0.000 description 2
- 150000002739 metals Chemical class 0.000 description 2
- 229910052697 platinum Inorganic materials 0.000 description 2
- 239000011148 porous material Substances 0.000 description 2
- 238000002360 preparation method Methods 0.000 description 2
- 238000012546 transfer Methods 0.000 description 2
- UGFAIRIUMAVXCW-UHFFFAOYSA-N Carbon monoxide Chemical compound [O+]#[C-] UGFAIRIUMAVXCW-UHFFFAOYSA-N 0.000 description 1
- ZAMOUSCENKQFHK-UHFFFAOYSA-N Chlorine atom Chemical compound [Cl] ZAMOUSCENKQFHK-UHFFFAOYSA-N 0.000 description 1
- PXGOKWXKJXAPGV-UHFFFAOYSA-N Fluorine Chemical compound FF PXGOKWXKJXAPGV-UHFFFAOYSA-N 0.000 description 1
- 229910019142 PO4 Inorganic materials 0.000 description 1
- NINIDFKCEFEMDL-UHFFFAOYSA-N Sulfur Chemical compound [S] NINIDFKCEFEMDL-UHFFFAOYSA-N 0.000 description 1
- 229910052776 Thorium Inorganic materials 0.000 description 1
- 229910052770 Uranium Inorganic materials 0.000 description 1
- 150000001336 alkenes Chemical class 0.000 description 1
- 229910052786 argon Inorganic materials 0.000 description 1
- 238000003491 array Methods 0.000 description 1
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 description 1
- 230000009286 beneficial effect Effects 0.000 description 1
- 230000008901 benefit Effects 0.000 description 1
- 230000001588 bifunctional effect Effects 0.000 description 1
- 229910052799 carbon Inorganic materials 0.000 description 1
- 238000006757 chemical reactions by type Methods 0.000 description 1
- 239000000460 chlorine Substances 0.000 description 1
- 229910052801 chlorine Inorganic materials 0.000 description 1
- 150000001875 compounds Chemical class 0.000 description 1
- 238000010276 construction Methods 0.000 description 1
- 239000010779 crude oil Substances 0.000 description 1
- 230000009849 deactivation Effects 0.000 description 1
- 238000011161 development Methods 0.000 description 1
- 238000010586 diagram Methods 0.000 description 1
- 239000002283 diesel fuel Substances 0.000 description 1
- 238000005553 drilling Methods 0.000 description 1
- 238000001035 drying Methods 0.000 description 1
- 238000002474 experimental method Methods 0.000 description 1
- 229910052731 fluorine Inorganic materials 0.000 description 1
- 239000011737 fluorine Substances 0.000 description 1
- 238000004817 gas chromatography Methods 0.000 description 1
- 238000002309 gasification Methods 0.000 description 1
- 239000003502 gasoline Substances 0.000 description 1
- 229910052735 hafnium Inorganic materials 0.000 description 1
- 229910052736 halogen Inorganic materials 0.000 description 1
- 150000002367 halogens Chemical class 0.000 description 1
- 238000005470 impregnation Methods 0.000 description 1
- 230000006872 improvement Effects 0.000 description 1
- 239000003701 inert diluent Substances 0.000 description 1
- 230000002452 interceptive effect Effects 0.000 description 1
- 239000003350 kerosene Substances 0.000 description 1
- 239000012263 liquid product Substances 0.000 description 1
- 238000011068 loading method Methods 0.000 description 1
- 230000001050 lubricating effect Effects 0.000 description 1
- 229910052749 magnesium Inorganic materials 0.000 description 1
- 238000012423 maintenance Methods 0.000 description 1
- 230000014759 maintenance of location Effects 0.000 description 1
- 239000006262 metallic foam Substances 0.000 description 1
- 238000005555 metalworking Methods 0.000 description 1
- 238000012986 modification Methods 0.000 description 1
- 230000004048 modification Effects 0.000 description 1
- 239000002808 molecular sieve Substances 0.000 description 1
- 229910052757 nitrogen Inorganic materials 0.000 description 1
- 229910017464 nitrogen compound Inorganic materials 0.000 description 1
- 150000002830 nitrogen compounds Chemical class 0.000 description 1
- 239000001301 oxygen Substances 0.000 description 1
- 229910052760 oxygen Inorganic materials 0.000 description 1
- 229910052763 palladium Inorganic materials 0.000 description 1
- 230000036961 partial effect Effects 0.000 description 1
- 230000000737 periodic effect Effects 0.000 description 1
- 230000002093 peripheral effect Effects 0.000 description 1
- 239000002243 precursor Substances 0.000 description 1
- 239000000376 reactant Substances 0.000 description 1
- 239000003870 refractory metal Substances 0.000 description 1
- 230000003716 rejuvenation Effects 0.000 description 1
- 230000000630 rising effect Effects 0.000 description 1
- 238000009991 scouring Methods 0.000 description 1
- URGAHOPLAPQHLN-UHFFFAOYSA-N sodium aluminosilicate Chemical compound [Na+].[Al+3].[O-][Si]([O-])=O.[O-][Si]([O-])=O URGAHOPLAPQHLN-UHFFFAOYSA-N 0.000 description 1
- 239000002904 solvent Substances 0.000 description 1
- 238000004230 steam cracking Methods 0.000 description 1
- 239000011593 sulfur Substances 0.000 description 1
- 229910052717 sulfur Inorganic materials 0.000 description 1
- 229910052721 tungsten Inorganic materials 0.000 description 1
- 229910052726 zirconium Inorganic materials 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
- C10G2/00—Production of liquid hydrocarbon mixtures of undefined composition from oxides of carbon
- C10G2/30—Production of liquid hydrocarbon mixtures of undefined composition from oxides of carbon from carbon monoxide with hydrogen
- C10G2/32—Production of liquid hydrocarbon mixtures of undefined composition from oxides of carbon from carbon monoxide with hydrogen with the use of catalysts
- C10G2/34—Apparatus, reactors
- C10G2/342—Apparatus, reactors with moving solid catalysts
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J19/00—Chemical, physical or physico-chemical processes in general; Their relevant apparatus
- B01J19/24—Stationary reactors without moving elements inside
- B01J19/248—Reactors comprising multiple separated flow channels
- B01J19/2485—Monolithic reactors
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J8/00—Chemical or physical processes in general, conducted in the presence of fluids and solid particles; Apparatus for such processes
- B01J8/005—Separating solid material from the gas/liquid stream
- B01J8/006—Separating solid material from the gas/liquid stream by filtration
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J8/00—Chemical or physical processes in general, conducted in the presence of fluids and solid particles; Apparatus for such processes
- B01J8/02—Chemical or physical processes in general, conducted in the presence of fluids and solid particles; Apparatus for such processes with stationary particles, e.g. in fixed beds
- B01J8/06—Chemical or physical processes in general, conducted in the presence of fluids and solid particles; Apparatus for such processes with stationary particles, e.g. in fixed beds in tube reactors; the solid particles being arranged in tubes
- B01J8/065—Feeding reactive fluids
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J8/00—Chemical or physical processes in general, conducted in the presence of fluids and solid particles; Apparatus for such processes
- B01J8/18—Chemical or physical processes in general, conducted in the presence of fluids and solid particles; Apparatus for such processes with fluidised particles
- B01J8/20—Chemical or physical processes in general, conducted in the presence of fluids and solid particles; Apparatus for such processes with fluidised particles with liquid as a fluidising medium
- B01J8/22—Chemical or physical processes in general, conducted in the presence of fluids and solid particles; Apparatus for such processes with fluidised particles with liquid as a fluidising medium gas being introduced into the liquid
- B01J8/224—Chemical or physical processes in general, conducted in the presence of fluids and solid particles; Apparatus for such processes with fluidised particles with liquid as a fluidising medium gas being introduced into the liquid the particles being subject to a circulatory movement
- B01J8/226—Chemical or physical processes in general, conducted in the presence of fluids and solid particles; Apparatus for such processes with fluidised particles with liquid as a fluidising medium gas being introduced into the liquid the particles being subject to a circulatory movement internally, i.e. the particles rotate within the vessel
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
- C10G45/00—Refining of hydrocarbon oils using hydrogen or hydrogen-generating compounds
- C10G45/58—Refining of hydrocarbon oils using hydrogen or hydrogen-generating compounds to change the structural skeleton of some of the hydrocarbon content without cracking the other hydrocarbons present, e.g. lowering pour point; Selective hydrocracking of normal paraffins
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J2208/00—Processes carried out in the presence of solid particles; Reactors therefor
- B01J2208/00796—Details of the reactor or of the particulate material
- B01J2208/00823—Mixing elements
- B01J2208/00831—Stationary elements
- B01J2208/0084—Stationary elements inside the bed, e.g. baffles
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J2208/00—Processes carried out in the presence of solid particles; Reactors therefor
- B01J2208/00796—Details of the reactor or of the particulate material
- B01J2208/00823—Mixing elements
- B01J2208/00831—Stationary elements
- B01J2208/00849—Stationary elements outside the bed, e.g. baffles
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J2208/00—Processes carried out in the presence of solid particles; Reactors therefor
- B01J2208/00796—Details of the reactor or of the particulate material
- B01J2208/00884—Means for supporting the bed of particles, e.g. grids, bars, perforated plates
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Oil, Petroleum & Natural Gas (AREA)
- Engineering & Computer Science (AREA)
- General Chemical & Material Sciences (AREA)
- Combustion & Propulsion (AREA)
- Crystallography & Structural Chemistry (AREA)
- Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
- Devices And Processes Conducted In The Presence Of Fluids And Solid Particles (AREA)
- Production Of Liquid Hydrocarbon Mixture For Refining Petroleum (AREA)
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| US09/992,372 US6555725B1 (en) | 2001-11-06 | 2001-11-06 | In-situ hydroisomerization of synthesized hydrocarbon liquid in a slurry fischer-tropsch reactor |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| ZA200403378B true ZA200403378B (en) | 2006-02-22 |
Family
ID=25538260
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| ZA200403378A ZA200403378B (en) | 2001-11-06 | 2004-05-04 | In-situ hydroisomerization of a synthesized hydrocarbon liquid in a slurry fischer-tropsch reactor. |
Country Status (15)
| Country | Link |
|---|---|
| US (1) | US6555725B1 (es) |
| EP (1) | EP1444180B1 (es) |
| JP (1) | JP4423034B2 (es) |
| CN (1) | CN1304533C (es) |
| AR (1) | AR037029A1 (es) |
| AT (1) | ATE392400T1 (es) |
| AU (1) | AU2002327751B2 (es) |
| CA (1) | CA2465976C (es) |
| DE (1) | DE60226165T2 (es) |
| DK (1) | DK1444180T3 (es) |
| ES (1) | ES2304448T3 (es) |
| SA (1) | SA02230388B1 (es) |
| TW (1) | TW548266B (es) |
| WO (1) | WO2003040068A2 (es) |
| ZA (1) | ZA200403378B (es) |
Families Citing this family (15)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| EP1593121A4 (en) | 2003-01-20 | 2009-09-30 | Lg Electronics Inc | RECORDING MEDIUM WITH A DATA STRUCTURE FOR MANAGING THE REPRODUCTION OF STILL IMAGES RECORDED OF IT, AND METHOD AND APPARATUS AND RECORDING APPARATUS AND APPARATUS |
| US8223607B2 (en) | 2003-07-04 | 2012-07-17 | Lg Electronics Inc. | Method and apparatus for managing a overwrite recording on optical disc write once |
| JP4776287B2 (ja) * | 2005-07-06 | 2011-09-21 | Ｊｘ日鉱日石エネルギー株式会社 | クリーンガソリン組成物及びその製造方法 |
| BRPI0705939A2 (pt) * | 2007-10-29 | 2009-06-23 | Petroleo Brasileiro Sa | processo para a produção de catalisadores hìbridos para a sìntese de fischer-tropsch e catalisador hìbrido produzido de acordo com o processo |
| BRPI0704436A2 (pt) * | 2007-11-30 | 2009-07-28 | Petroleo Brasileiro Sa | processo de produção de hidrocarbonetos |
| US9908093B2 (en) * | 2008-04-09 | 2018-03-06 | Velocys, Inc. | Process for converting a carbonaceous material to methane, methanol and/or dimethyl ether using microchannel process technology |
| US8100996B2 (en) * | 2008-04-09 | 2012-01-24 | Velocys, Inc. | Process for upgrading a carbonaceous material using microchannel process technology |
| CA2739325C (en) | 2008-10-10 | 2018-11-27 | Velocys Inc. | Process and apparatus employing microchannel process technology |
| US20100312030A1 (en) * | 2009-06-04 | 2010-12-09 | Chevron U.S.A., Inc. | Process of synthesis gas conversion to liquid fuels using synthesis gas conversion catalyst and noble metal-promoted acidic zeolite hydrocracking-hydroisomerization catalyst |
| CA2777183A1 (en) * | 2009-10-09 | 2011-04-14 | Velocys Inc. | Process for treating heavy oil |
| US20110160315A1 (en) * | 2009-12-30 | 2011-06-30 | Chevron U.S.A. Inc. | Process of synthesis gas conversion to liquid hydrocarbon mixtures using synthesis gas conversion catalyst and hydroisomerization catalyst |
| US9676623B2 (en) | 2013-03-14 | 2017-06-13 | Velocys, Inc. | Process and apparatus for conducting simultaneous endothermic and exothermic reactions |
| US11873455B2 (en) * | 2020-12-30 | 2024-01-16 | Chevron U.S.A. Inc. | Process having improved base oil yield |
| CN113877488B (zh) * | 2021-11-16 | 2023-07-04 | 中国石油大学(华东) | 一种基于管式微孔介质发泡机理的上流式加氢反应装置 |
| GB202213993D0 (en) * | 2022-09-26 | 2022-11-09 | Johnson Matthey Davy Technologies Ltd | Methods and apparatus for controlled discharge of components from a tube |
Family Cites Families (9)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US4423265A (en) * | 1982-12-01 | 1983-12-27 | Mobil Oil Corporation | Process for snygas conversions to liquid hydrocarbon products |
| FR2676749B1 (fr) * | 1991-05-21 | 1993-08-20 | Inst Francais Du Petrole | Procede d'hydroisomerisation de paraffines issues du procede fischer-tropsch a l'aide de catalyseurs a base de zeolithe h-y. |
| US5382748A (en) * | 1992-12-18 | 1995-01-17 | Exxon Research & Engineering Co. | Hydrocarbon synthesis reactor employing vertical downcomer with gas disengaging means |
| US5659108A (en) * | 1995-07-07 | 1997-08-19 | The Dow Chemical Company | Process for the complete saturation of halogenated hydrocarbon streams containing unsaturated compounds |
| US5811468A (en) * | 1997-05-06 | 1998-09-22 | Exxon Research And Engineering Company | Combination gas disengaging downcomer-rejuvenation tube for in-situ slurry catalyst rejuvenation (LAW541) |
| US5962537A (en) * | 1997-05-06 | 1999-10-05 | Exxon Research And Engineering Co | Multizone downcomer for slurry hydrocarbon syntheses process |
| US5811469A (en) * | 1997-05-06 | 1998-09-22 | Exxon Research And Engineering Company | Slurry hydrocarbon synthesis with downcomer fed product filtration (LAW552) |
| IT1301801B1 (it) * | 1998-06-25 | 2000-07-07 | Agip Petroli | Procedimento per la preparazione di idrocarburi da gas di sintesi |
| JP3648430B2 (ja) * | 2000-04-04 | 2005-05-18 | トヨタ自動車株式会社 | 合成ガスからの低級イソパラフィンの合成方法 |
-
2001
- 2001-11-06 US US09/992,372 patent/US6555725B1/en not_active Expired - Fee Related
-
2002
- 2002-09-27 DE DE60226165T patent/DE60226165T2/de not_active Expired - Lifetime
- 2002-09-27 WO PCT/US2002/030739 patent/WO2003040068A2/en active IP Right Grant
- 2002-09-27 AU AU2002327751A patent/AU2002327751B2/en not_active Ceased
- 2002-09-27 CN CNB02821689XA patent/CN1304533C/zh not_active Expired - Fee Related
- 2002-09-27 CA CA2465976A patent/CA2465976C/en not_active Expired - Fee Related
- 2002-09-27 ES ES02763758T patent/ES2304448T3/es not_active Expired - Lifetime
- 2002-09-27 JP JP2003542117A patent/JP4423034B2/ja not_active Expired - Fee Related
- 2002-09-27 EP EP02763758A patent/EP1444180B1/en not_active Expired - Lifetime
- 2002-09-27 AT AT02763758T patent/ATE392400T1/de not_active IP Right Cessation
- 2002-09-27 DK DK02763758T patent/DK1444180T3/da active
- 2002-10-03 TW TW091122860A patent/TW548266B/zh not_active IP Right Cessation
- 2002-10-19 SA SA02230388A patent/SA02230388B1/ar unknown
- 2002-10-25 AR ARP020104058A patent/AR037029A1/es unknown
-
2004
- 2004-05-04 ZA ZA200403378A patent/ZA200403378B/en unknown
Also Published As
| Publication number | Publication date |
|---|---|
| DE60226165T2 (de) | 2009-05-28 |
| DK1444180T3 (da) | 2008-07-21 |
| EP1444180A2 (en) | 2004-08-11 |
| WO2003040068A2 (en) | 2003-05-15 |
| EP1444180B1 (en) | 2008-04-16 |
| ES2304448T3 (es) | 2008-10-16 |
| DE60226165D1 (de) | 2008-05-29 |
| AU2002327751B2 (en) | 2007-07-19 |
| SA02230388B1 (ar) | 2007-07-31 |
| JP4423034B2 (ja) | 2010-03-03 |
| AR037029A1 (es) | 2004-10-20 |
| CA2465976C (en) | 2011-01-25 |
| TW548266B (en) | 2003-08-21 |
| US6555725B1 (en) | 2003-04-29 |
| JP2005508407A (ja) | 2005-03-31 |
| CN1578823A (zh) | 2005-02-09 |
| CN1304533C (zh) | 2007-03-14 |
| ATE392400T1 (de) | 2008-05-15 |
| CA2465976A1 (en) | 2003-05-15 |
| WO2003040068A3 (en) | 2003-12-04 |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| AU2002341972B2 (en) | Slurry hydrocarbon synthesis with external hydroisomerization in downcomer reactor loop | |
| AU2002327751B2 (en) | In-situ hydroisomerization of a synthesized hydrocarbon liquid in a slurry fischertropsch reactor | |
| AU2002327751A1 (en) | In-situ hydroisomerization of a synthesized hydrocarbon liquid in a slurry fischertropsch reactor | |
| US6649803B2 (en) | Slurry hydrocarbon synthesis with isomerization zone in external lift reactor loop | |
| US6717024B2 (en) | Slurry hydrocarbon synthesis with liquid hydroisomerization in the synthesis reactor | |
| AU2002327073A1 (en) | Slurry hydrocarbon synthesis with isomerization zone in external lift reactor loop | |
| AU2002327750A1 (en) | Slurry hydrocarbon synthesis with liquid hydroisomerization in the synthesis reactor |